CN106699149A - 一种高性能建筑复合陶瓷材料及其制备方法 - Google Patents

一种高性能建筑复合陶瓷材料及其制备方法 Download PDF

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CN106699149A
CN106699149A CN201611156069.9A CN201611156069A CN106699149A CN 106699149 A CN106699149 A CN 106699149A CN 201611156069 A CN201611156069 A CN 201611156069A CN 106699149 A CN106699149 A CN 106699149A
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胡圣武
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Wuhu Hao Quan Construction Engineering Co Ltd
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Abstract

本发明公开了一种高性能建筑复合陶瓷材料及其制备方法，包括由以下重量份的原料制备而成：花岗岩粉料20‑35份、石英20‑30份、方解石15‑30份、氧化锌10‑20份、陶瓷粘土8‑15份、瓷砂20‑35份、碳酸钡10‑12份、腐植酸钠11‑22份、硝酸铝7‑15份、硝酸镍8‑18份、烧结助剂5‑10份、聚乙二醇5‑10份。本发明采用花岗岩粉料、石英、方解石、氧化锌、陶瓷粘土等有效配比，得到建筑陶瓷材料，使用温度高达 900℃，完全防火，且强度高使用寿命长，可替代现有墙体材料和易燃的保温材料，大大提高了房屋建筑的安全性增强陶瓷强度高、致密性好、韧性明显提高，且耐高温和耐磨优异，可广泛用于各种对材料强度要求高的领域采用矿物及化工原料。

