CN106675833A - Preparation method of soft biomass automobile washing liquid - Google Patents
Preparation method of soft biomass automobile washing liquid Download PDFInfo
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- CN106675833A CN106675833A CN201611135213.0A CN201611135213A CN106675833A CN 106675833 A CN106675833 A CN 106675833A CN 201611135213 A CN201611135213 A CN 201611135213A CN 106675833 A CN106675833 A CN 106675833A
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- milk
- washing liquid
- skin
- mixing
- automobile
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- 239000007788 liquid Substances 0.000 title claims abstract description 57
- 238000005406 washing Methods 0.000 title claims abstract description 41
- 239000002028 Biomass Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 47
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 15
- 239000008103 glucose Substances 0.000 claims abstract description 15
- 241000287828 Gallus gallus Species 0.000 claims abstract description 14
- 241001122767 Theaceae Species 0.000 claims abstract description 11
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 9
- 210000002969 egg yolk Anatomy 0.000 claims abstract description 8
- 235000013336 milk Nutrition 0.000 claims description 49
- 239000008267 milk Substances 0.000 claims description 49
- 210000004080 milk Anatomy 0.000 claims description 49
- 238000002156 mixing Methods 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000012467 final product Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 16
- 238000000855 fermentation Methods 0.000 claims description 15
- 230000004151 fermentation Effects 0.000 claims description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 239000012634 fragment Substances 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 12
- 239000000284 extract Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 102000002322 Egg Proteins Human genes 0.000 claims description 8
- 108010000912 Egg Proteins Proteins 0.000 claims description 8
- 235000013345 egg yolk Nutrition 0.000 claims description 7
- 108010059892 Cellulase Proteins 0.000 claims description 6
- 229920003266 Leaf® Polymers 0.000 claims description 6
- 235000020246 buffalo milk Nutrition 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229940106157 cellulase Drugs 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 238000000280 densification Methods 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 229960004756 ethanol Drugs 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000000376 reactant Substances 0.000 claims description 6
- 238000002390 rotary evaporation Methods 0.000 claims description 6
- 210000002966 serum Anatomy 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 230000001954 sterilising effect Effects 0.000 claims description 6
- 238000004659 sterilization and disinfection Methods 0.000 claims description 6
- 239000006228 supernatant Substances 0.000 claims description 6
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 4
- 230000002255 enzymatic effect Effects 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 2
- 102000004190 Enzymes Human genes 0.000 claims description 2
- 229940088598 enzyme Drugs 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 5
- 229930195729 fatty acid Natural products 0.000 abstract description 5
- 239000000194 fatty acid Substances 0.000 abstract description 5
- 150000004665 fatty acids Chemical class 0.000 abstract description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 3
- 239000011574 phosphorus Substances 0.000 abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006065 biodegradation reaction Methods 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 abstract description 2
- 235000013824 polyphenols Nutrition 0.000 abstract description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 abstract description 2
- 229930182490 saponin Natural products 0.000 abstract description 2
- 150000007949 saponins Chemical class 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- 239000011593 sulfur Substances 0.000 abstract description 2
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 abstract 2
- 229940073499 decyl glucoside Drugs 0.000 abstract 2
- 230000002195 synergetic effect Effects 0.000 abstract 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 230000007794 irritation Effects 0.000 abstract 1
- 229940067606 lecithin Drugs 0.000 abstract 1
- 235000010445 lecithin Nutrition 0.000 abstract 1
- 239000000787 lecithin Substances 0.000 abstract 1
- 210000004185 liver Anatomy 0.000 abstract 1
- 235000021243 milk fat Nutrition 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 235000013616 tea Nutrition 0.000 description 9
- 238000007599 discharging Methods 0.000 description 5
- 239000010865 sewage Substances 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 235000009392 Vitis Nutrition 0.000 description 1
- 241000219095 Vitis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/04—Aqueous dispersions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/886—Ampholytes containing P
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a preparation method of soft biomass automobile washing liquid and belongs to the technical field of automobile cleaning and care articles. Milk fat is hydrolyzed under the acidic environment to produce higher fatty acid, the higher fatty acid is reduced into higher fatty acid alcohol under the action of reducing oxalic acid, the higher fatty acid alcohol reacts with glucose at high temperature to generate glycerinum and decyl glucoside, elements such as nitrogen, sulfur and phosphorus in chicken liver extracting liquid and the glycerinum are subjected to synergistic action to form one layer of chemical protective film on the surface of an automobile body to protect the automobile body and have a glazing effect, lecithin in yolk and the decyl glucoside serving as surfactants have strong detersive powder and rich foam and are fine and stable, and tea saponin and tea polyphenol in the tea extracting liquid have oxidation resistance and can improve the storage stability of the automobile washing liquid. The automobile washing liquid prepared by the method has obvious synergistic effect, is non-toxic, low in irritation and rapid and complete in biodegradation, avoids corrosion to the automobile body, and has excellent application prospect.
