CN106701337A - Viscous nonionic system liquid detergent composition - Google Patents
Viscous nonionic system liquid detergent composition Download PDFInfo
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- CN106701337A CN106701337A CN201611249185.5A CN201611249185A CN106701337A CN 106701337 A CN106701337 A CN 106701337A CN 201611249185 A CN201611249185 A CN 201611249185A CN 106701337 A CN106701337 A CN 106701337A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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Abstract
The invention relates to the field of washing compositions by mainly taking surfactant compounds as base materials, and particularly relates to a viscous nonionic system liquid detergent composition. The composition is characterized by being prepared from the following components in percent concentration by mass: 10-30 percent of a nonionic surfactant, 0.5-5 percent of a thickening agent, 1-5 percent of a detergent auxiliary, 0-1 percent of a chelating agent, 0-1 percent of a preservative and the balance of water. The viscous nonionic system liquid detergent composition has a stable system and various functions.
Description
Technical field
The present invention relates to cleaning compositions field mainly with surface active cpd as base-material, specially a kind of accompanied with sticky
Nonionic system liquid detergent composition.
Background technology
Current laundry liquid formulation system is mostly anion and nonionic compounding structure, and due to nonionic surfactant
There is non-ionizing feature in water, thus it is more superior compared with ionic surfactant performance in some aspects, such as in water
And have preferable dissolubility in organic solvent, stability is high in the solution, be difficult by strong electrolyte inorganic salts and acid, the shadow of alkali
Ring, with surface-active very high, the surface tension of its aqueous solution is low, critical micelle concentration is less than ionic surfactant,
There is good resistance to hard water ability, with multiple performances such as dispersion, emulsification, low bubble, wetting, solubilisings.It is with other types table in addition
Face context of vaccine administration is good, so often can well mix compounding use, especially can be with the cation of some functional forms
Surfactant compound is used.When there is special formulation demand, such as：Use with soft cation raw material, with solid
When the use of the cation raw material of color color protection and cationic germicide raw material are used, require that formula system has nonionic
Feature, the thickening of such nonionic system formulation is just particularly important.
The content of the invention
In order to overcome the defect of prior art, there is provided a kind of stable system, articles for washing vdiverse in function, the present invention is disclosed
A kind of accompanied with sticky nonionic system liquid detergent composition.
The present invention reaches goal of the invention by following technical solution：
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, it is characterized in that：Also include
Thickener, washing assisant, chelating agent, preservative, essence and water, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 10~30
Thickener 0.5~5
Washing assisant 1~5
Chelating agent 0~1
Preservative 0~1
Water surplus
Wherein：Nonionic surfactant is gathered from AEO, collateralization AEO, fatty amine
At least one in oxygen vinethene, alkyl-glucoside and polyglyceryl fatty acid ester；
Thickener is from any one in following a~f：
A. AEO acrylic copolymer；
B. fatty acid alkanol amides；
C. ethoxylated fatty acid polyglycerol ester；
D. the swelling association thickener of hydrophobically-modified alkali；By acid/acrylic copolymer as skeleton, while also containing ethyoxyl
Lipophilic group, is obtained through emulsion polymerization；
E. N- dodecyls -2-Pyrrolidone；Structural formula is：；
F. polyethylene glycol stearate diester；
Washing assisant selects sodium carbonate, sodium metasilicate, sodium citrate, sodium carboxymethylcellulose, sodium tartrate, borax and triethanolamine
In at least one；
Chelating agent selects MDGA（That is MGDA）, glutamic acid-N, N, the sodium of-oxalic acid four（That is GLDA）, ethylenediamine
Tetraacethyl sodium（That is EDTA）, sodium nitrilo triacetate（That is NTA）, carboxymethyl hydroxymalonic acid sodium（That is SCMT）, oxydiethanoic acid sodium and
Diethyl pentetic acid（That is DTPA）In at least one, or select organic phospho acid, the organic phospho acid selects hydroxyl second
Fork di 2 ethylhexyl phosphonic acid（That is HEDP）, sodium ethylenediamine tetramethylenephosphonate（That is EDTMPS）And diethylenetriamine penta（I.e.
