CN106684182B - Solar energy and lithium ion battery integration device - Google Patents
Solar energy and lithium ion battery integration device Download PDFInfo
- Publication number
- CN106684182B CN106684182B CN201510751773.8A CN201510751773A CN106684182B CN 106684182 B CN106684182 B CN 106684182B CN 201510751773 A CN201510751773 A CN 201510751773A CN 106684182 B CN106684182 B CN 106684182B
- Authority
- CN
- China
- Prior art keywords
- lithium ion
- ion battery
- layer
- solar energy
- integration device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 30
- 230000010354 integration Effects 0.000 title claims abstract description 20
- 239000004065 semiconductor Substances 0.000 claims abstract description 34
- 239000003792 electrolyte Substances 0.000 claims abstract description 8
- 239000010410 layer Substances 0.000 claims description 82
- 229910007541 Zn O Inorganic materials 0.000 claims description 13
- 239000010406 cathode material Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 239000010405 anode material Substances 0.000 claims description 3
- 239000007773 negative electrode material Substances 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims description 3
- 239000007784 solid electrolyte Substances 0.000 claims description 3
- 239000004020 conductor Substances 0.000 claims 2
- 239000000463 material Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 3
- 108091006146 Channels Proteins 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 108090000699 N-Type Calcium Channels Proteins 0.000 description 2
- 102000004129 N-Type Calcium Channels Human genes 0.000 description 2
- 108010075750 P-Type Calcium Channels Proteins 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 description 1
- -1 Shi Mo Chemical compound 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
- H01L31/0264—Inorganic materials
- H01L31/0296—Inorganic materials including, apart from doping material or other impurities, only AIIBVI compounds, e.g. CdS, ZnS, HgCdTe
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The present invention discloses a kind of solar energy and lithium ion battery integration device, comprising: semiconductor layer includes first surface and second surface；Anode and cathode, are arranged at intervals at the first surface；External circuits, external circuits and the cathode described in Zheng Ji ﹑ described in the Ban Dao Ti Ceng ﹑ are sequentially connected electrically to collectively form primary Ioops；Insulating layer is set to the second surface；Grid, is set to surface of the insulating layer far from the semiconductor layer, and the grid connects a first voltage；Wherein, the semiconductor layer is oxide semiconductor layer, and the oxide semiconductor layer is used as the active layer of solar battery and the electrolyte layer of lithium ion battery simultaneously.
Description
Technical field
The present invention relates to a kind of solar energy and lithium ion battery integration device.
Background technique
The storage and conversion of the energy are the important research directions in current energy conservation and environmental protection epoch.Conventional solar cell and lithium from
Sub- battery is mutually indepedent and separation two devices, therefore the storage and conversion of the energy are separation, need more materials,
And there is biggish volume.Currently, not yet finding grinding for the integrated device of integrated solar and lithium ion battery both at home and abroad
Study carefully.
Summary of the invention
The present invention provides a kind of solar energy and lithium ion battery integration device, can make solar energy and lithium ion both
It is separated from each other and mutually independent device integrates, so as to reduce materials'use and reduce volume, to be collected
At the integrated device of solar energy and lithium ion battery.
A kind of solar energy and lithium ion battery integration device, comprising: semiconductor layer includes first surface and the second table
Face；Anode and cathode, are arranged at intervals at the first surface；External circuits, it is outer described in Zheng Ji ﹑ described in the Ban Dao Ti Ceng ﹑
It connects circuit and the cathode is sequentially connected electrically to collectively form primary Ioops；Insulating layer is set to the second surface；Grid,
It is set to surface of the insulating layer far from the semiconductor layer, the grid connects a first voltage；Wherein, the semiconductor layer
For oxide semiconductor layer, the oxide semiconductor layer is simultaneously used as the active layer and lithium ion battery of solar battery
Electrolyte layer.
Further, the oxide semiconductor layer is single layer structure or multilayered structure.
Further, the oxide semiconductor layer includes two layers In-Ga-Zn-O layers (IGZO) and is held on described
In-Zn-O layer (IZO) between IGZO layers.
Further, described IGZO layers with a thickness of 10 nanometers to 50 nanometers.
Further, described IGZO layers with a thickness of 15 nanometers to 30 nanometers.
Further, described IZO layers with a thickness of 30 nanometers to 100 nanometers.
Further, described IZO layers with a thickness of 40 nanometers to 60 nanometers.
Further, it is further formed p-n junction between the anode and the semiconductor layer, when sunlight irradiates the p-
When n is tied, photogenerated current will form.
Further, the negative electrode material is selected from Shi Mo ﹑ tin base cathode material and silicon based anode material.
Further, the electrolyte layer is solid electrolyte layer.
Solar energy and lithium ion battery integration device provided by the invention, is used simultaneously by the oxide semiconductor layer
Make the active layer of solar battery and the electrolyte layer of lithium ion battery, so as to by solar battery and lithium ion battery
Effective integration together, so that reduce material uses and reduce volume, reduces cost.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of solar energy provided in an embodiment of the present invention and lithium ion battery integration device.
Specific embodiment
The present invention is described in further detail with reference to the accompanying drawings and examples.It is understood that this place is retouched
The specific embodiment stated is used only for explaining the present invention rather than limiting the invention.It also should be noted that in order to just
Only the parts related to the present invention are shown in description, attached drawing rather than entire infrastructure.
Please refer to Fig. 1, a kind of solar energy and lithium ion battery integration device 100, comprising:
Semiconductor layer 14, including first surface and second surface；
Anode 12 and cathode 11, are arranged at intervals at the first surface；
External circuits 10, external circuits 10 and the cathode 11 described in 12 ﹑ of anode described in 14 ﹑ of semiconductor layer are successively
Electrical connection is to collectively form primary Ioops；
Insulating layer 15 is set to the second surface；
Grid 13, is set to surface of the insulating layer 15 far from the semiconductor layer 14, and the grid 13 connects one first
Voltage VG。
The semiconductor layer 14 is oxide semiconductor layer, and the oxide semiconductor layer is used as solar battery simultaneously
The electrolyte layer of active layer and lithium ion battery.Preferably, the electrolyte layer is solid electrolyte layer.
The oxide semiconductor layer can be single layer structure or multilayered structure.In the present embodiment, the oxide is partly led
Body layer includes two layers of In-Ga-Zn-O layer 141/143 (IGZO) and is held between the In-Ga-Zn-O layer 141/143
In-Zn-O layer 142 (IZO).The IGZO layer 141/143 with a thickness of nanoscale, it is preferred that be 10 nanometers to 50 nanometers.More
Preferably, described IGZO layers with a thickness of 15 nanometers to 30 nanometers.In the present embodiment, the thickness of IGZO layer 141 is about 25 nanometers,
And the thickness of IGZO layer 143 is about 17 nanometers.The thickness of the IZO layer 142 is also nanoscale, it is preferred that is 30 nanometers to 100
Nanometer；It is furthermore preferred that described IZO layers with a thickness of 40 nanometers to 60 nanometers.In the present embodiment, the thickness of the IZO layer 142 is about
It is 50 nanometers.In use, N-type channel and P-type channel be will form in the oxide semiconductor layer, it further, can
To form p-type thin layer and/or the N-type thin layer on P-type channel on the N-type channel, the p-type thin layer and N-type thin layer
Thickness can control in the range of not hindering electric current to be sent to electrode from channel, it is preferable that be nanoscale.
Positive 12 material is selected from common lithium ion anode material, such as cobalt Suan Li ﹑ LiMn2O4 and iron lithium phosphate
Deng.Further, it is further formed p-n junction between described positive 12 and the semiconductor layer 14, when sunlight irradiates the p-n
When knot, photogenerated current will form.Specifically, being further formed between described positive 12 and In-Ga-Zn-O layer 141
P-n junction will form photogenerated current when sunlight irradiates the p-n junction.
The material of the cathode 11 is also selected from common ion cathode material lithium, such as Shi Mo ﹑ tin base cathode material and silicon
Base negative electrode material etc..
It is appreciated that when the grid 13 accesses the first voltage VGWhen, the semiconductor layer 14, which will form, leads hole
With the channel of electronics, further, when light is incident in the semiconductor layer 14, the hole and electricity in the semiconductor layer 14
Son can generate separation, and pass through 11 shapes of external circuits 10 described in 12 ﹑ of anode described in 14 ﹑ of semiconductor layer and the cathode
Anode 12 described in 14 ﹑ of semiconductor layer is stored respectively at circuit and the cathode 11 is formed by lithium ion battery.
Note that the above is only a better embodiment of the present invention and the applied technical principle.It will be appreciated by those skilled in the art that
The invention is not limited to the specific embodiments described herein, be able to carry out for a person skilled in the art it is various it is apparent variation,
It readjusts and substitutes without departing from protection scope of the present invention.Therefore, although being carried out by above embodiments to the present invention
It is described in further detail, but the present invention is not limited to the above embodiments only, without departing from the inventive concept, also
It may include more other equivalent embodiments, and the scope of the invention is determined by the scope of the appended claims.
Claims (10)
1. a kind of solar energy and lithium ion battery integration device characterized by comprising
Semiconductor layer includes first surface and second surface；
Anode and cathode, are arranged at intervals at the first surface；
External circuits, external circuits and the cathode described in Zheng Ji ﹑ described in the Ban Dao Ti Ceng ﹑ are sequentially connected electrically with common structure
At primary Ioops；
Insulating layer is set to the second surface；
Grid, is set to surface of the insulating layer far from the semiconductor layer, and the grid connects a first voltage；
Wherein, the semiconductor layer is oxide semiconductor layer, and the oxide semiconductor layer is used as solar battery simultaneously
The electrolyte layer of active layer and lithium ion battery.
2. solar energy according to claim 1 and lithium ion battery integration device, which is characterized in that the oxide half
Conductor layer is single layer structure or multilayered structure.
3. solar energy according to claim 1 and lithium ion battery integration device, which is characterized in that the oxide half
Conductor layer includes two layers In-Ga-Zn-O layers (IGZO) and the In-Zn-O layer being held between In-Ga-Zn-O layers described
(IZO)。
4. solar energy according to claim 3 and lithium ion battery integration device, which is characterized in that the In-Ga-
Zn-O layers with a thickness of 10 nanometers to 50 nanometers.
5. solar energy according to claim 4 and lithium ion battery integration device, which is characterized in that the In-Ga-
Zn-O layers with a thickness of 15 nanometers to 30 nanometers.
6. solar energy according to claim 3 and lithium ion battery integration device, which is characterized in that the In-Zn-O
Layer with a thickness of 30 nanometers to 100 nanometers.
7. solar energy according to claim 6 and lithium ion battery integration device, which is characterized in that the In-Zn-O
Layer with a thickness of 40 nanometers to 60 nanometers.
8. solar energy according to claim 1 and lithium ion battery integration device, which is characterized in that the anode and institute
It states and is further formed p-n junction between semiconductor layer, when sunlight irradiates the p-n junction, will form photogenerated current.
9. solar energy according to claim 1 and lithium ion battery integration device, which is characterized in that the negative electrode material
Selected from Shi Mo ﹑ tin base cathode material and silicon based anode material.
10. solar energy according to claim 1 and lithium ion battery integration device, which is characterized in that the electrolyte
Layer is solid electrolyte layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510751773.8A CN106684182B (en) | 2015-11-05 | 2015-11-05 | Solar energy and lithium ion battery integration device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510751773.8A CN106684182B (en) | 2015-11-05 | 2015-11-05 | Solar energy and lithium ion battery integration device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106684182A CN106684182A (en) | 2017-05-17 |
| CN106684182B true CN106684182B (en) | 2019-01-29 |
Family
ID=58862824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510751773.8A Active CN106684182B (en) | 2015-11-05 | 2015-11-05 | Solar energy and lithium ion battery integration device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106684182B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108511543A (en) * | 2018-01-25 | 2018-09-07 | 北京创昱科技有限公司 | A kind of integrated energy resource supply product and preparation method thereof and equipment |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101796654A (en) * | 2007-09-07 | 2010-08-04 | 奥立孔美国公司 | Integrated electrochemical and solar cell |
| CN102394321A (en) * | 2011-10-09 | 2012-03-28 | 福建瑞达精工股份有限公司 | Lamination type energy-storable solar battery and preparation method thereof |
| CN104541400A (en) * | 2012-08-20 | 2015-04-22 | 原子能和替代能源委员会 | Photovoltaic battery cell |
-
2015
- 2015-11-05 CN CN201510751773.8A patent/CN106684182B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101796654A (en) * | 2007-09-07 | 2010-08-04 | 奥立孔美国公司 | Integrated electrochemical and solar cell |
| CN102394321A (en) * | 2011-10-09 | 2012-03-28 | 福建瑞达精工股份有限公司 | Lamination type energy-storable solar battery and preparation method thereof |
| CN104541400A (en) * | 2012-08-20 | 2015-04-22 | 原子能和替代能源委员会 | Photovoltaic battery cell |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106684182A (en) | 2017-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2017180975A3 (en) | Thin film battery device and methods of formation | |
| CN107210368B (en) | Perovskite solar cell module | |
| JP2010245031A5 (en) | ||
| PH12017500970A1 (en) | Single pouch battery cells and methods of manufacture | |
| WO2016118972A3 (en) | Adaptable recharging and lighting station and methods of using the same | |
| WO2010044847A3 (en) | Nano-patterned active layers formed by nano-imprint lithography | |
| WO2010120601A3 (en) | High power, high energy and large area energy storage devices | |
| WO2010144480A3 (en) | Photovoltaic module and method of manufacturing a photovoltaic module having multiple semiconductor layer stacks | |
| WO2009031037A3 (en) | Electrode body, and lithium secondary battery employing the electrode body | |
| WO2011139754A3 (en) | Electronic gate enhancement of schottky junction solar cells | |
| WO2011090779A3 (en) | Low-cost, high power, high energy density, solid-state, bipolar metal hydride batteries | |
| EP2775533A3 (en) | Solar cell | |
| JP2018098200A5 (en) | Secondary battery and solid electrolyte | |
| WO2018062836A3 (en) | Multi-layer anode comprising natural graphite and artificial graphite, and lithium secondary battery comprising same | |
| JP2015082374A5 (en) | Electrode fabrication method | |
| MY188744A (en) | Stacked battery | |
| EP4273940A3 (en) | Power routing module for a solar cell array | |
| CN105474441B (en) | Fully solid secondary cell, its manufacturing method and electronic equipment | |
| SA518391957B1 (en) | A Solar Cell Comprising Grains of A Doped Semiconducting Material and A Method for Manufacturing The Solar Cell | |
| CN106684182B (en) | Solar energy and lithium ion battery integration device | |
| WO2017128751A1 (en) | Power source assembly and electronic device | |
| WO2016197636A1 (en) | Oled display apparatus with thin-film battery | |
| CN206931653U (en) | A kind of solid-state thin-film battery structure | |
| JP2012124471A5 (en) | Power storage device and charging device | |
| US20210126145A1 (en) | CIGS Lamination Structure and Portable Solar Charger Using Same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |