CN106726716A - Shampoo and preparation method thereof - Google Patents

Shampoo and preparation method thereof Download PDF

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Publication number
CN106726716A
CN106726716A CN201610996175.1A CN201610996175A CN106726716A CN 106726716 A CN106726716 A CN 106726716A CN 201610996175 A CN201610996175 A CN 201610996175A CN 106726716 A CN106726716 A CN 106726716A
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CN
China
Prior art keywords
parts
shampoo
glycine betaine
acid
bacteriostatic agent
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Pending
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CN201610996175.1A
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Chinese (zh)
Inventor
魏雪
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Long Life Biotechnology (shanghai) Co Ltd
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Long Life Biotechnology (shanghai) Co Ltd
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Priority to CN201610996175.1A priority Critical patent/CN106726716A/en
Publication of CN106726716A publication Critical patent/CN106726716A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/604Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/66Enzymes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/736Chitin; Chitosan; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/006Antidandruff preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a kind of shampoo and preparation method thereof, the shampoo is prepared from by following raw materials:0.0.075 parts of carboxymethyl chitosan 0.015,0.004 0.14 parts of algal polysaccharides, 0.1 0.3 parts of cecropin, 0.03 0.09 parts of N acetylmuramide glycanohydrlas, 5 15 parts of Dodecyl Polyglucosides, 1 10 parts of laureth sodium sulfovinate, 0.1 1 parts of ammonia end dimethyl silicone polymer, 0.1 1 parts of tetra- sodium of EDTA, 0.01 0.1 parts of essence, 5 15 parts of betaines surfactant, 0.02 0.2 parts of bacteriostatic agent, 75 95 parts of water.Shampoo of the present invention, due to containing marine biological sterilization agent composition, therefore, after use, can be effectively degerming, and then with antipruritic and anti-dandruff effect, and because each component of the shampoo for containing marine organism degerming component is nontoxic to skin, non-stimulated, free from corrosion material, therefore the shampoo also has non-stimulated to hair and hair, free from corrosion advantage.