DTPMPA）In at least one；
Preservative selects Kathon CG, the bromo- 2- nitros -1,3- propane diols of 2-, p-hydroxybenzoate, 1,2- benzisothiazoles -3-
At least one in ketone, hydantoins, imidazolidinyl urea, sodium hydroxy methyl glycinate, alkyl quaternary ammonium salts and alkyl benzyl quaternary ammonium salt；
Above-mentioned " salt " refers to alkali metal salt, typically from sodium salt.
Described accompanied with sticky nonionic system liquid detergent composition, it is characterized in that：Also include essence, the quality of essence
Percent concentration is 0.1%~1%, and essence is from least one set in following a~c components：
A. bergamot, oranges and tangerines, blue or green perfume, Ye Qing, melon perfume, fruity, draft, Xin Xiang and aldehyde it is fragrant at least one；
B. in the fragrance of a flower, honey peach, lavender, lily, cyclamen, jasmine, the lily of the valley, rose, carnation, Yilan and cloves extremely
It is few three kinds；
C. in Moschus, santal, amber, ambergris, Pogostemon cablin, tongue perfume, butterfat perfume, fragrant powder, vanillic aldehyde and the natural banksia rose extremely
Few one kind.
Described accompanied with sticky nonionic system liquid detergent composition, it is characterized in that：Non-ionic surfactant selects fat
Fat alcohol polyethenoxy ether class or aliphatic amine polyoxyethylene ether class,
The formula of fatty alcohol polyethenoxy ether class is R (CH2CH2O)nOH, R is C in formula10~C15Alkylol, n takes [5,11] scope
Interior positive integer；
The formula of aliphatic amine polyoxyethylene ether class is R'N (CH2CH2O)rH, R' is C in formula10~C18Alkyl, r takes [5,20] scope
Interior positive integer.
During present invention configuration, for a~e thickeners, softened water is added in preparation tank first, after being heated to 40 DEG C or so
Non-ionic surfactant is added, thickener and washing assisant is stirring evenly and then adding into, less than 30 DEG C are cooled to, essence is added,
Preservative, and excess water is supplied, packed after stirring.
During present invention configuration, for f thickeners, softened water is added in preparation tank first, start stirring, be heated to 70 DEG C
Thickener is added behind left and right, nonionic surfactant is continuously added after dissolving, be stirring evenly and then adding into washing assisant, cooled down
To less than 30 DEG C, essence, preservative are added, and supply excess water, packed after stirring.
The present invention is a kind of nonionic system liquid detergent composition of accompanied with sticky, solves nonionic system liquid and washes
Wash agent tradition thickener such as inorganic salts, CMEA, APG, amine oxide, cellulose ethers etc. and be difficult to the problem for thickening.Present invention choosing
With one or more special thickeners, nonionic surfactant system fluid composition is thickened, outward appearance of the present invention is saturating
It is bright, sticky, and can add on this basis some cationic bactericide, color stabilizer, softening agents etc. assign detergent with it is sterilized,
The special function demand such as color protection, softness.
The beneficial effects of the invention are as follows：Stable system, it is vdiverse in function.
Brief description of the drawings
Nothing.
Specific embodiment
The present invention is further illustrated below by way of specific embodiment.
