CN106675101A - Environment-friendly active calcium carbonate - Google Patents
Environment-friendly active calcium carbonate Download PDFInfo
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- CN106675101A CN106675101A CN201510752440.7A CN201510752440A CN106675101A CN 106675101 A CN106675101 A CN 106675101A CN 201510752440 A CN201510752440 A CN 201510752440A CN 106675101 A CN106675101 A CN 106675101A
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- calcium carbonate
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- sodium
- active calcium
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Abstract
The invention discloses environment-friendly active calcium carbonate, which is prepared from the following raw materials (by weight): 90-100 parts of calcium carbonate, 3-4 parts of polyethylene wax, 1-2 parts of glycerin, 1-3 parts of sodium sulfate, 0.2-0.4 part of sodium diacetate, 2-4 parts of polyether polyol, 3.3-4.5 parts of anilmomethyl triethoxy, 3-5 parts of copper stearate, 0.1-0.2 part of sodium alginate, 0.5-2.5 parts of styrene and a proper amount of deionized water. According to the formula, environment-friendly nontoxic raw materials are used, and safe and nontoxic ingredients are added. By the use of high-molecular polymer, strength, toughness and high temperature and low temperature resistance of the product are greatly enhanced.
Description
Technical field
The present invention relates to calcium carbonate field, more particularly to a kind of environment-friendly active calcium carbonate.
Background technology
Calcium carbonate is a kind of highly important functional inorganic filling, be widely used in plastics, rubber,
The industrial circle such as coating and papermaking.In the application of calcium carbonate, most products belong to the category of polymer,
Such as plastics, rubber, adhesive, coating etc., and occupy the important market share..However, dispersant
With the addition of surface modifier so that nano-calcium carbonate temperature is diminished significantly using window, reason is conventional
Dispersant and coupling agent are easily decomposes at high temperature, cause bubble, cracking, defect, deformation etc., and not
Beneficial to environmental protection;Activated Calcium carbonate is with calcium carbonate as base-material, using polyfunctional surfactant and compound height
Effect processing aid, is modified activation process and forms to inorganic powder surface.Calcium carbonate after modified process
Powder, surface forms a kind of special cladding structure, can significantly improve in the polymer matrixs such as polyolefin
Dispersiveness and compatibility, and interface interaction can be produced and between polymer matrix, so as to improve the anti-impact of product
Hit intensity, is a kind of incremental filling additive of function admirable.
A kind of environment-friendly active calcium carbonate disclosed by the invention, it is obtained by the raw material of following weight parts:Carbonic acid
Calcium 90-100, Tissuemat E 3-4, glycerine 1-2, sodium sulphate 1-3, sodium Diacetate 0.2-0.4, polyethers
Polyalcohol 2-4, anilinomethyl triethoxy 3.3-4.5, copper stearate 3-5, sodium alginate 0.1-0.2,
Styrene 0.5-2.5, appropriate deionized water.Inventive formulation adopts environment-protecting asepsis raw material, adds safety non-toxic
Composition, makes product cold can all improve a lot enhancing, toughness reinforcing, high temperature resistant are low with high molecular polymer.
The content of the invention
The technical solution adopted for the present invention to solve the technical problems is:A kind of environment-friendly active calcium carbonate, it is
It is obtained by the raw material of following weight parts:Calcium carbonate 90-100, Tissuemat E 3-4, glycerine 1-2, sulfuric acid
It is sodium 1-3, sodium Diacetate 0.2-0.4, PPG 2-4, anilinomethyl triethoxy 3.3-4.5, hard
Resin acid copper 3-5, sodium alginate 0.1-0.2, styrene 0.5-2.5, appropriate deionized water.
A kind of preparation method of environment-friendly active calcium carbonate of the present invention is comprised the following steps:
(1) calcium carbonate is added after homogenizer, adds Tissuemat E, glycerine, sodium sulphate, diacetic acid
Sodium, PPG, anilinomethyl triethoxy, copper stearate, sodium alginate, be warming up to 70-80 DEG C it
Between stir, insulation 20-30 minutes after pour out.
(2) appropriate deionized water, stirring is added to form suspension and pour out the material poured out while hot;
(3) suspension is mixed with styrene, is stirred 20 minutes, dried, be ground into fine powder.
The invention has the beneficial effects as follows:Formula adopts environment-protecting asepsis raw material, adds safety non-toxic composition, with height
Molecularly Imprinted Polymer makes product cold can all improve a lot enhancing, toughness reinforcing, high temperature resistant are low.
Specific embodiment
Specific embodiment:A kind of environment-friendly active calcium carbonate, it is obtained by the raw material of following weight parts:Calcium carbonate
90-100, Tissuemat E 3-4, glycerine 1-2, sodium sulphate 1-3, sodium Diacetate 0.2-0.4, polyether polyols
Alcohol 2-4, anilinomethyl triethoxy 3.3-4.5, copper stearate 3-5, sodium alginate 0.1-0.2, benzene second
Alkene 0.5-2.5, appropriate deionized water.