Description
Technical field
The present invention relates to a kind of preparation method of soft type biomass car washing liquid, belongs to automobile washing nursing materialss technology neck
Domain.
Background technology
Automobile maintenance industry is an industry in the ascendant in China, arises from the nineties in 20th century, with car increasingly
Many enters into private home, and automobile maintenance industry starts known to clan owning cars, the love of " seven points are supported, and three points are repaiied, and are repaiied with supporting generation "
Car new concept is progressively received by vast clan owning cars, particularly in recent years, the development, relevant policies along with Domestic Automotive Industry
Adjustment with it is perfect, and automobile pollution increases sharply, and automobile maintenance product market developments is swift and violent, and market prospect is extremely seen
It is good.
Car washing liquid class conventional products have at present three kinds：Concentration car washing liquid, car washing liquid companion, car washing liquid（Water wax pattern）.Carwash
Liquid class product is in addition to having stronger detergency, it is desirable on automobile organic coating without impact.Car washing water blowdown is big, easy contaminant water
Source, it is desirable to without phosphorus formula.Concentration car washing liquid is surfactant, organic base, organic solvent composition, and adding a small amount of silicone oil increases handss
Sense, car washing liquid requires there is preferable detergency simultaneously, to there is suitable foaming characteristic and defoaming, and foaming characteristic improves the decontamination of product
Power, the visuality of carwash, defoaming ensures water-saving, easily rinses；Car washing liquid companion is the emulsifying liquid product of wax, based on glazing, is increased
Plus the expelling water of car washing liquid, the damage being wiped repeatedly to car paint is reduced, it is adapted to computer carwash and uses.The condition of storage of car washing liquid companion
It is very crucial, it is stored above at 0 DEG C, forbid to endure cold.Wax liquor easy breakdown of emulsion layering after being frozen, affects performance.Car washing liquid（Water
Wax pattern）It is that carwash, one step of waxing are completed, is particularly suitable for DIY client, moderate foam is easily wiped, gloss, good hand touch.
Presently commercially available car cleaning products cleaning performance is uneven, and some not only do not reach the cleaning performance of needs,
More importantly life-time service may damage automobile, corrosive damage etc. occur, and driving safety can be also affected when serious.And
Most of abluent in use, needs a large amount of water to rinse, the great wave for water resource is caused of the sewage after flushing
Take.Therefore, with the progress and the raising of people's environmental consciousness of technology, a kind of new, efficient, professional, environmentally friendly cleaning is invented
Agent is a major issue of this area urgent need to resolve.