Description

Shampoo and preparation method thereof
Technical field
The present invention relates to daily-use chemical industry technical field, and in particular to a kind of shampoo and preparation method thereof.
Background technology
Shampoo be mainly compounded as main body with surfactant, scalp and hair with cleaning people, and protect The product of its beauty function is held, is the people in the very big daily chemical products of daily use amount.The component of shampoo includes Surfactant, stabilizer, functional additive, preservative and essence etc., suitable surfactant can reach foaming abundancy, Low stimulation, the effect that wash degree is high but degreasing power is weak, a kind of shampoo not still hair cleaning agent, but also with good Hair care and aesthetic effect, can make hair bright, attractive in appearance and obey after hair washing.
With scientific and technological progress and the improvement of people's living standards, the research and development of shampoo has new breakthrough and enters Exhibition, the feature and use feeling of consumer's also pay attention to day by day product.It is desirable to shampoo not only foaming abundancy, decontamination is excellent, And feel after having good use feeling and washing.The addition of good essence, can not only cover stock media bad breath and And it is intuitively vivid to assign shampoo product, play a part of that an apt word added to clinch the point.Consumer, can be with using during hair washing product The nasal receptor that quiet and tastefully laid out fragrance is brought is experienced, and the lasting and simple and elegant fragrance that product is stayed on hair can give Warm fine impression.The shampoo supply sold in the market is various in style, and quality discrepancy is also big.Generally only there is washing Effect, unitary function.Also, traditional shampoo adds the extremely strong tables of a large amount of alkalescence to improve cleaning force and ability of deoiling The compositions such as face activating agent, foaming agent, soap base, and the skin of human body is weakly acidic, use for a long time can stimulate skin.It is tighter Weight, the sebum film of skin can also be destroyed.Once losing sebum film, skin is highly susceptible to external injury.
The content of the invention
For above shortcomings in the prior art, one of technical problems to be solved by the invention are to provide one kind and wash Shampoo.
The two of the technical problem of solution of the invention are to provide a kind of preparation method of shampoo.
The present invention seeks to what is be achieved through the following technical solutions:
A kind of shampoo, is prepared from by following raw materials:Carboxymethyl chitosan 0.015-0.0.075 parts, algal polysaccharides 0.004-0.14 parts, cecropin 0.1-0.3 parts, N-acetylmuramide lycanohydrlase 0.03-0.09 parts, Dodecyl Polyglucosides 5-15 parts, it is 1-10 parts of laureth sodium sulfovinate, 0.1-1 parts of ammonia end dimethyl silicone polymer, sodium 0.1-1 parts of EDTA tetra-, fragrant It is smart 0.01-0.1 parts, betaines surfactant 5-15 parts, bacteriostatic agent 0.02-0.2 parts, water 75-95 parts.
Preferably, described essence is lemon extract, Mint Essence, lavender oil, flavoring rose essence etc..
Preferably, described betaines surfactant is Cocoamidopropyl betaine, 3- sulfopropyl cetyls One or more of mixture in diformazan glycine betaine, oleamide CAB.
It is highly preferred that described betaines surfactant is by Cocoamidopropyl betaine, 3- sulfopropyl hexadecanes Base diformazan glycine betaine, oleamide CAB are mixed, the Cocoamidopropyl betaine, 3- sulfopropyl cetyls Diformazan glycine betaine, the mass ratio of oleamide CAB are (1-3):(1-3):(1-3).
Preferably, described bacteriostatic agent is one or more in cinnamic acid, benzoic acid, caffeic acid of mixture.
It is highly preferred that described bacteriostatic agent is mixed by cinnamic acid, benzoic acid, caffeic acid, the cinnamic acid, rest in peace Fragrant sour, caffeinic mass ratio is (1-3):(1-3):(1-3).
Present invention also offers the preparation method of above-mentioned shampoo, comprise the following steps:
Heat water to and sequentially add laureth sodium sulfovinate, dodecyl glucose under 55-65 DEG C, stirring condition Glycosides, dimethyl silicone polymer, betaines surfactant are uniformly mixed, and are cooled to 25-35 DEG C, sequentially add carboxylic first Base enclosure glycan, algal polysaccharides, cecropin, N-acetylmuramide lycanohydrlase, the sodium of EDTA tetra-, essence, bacteriostatic agent stirring mixing Uniformly obtain final product.
Specifically, in the present invention:
Lemon extract, the lemon extract provided using Shanghai bright moon daily use chemicals Co., Ltd in the embodiment of the present invention.
Cocoamidopropyl betaine, No. CAS:86438-79-1.
3- sulfopropyl etradecyldimethylamine glycine betaines, No. CAS:2281-11-0.
Oleamide CAB, No. CAS:25054-76-6.
Carboxymethyl chitosan, No. CAS:83512-85-0, the medicine provided using the bright and clear bio tech ltd in Xi'an Level carboxymethyl chitosan.
Algal polysaccharides, the algal polysaccharides provided using the promise bio tech ltd of Shaanxi one, from Sargassaceae plant sea Wormwood artemisia (Classification system:Sargassum pallidum) middle extraction, withdrawal ratio 10:1.
Cecropin, using using number of patent application:Cecropin in 200710118975.4, its amino acid sequence is: LLLAQPTAAVRGRCQVQRYLLAA。
N-acetylmuramide lycanohydrlase, No. CAS:12650-88-3, using Anhui Lu Rong Bioisystech Co., Ltd The food-grade N-acetylmuramide lycanohydrlase of offer.
Dodecyl Polyglucosides, No. CAS:110615-47-9.
Cinnamic acid, No. CAS:621-82-9.
Benzoic acid, No. CAS:65-85-0.
Caffeic acid, No. CAS:331-39-5.
Ammonia end dimethyl silicone polymer, No. CAS:71750-80-6, uses the fragrant refined chemical industry in Guangzhou in the embodiment of the present invention The ammonia end dimethyl silicone polymer TCN-620 that Co., Ltd provides.
Laureth sodium sulfovinate, No. CAS:9004-82-4.There is provided using Japanese Kao company in the embodiment of the present invention Model EMAL 270S laureth sodium sulfovinate.
The sodium of EDTA tetra-, i.e. tetrasodium ethylenediamine tetraacetate, No. CAS:64-02-8.
Shampoo of the present invention, due to containing marine biological sterilization agent composition, therefore, after use, can be effectively degerming, and then With antipruritic and anti-dandruff effect, and because each component of the shampoo for containing marine organism degerming component is to skin Skin is nontoxic, non-stimulated, free from corrosion material, therefore the shampoo also has non-stimulated to hair and hair, free from corrosion advantage.
