CN106675414A - Environment-friendly type water-soluble gloss oil and preparation method thereof - Google Patents

Environment-friendly type water-soluble gloss oil and preparation method thereof Download PDF

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Publication number
CN106675414A
CN106675414A CN201611256127.5A CN201611256127A CN106675414A CN 106675414 A CN106675414 A CN 106675414A CN 201611256127 A CN201611256127 A CN 201611256127A CN 106675414 A CN106675414 A CN 106675414A
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CN
China
Prior art keywords
water
gloss oil
environment
emulsion
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611256127.5A
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Chinese (zh)
Inventor
韩中秋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huiyuan Printing & Packaging Technology (tianjin) Ltd By Share Ltd
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Huiyuan Printing & Packaging Technology (tianjin) Ltd By Share Ltd
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Application filed by Huiyuan Printing & Packaging Technology (tianjin) Ltd By Share Ltd filed Critical Huiyuan Printing & Packaging Technology (tianjin) Ltd By Share Ltd
Priority to CN201611256127.5A priority Critical patent/CN106675414A/en
Publication of CN106675414A publication Critical patent/CN106675414A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Paper (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses environment-friendly type water-soluble gloss oil, which is prepared from the following components in percentage by mass: 13-18% of water-soluble acrylic resin liquid (35% solid content), 35-38% of non-film forming emulsion, 33-37% of film forming emulsion, 3-6% of wax emulsion, 0.5-1% of wetting agent, 0.08-0.12% of defoaming agent, 0.08-0.1% of slipping and abrasion-resistant agent and the balance of water. According to the environment-friendly type water-soluble gloss oil disclosed by the invention, the respective components are mixed according to a certain proportion to form homogenic water-soluble gloss oil; as ethanol is not added, irritating odor is reduced, human health of an operator is ensured, energy source is saved, and cost is lowered; and coated gloss oil can effectively protect patterns or characters in a presswork, and can enable good smoothness and waterproofness as well as excellent abrasion resistance of a surface of the presswork.