The content of the invention
The invention mainly solves the technical problem of：For using chemical classes surface activity at present common car washing liquid more
Agent, foaming characteristic and dirt-removing power it is poor, upper optical property is low, life-time service can to vehicle body produce corrosion defect, there is provided Yi Zhongcong
Butterfat is extracted in milk, itself and glucose is synthesized into the natural surfactant containing glycerol in the presence of reproducibility oxalic acid,
The method that biomass film forming concentrated solution and tea extract are obtained car washing liquid is equipped with again, and the present invention is using butterfat under sour environment
Hydrolysis generates higher fatty acids, then higher aliphatic acid alcohol is reduced in the presence of reproducibility oxalic acid, by itself and glucose in height
The lower reaction of temperature generates element and the glycerol synergism such as glycerol and alkyl-glucoside, nitrogen, sulfur, phosphorus in Hepar Gallus domesticus extracting solution,
Bodywork surface forms a stratification protecting film, protects vehicle body and plays glossiness-giving effect, and the ovum lipoid and alkyl Fructus Vitis viniferae in egg yolk
Glucosides is used as surfactant, strong detergency, foaming abundancy, exquisiteness and stable, the tea saponin and tea in last tea extract
Polyphenol has antioxidation again, improves the bin stability of car washing liquid, and the obtained car washing liquid cooperative effect of the present invention is obvious, nothing
Malicious, low stimulation, biodegradation is thorough rapidly, to vehicle body without any corrosion, with splendid application prospect.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is：
（1）Take to be stood after the fresh buffalo milks of 2~3kg are poured into the pot and boiled and be cooled to 80~82 DEG C, at once pour warm milk 4 into
At~6 DEG C in precooled bowl, warm milk encounters cold bowl wall, and the lipochondrion in milk floats, and in bowl face the milk of densification is formed
Skin, presss from both sides out skin on boiled milk and is put in the there-necked flask with thermometer and agitator with the tweezers after sterilization；
（2）Above-mentioned there-necked flask is put in water-bath, 80~85 DEG C are heated to, 15~20min of isothermal holding makes skin on boiled milk
Melt and the moisture in evaporative removal skin on boiled milk, then the glucose and glucose quality 3~5% of the quality such as skin on boiled milk are added in flask
Oxalic acid, continue to be heated to 85~95 DEG C, start agitator, insulated and stirred reacts 2~3h, and question response is filtered after terminating and received
Collection filtrate, obtains final product the self-control natural surfactant containing glycerol, standby；
（3）In mass ratio it is 1:1:Egg yolk, Hepar Gallus domesticus and mass fraction are to be put into tissue homogenate after the mixing of 7% sodium chloride solution by 1
Slurry is ground in machine, the mixed serum for obtaining is fitted in fermentation tank, the methane liquid of Hepar Gallus domesticus quality 10%, stirring are added in tank
Sealing and fermenting 9~12 days are stood at 30~35 DEG C after uniform；
（4）It is in mass ratio 10 after above-mentioned fermentation ends:Fermented product and mass fraction are the mixing of 30% hydrogen peroxide by 1,70
15~20min of stirring reaction at~80 DEG C, reaction is centrifuged reactant centrifuge with 3000~4000r/min rotating speeds after terminating
15~20min is processed, isolated supernatant simultaneously proceeds to Rotary Evaporators concentrated by rotary evaporation to the 1/5 of its original volume, concentrated
Liquid, it is standby；
（5）100~200g fresh tea leafs are taken, is crushed with jet mill and obtain Folium Camelliae sinensis fragment after 20~30min, by Folium Camelliae sinensis fragment
Load enzymatic vessel with after the mixing of 300~500mL distilled water, 0.3~0.5g cellulase and 0.4~0.6g pectin are added in tank
Enzyme, 3~5h of insulation enzymolysis, is filtrated to get enzymolysis solution at 40~45 DEG C, is in mass ratio 4:1 mixes dehydrated alcohol and enzymolysis solution
After conjunction at 70~80 DEG C 2~4h of precipitate with ethanol, be filtrated to get precipitation, obtain final product Folium Camelliae sinensis extract after being dried；
（6）Count by weight, weigh 20~30 parts of steps（2）The standby self-control natural surfactant containing glycerol, 5~
10 parts of above-mentioned Folium Camelliae sinensis extracts, 15~25 parts of steps（4）Standby concentrated solution and 40~50 parts of deionized waters is put into glue after mixing
In body mill, discharging bottling, obtains final product soft type biomass car washing liquid after 1~2h of ground and mixed.
