CN106675823A - Door and window glass cleaning agent and preparation method thereof - Google Patents
Door and window glass cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN106675823A CN106675823A CN201611210782.7A CN201611210782A CN106675823A CN 106675823 A CN106675823 A CN 106675823A CN 201611210782 A CN201611210782 A CN 201611210782A CN 106675823 A CN106675823 A CN 106675823A
- Authority
- CN
- China
- Prior art keywords
- door glass
- glass
- water
- surfactant
- fatty alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000012459 cleaning agent Substances 0.000 title abstract 4
- 239000005357 flat glass Substances 0.000 title abstract 3
- 239000011521 glass Substances 0.000 claims abstract description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 11
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims description 13
- 150000002500 ions Chemical class 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- KYCQOKLOSUBEJK-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;bromide Chemical compound [Br-].CCCCN1C=C[N+](C)=C1 KYCQOKLOSUBEJK-UHFFFAOYSA-M 0.000 claims description 4
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 4
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- PRTXHLNVNLADCY-UHFFFAOYSA-N azanium;prop-2-enoic acid;chloride Chemical compound [NH4+].[Cl-].OC(=O)C=C PRTXHLNVNLADCY-UHFFFAOYSA-N 0.000 claims 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 9
- 238000011010 flushing procedure Methods 0.000 abstract description 3
- 229920001477 hydrophilic polymer Polymers 0.000 abstract description 3
- 239000002608 ionic liquid Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 125000002091 cationic group Chemical group 0.000 abstract description 2
- 239000000314 lubricant Substances 0.000 abstract description 2
- 230000007480 spreading Effects 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical group C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- -1 polydimethylsiloxane Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2h-imidazole Chemical class CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- UDABMXGGUSOLFT-UHFFFAOYSA-N benzene ethene prop-2-enoic acid Chemical group C=C.C(C=C)(=O)O.C1=CC=CC=C1 UDABMXGGUSOLFT-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
- C11D3/202—Monohydric alcohols branched fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of a daily chemical cleaning product, and specifically relates to a door and window glass cleaning agent and a preparation method thereof. The disclosed door and window glass cleaning agent comprises the following components, by mass percentage, 16-20% of a surfactant, 7-10% of fatty alcohol, 3-6% of cationic polymer, 1.5-3% of a water-soluble ionic liquid, 1.5-5% of an antifoaming agent, 1-3% of essence and 53-70% of water. Through addition of the cationic hydrophilic polymer, the hydrophilic performance of the glass surface can be improved, and the glass surface is given excellent waterdrop spreading performance, thereby providing the glass surface with a long-acting cleaning effect and flushing resistance. The water-soluble ionic liquid is taken as a lubricant and a slow-release component in the cleaning agent and has the function of protecting glass.
Description
Technical field
The invention belongs to daily use chemicals cleaning product technical field, and in particular to a kind of door glass abluent and its preparation side
Method.
Background technology
Glass has the advantages that smooth, transparent, hardness is high, reasonable price and be widely used in the doors such as building and automobile
On window.But glass surface is easily polluted by the dust of air, oil-containing impurity, not only have impact on transparency and aesthetic,
It is also possible to cause vehicle accident because affecting sight line.Therefore, keep glass surface cleaning significant.From the structure of glass
For upper, glass contains substantial amounts of silicon dioxide, is easily corroded by highly basic or organic solvent, causes rough surface.And glass
The flying dust on surface, oil stain are difficult to be cleaned up with traditional suds.Glass cleaner species on market is relatively more, and what is had makes
With phosphorus-containing compound, some use weak acid, corrosion is produced to other structures, contamination resistance is not strong after some cleanings.But it is existing
One technical barrier of glass cleaner is that glass cleaner easily forms in use the netted trace of new wire, strip
Mark, has had a strong impact on the attractive in appearance and transparency of glass.At present the main component of most commercial glass is SiO2, and SiO2Surface
Can carry certain negative charge in solution of the pH more than 4, thus the cationic polymer with positive charge in neutrallty condition and
Can be with active adsorption in glass surface, so as to change the physicochemical property of glass surface under alkalescence condition.
Chinese patent CN101821371B discloses the hard surface cleaner with extended residual cleaning benefit, described group
Compound includes hydrophilic polymer, at least one nonionic surfactant, at least one solvent, acid and water, although compositionss
Preferable hydrophilic remodeling effect is achieved to ceramic tile surface, but compositionss pH are below 3, although for soap scum and water
Dirt has preferable detergency, but can weaken the removal power to oils dirt at low ph values, may affect the bright of glass
Sense.
Chinese patent application CN104611147A discloses a kind of glass cleaner and preparation method thereof, by acrylic acid-benzene
Ethylene copolymer, surfactant, cosurfactant, solvent and deionized water composition, acrylic-styrene copolymer can be with
Glass surface formed one layer of shiny film, but due to the polymer it is not strong with the adhesion of glass surface so that it is this hydrophilic
Effect duration is limited, and does not possess the ability of water-fast flushing.Therefore in the urgent need to a kind of resistance to flushing of research and development and to glass
Door glass abluent with protective effect.
Prior art is solved the problems, such as, a kind of cleaning force of research and development is good and makes the glass after cleaning have the door of bright sense
Glass pane abluent is current top priority.
The content of the invention
To solve the bright sense of the impact glass that existing glass cleaner is present, the hydrophilic persistent period is short, do not possess water-fast
The problem of rinse capability, the present invention provides a kind of door glass abluent and preparation method thereof.
Door glass abluent of the present invention, including following components and its mass percent：
Surfactant 16~20%, fatty alcohol 7~10%, cationic polymer 3~6%, water soluble ion liquid 1.5
~3%, defoamer 1.5~5%, essence 1~3% and water 53~70%.
Preferably, described door glass abluent is made up of following components and its mass percent：
Surfactant 18%, fatty alcohol 8.5%, cationic polymer 4.5%, water soluble ion liquid 2.25%, disappear
Infusion 3.25%, essence 2% and water 61.5%.
Preferably, described surfactant is by OPEO and dodecylbenzene sodium sulfonate in mass ratio 3:
5 compositions.
Preferably, described fatty alcohol is by ethanol, isopropanol and glycerol in mass ratio 2:5:3 compositions.
Preferably, described cationic polymer is dimethyl diallyl ammonium chloride-acrylic acid copolymer.
Preferably, described water soluble ion liquid is 1-butyl-3-methylimidazolium bromide.
Preferably, described defoamer is polydimethylsiloxane.
In addition present invention also offers a kind of preparation method of door glass abluent, comprises the following steps：By cation
Polymer and water soluble ion liquid are added to the water, stirring and dissolving；Surfactant and fatty alcohol is added to stir；Stirring
Lower addition defoamer and essence, obtain final product.
OPEO CAS：9036-19-5；Dodecylbenzene sodium sulfonate CAS：25155-30-0；Diformazan
Base diallyl ammonium chloride-acrylic acid copolymer CAS：53694-17-0；1-butyl-3-methylimidazolium bromide CAS：
85100-77-2；Polydimethylsiloxane CAS：9016-00-6.
OPEO and dodecylbenzene sodium sulfonate make its solvable due to its special oleophylic and hydrophilic group
In organic solution and aqueous solution；The fatty alcohol being made up of ethanol, isopropanol and glycerol is due to its distinctive oh group and short alkane
Base chain makes it have good surface activity；Dimethyl diallyl ammonium chloride-acrylic acid copolymer is cationic polymer,
Can tively firm adsorb in glass surface, such that it is able to allow repeatedly to be rinsed with water, and give glass surface long-acting cleaning
Effect；The liquid brominated 1- butyl -3- Methylimidazole. favorable solubilities of water soluble ion, liquid state range width, the ionic liquid can
Protective film is formed on glass, rainwater assembles effect that protective glass is played when sliding on glass when raining；It is poly-
Dimethyl siloxane froth breaking is fast, suds effect is good, Diffusive Penetration is good, chemical stability is high.
Compatibility of the present invention is reasonable, science, and each component cooperates, synergism, is ensureing the invention glass cleaner
There is good cleaning performance while glass bright sense.
Compared with prior art, it is of the invention it is a technical advantage that：The hydrophilic polymer containing cationic is added, effectively
Improve the hydrophilicity of glass surface, give glass surface good water droplet spreading property, it is long-acting clear so as to provide glass surface
Clean effect and resistance to rinse capability water soluble ion liquid play protective glass as the gentle decorations component of lubricant in abluent
Effect.
Specific embodiment
The present invention is described in further details below by specific embodiment, these embodiments are only used for the mesh of illustration
, it is in no way intended to limit protection scope of the present invention.
Embodiment 1-3, comparative example 1-2
Table 1 lists the component and mass percent of embodiment of the present invention 1-3 and comparative example 1-2.