Specific embodiment
With reference to embodiment, the present invention is described further, as described below, is only to preferable implementation of the invention Example, not does the limitation of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above Technology contents be changed to the Equivalent embodiments of equal change.It is every without departing from the present invention program content, according to the present invention Technical spirit any simple modification that following examples are made or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Shampoo raw material (weight portion):0.045 part of carboxymethyl chitosan, 0.009 part of algal polysaccharides, 0.2 part of cecropin, N- 0.06 part of acetylmuramide glycanohydrla, 14 parts of Dodecyl Polyglucosides, 5 parts of laureth sodium sulfovinate, ammonia end poly- two 0.5 part of methylsiloxane, 0.2 part of tetra- sodium of EDTA, 0.03 part of lemon extract, 12 parts of betaines surfactant, bacteriostatic agent 0.03 part, 80 parts of water.
Described betaines surfactant is by Cocoamidopropyl betaine, 3- sulfopropyl etradecyldimethylamine beets Alkali, oleamide CAB are 1 in mass ratio:1:1 is uniformly mixed and obtains.
Described bacteriostatic agent is 1 by cinnamic acid, benzoic acid, caffeic acid in mass ratio:1:1 is uniformly mixed and obtains.
The preparation method of above-mentioned shampoo, comprises the following steps:
60 DEG C are heated water to, laureth sodium sulfovinate, dodecyl are sequentially added under 500 revs/min of stirring conditions Glucoside, dimethyl silicone polymer, betaines surfactant are stirred 15 minutes and are well mixed, and are cooled to 30 DEG C, then successively Add carboxymethyl chitosan, algal polysaccharides, cecropin, N-acetylmuramide lycanohydrlase, the sodium of EDTA tetra-, lemon extract, suppression Microbial inoculum continues 500 revs/min of stirrings and is well mixed for 30 minutes.Obtain the shampoo of embodiment 1.
Embodiment 2
It is substantially the same manner as Example 1, differ only in:Described bacteriostatic agent by benzoic acid, caffeic acid in mass ratio It is 1:1 is uniformly mixed and obtains.Obtain the shampoo of embodiment 2.
Embodiment 3
It is substantially the same manner as Example 1, differ only in:Described bacteriostatic agent is in mass ratio by cinnamic acid, caffeic acid 1:1 is uniformly mixed and obtains.Obtain the shampoo of embodiment 3.
Embodiment 4
It is substantially the same manner as Example 1, differ only in:Described bacteriostatic agent by cinnamic acid, benzoic acid in mass ratio It is 1:1 is uniformly mixed and obtains.Obtain the shampoo of embodiment 4.
Embodiment 5
It is substantially the same manner as Example 1, differ only in:Described betaines surfactant is by 3- sulfopropyls 16 Alkyl-dimethyl glycine betaine, oleamide CAB are 1 in mass ratio:1 is uniformly mixed and obtains.Obtain washing for embodiment 5 Shampoo.
Embodiment 6
It is substantially the same manner as Example 1, differ only in:Described betaines surfactant is by cocamidopropyl propyl amide Glycine betaine, oleamide CAB are 1 in mass ratio:1 is uniformly mixed and obtains.Obtain the shampoo of embodiment 6.
Embodiment 7
It is substantially the same manner as Example 1, differ only in:Described betaines surfactant is by cocamidopropyl propyl amide Glycine betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine are 1 in mass ratio:1 is uniformly mixed and obtains.Obtain embodiment 7 Shampoo.
Test case 1
According to《The foundation and application study of the anti-dandruff effect detection evaluation method of shampoo》Disclosed method is to embodiment Shampoo obtained in 1-7 carries out inhibition zone diameter test, and the anti-dandruff effect to shampoo product is evaluated.Inhibition zone diameter is got over Greatly, anti-dandruff effect is better.Test data is shown in Table 1.
Wherein, " foundation and application study of the anti-dandruff effect detection evaluation method of shampoo ", where, Wang Tan, Jia Zebao, flood Dawn roc, Peng Jin, research and development department of Si Bao daily use chemicals Co., Ltd, household chemicals science, o. 11th in 2009.
Table 1:Anti-dandruff efficacy test tables of data
Inhibition zone diameter, mm
Embodiment 1 26.1
Embodiment 2 20.4
Embodiment 3 22.3
Embodiment 4 18.9
Embodiment 5 21.6
Embodiment 6 19.8
Embodiment 7 23.2
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (cinnamic acid, benzoic acid, caffeic acid compounding) anti-dandruff effect are bright It is aobvious to be better than embodiment 2-4 (any the two compounding in cinnamic acid, benzoic acid, caffeic acid);Comparing embodiment 1 and embodiment 5-7, Embodiment 1 (Cocoamidopropyl betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine, oleamide CAB compounding) is gone Bits effect is substantially better than embodiment 5-7 (Cocoamidopropyl betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine, oleamide Any the two compounding in CAB).
Test case 2
Shampoo obtained in embodiment 1-7 is carried out into bacteriostasis property test, test strain:Escherichia coli ATYCC 25922, Staphylococcus aureus ATCC 6538.
Method:Each test strain is made bacteria suspension of physiological saline, and is diluted to the bacteria suspension that turbidity is 2.0McF, then With 100 times of normal saline dilution, 10 times then are diluted with RPMI-1640 culture mediums, finally washed with obtained in embodiment 1-7 respectively Shampoo doubling dilution, 96h is cultivated in 96 well culture plates, slight concussion, and photoelectric colorimetry is carried out at 490nm.Specific test result is shown in Table 2.
Table 2:Total plate count test list position:mg/mL
Staphylococcus aureus Escherichia coli
Embodiment 1 0.8 0.3
Embodiment 2 1.1 0.6
Embodiment 3 1.5 0.5
Embodiment 4 1.3 0.8
Embodiment 5 1.6 0.9
Embodiment 6 1.4 0.9
Embodiment 7 1.4 0.8
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (cinnamic acid, benzoic acid, caffeic acid compounding) bacteriostasis property are bright It is aobvious to be better than embodiment 2-4 (any the two compounding in cinnamic acid, benzoic acid, caffeic acid);Comparing embodiment 1 and embodiment 5-7, Embodiment 1 (Cocoamidopropyl betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine, oleamide CAB compounding) suppression Bacterium performance is substantially better than embodiment 5-7 (Cocoamidopropyl betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine, oleamide Any the two compounding in CAB).