Description

A kind of environment-friendly water-soluble gloss oil and preparation method thereof
Technical field
The present invention relates to the gloss oil technical field in paper printing, especially a kind of environment-friendly water-soluble gloss oil and its preparation Method.
Background technology
Printing is, through operations such as plate-making, Shi Mo, pressurizations, to make printing ink transfer to the surface of paper by original copys such as word, pictures On, common form is including tradition offset printing, silk-screen printing and digital printing etc..Books, packaging in people's daily life etc. are passed through Four-color press printing after form semi-finished product, these semi-finished product also need to carry out the operation of oil polish, will semi-finished product be put into In light oil machine, the transfer roller of glazing oil machine is uniformly brushed gloss oil in surface of semi-finished, then by finished product after drying.
The gloss oil used in said process based on resin gloss oil, with alcohol as solvent, substantially by 1:1 ratio is mixed After be obtained, the effect of the gloss oil is:1. prevent the ink of printed matter surface from fading;2. the surface of printed matter is kept to keep smooth, Waterproof;3. wearing layer is formed, ink is protected.Because alcoholic taste is dense, and belong to volatile, incendive dangerous material, make Excitant is stronger during with the gloss oil, is unfavorable for that operating personnel's is healthy, also creates potential safety hazard, at the same it is relatively costly, Waste the energy.
The content of the invention
For above-mentioned problem, it is an object of the invention to provide a kind of environment-friendly water-soluble gloss oil and its preparation side Method.
The technical scheme is that:A kind of environment-friendly water-soluble gloss oil, according to mass fraction meter, is formulated as follows:It is water-soluble Property acrylic resin liquid (35% contains admittedly) 13-18%, not filming emulsion 35-38%, filming emulsion 33-37%, wax emulsion 3- 6%, wetting agent 0.5-1%, defoamer 0.08-0.12%, smooth anti-wear agent 0.08-0.1%, remaining is water.
Further, according to mass fraction meter, formula is preferably:Water soluble acrylic resin's liquid (35% contains admittedly) 15%, Not filming emulsion 38%, filming emulsion 35%, wax emulsion 5%, wetting agent 0.5%, defoamer 0.1%, smooth anti-wear agent 0.1%, remaining is water.
Further, the wax emulsion is using any one in polythene wax emulsion, polypropylene wax wax emulsion and paraffin.
Further, the wax emulsion is preferably polythene wax emulsion, the ME 91240, Keim of model Mai Kemen MD2000 or D-816.
Further, the wetting agent uses Greesol A04PA.
Further, the defoamer uses Greesol DF85.
Further, the smooth anti-wear agent uses Greesol LE6.
A kind of preparation method of environment-friendly type water solution gloss oil, by water soluble acrylic resin's liquid (35% contains admittedly), not film forming Emulsion, filming emulsion, wax emulsion, wetting agent, defoamer, smooth anti-wear agent and water are mixed, and are finished product after mixing.
Compared with prior art, the beneficial effects of the invention are as follows:In the present invention, each component is mutual by certain proportion relation Mixing, forms the water-based gloss oil of homogeneous, without addition ethanol, reduces penetrating odor, it is ensured that the body of operating personnel is good for Health, has saved the energy, reduces cost, and the gloss oil for coating can effectively protect the pattern or word on printed matter, make print The smoothness and water resistance on brush product surface are fine, and anti-wear performance is excellent.
Specific embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment 1
A kind of environment-friendly water-soluble gloss oil, according to mass fraction meter, is formulated as follows:Water soluble acrylic resin's liquid (35% Gu contain) 13%, not filming emulsion 38%, filming emulsion 33%, wax emulsion 3%, wetting agent 0.5%, defoamer 0.12% is smooth Anti-wear agent 0.1%, remaining is water.
Wax emulsion uses polypropylene wax wax emulsion.
Wetting agent uses Greesol A04PA.
Defoamer uses Greesol DF85.
Smooth anti-wear agent uses Greesol LE6.
A kind of preparation method of environment-friendly type water solution gloss oil, by water soluble acrylic resin's liquid (35% contains admittedly), not film forming Emulsion, filming emulsion, wax emulsion, wetting agent, defoamer, smooth anti-wear agent and water are mixed, and are finished product after mixing.
From paper:Packing case outer surface paster;
The printing of pattern, word is carried out by normal process;
Above-mentioned finished product is added in glazing oil machine, by smearing, homogeneous light oil reservoir is formed in paper surface after drying.
The test data of the paper:
1. the different parts section for choosing paper is separately mounted on wear-resisting test machine, under the conditions of certain pressure, averagely Reciprocating friction does not fall the effect of ink for 30~50 times.
2. the different parts for choosing paper carry out water test, are not within more than 10 seconds the phenomenon soaked.
Embodiment 2
A kind of environment-friendly water-soluble gloss oil, according to mass fraction meter, is formulated as follows:Water soluble acrylic resin's liquid (35% Gu contain) 18%, not filming emulsion 35%, filming emulsion 37%, wax emulsion 6%, wetting agent 1%, defoamer 0.08% is smooth resistance to Grinding agent 0.08%, remaining is water.
Wax emulsion uses polythene wax emulsion, the ME 91240 of model Mai Kemen.
Wetting agent uses Greesol A04PA.
Defoamer uses Greesol DF85.
Smooth anti-wear agent uses Greesol LE6.
A kind of preparation method of environment-friendly type water solution gloss oil, by water soluble acrylic resin's liquid (35% contains admittedly), not film forming Emulsion, filming emulsion, wax emulsion, wetting agent, defoamer, smooth anti-wear agent and water are mixed, and are finished product after mixing.
From paper:Packing case outer surface paster;
The printing of pattern, word is carried out by normal process;
Above-mentioned finished product is added in glazing oil machine, by smearing, homogeneous light oil reservoir is formed in paper surface after drying.
The test data of the paper:
1. the different parts section for choosing paper is separately mounted on wear-resisting test machine, under the conditions of certain pressure, averagely Reciprocating friction does not fall the effect of ink for 30~50 times.
2. the different parts for choosing paper carry out water test, are not within more than 10 seconds the phenomenon soaked.
Embodiment 3
A kind of environment-friendly water-soluble gloss oil, according to mass fraction meter, is formulated as follows:Water soluble acrylic resin's liquid (35% Gu contain) 15%, not filming emulsion 38%, filming emulsion 35%, wax emulsion 5%, wetting agent 0.5%, defoamer 0.1% is smooth Anti-wear agent 0.1%, remaining is water.
Wax emulsion uses polythene wax emulsion, the Keim MD2000 of model Mai Kemen.
Wetting agent uses Greesol A04PA.
Defoamer uses Greesol DF85.
Smooth anti-wear agent uses Greesol LE6.
A kind of preparation method of environment-friendly type water solution gloss oil, by water soluble acrylic resin's liquid (35% contains admittedly), not film forming Emulsion, filming emulsion, wax emulsion, wetting agent, defoamer, smooth anti-wear agent and water are mixed, and are finished product after mixing.
From paper:Packing case outer surface paster;
The printing of pattern, word is carried out by normal process;
Above-mentioned finished product is added in glazing oil machine, by smearing, homogeneous light oil reservoir is formed in paper surface after drying.
The test data of the paper:
1. the different parts section for choosing paper is separately mounted on wear-resisting test machine, under the conditions of certain pressure, averagely Reciprocating friction does not fall the effect of ink for 30~50 times.
2. the different parts for choosing paper carry out water test, are not within more than 10 seconds the phenomenon soaked.
Water soluble acrylic resin's liquid can help levelling in formula, improve gloss and solubility, but water soluble propene The addition of acid resin liquid is excessive, and adhesive force can be caused to decline, and influences rate of drying and water resistance.So can not be in order to improve gloss And the unconfined aqueous soluble resin liquid of addition.
Wax emulsion kind is very more, and that is commonly used in oil polish has the products such as Tissuemat E, polypropylene wax, paraffin.Poly- second Alkene wax emulsion is due to softening point high, and anti-wear performance is excellent.If oil polish requirement high glaze high transparency can be selected Carymul 7605, high-wearing feature can select the ME 91240 of Mai Kemen, Keim MD2000, D-816,
The selection of wetting agent is very crucial, low especially for winter temperature, on the thick printed matter of layer of ink during light, if profit Humectant addition is improper, it may appear that water ripples, pit, the surface defect such as levelling is not good, at this moment can select Greesol A04PA, The multi-functional wetting agents of F04, can solve the problems, such as that most surface defects and contracting ring produce bubble.
Smooth anti-wear agent provides wearability in formula together with wax emulsion, and with very smooth feel and improves anti- Viscosity.But addition excessively may bring harmful effect, such as bad phenomenon of thermoprint to print post processing.
With above-mentioned according to desirable embodiment of the invention as enlightenment, by above-mentioned description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.