Description

一种高性能建筑复合陶瓷材料及其制备方法
技术领域
本发明涉及陶瓷制作技术领域，具体涉及一种高性能建筑复合陶瓷材料及其制备方法。
背景技术
现有陶瓷主要由瓷土和粘土烧制而成。由于瓷土的地域性和大量开采，其资源越来越受限，因此如何解决瓷土资源匮乏的问题成了本行业的一个重要研究课题。
陶瓷是人类生产过程中发展的高级材料，其具有良好的化学稳定性和观赏性。现代工业在传统工艺的基础上对陶瓷制品已经进行了大量的研究和实验，其中以铝化合物和硅化合物为主要成份的陶瓷产品研究最为深入，并且使其研究的领域较多地集中于上述范围内，从而限制陶瓷产品的发展。
陶瓷材料具有诸多优点，如美观大方、耐酸碱、耐高温等，在日用品、建材、机械加工等众多领域具有广泛用途。氧化铝和氧化锆是陶瓷材料中常见的两种组份，氧化铝具有比重低、耐高温等优异性能，在陶瓷材料领域具有广泛应用，但其抗折强度和断裂韧性较低；氧化锆具有良好的抗折强度，被誉为“陶瓷钢”，但其比重较大，通常会增加成品的重量。氧化锆和氧化铝两者的有机结合，制备复合陶瓷材料技术受到了越来越多的重视。氧化镍通常用作陶瓷材料的颜料。
发明内容
为解决上述问题，本发明提供了一种化学制备技术，制备结构有序、性能优异高性能建筑复合陶瓷材料及其制备方法。
为实现上述目的，本发明采取的技术方案为：
一种高性能建筑复合陶瓷材料及其制备方法，包括由以下重量份的原料制备而成：花岗岩粉料20-35份、石英20-30份、方解石15-30份、氧化锌10-20份、陶瓷粘土8-15份、瓷砂20-35份、碳酸钡10-12份、腐植酸钠11-22份、硝酸铝7-15份、硝酸镍8-18份、烧结助剂5-10份、聚乙二醇5-10份、起泡剂4-8份、外加胶凝剂5-9份。
进一步地，一种高性能建筑复合陶瓷材料，包括由以下重量份的原料制备而成：花岗岩粉料21-34份、石英21-28份、方解石16-27份、氧化锌11-19份、陶瓷粘土9-14份、瓷砂22-33份、碳酸钡11-12份、腐植酸钠15-20份、硝酸铝8-14份、硝酸镍9-17份、烧结助剂6-8份、聚乙二醇6-9份、起泡剂5-7份、外加胶凝剂6-8份。
进一步地，所述烧结助剂为三氧化二铝和氧化镁中的一种或两种混合物。
进一步地，一种高性能建筑复合陶瓷材料的制备方法，包括如下步骤：
S1、将花岗岩粉料21-34份、石英21-28份、方解石16-27份、陶瓷粘土8-15份、瓷砂20-35份加入球磨机进行球磨后，过150-200目筛，得到粉料；
S2、将硝酸铝8-14份、硝酸镍9-17份混合之后加入高浓度硝酸，搅拌反应得到反应溶液；
S3、将碳酸钡11-12份、氧化锌11-19份、烧结助剂6-8份、起泡剂5-7份、外加胶凝剂6-8份加水搅拌，加温至30-40℃，搅拌均匀；得到改性溶液；
S4、将步骤S2所得的反应溶液和步骤S3得到改性溶液混合均匀，加入步骤S1的粉料，经搅拌、过滤、干燥、热处理之后得到建筑复合陶瓷材料。
进一步地，一种高性能建筑复合陶瓷材料，包括由以下重量份的原料制备而成：花岗岩粉料28份、石英25份、方解石19份、氧化锌17份、陶瓷粘土11份、瓷砂27份、碳酸钡11份、腐植酸钠18份、硝酸铝11份、硝酸镍15份、烧结助剂7份、聚乙二醇8份、起泡剂6份、外加胶凝剂7份。
本发明采用花岗岩粉料、石英、方解石、氧化锌、陶瓷粘土、瓷砂、碳酸钡、腐植酸钠、硝酸铝、硝酸镍、烧结助剂、聚乙二醇有效配比，得到建筑陶瓷材料，使用温度高达 900℃，完全防火，且强度高使用寿命长，可替代现有墙体材料和易燃的保温材料，大大提高了房屋建筑的安全性增强陶瓷强度高、致密性好、韧性明显提高，且耐高温和耐磨优异，可广泛用于各种对材料强度要求高的领域采用矿物及化工原料，生产成本较低、易于规模生产，可制作多种造型及纹理，节约矿产资源；价格低廉、生产工艺简单，适合规模化生产。
具体实施方式
为了使本发明的目的及优点更加清楚明白，以下结合实施例对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
本发明包括由以下重量份的原料制备而成：花岗岩粉料20-35份、石英20-30份、方解石15-30份、氧化锌10-20份、陶瓷粘土8-15份、瓷砂20-35份、碳酸钡10-12份、腐植酸钠11-22份、硝酸铝7-15份、硝酸镍8-18份、烧结助剂5-10份、聚乙二醇5-10份、起泡剂4-8份、外加胶凝剂5-9份。
一种高性能建筑复合陶瓷材料，包括由以下重量份的原料制备而成：花岗岩粉料21-34份、石英21-28份、方解石16-27份、氧化锌11-19份、陶瓷粘土9-14份、瓷砂22-33份、碳酸钡11-12份、腐植酸钠15-20份、硝酸铝8-14份、硝酸镍9-17份、烧结助剂6-8份、聚乙二醇6-9份、起泡剂5-7份、外加胶凝剂6-8份。
所述烧结助剂为三氧化二铝和氧化镁中的一种或两种混合物。
一种高性能建筑复合陶瓷材料的制备方法，包括如下步骤：
S1、将花岗岩粉料21-34份、石英21-28份、方解石16-27份、陶瓷粘土8-15份、瓷砂20-35份加入球磨机进行球磨后，过150-200目筛，得到粉料；
S2、将硝酸铝8-14份、硝酸镍9-17份混合之后加入高浓度硝酸，搅拌反应得到反应溶液；
S3、将碳酸钡11-12份、氧化锌11-19份、烧结助剂6-8份、起泡剂5-7份、外加胶凝剂6-8份加水搅拌，加温至30-40℃，搅拌均匀；得到改性溶液；
S4、将步骤S2所得的反应溶液和步骤S3得到改性溶液混合均匀，加入步骤S1的粉料，经搅拌、过滤、干燥、热处理之后得到建筑复合陶瓷材料。
实施例1：
一种高性能建筑复合陶瓷材料的制备方法，包括如下步骤：
S1、将花岗岩粉料34份、石英28份、方解石27份、陶瓷粘土15份、瓷砂35份加入球磨机进行球磨后，过200目筛，得到粉料；
S2、将硝酸铝14份、硝酸镍17份混合之后加入高浓度硝酸，搅拌反应得到反应溶液；
S3、将碳酸钡12份、氧化锌19份、烧结助剂8份、起泡剂7份、外加胶凝剂8份加水搅拌，加温至40℃，搅拌均匀；得到改性溶液；
S4、将步骤S2所得的反应溶液和步骤S3得到改性溶液混合均匀，加入步骤S1的粉料，经搅拌、过滤、干燥、热处理之后得到建筑复合陶瓷材料。
实施例2：
一种高性能建筑复合陶瓷材料的制备方法，包括如下步骤：
S1、将花岗岩粉料21份、石英21份、方解石16份、陶瓷粘土8份、瓷砂20份加入球磨机进行球磨后，过150目筛，得到粉料；
S2、将硝酸铝8份、硝酸镍9份混合之后加入高浓度硝酸，搅拌反应得到反应溶液；
S3、将碳酸钡12份、氧化锌11份、烧结助剂6份、起泡剂5份、外加胶凝剂6份加水搅拌，加温至30℃，搅拌均匀；得到改性溶液；
S4、将步骤S2所得的反应溶液和步骤S3得到改性溶液混合均匀，加入步骤S1的粉料，经搅拌、过滤、干燥、热处理之后得到建筑复合陶瓷材料。
实施例3：
一种高性能建筑复合陶瓷材料的制备方法，包括如下步骤：
S1、将花岗岩粉料26份、石英28份、方解石19份、陶瓷粘土14份、瓷砂24份加入球磨机进行球磨后，过170目筛，得到粉料；
S2、将硝酸铝11份、硝酸镍14份混合之后加入高浓度硝酸，搅拌反应得到反应溶液；
S3、将碳酸钡12份、氧化锌15份、烧结助剂7份、起泡剂6份、外加胶凝剂7份加水搅拌，加温至35℃，搅拌均匀；得到改性溶液；
S4、将步骤S2所得的反应溶液和步骤S3得到改性溶液混合均匀，加入步骤S1的粉料，经搅拌、过滤、干燥、热处理之后得到建筑复合陶瓷材料。
本发明采用花岗岩粉料、石英、方解石、氧化锌、陶瓷粘土、瓷砂、碳酸钡、腐植酸钠、硝酸铝、硝酸镍、烧结助剂、聚乙二醇有效配比，得到建筑陶瓷材料，使用温度高达 900℃，完全防火，且强度高使用寿命长，可替代现有墙体材料和易燃的保温材料，大大提高了房屋建筑的安全性增强陶瓷强度高、致密性好、韧性明显提高，且耐高温和耐磨优异，可广泛用于各种对材料强度要求高的领域采用矿物及化工原料，生产成本较低、易于规模生产，可制作多种造型及纹理，节约矿产资源；价格低廉、生产工艺简单，适合规模化生产。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以作出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (5)

1.一种高性能建筑复合陶瓷材料，其特征在于，包括由以下重量份的原料制备而成：花岗岩粉料20-35份、石英20-30份、方解石15-30份、氧化锌10-20份、陶瓷粘土8-15份、瓷砂20-35份、碳酸钡10-12份、腐植酸钠11-22份、硝酸铝7-15份、硝酸镍8-18份、烧结助剂5-10份、聚乙二醇5-10份、起泡剂4-8份、外加胶凝剂5-9份。
2.根据权利要求1所述的一种高性能建筑复合陶瓷材料，其特征在于，包括由以下重量份的原料制备而成：花岗岩粉料21-34份、石英21-28份、方解石16-27份、氧化锌11-19份、陶瓷粘土9-14份、瓷砂22-33份、碳酸钡11-12份、腐植酸钠15-20份、硝酸铝8-14份、硝酸镍9-17份、烧结助剂6-8份、聚乙二醇6-9份、起泡剂5-7份、外加胶凝剂6-8份。
3.根据权利要求1所述的一种高性能建筑复合陶瓷材料，其特征在于，所述烧结助剂为三氧化二铝和氧化镁中的一种或两种混合物。
4.根据权利要求1所述的一种高性能建筑复合陶瓷材料的制备方法，其特征在于，包括如下步骤：
S1、将花岗岩粉料21-34份、石英21-28份、方解石16-27份、陶瓷粘土8-15份、瓷砂20-35份加入球磨机进行球磨后，过150-200目筛，得到粉料；
S2、将硝酸铝8-14份、硝酸镍9-17份混合之后加入高浓度硝酸，搅拌反应得到反应溶液；
S3、将碳酸钡11-12份、氧化锌11-19份、烧结助剂6-8份、起泡剂5-7份、外加胶凝剂6-8份加水搅拌，加温至30-40℃，搅拌均匀；得到改性溶液；
S4、将步骤S2所得的反应溶液和步骤S3得到改性溶液混合均匀，加入步骤S1的粉料，经搅拌、过滤、干燥、热处理之后得到建筑复合陶瓷材料。
5.根据权利要求1所述的一种高性能建筑复合陶瓷材料，其特征在于，包括由以下重量份的原料制备而成：花岗岩粉料28份、石英25份、方解石19份、氧化锌17份、陶瓷粘土11份、瓷砂27份、碳酸钡11份、腐植酸钠18份、硝酸铝11份、硝酸镍15份、烧结助剂7份、聚乙二醇8份、起泡剂6份、外加胶凝剂7份。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046746A (zh) * 2017-11-02 2018-05-18 安徽嘉中金属材料有限公司 一种建筑用改性复合环保的陶瓷材料及其制备方法
CN108298948A (zh) * 2017-12-15 2018-07-20 安徽嘉中金属材料有限公司 一种高强度复合建筑陶瓷材料及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104045319A (zh) * 2014-06-24 2014-09-17 金博(上海)建工集团有限公司 一种废石粉陶瓷及其制备方法
CN104829263A (zh) * 2015-05-25 2015-08-12 吴江华诚复合材料科技有限公司 一种新型轻质陶瓷复合保温建筑材料及制备方法
CN105174912A (zh) * 2015-09-16 2015-12-23 季红军 一种建筑复合陶瓷材料及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104045319A (zh) * 2014-06-24 2014-09-17 金博(上海)建工集团有限公司 一种废石粉陶瓷及其制备方法
CN104829263A (zh) * 2015-05-25 2015-08-12 吴江华诚复合材料科技有限公司 一种新型轻质陶瓷复合保温建筑材料及制备方法
CN105174912A (zh) * 2015-09-16 2015-12-23 季红军 一种建筑复合陶瓷材料及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046746A (zh) * 2017-11-02 2018-05-18 安徽嘉中金属材料有限公司 一种建筑用改性复合环保的陶瓷材料及其制备方法
CN108298948A (zh) * 2017-12-15 2018-07-20 安徽嘉中金属材料有限公司 一种高强度复合建筑陶瓷材料及其制备方法

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