Embodiment 1
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing assisant
And water, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 10
Thickener 0.5
Washing assisant 1
Water surplus
Nonionic surfactant is gathered from AEO, collateralization AEO, fatty amine successively
One kind in oxygen vinethene, alkyl-glucoside and polyglyceryl fatty acid ester；
Thickener is successively from the one kind in following a~e：
A. AEO acrylic copolymer, is the Multifunction special surface activating agent of AMS-100 types, is
It is light yellow to clear yellow viscous body, active matter content >=93%, the pH value of 1% aqueous solution is 6 ± 1；
B. fatty acid alkanol amides, the carbon number of aliphatic acid is 6~24, and alkylol number is 0~2, and preferred fatty acid carbon number is 8
~18 glycollic amide, diglycollic amide and isopropanol amide, such as lauric acid amide of ethanol；
C. ethoxylated fatty acid polyglycerol ester, is Clariant（Clariant）The Hostagel LT that company produces, that is, be used for
Electrolyte cannot be fully under thickened systems extraordinary concentration components；
D. the swelling association thickener of hydrophobically-modified alkali, by acid/acrylic copolymer as skeleton, while also containing ethyoxyl
Lipophilic group, by emulsion polymerization be obtained, with alkali and play thickening power, be Lu Borun（Lubrizol）What company produced
HC200, is a kind of association type alkali swollen thickener of particular design（That is HASE）, it is the thickening of hydrophobically modified type acrylic emulsion
Agent；
E. N- dodecyls -2-Pyrrolidone；Structural formula is：,
It is Ya Shilan（Ashland）The Surfadone LP-300 that company produces；
Washing assisant selects sodium carbonate, sodium metasilicate, sodium citrate, sodium carboxymethylcellulose, sodium tartrate, borax and three second successively
One kind in hydramine；
When the present embodiment is configured, the softened water of total Water 1/3 is added first in preparation tank, the water surface was not had stirring rod bottom,
40 DEG C or so rear addition non-ionic surfactants are heated to, thickener and washing assisant is stirring evenly and then adding into, 30 DEG C are cooled to
Hereinafter, and excess water is supplied, is packed after stirring.
Embodiment 2
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing assisant
And water, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 15
Thickener 2
Washing assisant 2
Water surplus
Wherein：The selection material of non-ionic surfactant and washing assisant is with embodiment 1；Thickener is double stearic from polyethylene glycol
Acid esters.
When the present embodiment is configured, the softened water of total Water 1/3 is added first in preparation tank, the water surface was not had stirring rod bottom
Portion, starts stirring, is heated to 70 DEG C or so rear addition thickeners, and nonionic surfactant is continuously added after dissolving, and stirs
Washing assisant is added after uniform, less than 30 DEG C are cooled to, and supplies excess water, packed after stirring.
Embodiment 3
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing assisant
And water, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 20
Thickener 3
Washing assisant 3
Water surplus
Wherein：The selection material of non-ionic surfactant, thickener and washing assisant is all with embodiment 1.
The collocation method of the present embodiment is with embodiment 1.
Embodiment 4
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing assisant
And water, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 25
Thickener 4
Washing assisant 4
Water surplus
Wherein：The selection material of non-ionic surfactant, thickener and washing assisant is all with embodiment 2.
The collocation method of the present embodiment is with embodiment 2.
Embodiment 5
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing assisant
And water, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 30
Thickener 5
Washing assisant 5
Water surplus
Wherein：The selection material of non-ionic surfactant, thickener and washing assisant is all with embodiment 1.
The collocation method of the present embodiment is with embodiment 1.
Embodiment 6
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent and preservative, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 10
Thickener 0.5
Washing assisant 1
Chelating agent 0.2
Preservative 0.2
Water surplus
Wherein：The selection material of nonionic surfactant, thickener and washing assisant is all with embodiment 1；
Chelating agent selects MDGA successively（That is MGDA）, glutamic acid-N, N, the sodium of-oxalic acid four（That is GLDA）, second
Sodium ethylene diamine tetracetate（That is EDTA）, sodium nitrilo triacetate（That is NTA）, carboxymethyl hydroxymalonic acid sodium（That is SCMT）, oxydiethanoic acid
Sodium and diethyl pentetic acid（That is DTPA）In at least one, or select organic phospho acid, the organic phospho acid selects hydroxyl
Base ethylene-diphosphonic acid（That is HEDP）, sodium ethylenediamine tetramethylenephosphonate（That is EDTMPS）And diethylenetriamine penta
（That is DTPMPA）In one kind；
Preservative selects Kathon CG, the bromo- 2- nitros -1,3- propane diols of 2- successively（Chemical abbreviation Bronopol or Bronopol）, it is right
Hydroxybenzoate, 1,2- benzisothiazole-3-ketones（That is BIT）, hydantoins, imidazolidinyl urea, sodium hydroxy methyl glycinate,
One kind in alkyl quaternary ammonium salts and alkyl benzyl quaternary ammonium salt；Above-mentioned " salt " refers to alkali metal salt, and the present embodiment selects sodium salt.