The application process of the present invention：Soft type biomass car washing liquid prepared by the present invention and water in mass ratio 1:25~1:
30 mixing, stir 3~5min, and mixed liquor is obtained, then mixed liquor liquid-spreader is uniformly sprayed into vehicle body, wheel hub, tire, use
The car washer of 6~8MPa carries out high pressure rinse, and car washing liquid is dried after the position that hydro-peening is crossed stands 2~3min.Jing is examined
Survey, compared with using traditional car washing liquid, its water consumption reduces by 45~50%, and car-cleaning time reduces by 45~52%, and car surface
Without vestige, corrosion-free, and reduce sewage discharge more than 45%.
The invention has the beneficial effects as follows：
（1）Soft type biomass car washing liquid prepared by the present invention is neutrality, non-stimulated to skin, corrosion-free to vehicle body coating, right
Environmental nonpollution；
（2）Obtained soft type biomass carwash liquid energy of the invention effectively removes car body surface electrostatic, effectively prevents the heavy of dust
Product, and technological operation is simple and safe, and environmentally friendly, biodegradability is excellent.
Specific embodiment
Take to be stood after the fresh buffalo milks of 2~3kg are poured into the pot and boiled and be cooled to 80~82 DEG C, at once pour into warm milk
At 4~6 DEG C in precooled bowl, warm milk encounters cold bowl wall, and the lipochondrion in milk floats, and in bowl face the milk of densification is formed
Skin, presss from both sides out skin on boiled milk and is put in the there-necked flask with thermometer and agitator with the tweezers after sterilization；By above-mentioned there-necked flask
In being put into water-bath, 80~85 DEG C are heated to, 15~20min of isothermal holding melts skin on boiled milk and in evaporative removal skin on boiled milk
Moisture, then the glucose and the oxalic acid of glucose quality 3~5% of the quality such as skin on boiled milk are added in flask, continue to be heated to 85
~95 DEG C, start agitator, insulated and stirred reacts 2~3h, and question response is collected by filtration filtrate after terminating, obtain final product oneself containing glycerol
Natural surfactant processed, is in mass ratio 1:1:Egg yolk, Hepar Gallus domesticus and mass fraction are to put after the mixing of 7% sodium chloride solution by 1
Enter and be ground in tissue refiner slurry, the mixed serum for obtaining is fitted in fermentation tank, the natural pond of Hepar Gallus domesticus quality 10% is added in tank
Gas-liquid, stands at 30~35 DEG C sealing and fermenting 9~12 days after stirring；It is in mass ratio 10 after above-mentioned fermentation ends:
Fermented product and mass fraction are the mixing of 30% hydrogen peroxide by 1, and 15~20min of stirring reaction at 70~80 DEG C, reaction will after terminating
Reactant centrifuge simultaneously proceeds to rotation with 3000~4000r/min rotating speed 15~20min of centrifugal treating, isolated supernatant
Evaporimeter concentrated by rotary evaporation obtains concentrated solution to the 1/5 of its original volume, takes 100~200g fresh tea leafs, is crushed with jet mill
Folium Camelliae sinensis fragment is obtained after 20~30min, will Folium Camelliae sinensis fragment and 300~500mL distilled water mixing after load enzymatic vessel, in tank plus
Enter 0.3~0.5g cellulase and 0.4~0.6g pectases, 3~5h of insulation enzymolysis, is filtrated to get enzymolysis at 40~45 DEG C
Liquid, is in mass ratio 4:1 by after dehydrated alcohol and enzymolysis solution mixing at 70~80 DEG C 2~4h of precipitate with ethanol, be filtrated to get precipitation, it is dry
Folium Camelliae sinensis extract is obtained final product after dry；Count by weight, weigh 20~30 portions of self-control natural surfactants containing glycerol, 5~
It is put in colloid mill after 10 parts of above-mentioned Folium Camelliae sinensis extracts, 15~25 parts of concentrated solutions and 40~50 parts of deionized water mixing, grinding is mixed
Discharging bottling after 1~2h is closed, soft type biomass car washing liquid is obtained final product.
