CN106732242B - The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol - Google Patents

The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol Download PDF

Info

Publication number
CN106732242B
CN106732242B CN201710029063.3A CN201710029063A CN106732242B CN 106732242 B CN106732242 B CN 106732242B CN 201710029063 A CN201710029063 A CN 201710029063A CN 106732242 B CN106732242 B CN 106732242B
Authority
CN
China
Prior art keywords
photo catalysis
catalysis reactor
valve
meter
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710029063.3A
Other languages
Chinese (zh)
Other versions
CN106732242A (en
Inventor
胡英
赵飞龙
郝梦樊
李俊鹏
刘春雨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xidian University
Original Assignee
Xidian University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xidian University filed Critical Xidian University
Priority to CN201710029063.3A priority Critical patent/CN106732242B/en
Publication of CN106732242A publication Critical patent/CN106732242A/en
Application granted granted Critical
Publication of CN106732242B publication Critical patent/CN106732242B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves
    • B01J19/127—Sunlight; Visible light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/159—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with reducing agents other than hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0884—Gas-liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0892—Materials to be treated involving catalytically active material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/12—Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)

Abstract

The present invention relates to the systems that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol, it includes photo catalysis reactor, photo catalysis reactor is set in water circulation constant temperature bath cabinet, photo catalysis reactor bottom is equipped with jet sand core, the first pH meter is additionally provided at the top of photo catalysis reactor, thermometer, barometer, second pH meter and charge pipe, air inlet pipe is equipped in the middle part of the bottom of photo catalysis reactor, the outer end of air inlet pipe is equipped with the first air valve, the top of photo catalysis reactor is connected with air inlet pipe, the top of photo catalysis reactor is connected with condenser, the side wall upper part of the side of water circulation constant temperature bath cabinet is equipped with water outlet, water circulation constant temperature bath cabinet is equipped with water inlet with respect to other side sidewall bottom, solar concentrator is set at photo catalysis reactor vertical direction, intelligent controller and solar concentrator, first pH meter, thermometer, barometer, the Two pH meters, the first air valve, the second air valve, charging valve, gas delivery valve, liquid delivery valve are connected.