When the present embodiment is configured, softened water is added in preparation tank first, be heated to 40 DEG C or so rear addition nonionic tables
Face work agent, is stirring evenly and then adding into thickener, washing assisant and chelating agent, is cooled to less than 30 DEG C, adds preservative, and supply
Excess water, packs after stirring.
Embodiment 7
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent and preservative, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 15
Thickener 2
Washing assisant 2
Chelating agent 0.4
Preservative 0.4
Water surplus
Wherein：The selection material of nonionic surfactant, thickener and washing assisant is all with embodiment 2；Chelating agent and anti-corrosion
The selection material of agent is with embodiment 6.
When the present embodiment is configured, softened water is added in preparation tank first, start stirring, be heated to 70 DEG C or so rear additions
Thickener, continuously adds nonionic surfactant after dissolving, and is stirring evenly and then adding into washing assisant and chelating agent, is cooled to
Less than 30 DEG C, preservative is added, and supply excess water, packed after stirring.
Embodiment 8
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent and preservative, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 20
Thickener 3
Washing assisant 3
Chelating agent 0.6
Preservative 0.6
Water surplus
Wherein：The selection material of nonionic surfactant, thickener, washing assisant, chelating agent and preservative is with embodiment 6.
The collocation method of the present embodiment is with embodiment 6.
Embodiment 9
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent and preservative, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 25
Thickener 4
Washing assisant 4
Chelating agent 0.8
Preservative 0.8
Water surplus
Wherein：The selection material of nonionic surfactant, thickener, washing assisant, chelating agent and preservative is with embodiment 7.
The collocation method of the present embodiment is with embodiment 7.
Embodiment 10
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent and preservative, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 30
Thickener 5
Washing assisant 5
Chelating agent 1
Preservative 1
Water surplus
Wherein：The selection material of nonionic surfactant, thickener, washing assisant, chelating agent and preservative is with embodiment 6.
The collocation method of the present embodiment is with embodiment 6.
Embodiment 11
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent, preservative and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 10
Thickener 0.5
Washing assisant 1
Chelating agent 0.2
Preservative 0.2
Essence 0.1
Water surplus
Wherein：Nonionic surfactant selects fatty alcohol polyethenoxy ether class and aliphatic amine polyoxyethylene ether class, fat successively
The formula of alcohol polyethenoxy ether class is R (CH2CH2O)nOH, R is C in formula10~C15Alkylol, n takes just whole in the range of [5,11]
Number, the formula of aliphatic amine polyoxyethylene ether class is R'N (CH2CH2O)rH, R' is C in formula10~C18Alkyl, r takes [5,20] scope
Interior positive integer；
Essence is successively from a group in following a~c components：
A. bergamot, oranges and tangerines, blue or green perfume, Ye Qing, melon perfume, fruity, draft, Xin Xiang and aldehyde it is fragrant at least one；
B. in the fragrance of a flower, honey peach, lavender, lily, cyclamen, jasmine, the lily of the valley, rose, carnation, Yilan and cloves extremely
It is few three kinds；
C. in Moschus, santal, amber, ambergris, Pogostemon cablin, tongue perfume, butterfat perfume, fragrant powder, vanillic aldehyde and the natural banksia rose extremely
Few one kind；
The selection material of thickener, washing assisant, chelating agent and preservative is with embodiment 6.
When the present embodiment is configured, softened water is added in preparation tank first, be heated to 40 DEG C or so rear addition nonionic tables
Face work agent, is stirring evenly and then adding into thickener, washing assisant and chelating agent, is cooled to less than 30 DEG C, adds preservative and essence,
And excess water is supplied, packed after stirring.
Embodiment 12
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent, preservative and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 15
Thickener 2
Washing assisant 2
Chelating agent 0.4
Preservative 0.4
Essence 0.4
Water surplus
Wherein：The selection material of nonionic surfactant and essence is with embodiment 11；Thickener, washing assisant, chelating agent and
The selection material of preservative is with embodiment 7.