Example 1
Take to be stood after the fresh buffalo milks of 2kg are poured into the pot and boiled and be cooled to 80 DEG C, at once pour into warm milk precooled at 4 DEG C
Bowl in, warm milk encounters cold bowl wall, and lipochondrion in milk floats, and the skin on boiled milk of densification is formed in bowl face, after sterilization
Tweezers press from both sides out skin on boiled milk and are put in the there-necked flask with thermometer and agitator；Above-mentioned there-necked flask is put in water-bath,
80 DEG C are heated to, isothermal holding 15min melts skin on boiled milk and the moisture in evaporative removal skin on boiled milk, then adds milk in flask
The glucose of the quality such as skin and the oxalic acid of glucose quality 3%, continue to be heated to 85 DEG C, start agitator, and insulated and stirred is anti-
Answer 2h, question response that filtrate is collected by filtration after terminating, obtain final product the self-control natural surfactant containing glycerol, be in mass ratio 1:1:
Egg yolk, Hepar Gallus domesticus and mass fraction are to be put in tissue refiner to be ground into slurry after the mixing of 7% sodium chloride solution by 1, by what is obtained
Mixed serum is fitted in fermentation tank, and the methane liquid of Hepar Gallus domesticus quality 10% is added in tank, stands at 30 DEG C after stirring and seals
Fermentation 9 days；It is in mass ratio 10 after above-mentioned fermentation ends:Fermented product and mass fraction are the mixing of 30% hydrogen peroxide by 1,70
Stirring reaction 15min at DEG C, reacts reactant centrifuge after terminating with 3000r/min rotating speed centrifugal treating 15min, separates
Obtain supernatant and proceed to Rotary Evaporators concentrated by rotary evaporation to the 1/5 of its original volume, obtain concentrated solution, take 100g fresh tea leafs,
Crushed with jet mill and obtain Folium Camelliae sinensis fragment after 20min, enzymatic vessel will be loaded after Folium Camelliae sinensis fragment and the mixing of 300mL distilled water,
0.3g cellulase and 0.4g pectases are added in tank, insulation enzymolysis 3h, is filtrated to get enzymolysis solution, in mass ratio at 40 DEG C
For 4:1 by after dehydrated alcohol and enzymolysis solution mixing at 70 DEG C precipitate with ethanol 2h, be filtrated to get precipitation, Folium Camelliae sinensis are obtained final product after being dried and are extracted
Thing；Count by weight, weigh 20 portions of self-control natural surfactants containing glycerol, 5 parts of above-mentioned Folium Camelliae sinensis extracts, 15 parts it is dense
It is put in colloid mill after contracting liquid and 40 parts of deionized water mixing, discharging bottling, obtains final product soft type biomass and wash after ground and mixed 1h
Car liquid.
Soft type biomass car washing liquid prepared by the present invention and water in mass ratio 1:25 mixing, stir 3min, are obtained mixed
Liquid is closed, then mixed liquor liquid-spreader is uniformly sprayed into vehicle body, wheel hub, tire, using the car washer of 6MPa high pressure rinse is carried out,
Car washing liquid is dried after the position that hydro-peening is crossed stands 2min.After testing, compared with using traditional car washing liquid, it uses water
Amount reduces by 45%, and car-cleaning time reduces 45%, and car surface is without vestige, corrosion-free, and reduces sewage discharge 46%.
Example 2
Take to be stood after the fresh buffalo milks of 2kg are poured into the pot and boiled and be cooled to 82 DEG C, at once pour into warm milk precooled at 6 DEG C
Bowl in, warm milk encounters cold bowl wall, and lipochondrion in milk floats, and the skin on boiled milk of densification is formed in bowl face, after sterilization
Tweezers press from both sides out skin on boiled milk and are put in the there-necked flask with thermometer and agitator；Above-mentioned there-necked flask is put in water-bath,
85 DEG C are heated to, isothermal holding 20min melts skin on boiled milk and the moisture in evaporative removal skin on boiled milk, then adds milk in flask
The glucose of the quality such as skin and the oxalic acid of glucose quality 5%, continue to be heated to 95 DEG C, start agitator, and insulated and stirred is anti-
Answer 3h, question response that filtrate is collected by filtration after terminating, obtain final product the self-control natural surfactant containing glycerol, be in mass ratio 1:1:
Egg yolk, Hepar Gallus domesticus and mass fraction are to be put in tissue refiner to be ground into slurry after the mixing of 7% sodium chloride solution by 1, by what is obtained
Mixed serum is fitted in fermentation tank, and the methane liquid of Hepar Gallus domesticus quality 10% is added in tank, stands at 35 DEG C after stirring and seals
Fermentation 12 days；It is in mass ratio 10 after above-mentioned fermentation ends:Fermented product and mass fraction are the mixing of 30% hydrogen peroxide by 1,
Stirring reaction 20min at 80 DEG C, reacts reactant centrifuge after terminating with 4000r/min rotating speed centrifugal treating 20min, point
From obtaining supernatant and proceeding to Rotary Evaporators concentrated by rotary evaporation to the 1/5 of its original volume, concentrated solution is obtained, take 200g fresh teas
Leaf, is crushed with jet mill and obtain Folium Camelliae sinensis fragment after 30min, will load enzymolysis after Folium Camelliae sinensis fragment and the mixing of 500mL distilled water
Tank, 0.5g cellulase and 0.6g pectases are added in tank, and insulation enzymolysis 5h, is filtrated to get enzymolysis solution, by matter at 45 DEG C
Amount is than being 4:1 by after dehydrated alcohol and enzymolysis solution mixing at 80 DEG C precipitate with ethanol 4h, be filtrated to get precipitation, obtain final product Folium Camelliae sinensis after drying and carry
Take thing；Count by weight, weigh 30 portions of self-control natural surfactants containing glycerol, 10 parts of above-mentioned Folium Camelliae sinensis extracts, 25
It is put in colloid mill after part concentrated solution and 50 parts of deionized waters mixing, discharging bottling after ground and mixed 2h obtains final product soft type biological
Matter car washing liquid.
Soft type biomass car washing liquid prepared by the present invention and water in mass ratio 1:30 mixing, stir 5min, are obtained mixed
Liquid is closed, then mixed liquor liquid-spreader is uniformly sprayed into vehicle body, wheel hub, tire, using the car washer of 8MPa high pressure rinse is carried out,
Car washing liquid is dried after the position that hydro-peening is crossed stands 3min.After testing, compared with using traditional car washing liquid, it uses water
Amount reduces by 50%, and car-cleaning time reduces 52%, and car surface is without vestige, corrosion-free, and reduces sewage discharge 47%.
Example 3
Take to be stood after the fresh buffalo milks of 3kg are poured into the pot and boiled and be cooled to 81 DEG C, at once pour into warm milk precooled at 5 DEG C
Bowl in, warm milk encounters cold bowl wall, and lipochondrion in milk floats, and the skin on boiled milk of densification is formed in bowl face, after sterilization
Tweezers press from both sides out skin on boiled milk and are put in the there-necked flask with thermometer and agitator；Above-mentioned there-necked flask is put in water-bath,
83 DEG C are heated to, isothermal holding 18min melts skin on boiled milk and the moisture in evaporative removal skin on boiled milk, then adds milk in flask
The glucose of the quality such as skin and the oxalic acid of glucose quality 4%, continue to be heated to 90 DEG C, start agitator, and insulated and stirred is anti-
Answer 3h, question response that filtrate is collected by filtration after terminating, obtain final product the self-control natural surfactant containing glycerol, be in mass ratio 1:1:
Egg yolk, Hepar Gallus domesticus and mass fraction are to be put in tissue refiner to be ground into slurry after the mixing of 7% sodium chloride solution by 1, by what is obtained
Mixed serum is fitted in fermentation tank, and the methane liquid of Hepar Gallus domesticus quality 10% is added in tank, stands at 33 DEG C after stirring and seals
Fermentation 11 days；It is in mass ratio 10 after above-mentioned fermentation ends:Fermented product and mass fraction are the mixing of 30% hydrogen peroxide by 1,
Stirring reaction 18min at 75 DEG C, reacts reactant centrifuge after terminating with 3500r/min rotating speed centrifugal treating 18min, point
From obtaining supernatant and proceeding to Rotary Evaporators concentrated by rotary evaporation to the 1/5 of its original volume, concentrated solution is obtained, take 150g fresh teas
Leaf, is crushed with jet mill and obtain Folium Camelliae sinensis fragment after 25min, will load enzymolysis after Folium Camelliae sinensis fragment and the mixing of 400mL distilled water
Tank, 0.4g cellulase and 0.5g pectases are added in tank, and insulation enzymolysis 4h, is filtrated to get enzymolysis solution, by matter at 43 DEG C
Amount is than being 4:1 by after dehydrated alcohol and enzymolysis solution mixing at 75 DEG C precipitate with ethanol 3h, be filtrated to get precipitation, obtain final product Folium Camelliae sinensis after drying and carry
Take thing；Count by weight, weigh 25 portions of self-control natural surfactants containing glycerol, 8 parts of above-mentioned Folium Camelliae sinensis extracts, 20 parts
It is put in colloid mill after concentrated solution and 45 parts of deionized water mixing, discharging bottling, obtains final product soft type biomass after ground and mixed 2h
Car washing liquid.
Soft type biomass car washing liquid prepared by the present invention and water in mass ratio 1:28 mixing, stir 4min, are obtained mixed
Liquid is closed, then mixed liquor liquid-spreader is uniformly sprayed into vehicle body, wheel hub, tire, using the car washer of 7MPa high pressure rinse is carried out,
Car washing liquid is dried after the position that hydro-peening is crossed stands 3min.After testing, compared with using traditional car washing liquid, it uses water
Amount reduces by 48%, and car-cleaning time reduces 49%, and car surface is without vestige, corrosion-free, and reduces sewage discharge 46%.