A kind of preparation method of environment-friendly active calcium carbonate of the present invention is comprised the following steps:
(1) calcium carbonate is added after homogenizer, adds Tissuemat E, glycerine, sodium sulphate, diacetic acid
Sodium, PPG, anilinomethyl triethoxy, copper stearate, sodium alginate, be warming up to 70-80 DEG C it
Between stir, insulation 20-30 minutes after pour out.
(2) appropriate deionized water, stirring is added to form suspension and pour out the material poured out while hot;
(3) suspension is mixed with styrene, is stirred 20 minutes, dried, be ground into fine powder.
Inventive formulation adopts environment-protecting asepsis raw material, adds safety non-toxic composition, and with high molecular polymer product is made
Product cold can all improve a lot enhancing, toughness reinforcing, high temperature resistant are low.
Obviously, above-described embodiment is only intended to clearly illustrate example, and not to embodiment
Limit.For those of ordinary skill in the field, it can also be made on the basis of the above description
The change or variation of its multi-form.There is no need to be exhaustive to all of embodiment.And by
Among this obvious change extended out or variation are still in the protection domain of the invention.
Claims (2)
1. a kind of environment-friendly active calcium carbonate, it is characterised in that:It is obtained by the raw material of following weight parts:Carbonic acid
Calcium 90-100, Tissuemat E 3-4, glycerine 1-2, sodium sulphate 1-3, sodium Diacetate 0.2-0.4, polyethers
Polyalcohol 2-4, anilinomethyl triethoxy 3.3-4.5, copper stearate 3-5, sodium alginate 0.1-0.2,
Styrene 0.5-2.5, appropriate deionized water.
2. a kind of environment-friendly active calcium carbonate according to claim 1, it is characterised in that:Preparation method include with
Lower step:
(1) by calcium carbonate add homogenizer after, add Tissuemat E, glycerine, sodium sulphate, sodium Diacetate,
PPG, anilinomethyl triethoxy, copper stearate, sodium alginate, are warming up between 70-80 DEG C and stir
Mix uniform, pour out after insulation 20-30 minutes.
(2) appropriate deionized water, stirring is added to form suspension and pour out the material poured out while hot;
(3) suspension is mixed with styrene, is stirred 20 minutes, dried, be ground into fine powder.
Priority Applications (1)
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CN201510752440.7A CN106675101A (en) | 2015-11-05 | 2015-11-05 | Environment-friendly active calcium carbonate |
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CN201510752440.7A CN106675101A (en) | 2015-11-05 | 2015-11-05 | Environment-friendly active calcium carbonate |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112143257A (en) * | 2020-10-27 | 2020-12-29 | 池州市金隆钙业有限公司 | Environment-friendly active calcium carbonate and preparation method thereof |
CN113621253A (en) * | 2021-08-05 | 2021-11-09 | 池州市贵兴非矿新材料有限公司 | Method for processing active calcium carbonate powder |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103360680A (en) * | 2013-05-23 | 2013-10-23 | 建德市新裕塑胶材料有限公司 | Calcium carbonate filler master batch for polypropylene and polyethylene and preparation process thereof |
CN103554704A (en) * | 2013-07-02 | 2014-02-05 | 安徽金阳电器科技发展有限责任公司 | Modified calcium carbonate for anti-ultraviolet electric cable material, and preparation method thereof |
CN104910548A (en) * | 2015-05-28 | 2015-09-16 | 青阳县恒源化工原料有限责任公司 | Environmental protection shell powder active calcium carbonate |
-
2015
- 2015-11-05 CN CN201510752440.7A patent/CN106675101A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103360680A (en) * | 2013-05-23 | 2013-10-23 | 建德市新裕塑胶材料有限公司 | Calcium carbonate filler master batch for polypropylene and polyethylene and preparation process thereof |
CN103554704A (en) * | 2013-07-02 | 2014-02-05 | 安徽金阳电器科技发展有限责任公司 | Modified calcium carbonate for anti-ultraviolet electric cable material, and preparation method thereof |
CN104910548A (en) * | 2015-05-28 | 2015-09-16 | 青阳县恒源化工原料有限责任公司 | Environmental protection shell powder active calcium carbonate |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112143257A (en) * | 2020-10-27 | 2020-12-29 | 池州市金隆钙业有限公司 | Environment-friendly active calcium carbonate and preparation method thereof |
CN113621253A (en) * | 2021-08-05 | 2021-11-09 | 池州市贵兴非矿新材料有限公司 | Method for processing active calcium carbonate powder |
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Application publication date: 20170517 |
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