When the present embodiment is configured, softened water is added in preparation tank first, start stirring, be heated to 70 DEG C or so rear additions
Thickener, continuously adds nonionic surfactant after dissolving, and is stirring evenly and then adding into washing assisant and chelating agent, is cooled to
Less than 30 DEG C, preservative and essence are added, and supply excess water, packed after stirring.
Embodiment 13
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent, preservative and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 20
Thickener 3
Washing assisant 3
Chelating agent 0.6
Preservative 0.6
Essence 0.6
Water surplus
Wherein：The selection material of nonionic surfactant and essence is with embodiment 11；Thickener, washing assisant, chelating agent and
The selection material of preservative is with embodiment 6.
The collocation method of the present embodiment is with embodiment 11.
Embodiment 14
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent, preservative and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 25
Thickener 4
Washing assisant 4
Chelating agent 0.8
Preservative 0.8
Essence 0.8
Water surplus
Wherein：The selection material of nonionic surfactant and essence is with embodiment 11；Thickener, washing assisant, chelating agent and
The selection material of preservative is with embodiment 7.
The collocation method of the present embodiment is with embodiment 12.
Embodiment 15
A kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, thickener, washing are helped
Agent, chelating agent, preservative and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 30
Thickener 5
Washing assisant 5
Chelating agent 1
Preservative 1
Essence 1
Water surplus
Wherein：The selection material of nonionic surfactant and essence is with embodiment 11；Thickener, washing assisant, chelating agent and
The selection material of preservative is with embodiment 6.
The collocation method of the present embodiment is with embodiment 11.
Embodiment 16
A kind of accompanied with sticky nonionic system liquid detergent composition, including non-ionic surfactant, thickener, washing assisant are anti-
Rotten agent and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Non-ionic surfactant 18
Thickener 4
Washing assisant 2
Preservative 2
Essence 0.3
Water surplus
Wherein：Non-ionic surfactant selects AEO-9, AEO-7 and coconut oil fat acyl diethanol amine (1:1) type（1:1 refers to cocounut oil fat
The mol ratio of fat acyl and diethanol amine is 1:1）It is 5 with mass ratio:4:2 compounding；
Thickener selects N- dodecyls -2-Pyrrolidone；Structural formula is：；It is Ya Shilan（Ashland）What company produced
Surfadone LP-300；
Washing assisant selects hexadecyltrimethylammonium chloride, is cationic softener, molecular formula C19H42ClN, molecular weight
319.5, also known as 1631；
Preservative selects dodecyl benzyl dimethyl ammonium chloride, is cationic bactericide, molecular formula C21H38NCl, molecular weight
339.5, also known as benzalkonium chloride, 1227, alkyldimethylbenzylammonium chloride, DDBAC；
The selection material of essence is all with embodiment 12.
The collocation method of the present embodiment is with embodiment 12.
Claims (3)
1. a kind of accompanied with sticky nonionic system liquid detergent composition, including nonionic surfactant, it is characterized in that：Also wrap
Thickener, washing assisant, chelating agent, preservative, essence and water are included, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Nonionic surfactant 10~30
Thickener 0.5~5
Washing assisant 1~5
Chelating agent 0~1
Preservative 0~1
Water surplus
Wherein：Nonionic surfactant is gathered from AEO, collateralization AEO, fatty amine
At least one in oxygen vinethene, alkyl-glucoside and polyglyceryl fatty acid ester；
Thickener is from any one in following a~f：
A. AEO acrylic copolymer；
B. fatty acid alkanol amides；
C. ethoxylated fatty acid polyglycerol ester；
D. the swelling association thickener of hydrophobically-modified alkali；By acid/acrylic copolymer as skeleton, while also containing ethyoxyl
Lipophilic group, is obtained through emulsion polymerization；
E. N- dodecyls -2-Pyrrolidone；Structural formula is：；
F. polyethylene glycol stearate diester；
Washing assisant selects sodium carbonate, sodium metasilicate, sodium citrate, sodium carboxymethylcellulose, sodium tartrate, borax and triethanolamine
In at least one；
Chelating agent selects MDGA, glutamic acid-N, N, the sodium of-oxalic acid four, sodium ethylene diamine tetracetate, the second of nitrilo three
At least one in sour sodium, carboxymethyl hydroxymalonic acid sodium, oxydiethanoic acid sodium and diethyl pentetic acid, or from organic
Phosphonic acids, the organic phospho acid selects 1-hydroxy ethylidene-1,1-diphosphonic acid, sodium ethylenediamine tetramethylenephosphonate and diethylenetriamine pentamethylene
At least one in phosphonic acids；
Preservative selects Kathon CG, the bromo- 2- nitros -1,3- propane diols of 2-, p-hydroxybenzoate, 1,2- benzisothiazoles -3-
At least one in ketone, hydantoins, imidazolidinyl urea, sodium hydroxy methyl glycinate, alkyl quaternary ammonium salts and alkyl benzyl quaternary ammonium salt.
2. accompanied with sticky nonionic system liquid detergent composition as claimed in claim 1, it is characterized in that：Also include essence,
The mass percent concentration of essence is 0.1%~1%, and essence is from least one set in following a~c components：
A. bergamot, oranges and tangerines, blue or green perfume, Ye Qing, melon perfume, fruity, draft, Xin Xiang and aldehyde it is fragrant at least one；
B. in the fragrance of a flower, honey peach, lavender, lily, cyclamen, jasmine, the lily of the valley, rose, carnation, Yilan and cloves extremely
It is few three kinds；
C. in Moschus, santal, amber, ambergris, Pogostemon cablin, tongue perfume, butterfat perfume, fragrant powder, vanillic aldehyde and the natural banksia rose extremely
Few one kind.
3. accompanied with sticky nonionic system liquid detergent composition as claimed in claim 1 or 2, it is characterized in that：Nonionic table
Agent is lived from fatty alcohol polyethenoxy ether class or aliphatic amine polyoxyethylene ether class in face,
The formula of fatty alcohol polyethenoxy ether class is R (CH2CH2O)nOH, R is C in formula10~C15Alkylol, n takes [5,11] scope
Interior positive integer；
The formula of aliphatic amine polyoxyethylene ether class is R'N (CH2CH2O)rH, R' is C in formula10~C18Alkyl, r takes [5,20] scope
Interior positive integer.
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| CN201611249185.5A CN106701337A (en) | 2016-12-29 | 2016-12-29 | Viscous nonionic system liquid detergent composition |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108251225A (en) * | 2017-12-01 | 2018-07-06 | 广州佰信生物科技有限公司 | A kind of neutrality environment-protecting clean stoste and preparation method thereof |
| CN108841459A (en) * | 2018-04-10 | 2018-11-20 | 湖北健客日化有限公司 | A kind of mandarin oil amino acid detergent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1130679A (en) * | 1995-03-03 | 1996-09-11 | 王麟 | Natural soft smooth shower lotion |
| CN101427990A (en) * | 2008-12-12 | 2009-05-13 | 上海蔻漫生物科技有限公司 | Skin cleaning article |
| CN103146506A (en) * | 2013-03-05 | 2013-06-12 | 广州立白企业集团有限公司 | Dish washing detergent composition with tea stain cleaning effect |
-
2016
- 2016-12-29 CN CN201611249185.5A patent/CN106701337A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1130679A (en) * | 1995-03-03 | 1996-09-11 | 王麟 | Natural soft smooth shower lotion |
| CN101427990A (en) * | 2008-12-12 | 2009-05-13 | 上海蔻漫生物科技有限公司 | Skin cleaning article |
| CN103146506A (en) * | 2013-03-05 | 2013-06-12 | 广州立白企业集团有限公司 | Dish washing detergent composition with tea stain cleaning effect |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108251225A (en) * | 2017-12-01 | 2018-07-06 | 广州佰信生物科技有限公司 | A kind of neutrality environment-protecting clean stoste and preparation method thereof |
| CN108841459A (en) * | 2018-04-10 | 2018-11-20 | 湖北健客日化有限公司 | A kind of mandarin oil amino acid detergent |
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