Claims (1)
1. a kind of preparation method of soft type biomass car washing liquid, it is characterised in that concrete preparation process is：
（1）Take to be stood after the fresh buffalo milks of 2~3kg are poured into the pot and boiled and be cooled to 80~82 DEG C, at once pour warm milk 4 into
At~6 DEG C in precooled bowl, warm milk encounters cold bowl wall, and the lipochondrion in milk floats, and in bowl face the milk of densification is formed
Skin, presss from both sides out skin on boiled milk and is put in the there-necked flask with thermometer and agitator with the tweezers after sterilization；
（2）Above-mentioned there-necked flask is put in water-bath, 80~85 DEG C are heated to, 15~20min of isothermal holding makes skin on boiled milk
Melt and the moisture in evaporative removal skin on boiled milk, then the glucose and glucose quality 3~5% of the quality such as skin on boiled milk are added in flask
Oxalic acid, continue to be heated to 85~95 DEG C, start agitator, insulated and stirred reacts 2~3h, and question response is filtered after terminating and received
Collection filtrate, obtains final product the self-control natural surfactant containing glycerol, standby；
（3）In mass ratio it is 1:1:Egg yolk, Hepar Gallus domesticus and mass fraction are to be put into tissue homogenate after the mixing of 7% sodium chloride solution by 1
Slurry is ground in machine, the mixed serum for obtaining is fitted in fermentation tank, the methane liquid of Hepar Gallus domesticus quality 10%, stirring are added in tank
Sealing and fermenting 9~12 days are stood at 30~35 DEG C after uniform；
（4）It is in mass ratio 10 after above-mentioned fermentation ends:Fermented product and mass fraction are the mixing of 30% hydrogen peroxide by 1,70
15~20min of stirring reaction at~80 DEG C, reaction is centrifuged reactant centrifuge with 3000~4000r/min rotating speeds after terminating
15~20min is processed, isolated supernatant simultaneously proceeds to Rotary Evaporators concentrated by rotary evaporation to the 1/5 of its original volume, concentrated
Liquid, it is standby；
（5）100~200g fresh tea leafs are taken, is crushed with jet mill and obtain Folium Camelliae sinensis fragment after 20~30min, by Folium Camelliae sinensis fragment
Load enzymatic vessel with after the mixing of 300~500mL distilled water, 0.3~0.5g cellulase and 0.4~0.6g pectin are added in tank
Enzyme, 3~5h of insulation enzymolysis, is filtrated to get enzymolysis solution at 40~45 DEG C, is in mass ratio 4:1 mixes dehydrated alcohol and enzymolysis solution
After conjunction at 70~80 DEG C 2~4h of precipitate with ethanol, be filtrated to get precipitation, obtain final product Folium Camelliae sinensis extract after being dried；
（6）Count by weight, weigh 20~30 parts of steps（2）The standby self-control natural surfactant containing glycerol, 5~
10 parts of above-mentioned Folium Camelliae sinensis extracts, 15~25 parts of steps（4）Standby concentrated solution and 40~50 parts of deionized waters is put into glue after mixing
In body mill, discharge after 1~2h of ground and mixed, bottling obtains final product soft type biomass car washing liquid.
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Citations (6)
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| KR100473528B1 (en) * | 2002-03-04 | 2005-03-08 | 황판권 | Natural Detergent Composition for Car and Interior Decoration |
| CN102010807A (en) * | 2010-12-13 | 2011-04-13 | 湖南农业大学 | Method for preparing natural-detergent feed solution by using tea saponin fluid |
| CN102653708A (en) * | 2011-12-21 | 2012-09-05 | 上海东昊油品有限公司 | All-around automobile windshield washing agent |
| CN103275821A (en) * | 2013-02-25 | 2013-09-04 | 冯俏琼 | Automobile dry cleaning agent and preparation method thereof |
| CN105886151A (en) * | 2016-03-24 | 2016-08-24 | 陈国丰 | Car plant cleaner |
| CN105950325A (en) * | 2016-05-11 | 2016-09-21 | 浙江金驰环保科技有限公司 | Automobile cleaning and polishing agent capable of avoiding scratches as well as preparation and application of automobile cleaning and polishing agent |
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- 2016-12-11 CN CN201611135213.0A patent/CN106675833A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100473528B1 (en) * | 2002-03-04 | 2005-03-08 | 황판권 | Natural Detergent Composition for Car and Interior Decoration |
| CN102010807A (en) * | 2010-12-13 | 2011-04-13 | 湖南农业大学 | Method for preparing natural-detergent feed solution by using tea saponin fluid |
| CN102653708A (en) * | 2011-12-21 | 2012-09-05 | 上海东昊油品有限公司 | All-around automobile windshield washing agent |
| CN103275821A (en) * | 2013-02-25 | 2013-09-04 | 冯俏琼 | Automobile dry cleaning agent and preparation method thereof |
| CN105886151A (en) * | 2016-03-24 | 2016-08-24 | 陈国丰 | Car plant cleaner |
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