The component and mass percent of the embodiment of table 1 and comparative example glass cleaner
Comparative example 1 is with the difference of embodiment 2：Without water soluble ion liquid, increase the content of surfactant.
Comparative example 2 is with the difference of embodiment 2：Cation-containing copolymer, does not increase the content of surfactant.
The preparation method of the door glass abluent of embodiment 2：Cationic polymer and water soluble ion liquid are added to
In water, stirring and dissolving；Surfactant and fatty alcohol is added to stir；Stirring is lower to add defoamer and essence, obtains final product.
The preparation method of the door glass abluent of embodiment 1, embodiment 3 and comparative example 1-2 is similar to Example 2.
Properties of product evaluation test
Glass cleaning experiment is carried out to the door glass abluent of above example 1-3 and comparative example 1-2,2 are the results are shown in Table.
The cleaning performance of the embodiment of table 2 and comparative example door glass abluent
As can be seen from the above data, the glass cleaner of embodiment 1-3 that the present invention is provided can be very compared with comparative example 1-2
The washing of oil stain on glass surface is carried out well, it is corrosion-free without miscellaneous point, glass surface after continuously using and washing 100 times.
Explanation：(1) test specimen cleaning forefathers are by putting naturally after upper finger-marks 10 days；(2) apparent condition after test specimen cleaning
It is to estimate under 80 times of optical microscopes；(3) lattice of ink hundred experiment is continuous under 60oC*95% damp conditions after test specimen cleaning
After carrying out hot and humid experiment 240 hours, according to《The scratch experiment of GB/T9286-1998 paint and varnish paint films》Carry out.
The above is only the preferred embodiment of the present invention, it is noted that it is right that above-mentioned preferred implementation is not construed as
The restriction of the present invention, protection scope of the present invention should be defined by claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change
Enter and retouch also to should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of door glass abluent, it is characterised in that including following components and its mass percent：
Surfactant 16~20%, fatty alcohol 7~10%, cationic polymer 3~6%, water soluble ion liquid 1.5~
3%th, defoamer 1.5~5%, essence 1~3% and water 53~70%.
2. door glass abluent according to claim 1, it is characterised in that by following components and its mass percent group
Into：
Surfactant 18%, fatty alcohol 8.5%, cationic polymer 4.5%, water soluble ion liquid 2.25%, defoamer
3.25%th, essence 2% and water 61.5%.
3. door glass abluent according to claim 1 and 2, it is characterised in that described surfactant is by octyl group
Phenol polyethenoxy ether and dodecylbenzene sodium sulfonate in mass ratio 3:5 compositions.
4. door glass abluent according to claim 1 and 2, it is characterised in that described fatty alcohol is by ethanol, isopropyl
Alcohol and glycerol in mass ratio 2:5:3 compositions.
5. door glass abluent according to claim 1 and 2, it is characterised in that described cationic polymer is two
Methyl diallyl ammonium chloride-acrylic acid copolymer.
6. door glass abluent according to claim 1 and 2, it is characterised in that described water soluble ion liquid is
1-butyl-3-methylimidazolium bromide.
7. door glass abluent according to claim 1 and 2, it is characterised in that described defoamer is poly dimethyl
Siloxanes.
