CN106675222A - Oil paint composition and painted piece - Google Patents
Oil paint composition and painted piece Download PDFInfo
- Publication number
- CN106675222A CN106675222A CN201611271156.9A CN201611271156A CN106675222A CN 106675222 A CN106675222 A CN 106675222A CN 201611271156 A CN201611271156 A CN 201611271156A CN 106675222 A CN106675222 A CN 106675222A
- Authority
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- Prior art keywords
- parts
- paint composite
- paint
- silicon dioxide
- dioxide gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D115/00—Coating compositions based on rubber derivatives
- C09D115/02—Rubber derivatives containing halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides an oil paint composition and a painted piece. The oil paint composition contains resin, a silicon dioxide sol rubber, zirconium oxide and an organic solvent. The invention also provides a painted piece for the oil paint composition to paint. The oil paint composition provided by the invention forms an oil paint layer with high temperature resistance, high scratch resistance and high hardness on the surface of a base material.
Description
Technical field
The present invention relates to technical field of electronic device, more particularly to a kind of paint composite and using the paint composite
Painted piece.
Background technology
The surface-coated paint composite in electronic installations such as mobile phones is generally needed, in mobile phone surface skin of paint is formed, with
Improve the aesthetic feeling of mobile phone, and the service life of extending cell phone.However, existing paint non-refractory, not scratch resistant.Cause coating
In mobile phone surface skin of paint also non-refractory, easily there is scratch.
The content of the invention
Present invention is primarily targeted at providing a kind of paint composite, it is desirable to provide a kind of high temperature resistant, the oil of scratch resistant
Coating compositions.
For achieving the above object, the present invention provide paint composite contain have resin, silicon dioxide gel, zirconium oxide,
And organic solvent.
Preferably, the resin includes epoxy resin and amino resins.
Preferably, by weight, the paint composite includes：0.8~4 part of amino resins, 2~11 parts of epoxy resin,
2~10 parts of 30~60 parts of silicon dioxide gel, 5~15 parts of zirconium oxide and organic solvent.
Preferably, by weight, the paint composite also includes：2~8 parts of mica powder, 0.05~0.6 part of white carbon black.
Preferably, the paint composite also includes fluorinated modified nitrile rubber, by weight, the paint composite
In, the fluorinated modified nitrile rubber is 5~15 parts.
Preferably, the paint composite also includes organosiloxane, by weight, described in the paint composite
Organosiloxane is 10~40 parts.
Preferably, the paint composite also includes organic acid, smooth agent and filler, by weight, the coating compositions
In thing, the organic acid is 0.5~3 part, the smooth agent is 3~9 parts, described filler is 4~14 parts.
Preferably, the silicon dioxide gel is silane coupler modified silicon dioxide gel.
The present invention also provides a kind of painted piece, and it includes base material and is formed at the skin of paint of substrate surface, and the skin of paint contains
There are resin, silicon dioxide gel and zirconium oxide.
Preferably, the painted piece is the housing of electronic installation.
Compared with prior art, the present invention has the advantages that：The paint composite of the present invention contains resin, dioxy
SiClx colloidal sol, zirconium oxide and organic solvent, the silicon dioxide gel and resin have preferably film forming characteristicss so that described
Paint composite can be in the good skin of paint of the surface forming properties of matrix；The zirconium oxide can increase the hard of the skin of paint
Degree, meanwhile, can make the skin of paint that there is preferably thermostability and stability.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement
Example a part of embodiment only of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, this area is general
The every other embodiment that logical technical staff is obtained under the premise of creative work is not made, belongs to present invention protection
Scope.
In addition, the technical scheme between each embodiment can be combined with each other, but must be with ordinary skill
Personnel can be implemented as basis, when the combination appearance of technical scheme is conflicting or cannot realize it will be understood that this technical side
The combination of case is not present, also not within the protection domain of application claims.
The present invention provides a kind of paint composite.
Paint composite described in the paint composite contains resin, silicon dioxide gel, zirconium oxide and organic solvent.
The organosiloxane is dimethyl siloxane, hexamethyl siloxane or octamethylcy-clotetrasiloxane etc..
The organic solvent can be polar organic solvent, and the polar organic solvent can be lower alcohols solvent.It is described low
At least one of the level alcohols solvent in ethanol, normal propyl alcohol and isopropyl keto-alcohol.
The paint composite of technical solution of the present invention contain resin, silicon dioxide gel, zirconium oxide, organosiloxane and
Organic solvent, the silicon dioxide gel and resin have preferably film forming characteristicss so that the paint composite can be in matrix
The good skin of paint of surface forming properties；The zirconium oxide can increase the hardness of the skin of paint, meanwhile, the paint can be made
Layer has preferably thermostability and stability.The each component of the paint composite dissolves in or is scattered in the organic solvent
In, so that each component mix homogeneously of the paint composite.
The resin includes epoxy resin and amino resins.
The epoxy resin refers to the organic compound containing two or more epoxide groups in molecule.The asphalt mixtures modified by epoxy resin
Fat can be bicyclic for phenolic group propane epoxy resin, phenolphthalein epoxy resin, four phenolic group epoxy resin, resorcinol type epoxy, oxidation
Amyl group ether resin or bicyclopentadiene dioxide expoxy resin etc..
The amino resins can be Lauxite (UF), melamine resin (MF) or polyamide polyamines epoxy chloropropionate
Alkane (PAE) etc..
The resin of technical solution of the present invention includes epoxy resin and amino resins, the epoxy resin and the amino resins
The skin of paint of high rigidity can be formed.
By weight, the paint composite includes：0.8~4 part of amino resins, 2~11 parts of epoxy resin, silicon dioxide
2~10 parts of 30~60 parts of colloidal sol, 5~15 parts of zirconium oxide and organic solvent
By weight, the paint composite of technical solution of the present invention contains 10~20 parts of saturated polyester resin, epoxy resin 1
~5 parts, 30~60 parts of silicon dioxide gel, 5~15 parts of zirconium oxide and organic solvent are 2~10 parts, by the proportions
When paint composite coats to form skin of paint, the skin of paint can be after high temperature resistant, scratch resistant, and inversion temperature environment, such as by height
Warm context conversion is low temperature environment or is converted to hot environment by low temperature environment, and the property retention temperature of the skin of paint still may be used
High temperature resistant, scratch resistant.
By weight, the paint composite also includes：2~8 parts of mica powder, 0.05~0.6 part of white carbon black.
The mica powder characteristic such as have good elasticity, toughness, insulating properties, high temperature resistant, acid and alkali-resistance, corrosion-resistant, adhesive force strong.
The white carbon black can make paint composite have preferably weatherability and stability.
By weight, the paint composite of technical solution of the present invention contains 2~8 parts of mica powder, 0.05~0.6 part of white carbon black,
The mica powder and the white carbon black can make the paint composite have preferably weatherability, stability, insulating properties, high temperature resistant,
The characteristic such as acid and alkali-resistance, corrosion-resistant, adhesive force is strong.
In the paint composite, the paint composite also contains fluorinated modified nitrile rubber, by weight, the fluorine
It is 5~15 parts to change modified butadiene acrylonitrile rubber.
The paint composite of technical solution of the present invention also contains fluorinated modified nitrile rubber, the fluorinated modified nitrile rubber
The coating compositions film can be made to be formed after skin of paint by coating, skin of paint has preferably lubricity and toughness, is that user carries
For preferably feel.
The paint composite also includes organosiloxane, by weight, in the paint composite, organic silica
Alkane is 10~40 parts.
The paint composite of technical solution of the present invention also contains organosiloxane, and the organosiloxane can make the paint
Combined films are formed after skin of paint by coating, and skin of paint has ceramic outward appearance.
The paint composite also contains organic acid, and by weight, in the paint composite, the organic acid is 0.5
~3 parts.
The organic acid can be acetic acid.
Technical solution of the present invention also contains organic acid, and the organic acid can provide preferably texture for the skin of paint.
The paint composite also contains smooth agent, and by weight, in the paint composite, the smooth agent is 3~9
Part.
The smooth agent can be aluminium hydroxide or calcium stearate.
The paint composite of technical solution of the present invention also contains smooth agent, and it is flat that the smooth agent has can the skin of paint
Sliding outward appearance.
The paint composite also contains 4~14 parts of fillers.Described filler includes optical brightener, color tablets and Pulvis Talci, by weight
Amount part, in the paint composite, the optical brightener is 2~4 parts, and the color tablets are 1~5 part, and the Pulvis Talci is 1~5 part.