Claims (6)

1. a kind of shampoo, it is characterised in that be prepared from by following raw materials:Carboxymethyl chitosan 0.015-0.0.075 parts, sea Polysaccharides 0.004-0.14 parts, cecropin 0.1-0.3 parts, N-acetylmuramide lycanohydrlase 0.03-0.09 parts, dodecyl Glucoside 5-15 parts, 1-10 parts of laureth sodium sulfovinate, 0.1-1 parts of ammonia end dimethyl silicone polymer, the sodium 0.1-1 of EDTA tetra- Part, essence 0.01-0.1 parts, betaines surfactant 5-15 parts, bacteriostatic agent 0.02-0.2 parts, water 75-95 parts.
2. shampoo as claimed in claim 1, it is characterised in that:Described betaines surfactant is coconut oleoyl amine third One or more of mixture in base glycine betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine, oleamide CAB.
3. shampoo as claimed in claim 2, it is characterised in that:Described betaines surfactant is by coconut oleoyl amine third Base glycine betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine, oleamide CAB are mixed, the cocamidopropyl propyl amide Glycine betaine, 3- sulfopropyl etradecyldimethylamines glycine betaine, the mass ratio of oleamide CAB are (1-3):(1-3):(1- 3)。
4. the shampoo as any one of claim 1-3, it is characterised in that:Described bacteriostatic agent is cinnamic acid, rests in peace One or more of mixture in fragrant acid, caffeic acid.
5. shampoo as claimed in claim 4, it is characterised in that:Described bacteriostatic agent is by cinnamic acid, benzoic acid, caffeic acid Mix, the cinnamic acid, benzoic acid, caffeinic mass ratio are (1-3):(1-3):(1-3).
6. the preparation method of the shampoo as any one of claim 1-5, it is characterised in that comprise the following steps:
Heat water to and sequentially add under 55-65 DEG C, stirring condition laureth sodium sulfovinate, Dodecyl Polyglucosides, poly- Dimethyl siloxane, betaines surfactant are uniformly mixed, and are cooled to 25-35 DEG C, sequentially add carboxymethyl shell Glycan, algal polysaccharides, cecropin, N-acetylmuramide lycanohydrlase, the sodium of EDTA tetra-, essence, bacteriostatic agent are uniformly mixed Obtain final product.
CN201610996175.1A 2016-11-12 2016-11-12 Shampoo and preparation method thereof Pending CN106726716A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108771636A (en) * 2018-08-13 2018-11-09 陈丽芬 A kind of lysozyme formulation

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103027857A (en) * 2012-12-25 2013-04-10 青岛海芬海洋生物科技有限公司 Shampoo containing marine biological degerming components and preparation method of shampoo

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN103027857A (en) * 2012-12-25 2013-04-10 青岛海芬海洋生物科技有限公司 Shampoo containing marine biological degerming components and preparation method of shampoo

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衷平海: "《生物化学品生产技术》", 31 May 2007, 江西科学技术出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108771636A (en) * 2018-08-13 2018-11-09 陈丽芬 A kind of lysozyme formulation
CN108771636B (en) * 2018-08-13 2021-03-26 陈丽芬 Lysozyme preparation

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Application publication date: 20170531