Description

The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol
Technical field
The invention belongs to field of environment engineering, and in particular to the system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol.
Background technique
The energy, environment, weather are the three major issues that the mankind are faced.90% or more of the presently used energy all comes as stone Change class.The final product of the petrochemical industry class energy is mainly with CO2Based on, additionally containing a small amount of nitrogen oxides and oxysulfide etc..Greatly Measure CO2Discharge cause environmental pollution, containing the higher, climate warming of carbon emission etc.；Nitrogen oxides, oxysulfide, dust etc. are shapes At the major source of haze.
How the final product of the efficient and rational processing petrochemical industry class energy be solve environment in height containing carbon emission and haze It is crucial.
Petrochemical industry class energy final product is mainly derived from traditional coal industry, thermal power generation, fuel oil vehicles etc., stone Changing class energy final product is mainly to pass through in air that it is discharged using device end, controls the discharge gas of terminal and right It is where current petrochemical industry class energy system is faced and solved the problems, such as that it, which carries out efficient and rationalization processing,.
CO in air2Normal contents be 0.03%, traditional coal industry, thermal power generation, fuel-engined vehicle make carbon containing It discharges significantly exceeded.China's thermal power generation accounts for total power generation 83.2%, and the 49% of consumption of coal total amount is for generating electricity.Therefore firepower Almost occupy the coal consumption amount of half in power generation caused by coal burning containing carbon emission.It is reference with coal-fired thermal power generation, Calculate the emission factor of electric power.Use the emission factor (kg) of 1 degree (kWh) electric (converting standard coal 0.4kg) are as follows: carbon emission/ 0.272、CO2Discharge/0.997, SO2Discharge/0.03,0.015 discharge/NOX, wherein CO2Main body is accounted for, a small amount of SO is contained2And NOX。CO2 It is used primarily in food processing, fire extinguishing material and oilfield exploitation etc..Due to the CO of coal burning discharge2In contain SO2And NOX Equal ingredients are not easy to be directly used in food processing and fire extinguishing material, untreated discharge gas still cause the arch-criminal of haze.
The CO that coal burning is generated at present2And subsidiary gas mainly uses underground sequestration or injects gas as oilfield exploitation Body etc..CO2Gas is by underground sequestration not by CO2It consumes or changes, and seal CO up for safekeeping2It is more demanding to geological conditions, envelope The process of depositing needs to consume mass energy, is not the more excellent method for handling petrochemical industry class A fuel A final product.
Various countries gradually adopt the natural resources low cost of the other forms such as sunlight by CO in recent years2It captures and effectively restores At the ideal method of available hydrocarbon fuel, but such method Major Difficulties is (1) CO2Stabilization is not easy to capture；(2)CO2 Photocatalysis important active substances CO2 -Reduction potential CO2/·CO2 -Up to -1.9V (PH=7) is not easy to carry out；(3) it is existing compared at Ripe photochemical catalyst TiO2(forbidden bandwidth 3.2eV) is that too low to the utilization rate of sunlight (ultraviolet light accounts for too ultraviolet light catalyst Below sunlight 4%), catalytic effect is bad.
But at present on the not more mature system that hydrocarbon fuel methanol is prepared by photocatalysis carbon dioxide.
Summary of the invention
Goal of the invention: the present invention has made improvements in view of the above-mentioned problems of the prior art, i.e., the invention discloses light to urge Change the system that carbon dioxide prepares hydrocarbon fuel methanol.
Technical solution: the system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol, including photo catalysis reactor, water circulation Constant temperature bath cabinet, peristaltic pump, solar concentrator, condenser and intelligent controller,
The photo catalysis reactor wraps mode in the water circulation constant temperature bath cabinet by external sealed, the light The inner wall bottom of catalytic reactor is equipped with jet sand core, fills saturated solution in the photo catalysis reactor,
The first pH meter, thermometer, barometer, the second pH meter and charge pipe are additionally provided at the top of the photo catalysis reactor, The outer end of the charge pipe is equipped with charging valve, the bottom of first pH meter, the thermometer bottom and on saturated solution Liquid level is in contact, the bottom of second pH meter and the bottom connection of the saturated solution are touched,
The middle part of the bottom of the photo catalysis reactor is equipped with air inlet pipe, and air inlet pipe air pump, air inlet are equipped in air inlet pipe The outer end of pipe is equipped with the first air valve,
The top of the photo catalysis reactor is connected by pipeline with air inlet pipe, and the second air valve is equipped in the pipeline,
The top of the photo catalysis reactor is connected by condenser pipe with the condenser, and gas is equipped in the condenser pipe Delivery valve,
The condenser is equipped with outlet tube, which is equipped with liquid delivery valve,
The side wall upper part of the side of the water circulation constant temperature bath cabinet be equipped with water outlet, the water circulation constant temperature bath cabinet it is opposite The sidewall bottom of the other side is equipped with water inlet, and the water outlet is connected with the water inlet by pipeline, which is equipped with Peristaltic pump controls the constant temperature inside photo catalysis reactor the temperature of recirculated water in a manner of water-bath,
Solar concentrator is fixedly arranged at photo catalysis reactor vertical direction by outside support,