Claims (8)

1. a kind of environment-friendly water-soluble gloss oil, it is characterised in that according to mass fraction meter, is formulated as follows:Water-soluble acrylic tree Fat liquid (35% contains admittedly) 13-18%, not filming emulsion 35-38%, filming emulsion 33-37%, wax emulsion 3-6%, wetting agent 0.5-1%, defoamer 0.08-0.12%, smooth anti-wear agent 0.08-0.1%, remaining is water.
2. a kind of environment-friendly water-soluble gloss oil according to claim 1, it is characterised in that according to mass fraction meter, formula Preferably:Water soluble acrylic resin's liquid (35% contains admittedly) 15%, not filming emulsion 38%, filming emulsion 35%, wax emulsion 5%, wetting agent 0.5%, defoamer 0.1%, smooth anti-wear agent 0.1%, remaining is water.
3. a kind of environment-friendly water-soluble gloss oil according to claim 1 and 2, it is characterised in that the wax emulsion is using poly- Any one in ethene wax emulsion, polypropylene wax wax emulsion and paraffin.
4. a kind of environment-friendly water-soluble gloss oil according to claim 1 and 2, it is characterised in that the wetting agent is used Greesol A04PA。
5. a kind of environment-friendly water-soluble gloss oil according to claim 1 and 2, it is characterised in that the defoamer is used Greesol DF85。
6. a kind of environment-friendly water-soluble gloss oil according to claim 1 and 2, it is characterised in that the smooth anti-wear agent is adopted Use Greesol LE6.
7. a kind of environment-friendly water-soluble gloss oil according to claim 3, it is characterised in that the wax emulsion is preferably poly- second Alkene wax emulsion, the ME 91240 of model Mai Kemen, Keim MD2000 or D-816.
8. a kind of preparation method of any one of environment-friendly type water solution gloss oil in claim 1-7, its feature Be, by water soluble acrylic resin's liquid (35% contains admittedly), not filming emulsion, filming emulsion, wax emulsion, wetting agent, defoamer, Smooth anti-wear agent and water are mixed, and are finished product after mixing.
CN201611256127.5A 2016-12-30 2016-12-30 Environment-friendly type water-soluble gloss oil and preparation method thereof Pending CN106675414A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611256127.5A CN106675414A (en) 2016-12-30 2016-12-30 Environment-friendly type water-soluble gloss oil and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611256127.5A CN106675414A (en) 2016-12-30 2016-12-30 Environment-friendly type water-soluble gloss oil and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106675414A true CN106675414A (en) 2017-05-17

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111187573A (en) * 2020-02-21 2020-05-22 梁文波 Playing card gloss oil and preparation method thereof
CN112095363A (en) * 2019-11-04 2020-12-18 上海映通印刷包装有限公司 Paper special for mark pen drawing
CN114922000A (en) * 2022-06-17 2022-08-19 南京百聚科技有限公司 Paper coating water-based varnish and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112095363A (en) * 2019-11-04 2020-12-18 上海映通印刷包装有限公司 Paper special for mark pen drawing
CN111187573A (en) * 2020-02-21 2020-05-22 梁文波 Playing card gloss oil and preparation method thereof
CN114922000A (en) * 2022-06-17 2022-08-19 南京百聚科技有限公司 Paper coating water-based varnish and preparation method thereof

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Application publication date: 20170517

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