8. the preparation method of the door glass abluent according to any one of claim 1-7, it is characterised in that including following
Step：Cationic polymer and water soluble ion liquid are added to the water, stirring and dissolving；Add surfactant and fatty alcohol
Stir；Stirring is lower to add defoamer and essence, obtains final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210782.7A CN106675823A (en) | 2016-12-24 | 2016-12-24 | Door and window glass cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210782.7A CN106675823A (en) | 2016-12-24 | 2016-12-24 | Door and window glass cleaning agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106675823A true CN106675823A (en) | 2017-05-17 |
Family
ID=58871501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611210782.7A Pending CN106675823A (en) | 2016-12-24 | 2016-12-24 | Door and window glass cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106675823A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108300580A (en) * | 2018-02-05 | 2018-07-20 | 安阳工学院 | A kind of low freezing point automatically cleaning vehicle glass water |
| CN110194597A (en) * | 2019-06-24 | 2019-09-03 | 浙江跃维新材料科技有限公司 | A kind of hydrophily antirain agent and preparation method thereof and antirain agent coating production |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1662638A (en) * | 2002-06-28 | 2005-08-31 | 宝洁公司 | Ionic liquid based products and method of using the same |
| CN101821371A (en) * | 2007-08-14 | 2010-09-01 | S.C.约翰逊父子公司 | Hard surface cleaner with extended residual cleaning benefit |
| CN102181326A (en) * | 2011-04-01 | 2011-09-14 | 中国铁道科学研究院金属及化学研究所 | Glass cleaner and application thereof |
| CN104342298A (en) * | 2014-10-26 | 2015-02-11 | 青岛智谷创新技术有限公司 | Efficient glass cleaning fluid |
| CN104560429A (en) * | 2014-12-18 | 2015-04-29 | 无锡伊诺永利文化创意有限公司 | Door and window glass cleaning agent and preparation method thereof |
| CN105176716A (en) * | 2015-09-10 | 2015-12-23 | 安徽网动车簇汽车清洁服务有限公司 | Environment-friendly automotive windshield water |
-
2016
- 2016-12-24 CN CN201611210782.7A patent/CN106675823A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1662638A (en) * | 2002-06-28 | 2005-08-31 | 宝洁公司 | Ionic liquid based products and method of using the same |
| CN101821371A (en) * | 2007-08-14 | 2010-09-01 | S.C.约翰逊父子公司 | Hard surface cleaner with extended residual cleaning benefit |
| CN102181326A (en) * | 2011-04-01 | 2011-09-14 | 中国铁道科学研究院金属及化学研究所 | Glass cleaner and application thereof |
| CN104342298A (en) * | 2014-10-26 | 2015-02-11 | 青岛智谷创新技术有限公司 | Efficient glass cleaning fluid |
| CN104560429A (en) * | 2014-12-18 | 2015-04-29 | 无锡伊诺永利文化创意有限公司 | Door and window glass cleaning agent and preparation method thereof |
| CN105176716A (en) * | 2015-09-10 | 2015-12-23 | 安徽网动车簇汽车清洁服务有限公司 | Environment-friendly automotive windshield water |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108300580A (en) * | 2018-02-05 | 2018-07-20 | 安阳工学院 | A kind of low freezing point automatically cleaning vehicle glass water |
| CN110194597A (en) * | 2019-06-24 | 2019-09-03 | 浙江跃维新材料科技有限公司 | A kind of hydrophily antirain agent and preparation method thereof and antirain agent coating production |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101798550B (en) | Anti-static automobile glass cleaning agent | |
| CN117925329A (en) | Concentrated anti-fog glass cleaning agent | |
| CN103849509A (en) | Glass cleaning agent and preparation method thereof | |
| CN103666830A (en) | Freezing point adjustable glass cleaning agent, as well as preparation and application thereof | |
| CN104651074A (en) | Automobile glass cleaning agent | |
| KR20170129184A (en) | Compositions suitable for protection, including copolymers and hydrophilic silanes | |
| JP4840899B2 (en) | Hydrophilic antifouling coating composition, film forming method using the same and use thereof | |
| CN104130871A (en) | Summer automotive wind-shield cleaning composition and preparation method thereof | |
| CN106675823A (en) | Door and window glass cleaning agent and preparation method thereof | |
| CN109777291B (en) | Self-cleaning glass hydrophobing agent | |
| US10808209B2 (en) | Formulations for applying a hydrophobic film to a substrate | |
| CN107760482A (en) | A kind of environment protection type automobile wind screen efficient cleaner and its preparation technology | |
| CN104212655A (en) | Automotive glass cleaner | |
| WO2014025654A1 (en) | Moisture absorbing anti-fog composition and process for the use thereof | |
| KR100527924B1 (en) | A composition of cleaning solution for wind shield glass | |
| CN111393926A (en) | Water-based coating liquid | |
| CN103614251A (en) | Automobile glass detergent for removing stubborn dirt | |
| CN107955762A (en) | A kind of vehicle window wash liquid | |
| CN113214917A (en) | Anti-freezing automobile glass cleaning agent and preparation method thereof | |
| JP2001115151A (en) | One-part aqueous water-repellent agent, two-part aqueous water-repellent agent, and method for water- repellent treatment of inorganic surface | |
| CN113046197A (en) | Glass cleaning fluid and preparation method and application thereof | |
| CN109207279A (en) | A kind of antifog antifreeze detergent of vehicle glass | |
| US9394506B2 (en) | Cleaning composition for hard surfaces | |
| CN103865698A (en) | Multi-surface cleaning agent | |
| KR20040090674A (en) | Composition of cleaning solution for wind shield glass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170517 |
|
| WD01 | Invention patent application deemed withdrawn after publication |