The intelligent controller respectively with solar concentrator, the first pH meter, thermometer, barometer, the second pH meter, first Air valve, the second air valve, charging valve, gas delivery valve, liquid delivery valve be connected, for control solar concentrator, the first air valve, The closure of second air valve, charging valve, gas delivery valve, liquid delivery valve.
Further, photo catalysis reactor is transparent glass photo catalysis reactor.
Further, saturated solution is containing SrTi1-xFexO3-δThe saturation sodium hydroxide of (0≤x≤1,0 < δ < 1) powder Aqueous solution.
The utility model has the advantages that photocatalysis carbon dioxide disclosed by the invention prepares the system of hydrocarbon fuel methanol with beneficial below Effect:
1, high pressure and high-temperature process that conventional carbon dioxide prepares hydrocarbon fuel are avoided using sun natural light, energy conservation, It is safe and environment-friendly；
2, photochemical catalyst and NaOH are not consumed theoretically, only need regular replenishment water and constantly import CO2It is converted into fuel first Alcohol realizes the zero-emission of petrochemical industry class A fuel A burning C；
3. the nature for realizing the carbon in addition to photosynthesis is recycled.
Detailed description of the invention
Fig. 1 is the system structure diagram that carbon dioxide disclosed by the invention prepares methanol；
Wherein:
1- photo catalysis reactor 2- water circulation constant temperature bath cabinet
3- peristaltic pump 4- air inlet pipe air pump
5- solar concentrator 6- condenser
7- intelligent controller 8- jet sand core
9- the first pH meter 10- thermometer
11- barometer the second pH meter of 12-
13- the first air valve the second air valve of 14-
15- charging valve 16- gas delivery valve
17- liquid delivery valve 18- saturated solution
Specific embodiment:
Detailed description of specific embodiments of the present invention below.
As shown in Figure 1, the system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol, including photo catalysis reactor 1, water follow Ring constant temperature bath cabinet 2, peristaltic pump 3, solar concentrator 5, condenser 6 and intelligent controller 7,
Photo catalysis reactor 1 wraps mode in water circulation constant temperature bath cabinet 2 by external sealed, photo catalysis reactor 1 inner wall bottom is equipped with jet sand core 8, fills saturated solution 18 in photo catalysis reactor 1,
The top of photo catalysis reactor 1 is additionally provided with the first pH meter 9, thermometer 10, barometer 11, the second pH meter 12 and charging Pipe, the outer end of charge pipe are equipped with charging valve 15, the bottom of the first pH meter 9, thermometer 10 bottom with 18 upper liquid of saturated solution Face is in contact, the bottom of the second pH meter 12 and the bottom connection of saturated solution 18 are touched,
The middle part of the bottom of photo catalysis reactor 1 is equipped with air inlet pipe, and air inlet pipe air pump 4, air inlet pipe are equipped in air inlet pipe Outer end be equipped with the first air valve 13,
The top of photo catalysis reactor 1 is connected by pipeline with air inlet pipe, and the second air valve 14 is equipped in the pipeline,
The top of photo catalysis reactor 1 is connected by condenser pipe with condenser 6, and gas delivery valve 16 is equipped in condenser pipe,
Condenser 6 is equipped with outlet tube, which is equipped with liquid delivery valve 17,
The side wall upper part of the side of water circulation constant temperature bath cabinet 2 is equipped with water outlet, the opposite other side of water circulation constant temperature bath cabinet 2 Sidewall bottom be equipped with water inlet, water outlet is connected with water inlet by pipeline, which is equipped with peristaltic pump 3, by following The temperature of ring water controls the constant temperature inside photo catalysis reactor 1 in a manner of water-bath,
Solar concentrator 5 is fixedly arranged at 1 vertical direction of photo catalysis reactor by outside support,
Intelligent controller 7 respectively with solar concentrator 5, the first pH meter 9, thermometer 10, barometer 11, the second pH meter 12, the first air valve 13, the second air valve 14, charging valve 15, gas delivery valve 16, liquid delivery valve 17 are connected, for controlling the sun The closure of energy condenser 5, the first air valve 13, the second air valve 14, charging valve 15, gas delivery valve 16, liquid delivery valve 17.
Further, photo catalysis reactor 1 is transparent glass photo catalysis reactor.
Further, saturated solution 18 is containing SrTi1-xFexO3-δThe saturation hydroxide of (0≤x≤1,0 < δ < 1) powder Sodium water solution.SrTi1-xFexO3-δConcentration be 0.5~2g/L (namely to saturation sodium hydrate aqueous solution in be added it is suitable SrTi1-xFexO3-δPowder, the 0.5~2g/L of concentration made).
In use, first passing through air inlet pipe air pump 4 and air inlet pipe, carbon dioxide is added into photo catalysis reactor 1, light is controlled Air pressure in catalytic reactor 1 when the solution ph in photo catalysis reactor 1 is 8.3~8.4, stops in scope of design CO is conveyed to photochemical catalyst reactor2Gas；
Then, solar concentrator 5 is opened by intelligent controller 7, carries out light-catalyzed reaction, control photo catalysis reactor Air pressure in 1 when the solution ph in photo catalysis reactor 1 is 11~14, closes solar concentrator in scope of design 5, the peristaltic pump 3 of water bath with thermostatic control is then opened, controlling temperature in photo catalysis reactor 1 is 65~70 DEG C；Open gas delivery valve 16, when the liquid in and condenser 6 invariable when the pressure in catalyst reactor 1 is constant, close the wriggling of water bath with thermostatic control Pump 3 stops reaction, then obtains Product liquid methanol in condenser 6.
Embodiments of the present invention are elaborated above.But present invention is not limited to the embodiments described above, Technical field those of ordinary skill within the scope of knowledge, can also do without departing from the purpose of the present invention Various change out.

Claims (2)

1. the system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol, which is characterized in that recycled including photo catalysis reactor, water Constant temperature bath cabinet, peristaltic pump, solar concentrator, condenser and intelligent controller；
The photo catalysis reactor wraps mode in the water circulation constant temperature bath cabinet by external sealed, the photocatalysis The inner wall bottom of reactor is equipped with jet sand core, fills saturated solution in the photo catalysis reactor, saturated solution be containing SrTi1-xFexO3-δThe saturation sodium hydrate aqueous solution of powder, in which: 0≤x≤1,0 < δ < 1；
The first pH meter, thermometer, barometer, the second pH meter and charge pipe are additionally provided at the top of the photo catalysis reactor, it is described The outer end of charge pipe is equipped with charging valve, the bottom of first pH meter, the thermometer bottom with liquid level on saturated solution It is in contact, the bottom connection touching of the bottom of second pH meter and the saturated solution；
The middle part of the bottom of the photo catalysis reactor is equipped with air inlet pipe, and air inlet pipe air pump is equipped in air inlet pipe, air inlet pipe Outer end is equipped with the first air valve；
The top of the photo catalysis reactor is connected by pipeline with air inlet pipe, and the second air valve is equipped in the pipeline；
The top of the photo catalysis reactor is connected by condenser pipe with the condenser, and gas is equipped in the condenser pipe and is exported Valve；
The condenser is equipped with outlet tube, which is equipped with liquid delivery valve；
The side wall upper part of the side of the water circulation constant temperature bath cabinet be equipped with water outlet, the water circulation constant temperature bath cabinet it is relatively another The sidewall bottom of side is equipped with water inlet, and the water outlet is connected with the water inlet by pipeline, which, which is equipped with, wriggles Pump, controls the constant temperature inside photo catalysis reactor the temperature of recirculated water in a manner of water-bath；
Solar concentrator is fixedly arranged at photo catalysis reactor vertical direction by outside support；
The intelligent controller respectively with solar concentrator, the first pH meter, thermometer, barometer, the second pH meter, the first gas Valve, the second air valve, charging valve, gas delivery valve, liquid delivery valve are connected, for controlling solar concentrator, the first air valve, the The closure of two air valves, charging valve, gas delivery valve, liquid delivery valve.
2. the system that photocatalysis carbon dioxide according to claim 1 prepares hydrocarbon fuel methanol, which is characterized in that light is urged Change reactor is transparent glass photo catalysis reactor.
CN201710029063.3A 2017-01-16 2017-01-16 The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol Active CN106732242B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710029063.3A CN106732242B (en) 2017-01-16 2017-01-16 The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710029063.3A CN106732242B (en) 2017-01-16 2017-01-16 The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol

Publications (2)

Publication Number Publication Date
CN106732242A CN106732242A (en) 2017-05-31
CN106732242B true CN106732242B (en) 2019-07-05

Family

ID=58946903

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710029063.3A Active CN106732242B (en) 2017-01-16 2017-01-16 The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol

Country Status (1)

Country Link
CN (1) CN106732242B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107837679B (en) * 2017-11-17 2023-03-28 华中科技大学 Method for cooperatively desulfurizing hydrocarbon fuel prepared from flue gas and photocatalytic device for realizing method
CN108212028A (en) * 2018-03-27 2018-06-29 安徽理工大学 A kind of novel photo catalytic reduction CO2Device
CN112337298B (en) * 2020-10-19 2021-08-03 华中科技大学 Photocatalytic reactor and method for preparing hydrocarbon fuel and desulfurizing under coordination by using oxygen-enriched flue gas
CN113603055A (en) * 2021-09-16 2021-11-05 宁夏大学 System and method for photocatalytic hydrogen production
CN113786702B (en) * 2021-09-23 2022-06-07 西安电子科技大学 Circulating reactor, system and method for flue gas desulfurization, denitrification and haze reduction

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102151534A (en) * 2011-01-30 2011-08-17 西北大学 Multifunctional photocatalytic reaction device
CN205833143U (en) * 2016-07-22 2016-12-28 中盈长江国际新能源投资有限公司 Photocatalytic reduction of carbon oxide prepares the device of methanol

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2898741C (en) * 2013-01-24 2020-03-31 Clean Wave Energy Corp Hydrogen production system and methods of using same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102151534A (en) * 2011-01-30 2011-08-17 西北大学 Multifunctional photocatalytic reaction device
CN205833143U (en) * 2016-07-22 2016-12-28 中盈长江国际新能源投资有限公司 Photocatalytic reduction of carbon oxide prepares the device of methanol

Also Published As

Publication number Publication date
CN106732242A (en) 2017-05-31

Similar Documents

Publication Publication Date Title
CN106732242B (en) The system that photocatalysis carbon dioxide prepares hydrocarbon fuel methanol
CN203683679U (en) Oxygen/hydrogen generator
CN105600747A (en) Chemical chain hydrogen production device and method based on metal oxygen carrier
CN101857204B (en) Process and device for purifying sulfuric acid phase in iodine and sulfur cycle under low pressure
CN100560476C (en) The light-catalysed device for producing hydrogen of a kind of employing
CN204494367U (en) A kind of boiler energy-saving water replanishing device
CN106833763B (en) Processing petrochemical industry class fire emission subtracts haze and the method for generating hydrocarbon fuel methanol
CN205398641U (en) Solar energy biomass energy chemical conversion fermenting installation
CN206408682U (en) A kind of frequency conversion water supply facility
CN110055118A (en) A kind of method and device of biogas desulfurization
CN206359947U (en) A kind of energy-conserving and environment-protective water guider
CN201568955U (en) Marsh gas recycling device
CN208457935U (en) A kind of high pressure steam boiler
CN204785528U (en) Novel gas storage tank device
CN203203013U (en) Biomass steam generator
CN205730828U (en) A kind of CFB boiler NOxthe denitrification apparatus of minimum discharge
CN206861578U (en) A kind of boiler oxygen-enriched combustion system
CN205420560U (en) Hydrogen device is produced to photoelectrocatalysis
CN204550047U (en) A kind of device for preparing hydrogen through hydrolysis
CN205241232U (en) Oxyhydrogen separation produces energy system
CN212651608U (en) System capable of quickly adjusting ammonia gas supply
CN205174801U (en) Tangential air inlet eddy -currents suspension firing biomass burning machine
CN219064225U (en) Boiler waste heat utilization water heater
CN204084908U (en) A kind of thermostatic type solar water container temperature regulating device
CN203035171U (en) Intelligent skid-mounted water injection station used for oilfield water injection

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant