CN106676341A - Rolling technique of microalloy aluminum base composite materials - Google Patents

Rolling technique of microalloy aluminum base composite materials Download PDF

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Publication number
CN106676341A
CN106676341A CN201611179327.5A CN201611179327A CN106676341A CN 106676341 A CN106676341 A CN 106676341A CN 201611179327 A CN201611179327 A CN 201611179327A CN 106676341 A CN106676341 A CN 106676341A
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microalloy
temperature
rolling
matrix composite
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CN106676341B (en
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张松利
梁智萍
张炳荣
张冬梅
窦炳玥
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Zhenjiang Powerise Special Alloy Technology Development Co Ltd
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Zhenjiang Powerise Special Alloy Technology Development Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1036Alloys containing non-metals starting from a melt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1036Alloys containing non-metals starting from a melt
    • C22C1/1047Alloys containing non-metals starting from a melt by mixing and casting liquid metal matrix composites
    • C22C1/1052Alloys containing non-metals starting from a melt by mixing and casting liquid metal matrix composites by mixing and casting metal matrix composites with reaction
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0073Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only borides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Metal Rolling (AREA)

Abstract

The invention relates to a preparation technique of microalloy aluminum base composite materials, in particular to a rolling technique of the microalloy composite materials. According to the rolling technique of the microalloy aluminum base composite materials, dried potassium zirconium fluoride and potassium fluoborate powder are added into an AlSi9Cu3 alloy which is molten to a certain temperature, then reaction is conducted, and stirring is conducted in a certain way during the reaction process; and after reaction is conducted for a certain time, a melt is subjected to drossing and refining, then the temperature is lowered to a certain degree to add Al-10Ce, reaction is conducted, after the reaction is conducted for a certain time, drossing and refining are conducted again, after finishing, copper mold casting is conducted, and after casting, a copper mold is subjected to direct rolling after being lowered to a certain temperature. Through the method, prepared aluminum base composite material crystal particles are small, mellow and evenly distributed, silicon phases in the materials are evenly distributed, and shapes of the silicon phases are each of an ellipsoidal structure, the mechanical property of the composite materials is improved, and particularly the high-temperature mechanical property is also more excellent than a base alloy of the composite materials.

Description

A kind of rolling mill practice of microalloy aluminum matrix composite
Technical field
The present invention relates to a kind of preparation method of microalloying composite, microalloying aluminum matrix composite is specifically referred to A kind of rolling mill practice.
Background technology
Microalloying is that certain modified one kind is carried out to material by adding some micro specific elements to material Method, by microalloying, can by changing fragility phase morphology in material while may generate some phases of disperse second Grain improves the mechanical property of material.Material mechanical performance is greatly improved by adding a small amount of alloying element, is come from source Material is improved, certain cost has been saved.The research of microalloying is carried out to composite at present seldom, by aluminum-base composite The microalloying of material can be modified the pattern of Si phases in aluminum matrix composite and the reunion situation that improves in-situ particle, improve The mechanical property of composite.
Big plastic deformation is carried out by the aluminum matrix composite rolled to microalloying, can be by this larger deformation The particle of reunion is spread out, at the same in the material that breaks needle-like silicon phase and larger brittlement phase, make material structure more Uniformly, the mechanical property of aluminum matrix composite is improved.Hot rolling simultaneously can eliminate hole in material, tight material structure and By recrystallizing the crystal grain come refiner material, the mechanical property of material is increased substantially.By multiple to microalloying aluminum-base composite Condensation material rolling finds, compared to its matrix alloy, mechanical behavior under high temperature greatly excellent its matrix alloy of composite.Illustrating can Plate is rolled to prepare high-temperature resistant composite material by rolling, can be applied in hot environment.
Existing literature search is found:Application No. 201510334398.7, a kind of entitled rolling high-strength degree duralumin The method of alloy, it will carry out the pre-heat treatment in the operation of rolling, and the present invention is saved using casting casting waste heat Direct Rolling Processing step, reduces cost.Application No. 201510939875.2, a kind of entitled aluminium alloy thick plate laminated rolling technique, its Preparation process includes:Melt melting, ingot casting casting, ingot mill surface and Homogenization Treatments, surface treatment, lamination electric welding, lamination expand The processing steps such as annealing, hot rolling are dissipated, main technological steps of the present invention are melting, and hot rolling, annealing is cold rolling.The present invention need not roll Pretreatment before system, process is simple is with short production cycle, cost-effective.
The content of the invention
Plate can be rolled with high-temperature resistant composite material it is an object of the invention to provide one kind, by microalloying and the knot of rolling Its mechanical behavior under high temperature is improved while conjunction to improve material ambient temperature mechanical properties.
Preparation method of the invention is comprised the following steps:(1)By fluorine zirconic acid sylvite and the drying of potassium fluoborate powder with standby; (2)The AlSi9Cu3 alloys of 600g are put into and are preheated in 375 ~ 440 DEG C of graphite crucibles heating and melting and are heated to 795 ~ 830 ℃;(3)60g standby potassium fluorozirconate and potassium fluoborate mixed-powder point are put into graphite crucible and according to certain way for 2 times Stir, agitating mode is:Manually stirred using graphite rod, 10min is stirred every time, melt is quiet to 10min, this step weight It is multiple 1 time, while temperature is maintained at 795 ~ 830 DEG C in whipping process;(4)After stirring terminates, melt in graphite crucible is incubated 5min, soaking time terminate after by melt be down to 735 ~ 760 DEG C and skim in a certain way, it is concise, its certain way refers to: At 735 ~ 760 DEG C, manually skimmed using Slag Tool, after end of skimming, add refining agent refining, and stand 2min, work as standing Add slagging agent to skim again after end, continue to be put into refining agent being refined again after end of skimming;(5)After concise Melt is incubated 3 ~ 5min, and the Al-10Ce of 3 ~ 9g is added after insulation terminates, and carries out reaction certain hour according to certain way, instead According to step after terminating between seasonable(4)Mode skimmed again and refined;(6)After concise end, melt is down to 720 ~ 750 DEG C carry out copper mold casting, and copper mold is preheated to 120 ~ 150 DEG C in advance, and copper mold size is 100mm × 50mm × 12mm, has been cast Into the cooling of relief copper mold Temperature fall;(7)After copper mold is down to 280 ~ 350 DEG C, ingot casting is taken out, directly rolled, rolled Method is:Hot rolling+cold rolling, carries out 375 DEG C × 1h and anneals and be air cooled to room temperature after hot rolling, continuing cold rolling, hot rolling total deformation It is 50 ~ 60%, cold rolling total deformation is 17 ~ 20%.
Compared with prior art, the present invention improves the mechanical property of aluminum matrix composite by microalloying from source Can, internal flaw and crystal grain thinning in material are eliminated further through hot rolling, and rolled in the case of half as cast condition, subtract Lack processing step, it is cost-effective, while carrying out surface peening, the overall normal temperature mechanics for improving material to material further through cold rolling Performance, in addition, also improves the mechanical behavior under high temperature of material, and rolling plate to prepare high temperature resistant composite provides possibility side Case.
Specific embodiment
Embodiments of the invention are elaborated below:The present embodiment is carried out under premised on technical solution of the present invention Implement, give detailed implementation method and specific operating process, but protection scope of the present invention is not limited to following implementations Case.
Implementation method 1:
Material of the invention is:TiB2/ AlSi9Cu3 composites, its composition is:Si:8 ~ 9.5%, Cu:2 ~ 3%, TiB2: 1.4%, Ce:0.05%, remaining is Al.
Processing step:(1)By fluorine zirconic acid sylvite and the drying of potassium fluoborate powder with standby;(2)By the AlSi9Cu3 of 600g Alloy is put into and is preheated in 375 ~ 440 DEG C of graphite crucibles heating and melting and is heated to 795 ~ 830 DEG C;(3)By the standby fluorine zirconiums of 60g Sour potassium and potassium fluoborate mixed-powder point are put into graphite crucible for 2 times and are stirred according to certain way, and agitating mode is:Using stone Inker is manually stirred, and 10min is stirred every time, and melt is quiet to 10min, and this step is repeated 1 times, while the middle temperature of whipping process Degree is maintained at 795 ~ 830 DEG C;(4)After stirring terminates, by melt insulation 5min in graphite crucible, soaking time terminate after by melt Be down to 735 ~ 760 DEG C and skim in a certain way, it is concise, its certain way refers to:At 735 ~ 760 DEG C, using Slag Tool Manually skim, after end of skimming, add refining agent refining, and stand 2min, add slagging agent to skim again after standing terminates, To skim continue to be put into refining agent after end and refined again;(5)Melt after will be concise is incubated 3 ~ 5min, when insulation terminates Add the Al-10Ce of 3g afterwards, reaction certain hour carried out according to certain way, the reaction time terminate after according to step(4)Side Formula is skimmed and is refined again;(6)After concise end, melt is down into 720 ~ 750 DEG C carries out copper mold casting, and copper mold shifts to an earlier date pre- To 120 ~ 150 DEG C, copper mold size is 100mm × 50mm × 12mm to heat, allows copper mold Temperature fall to be lowered the temperature after the completion of casting;(7)When After copper mold is down to 280 ~ 350 DEG C, ingot casting is taken out, directly rolled, milling method is:Hot rolling+cold rolling, is carried out after hot rolling 375 DEG C × 1h anneals and is air cooled to room temperature, is continuing cold rolling, and hot rolling total deformation is 50 ~ 60%, and cold rolling total deformation is 17 ~ 20%。
Implementation method 2:
Material of the invention is:TiB2/ AlSi9Cu3 composites, its composition is:Si:8 ~ 9.5%, Cu:2 ~ 3%, TiB2: 1.4%, Ce:0.1%, remaining is Al.
Processing step:(1)By fluorine zirconic acid sylvite and the drying of potassium fluoborate powder with standby;(2)By the AlSi9Cu3 of 600g Alloy is put into and is preheated in 375 ~ 440 DEG C of graphite crucibles heating and melting and is heated to 795 ~ 830 DEG C;(3)By the standby fluorine zirconiums of 60g Sour potassium and potassium fluoborate mixed-powder point are put into graphite crucible for 2 times and are stirred according to certain way, and agitating mode is:Using stone Inker is manually stirred, and 10min is stirred every time, and melt is quiet to 10min, and this step is repeated 1 times, while the middle temperature of whipping process Degree is maintained at 795 ~ 830 DEG C;(4)After stirring terminates, by melt insulation 5min in graphite crucible, soaking time terminate after by melt Be down to 735 ~ 760 DEG C and skim in a certain way, it is concise, its certain way refers to:At 735 ~ 760 DEG C, using Slag Tool Manually skim, after end of skimming, add refining agent refining, and stand 2min, add slagging agent to skim again after standing terminates, To skim continue to be put into refining agent after end and refined again;(5)Melt after will be concise is incubated 3 ~ 5min, when insulation terminates Add the Al-10Ce of 6g afterwards, reaction certain hour carried out according to certain way, the reaction time terminate after according to step(4)Side Formula is skimmed and is refined again;(6)After concise end, melt is down into 720 ~ 750 DEG C carries out copper mold casting, and copper mold shifts to an earlier date pre- To 120 ~ 150 DEG C, copper mold size is 100mm × 50mm × 12mm to heat, allows copper mold Temperature fall to be lowered the temperature after the completion of casting;(7)When After copper mold is down to 280 ~ 350 DEG C, ingot casting is taken out, directly rolled, milling method is:Hot rolling+cold rolling, is carried out after hot rolling 375 DEG C × 1h anneals and is air cooled to room temperature, is continuing cold rolling, and hot rolling total deformation is 50 ~ 60%, and cold rolling total deformation is 17 ~ 20%。
Implementation method 3:
Material of the invention is:TiB2/ AlSi9Cu3 composites, its composition is:Si:8 ~ 9.5%, Cu:2 ~ 3%, TiB2: 1.4%, Ce:0.15%, remaining is Al.
Processing step:(1)By fluorine zirconic acid sylvite and the drying of potassium fluoborate powder with standby;(2)By the AlSi9Cu3 of 600g Alloy is put into and is preheated in 375 ~ 440 DEG C of graphite crucibles heating and melting and is heated to 795 ~ 830 DEG C;(3)By the standby fluorine zirconiums of 60g Sour potassium and potassium fluoborate mixed-powder point are put into graphite crucible for 2 times and are stirred according to certain way, and agitating mode is:Using stone Inker is manually stirred, and 10min is stirred every time, and melt is quiet to 10min, and this step is repeated 1 times, while the middle temperature of whipping process Degree is maintained at 795 ~ 830 DEG C;(4)After stirring terminates, by melt insulation 5min in graphite crucible, soaking time terminate after by melt Be down to 735 ~ 760 DEG C and skim in a certain way, it is concise, its certain way refers to:At 735 ~ 760 DEG C, using Slag Tool Manually skim, after end of skimming, add refining agent refining, and stand 2min, add slagging agent to skim again after standing terminates, To skim continue to be put into refining agent after end and refined again;(5)Melt after will be concise is incubated 3 ~ 5min, when insulation terminates Add the Al-10Ce of 9g afterwards, reaction certain hour carried out according to certain way, the reaction time terminate after according to step(4)Side Formula is skimmed and is refined again;(6)After concise end, melt is down into 720 ~ 750 DEG C carries out copper mold casting, and copper mold shifts to an earlier date pre- To 120 ~ 150 DEG C, copper mold size is 100mm × 50mm × 12mm to heat, allows copper mold Temperature fall to be lowered the temperature after the completion of casting;(7)When After copper mold is down to 280 ~ 350 DEG C, ingot casting is taken out, directly rolled, milling method is:Hot rolling+cold rolling, is carried out after hot rolling 375 DEG C × 1h anneals and is air cooled to room temperature, is continuing cold rolling, and hot rolling total deformation is 50 ~ 60%, and cold rolling total deformation is 17 ~ 20%。
The following is composite materials property table:
Table 1:Different materials mechanical property after rolling
Table 2:Without rolling different materials mechanical property
By the table 2 of table 1 it can be seen that microalloying can increase substantially material mechanical performance, rolling can also be increased substantially Material mechanical performance, in addition the mechanical behavior under high temperature by microalloying and the composite of rolling is more excellent in not rolling The alloy of system and the composite with it as matrix.

Claims (10)

1. a kind of rolling mill practice of microalloy aluminum matrix composite, it is characterised in that following steps:
(1)A certain amount of AlSi9Cu3 alloys are put into uniform temperature graphite crucible heating and melting and uniform temperature is heated to;
(2)A certain amount of standby potassium fluorozirconate and potassium fluoborate mixed-powder are put into graphite crucible simultaneously according to certain way Stirred according to certain way;
(3)After stirring terminates, by melt held for some time in graphite crucible, melt is down to a constant temperature by soaking time after terminating Spend and skim in a certain way, it is concise;
(4)Melt held for some time after will be concise, adds a certain amount of Al-10Ce, according to certain after insulation terminates Mode carries out reaction certain hour, the reaction time terminate after according to step(3)Mode skimmed again and refined;
(5)After concise end, melt is down into 720 ~ 750 DEG C carries out copper mold casting, and copper mold is allowed after the completion of casting according to certain side Formula is lowered the temperature;
(6)After copper mold is down to uniform temperature, ingot casting is taken out, directly carry out the rolling of certain way;
Above-mentioned microalloy aluminum matrix composite refers to ZrB2Particle REINFORCED Al Si9Cu3 composites, its component is:Si:8~ 9.5%, Cu:2 ~ 3%, TiB2:1.4%, Ce:0.05 ~ 0.15%, remaining is Al.
2. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(1)Institute The uniform temperature graphite crucible stated refers to:Graphite crucible is preheated to 375 ~ 440 DEG C in advance, be heated to uniform temperature refer to 795 ~ 830℃。
3. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(2)Institute A certain amount of potassium fluorozirconate and potassium fluoborate mixed-powder stated refer to:Powder accounts for substrate quality 8 ~ 9%;Wherein according to certain side Formula add powder refer to:By in 2 addition melts of powder point, addition time interval is 3min, and 1 is all carried out after adding powder every time The artificial stirring of ~ 2min.
4. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(2)Institute The certain way stated is stirred:Manually stirred using graphite rod, 10min is stirred every time, melt is quiet to 10min, this Step is repeated 1 times, while temperature is maintained at 795 ~ 830 DEG C in whipping process.
5. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(3)Institute The held for some time stated refers to 5min;Insulation is down to uniform temperature after terminating:735~760℃.
6. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(3)Institute The certain way stated is skimmed, is refined:At 735 ~ 760 DEG C, manually skimmed using Slag Tool, after end of skimming, added Refining agent is refined, and stands 2min, adds slagging agent to skim again after standing terminates, and continues to be put into refining agent after end of skimming Refined again.
7. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(4)Institute What is stated refers to by melt held for some time:3~5min;A certain amount of Al-10Ce is added to refer to:Addition quality be matrix 0.5 ~ 1.5% Al-10Ce.
8. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(4)Institute State according to certain way reaction certain hour refer to:At 735 ~ 760 DEG C, Al-10Ce is added, electrographite stirring after addition 1 ~ 2nin, and stand 3 ~ 5min of reaction.
9. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(5)Institute The copper mold stated is lowered the temperature according to certain way:Natural air cooling mode, and temperature test is carried out in cooling, copper mold size is 100mm × 50mm × 12mm, and copper mold is preheated to 120 ~ 150 DEG C in advance.
10. a kind of rolling mill practice of described microalloy aluminum matrix composite is required according to right 1, it is characterized in that:Step(6)Institute The uniform temperature of being down to stated refers to:280 ~ 350 DEG C, certain way rolls and refers to:Roll is heated to 200 DEG C in advance, by casting Direct Rolling, each volume under pressure is 2mm, is rolled 3 times altogether, and total deformation is 50 ~ 60%;Rolled parts is existed after the completion of hot rolling Annealed at 375 DEG C and 1h and be air cooled to room temperature, roll is also also air cooled to room temperature, carry out cold rolling, cold rolling each volume under pressure is 0.5mm, rolls 4 times altogether, and total deformation is 17 ~ 20%.
CN201611179327.5A 2016-12-19 2016-12-19 A kind of rolling mill practice of microalloy aluminum matrix composite Expired - Fee Related CN106676341B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108237147A (en) * 2017-12-26 2018-07-03 江苏大学 The rolling mill practice of vehicle body in-situ nano particle enhanced aluminum-based composite material
CN108342606A (en) * 2018-01-19 2018-07-31 江苏大学 A kind of method that mischmetal improves in-situ Al-base composition tissue and performance
CN111020300A (en) * 2019-12-05 2020-04-17 江苏大学 Preparation method of thermal cracking resistant binary nanoparticle reinforced aluminum matrix composite
WO2023077668A1 (en) * 2021-11-02 2023-05-11 山东博源精密机械有限公司 Method for preparing new energy vehicle low-segregation motor rotor micro-alloy aluminum and micro-alloy aluminum prepared thereby

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6918970B2 (en) * 2002-04-10 2005-07-19 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration High strength aluminum alloy for high temperature applications
JP2008285739A (en) * 2007-05-21 2008-11-27 Isuzu Motors Ltd Method for producing particle-dispersed aluminum alloy composite material, and method for regulating its composition
CN105779915A (en) * 2016-03-17 2016-07-20 江苏大学 Preparation method of high-toughness aluminum base nanometer composite material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6918970B2 (en) * 2002-04-10 2005-07-19 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration High strength aluminum alloy for high temperature applications
JP2008285739A (en) * 2007-05-21 2008-11-27 Isuzu Motors Ltd Method for producing particle-dispersed aluminum alloy composite material, and method for regulating its composition
CN105779915A (en) * 2016-03-17 2016-07-20 江苏大学 Preparation method of high-toughness aluminum base nanometer composite material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108237147A (en) * 2017-12-26 2018-07-03 江苏大学 The rolling mill practice of vehicle body in-situ nano particle enhanced aluminum-based composite material
CN108237147B (en) * 2017-12-26 2019-10-01 江苏大学 The rolling mill practice of vehicle body in-situ nano particle enhanced aluminum-based composite material
CN108342606A (en) * 2018-01-19 2018-07-31 江苏大学 A kind of method that mischmetal improves in-situ Al-base composition tissue and performance
CN111020300A (en) * 2019-12-05 2020-04-17 江苏大学 Preparation method of thermal cracking resistant binary nanoparticle reinforced aluminum matrix composite
WO2023077668A1 (en) * 2021-11-02 2023-05-11 山东博源精密机械有限公司 Method for preparing new energy vehicle low-segregation motor rotor micro-alloy aluminum and micro-alloy aluminum prepared thereby

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