CN106701359A - Industrial heavy oil cleaning agent and preparation method thereof - Google Patents

Industrial heavy oil cleaning agent and preparation method thereof Download PDF

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Publication number
CN106701359A
CN106701359A CN201611011144.2A CN201611011144A CN106701359A CN 106701359 A CN106701359 A CN 106701359A CN 201611011144 A CN201611011144 A CN 201611011144A CN 106701359 A CN106701359 A CN 106701359A
Authority
CN
China
Prior art keywords
parts
greasy dirt
industrial heavy
cleaning agent
sulfonic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611011144.2A
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Chinese (zh)
Inventor
卢海凤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201611011144.2A priority Critical patent/CN106701359A/en
Publication of CN106701359A publication Critical patent/CN106701359A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/3418Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0094Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/32Amides; Substituted amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to the technical field of industrial cleaning, and particularly relates to an industrial heavy oil cleaning agent and a preparation method thereof. The cleaning agent is characterized by being prepared from, by weight, 50-80 parts of water, 40-60 parts of dimethyl-benzenesulfonic acid sodium, 9-20 parts of diethanol amine, 15-35 parts of poly benzene sulfonic acid, 18-52 parts of surface active agent, 6-20 parts of essence, 5-10 parts of caustic soda, 8-25 parts of fatty acid amide and 3-10 parts of potassium silicate. The materials used in the cleaning agent are widely sourced. The oil removal rate reaches 98%. The low cost and high efficiency are achieved. The promotion value is high. The cleaning agent contains no chlorofluorocarbons, causes no damage to the natural environment, and can greatly reduce harm to the human body.

Description

A kind of industrial heavy greasy dirt detergent and preparation method thereof
Technical field
Invention belongs to industry cleaning link technical field, and in particular to a kind of industrial heavy greasy dirt detergent and preparation method thereof.
Background technology
In actual life, in fields such as auto repair, product printing, mechanical executions, there is greasy dirt phenomenon in metal surface Very universal, not thoroughly, using gasoline as having is clear for the general simple still cleaning of existing metal surface greasy dirt cleaning method Raw material is washed, petroleum resources is so not only wasted, but also there is the drawbacks such as inflammable gasoline, high cost, pollution.To the clear of greasy dirt It is a pith in industry cleaning link to wash, and existing cleaning agent is more single to the cleansing power of greasy dirt and normal to part It is corrosive with cleaning materials.If using the organic solvent that some toxic and side effects are larger, although cleaning action preferably, but is cleaned Waste liquid afterwards causes greatly pollution to environment.Develop a kind of cleaning performance excellent and to human body and environment-friendly industrial heavy Greasy dirt detergent has turned into this area technical problem urgently to be resolved hurrily.
The content of the invention
For above-mentioned deficiency, the invention provides industrial heavy greasy dirt detergent of one kind and preparation method thereof, clearly The heavy oil for washing the various surfaces such as excellent effect, various processing equipments capable of washing, lathe, transformer, power distribution cabinet, terrazzo is dirty, uses Amount letter is saved, and preparation method is simple and easy to apply, easy to implement, stable in properties, can deposit for a long time, to the clearance rate of greasy dirt up to 98%.
To achieve these goals, the technical solution adopted by the present invention is as follows:
A kind of industrial heavy greasy dirt detergent, it is characterised in that be made up of the raw material of following weight portion:Water 50-80 parts, dimethyl Benzene sulfonic acid sodium salt 40-60 parts, diethanol amine 9-20 parts, 15-35 parts of polyoxyethylene alkylphenyl sulfonic acid, surfactant 18-52 parts, essence 6-20 Part, NaOH 5-10 parts, fatty acid amide 8-25 parts, potassium silicate 3-10 parts.
Further, the cleaning agent is made up of the raw material of following weight portion:60 parts of water, 50 parts of acid dimethyl sodium, 12 parts of diethanol amine, 25 parts of polyoxyethylene alkylphenyl sulfonic acid, 34 parts of surfactant, 15 parts of essence, 8 parts of NaOH, fatty acid amide 18 parts, 7 parts of potassium silicate.
Further, the essence is lemon flavouring.
Further, the surfactant is neopelex.
Further, the preparation method of the industrial heavy greasy dirt detergent is comprised the steps of:
The first step, dilutes during acid dimethyl sodium, diethanol amine are sequentially added into water, 10min is stirred, in whipping process Slowly add NaOH, after sequentially add polyoxyethylene alkylphenyl sulfonic acid, surfactant, essence, be warming up to 60-70 DEG C, continue to stir 30min is mixed, mixture is obtained;
Second step, by fatty acid amide, potassium silicate sequentially add step one gained mixture in, stir 30min, be cooled to 35-40 DEG C, constant temperature stirring 40min is made the cleaning agent.
Further, the mixing speed described in step one and step 2 is 150-200r/min.
In sum, as a result of such scheme, the present invention has advantages below to the present invention:
Each raw material sources used of the invention are cheap extensively, and oily waste degradation rate reaches 98%, realizes low-cost high-efficiency, With good promotional value;Cleaning agent of the invention is free of fluorochlorohydrocarbon, will not destroy natural environment, the harm produced to human body Substantially reduce.
Specific embodiment
With reference to embodiment to a kind of industrial heavy greasy dirt detergent of the invention and preparation method thereof, make furtherly It is bright.
Table 1:The raw-material weight part of cleaning agent in the embodiment of the present invention
Embodiment 1:
Selection chemical composition and raw-material weight part are the component of embodiment 1 in table 1.
Its preparation method specifically includes following steps:
The first step, dilutes during acid dimethyl sodium, diethanol amine are sequentially added into water, stirs 10min, and mixing speed is 150r/min, in whipping process slowly add NaOH, after sequentially add polyoxyethylene alkylphenyl sulfonic acid, DBSA Sodium, lemon flavouring, are warming up to 60 DEG C, continue to stir 30min, obtain mixture;
Second step, by fatty acid amide, potassium silicate sequentially add step one gained mixture in, stir 30min, mixing speed It is 150r/min, is cooled to 35 DEG C, constant temperature stirring 40min is made the cleaning agent.
Embodiment 2:
Selection chemical composition and raw-material weight part are the component of embodiment 2 in table 1.
Its preparation method specifically includes following steps:
The first step, dilutes during acid dimethyl sodium, diethanol amine are sequentially added into water, stirs 10min, and mixing speed is 180r/min, in whipping process slowly add NaOH, after sequentially add polyoxyethylene alkylphenyl sulfonic acid, DBSA Sodium, lemon flavouring, are warming up to 65 DEG C, continue to stir 30min, obtain mixture;
Second step, by fatty acid amide, potassium silicate sequentially add step one gained mixture in, stir 30min, mixing speed It is 180r/min, is cooled to 38 DEG C, constant temperature stirring 40min is made the cleaning agent.
Embodiment 3:
Selection chemical composition and raw-material weight part are the component of embodiment 3 in table 1.
Its preparation method specifically includes following steps:
The first step, dilutes during acid dimethyl sodium, diethanol amine are sequentially added into water, stirs 10min, and mixing speed is 200r/min, in whipping process slowly add NaOH, after sequentially add polyoxyethylene alkylphenyl sulfonic acid, DBSA Sodium, lemon flavouring, are warming up to 70 DEG C, continue to stir 30min, obtain mixture;
Second step, by fatty acid amide, potassium silicate sequentially add step one gained mixture in, stir 30min, mixing speed It is 200r/min, is cooled to 40 DEG C, constant temperature stirring 40min is made the cleaning agent.
The preferred embodiment of invention is the foregoing is only, is not intended to limit the invention, it is all in spirit of the invention Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.