The paint composite of technical solution of the present invention also contains filler, and described filler includes optical brightener, color tablets and Pulvis Talci,
The Pulvis Talci can increase the stability of skin of paint, tensile strength, shear strength, flexing intensity, the intensity of pressure, reduce deformation,
Extension rate, thermal coefficient of expansion, whiteness are high, epigranular dispersibility is strong etc.；The color tablets can be aluminium oxide or other applicable face
Material, can make the skin of paint have color；The optical brightener can be barite, can increase the brightness of the skin of paint.
The silicon dioxide gel is silane coupler modified silicon dioxide gel.
The silicon dioxide gel of technical solution of the present invention is silane coupler modified silicon dioxide gel, compared to dioxy
SiClx colloidal sol, the silane coupler modified silicon dioxide gel has preferably filming performance.
The silane coupler modified silicon dioxide gel is silane coupler to be added to pending silicon dioxide
It is obtained in colloidal sol, by weight, the silane coupler is 10~25 parts, and the silicon dioxide gel is 40~65 parts.
Specifically, the preparation method of the silane coupler modified silicon dioxide gel is：
40~65 parts pending of silicon dioxide gel is provided, the pending silicon dioxide gel contains quality percentage
Than the silicon dioxide that content is 30~50%；
10~25 parts of silane coupler is provided；
Lower alcohols solvent 5-15 parts, 30~40 parts of water are provided；
Mix the pending silicon dioxide gel, silane coupler, lower alcohols solvent and water, temperature be 30~
35 DEG C, pH be 4.0~4.5 under conditions of, react 4.0~6.5 hours be obtained.
The silane coupler is the oxygen methyl-monosilane of methyl three, vinyl three (2- methoxy ethoxy) silane, 3- front threes
TMOS propyl acrylate, 3- urea propyl trimethoxy silicanes, allyltriethoxysilane, dimethyldiacetoxy silicon
Alkane, vinyltrimethoxy silane, methyl vinyl diethoxysilane, 3- (methacryloxypropyl) propyl trimethoxy silicon
Alkane or allyltrimethoxysilanis.
The preparation method of the silane coupler modified silicon dioxide gel of technical solution of the present invention is simple, the silane idol
The modified silicon dioxide gel of connection agent can make the skin of paint have preferably filming performance.
Embodiment one：
By weight, the paint composite contains：
0.8 part of amino resins,
2 parts of epoxy resin,
2 parts of mica powder,
0.05 part of white carbon black,
Silane coupler modified 30 parts of silicon dioxide gel,
5 parts of zirconium oxide,
10 parts of organosiloxane,
Organic solvent be 2 parts,
5 parts of fluorinated modified nitrile rubber
0.5 part of organic acid
3 parts of smooth agent
2 parts of optical brightener,
Color tablets are 1 part,
Pulvis Talci is 1 part
The preparation method of the silane coupler modified silicon dioxide gel is：
40 parts pending of silicon dioxide gel is provided, the pending silicon dioxide gel contains mass percent and contains
Measure the silicon dioxide for 30%；
10 parts of silane coupler is provided；
5 parts of lower alcohols solvent, 30 parts of water are provided；
Mix the pending silicon dioxide gel, silane coupler, lower alcohols solvent and water, be 30 in temperature
DEG C, pH be 4.0 under conditions of, react 4.0 hours be obtained.
Embodiment two：
By weight, the paint composite contains：
4 parts of amino resins,
11 parts of epoxy resin,
8 parts of mica powder,
0.6 part of white carbon black,
Silane coupler modified 60 parts of silicon dioxide gel,
15 parts of zirconium oxide,
40 parts of organosiloxane,
10 parts of organic solvent,
15 parts of fluorinated modified nitrile rubber
3 parts of organic acid
9 parts of smooth agent
4 parts of optical brightener,
5 parts of color tablets,
5 parts of Pulvis Talci
The preparation method of the silane coupler modified silicon dioxide gel is：
65 parts pending of silicon dioxide gel is provided, the pending silicon dioxide gel contains mass percent and contains
Measure the silicon dioxide for 50%；
25 parts of silane coupler is provided；
15 parts of lower alcohols solvent, 40 parts of water are provided；
Mix the pending silicon dioxide gel, silane coupler, lower alcohols solvent and water, be 35 in temperature
DEG C, pH be 4.5 under conditions of, react 6.5 hours be obtained.
Embodiment three：
By weight, the paint composite contains：
2 parts of amino resins,
7 parts of epoxy resin,
5 parts of mica powder,
0.3 part of white carbon black,
Silane coupler modified 40 parts of silicon dioxide gel,
10 parts of zirconium oxide,
25 parts of organosiloxane,
6 parts of organic solvent,
10 parts of fluorinated modified nitrile rubber
2 parts of organic acid
5 parts of smooth agent
3 parts of optical brightener,
2 parts of color tablets,
3 parts of Pulvis Talci
The preparation method of the silane coupler modified silicon dioxide gel is：
50 parts pending of silicon dioxide gel is provided, the pending silicon dioxide gel contains mass percent and contains
Measure the silicon dioxide for 40%；
15 parts of silane coupler is provided；
10 parts of lower alcohols solvent, 35 parts of water are provided；
Mix the pending silicon dioxide gel, silane coupler, lower alcohols solvent and water, be 32 in temperature
DEG C, pH be 4.2 under conditions of, react 5 hours be obtained.
The present invention also provides a kind of painted piece (not shown) being coated using the paint composite, and it includes base material
And the skin of paint of substrate surface is formed at, the skin of paint contains resin, silicon dioxide gel, zirconium oxide, organosiloxane and has
Machine solvent.The thickness of the skin of paint can be 15~40 microns.
It should be understood that can also form described on the prime coat after the surface-coated prime coat of the base material
Skin of paint；Also directly the skin of paint can be formed in the surface of the base material.
It should be understood that the painted piece can be used as the housing of electronic installation.The electronic installation can be mobile phone, notebook
Computer, panel computer etc..
Painted piece damage resistant, non-scale, the difficult for drop-off, high temperature resistant of the present invention.
The hardness of the painted piece of the present invention is not less than 6H.
To the present invention painted piece carry out salt spray test, as a result show it is described paint layer surface without discoloration, peeling, come off,
The phenomenon such as colour fading and corrosion.Adhesive force and wear-resisting test should meet the requirements.
Steel ball shock-testing is carried out to the painted piece of the present invention, as a result shows that the painted piece is existing without flaking and cracking
As.
Steel wire lump test is carried out to the painted piece of the present invention, as a result shows that the paint layer surface is scratched without scuffing, nothing.
Heatproof test is carried out to the painted piece of the present invention, as a result show the painting layer without coming off, flawless, without change
Color etc. is abnormal.
The preparation method of the paint composite is：
10~20 parts of saturated polyester resin is provided, the preparation method of the saturated polyester resin is：Blending epoxy, cloud
Female powder, white carbon black and amino resins.In saturated polyester resin, 10~30 parts of epoxy resin, 20~40 parts of mica powder, white carbon black 0.5
~3 parts, 8~20 parts of amino resins.
30~60 parts of silane coupler modified silicon dioxide gels, the silane coupler modified silicon dioxide are provided
The preparation method of colloidal sol is：40~65 parts pending of silicon dioxide gel is provided, the pending silicon dioxide gel contains
There is the silicon dioxide that mass percentage content is 30~50%；10~25 parts of silane coupler is provided；Lower alcohols solvent is provided
5-15 parts, 30~40 parts of water；Mix the pending silicon dioxide gel, silane coupler, lower alcohols solvent and water,
Temperature be 30~35 DEG C, pH be 4.0~4.5 under conditions of, react 4.0~6.5 hours be obtained.
1~5 part of epoxy resin, 5~15 parts of zirconium oxide, 10~40 parts of organosiloxane, fluorinated modified nitrile rubber 5 are provided
~15 parts, organic acid be 0.5~3 part, smooth agent be 3~9 parts, optical brightener be 2~4 parts, 1~5 part of color tablets, Pulvis Talci 1~5
Part.
By 10~20 parts of saturated polyester resin, 1~5 part of epoxy resin, silane coupler modified silicon dioxide gel 30
~60 parts, 5~15 parts of zirconium oxide, 10~40 parts of organosiloxane, 5~15 parts of fluorinated modified nitrile rubber, organic acid be 0.5~
3 parts, smooth agent be 3~9 parts, optical brightener be 2~4 parts, 1~5 part of color tablets, 1~5 part of Pulvis Talci be mixed in 2~10 parts organic
Solvent, is obtained the paint composite.
The preferred embodiments of the present invention are these are only, the scope of the claims of the present invention is not thereby limited, it is every using this
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (10)
1. a kind of paint composite, it is characterised in that the paint composite contain resin, silicon dioxide gel, zirconium oxide and
Organic solvent.
2. paint composite as claimed in claim 1, it is characterised in that the resin includes epoxy resin and amino resins.
3. paint composite as claimed in claim 2, it is characterised in that by weight, the paint composite includes：Amino
0.8~4 part of resin, 2~11 parts of epoxy resin, 30~60 parts of silicon dioxide gel, 5~15 parts of zirconium oxide and organic solvent 2~
10 parts.
4. paint composite as claimed in claim 3, it is characterised in that by weight, the paint composite also includes：Cloud
2~8 parts of female powder, 0.05~0.6 part of white carbon black.
5. paint composite as claimed in claim 1, it is characterised in that the paint composite also includes fluorinated modified butyronitrile
Rubber, by weight, in the paint composite, the fluorinated modified nitrile rubber is 5~15 parts.
6. paint composite as claimed in claim 1, it is characterised in that the paint composite also includes organosiloxane,
By weight, in the paint composite, the organosiloxane is 10~40 parts.
7. paint composite as claimed in claim 1, it is characterised in that the paint composite also includes organic acid, smooth
Agent and filler, by weight, in the paint composite, the organic acid is 0.5~3 part, the smooth agent is 3~9 parts, institute
Filler is stated for 4~14 parts.
8. the paint composite as described in any one of claim 1-7, it is characterised in that the silicon dioxide gel is silane idol
The modified silicon dioxide gel of connection agent.
9. a kind of painted piece, it is characterised in that the painted piece includes base material and is formed at the skin of paint of substrate surface, the paint
Layer contains resin, silicon dioxide gel and zirconium oxide.
10. painted piece as claimed in claim 9, it is characterised in that the painted piece for electronic installation housing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611271156.9A CN106675222A (en) | 2016-12-30 | 2016-12-30 | Oil paint composition and painted piece |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611271156.9A CN106675222A (en) | 2016-12-30 | 2016-12-30 | Oil paint composition and painted piece |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106675222A true CN106675222A (en) | 2017-05-17 |
Family
ID=58849219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611271156.9A Pending CN106675222A (en) | 2016-12-30 | 2016-12-30 | Oil paint composition and painted piece |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106675222A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101056505A (en) * | 2006-04-14 | 2007-10-17 | 郭春樱 | Abrasion-proof portable electronic device casing |
| CN103261345A (en) * | 2010-12-17 | 2013-08-21 | 阿克佐诺贝尔国际涂料股份有限公司 | Organic-inorganic hybrid paint composition |
| CN103374277A (en) * | 2012-04-16 | 2013-10-30 | 深圳富泰宏精密工业有限公司 | Shell and preparation method thereof |
| WO2015126216A1 (en) * | 2014-02-24 | 2015-08-27 | 주식회사 에코인프라홀딩스 | Composite ceramic prepared by using sol-gel method, thin film coating material with ultra-high temperature heat resistance and high corrosion resistance, containing same, and preparation method therefor |
| CN105670350A (en) * | 2016-02-17 | 2016-06-15 | 上海新安纳电子科技有限公司 | Film forming silica sol and preparation method and application thereof |
| CN105949831A (en) * | 2016-06-28 | 2016-09-21 | 佛山市珀力玛高新材料有限公司 | Ceramic coating with high hardness in hot environment |
-
2016
- 2016-12-30 CN CN201611271156.9A patent/CN106675222A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101056505A (en) * | 2006-04-14 | 2007-10-17 | 郭春樱 | Abrasion-proof portable electronic device casing |
| CN103261345A (en) * | 2010-12-17 | 2013-08-21 | 阿克佐诺贝尔国际涂料股份有限公司 | Organic-inorganic hybrid paint composition |
| CN103374277A (en) * | 2012-04-16 | 2013-10-30 | 深圳富泰宏精密工业有限公司 | Shell and preparation method thereof |
| WO2015126216A1 (en) * | 2014-02-24 | 2015-08-27 | 주식회사 에코인프라홀딩스 | Composite ceramic prepared by using sol-gel method, thin film coating material with ultra-high temperature heat resistance and high corrosion resistance, containing same, and preparation method therefor |
| CN105670350A (en) * | 2016-02-17 | 2016-06-15 | 上海新安纳电子科技有限公司 | Film forming silica sol and preparation method and application thereof |
| CN105949831A (en) * | 2016-06-28 | 2016-09-21 | 佛山市珀力玛高新材料有限公司 | Ceramic coating with high hardness in hot environment |
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Application publication date: 20170517 |