Claims (6)

1. a kind of industrial heavy greasy dirt detergent, it is characterised in that be made up of the raw material of following weight portion:Water 50-80 parts, diformazan 40-60 parts of base benzene sulfonic acid sodium salt, diethanol amine 9-20 parts, 15-35 parts of polyoxyethylene alkylphenyl sulfonic acid, surfactant 18-52 parts, essence 6- 20 parts, NaOH 5-10 parts, fatty acid amide 8-25 parts, potassium silicate 3-10 parts.
2. industrial heavy greasy dirt detergent according to claim 1, it is characterised in that by the raw material system of following weight portion Into:60 parts of water, 50 parts of acid dimethyl sodium, 12 parts of diethanol amine, 25 parts of polyoxyethylene alkylphenyl sulfonic acid, 34 parts of surfactant, perfume 15 parts of essence, 8 parts of NaOH, 18 parts of fatty acid amide, 7 parts of potassium silicate.
3. industrial heavy greasy dirt detergent according to claim 1, it is characterised in that:The essence is lemon flavouring.
4. industrial heavy greasy dirt detergent according to claim 1, it is characterised in that:The surfactant is dodecane Base benzene sulfonic acid sodium salt.
5. the preparation method of industrial heavy greasy dirt detergent according to claim 1, it is characterised in that comprising following step Suddenly:
The first step, dilutes during acid dimethyl sodium, diethanol amine are sequentially added into water, 10min is stirred, in whipping process Slowly add NaOH, after sequentially add polyoxyethylene alkylphenyl sulfonic acid, surfactant, essence, be warming up to 60-70 DEG C, continue to stir 30min is mixed, mixture is obtained;
Second step, by fatty acid amide, potassium silicate sequentially add step one gained mixture in, stir 30min, be cooled to 35-40 DEG C, constant temperature stirring 40min is made the cleaning agent.
6. the preparation method of the industrial heavy greasy dirt detergent according to according to claim 5, it is characterised in that:Step one and step Mixing speed described in rapid two is 150-200r/min.
CN201611011144.2A 2016-11-17 2016-11-17 Industrial heavy oil cleaning agent and preparation method thereof Pending CN106701359A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611011144.2A CN106701359A (en) 2016-11-17 2016-11-17 Industrial heavy oil cleaning agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611011144.2A CN106701359A (en) 2016-11-17 2016-11-17 Industrial heavy oil cleaning agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106701359A true CN106701359A (en) 2017-05-24

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Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108102808A (en) * 2017-12-26 2018-06-01 徐州孝科编织有限公司 A kind of industrial cleaning agent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101368143A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Magnetic recording head detergent
CN102051272A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 Multifunctional environmental-protection cleaning agent
CN104893833A (en) * 2015-05-25 2015-09-09 时修官 Industrial heavy oil contamination cleaning agent
CN105199880A (en) * 2014-11-13 2015-12-30 深圳市合明科技有限公司 Cleaning agent, and preparation method and application thereof
CN105623890A (en) * 2014-11-04 2016-06-01 南京精锐化工科技有限公司 Efficient and environmentally friendly industrial heavy oil stain cleaning agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101368143A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Magnetic recording head detergent
CN102051272A (en) * 2011-01-24 2011-05-11 北京洛娃日化有限公司 Multifunctional environmental-protection cleaning agent
CN105623890A (en) * 2014-11-04 2016-06-01 南京精锐化工科技有限公司 Efficient and environmentally friendly industrial heavy oil stain cleaning agent
CN105199880A (en) * 2014-11-13 2015-12-30 深圳市合明科技有限公司 Cleaning agent, and preparation method and application thereof
CN104893833A (en) * 2015-05-25 2015-09-09 时修官 Industrial heavy oil contamination cleaning agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108102808A (en) * 2017-12-26 2018-06-01 徐州孝科编织有限公司 A kind of industrial cleaning agent

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Application publication date: 20170524