CN106670231A - Preparation method for aluminum and nickel bimetal composite strip material - Google Patents
Preparation method for aluminum and nickel bimetal composite strip material Download PDFInfo
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- CN106670231A CN106670231A CN201611148165.9A CN201611148165A CN106670231A CN 106670231 A CN106670231 A CN 106670231A CN 201611148165 A CN201611148165 A CN 201611148165A CN 106670231 A CN106670231 A CN 106670231A
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- nickel
- aluminium
- composite strip
- metal composite
- double metal
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2261/00—Product parameters
- B21B2261/02—Transverse dimensions
- B21B2261/04—Thickness, gauge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2261/00—Product parameters
- B21B2261/20—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2261/00—Product parameters
- B21B2261/22—Hardness
Abstract
The invention discloses a preparation method for an aluminum and nickel bimetal composite strip material and belongs to the field of metal material processing. According to the preparation method, a heated aluminum strip and a softened and annealed nickel strip are composited in a rolling manner to acquire an aluminum and nickel composite strip blank; and then diffusion annealing is performed on the aluminum and nickel composite strip blank, the hardness of the aluminum and nickel composite strip blank is controlled by means of room temperature rolling, and the aluminum and nickel bimetal composite strip material finished product is acquired. The aluminum and nickel bimetal composite strip material is prepared through the preparation method, the beneficial effects that the process is simple, operation is easy, the product performance can be controlled easily, the interface binding strength is high, and the subsequent forming performance of the product is good are achieved, and the performance requirement of the aluminum and nickel bimetal composite strip material product used for lithium battery pole lugs can be met.
Description
Technical field:
The invention belongs to metal material processing technical field, more particularly to a kind of preparation side of aluminium nickel double metal composite strip
Method.
Background technology:
In recent years, the portable type electronic product such as demand such as mobile phone, notebook computer rapidly increases and to the side of light high-efficiency
To development, thus as its power resources all kinds of battery products also obtained it is great development and it is gradually close to lightweight, high energy
Degree direction is developed.In order to realize this target, the case material majority of current battery is changed to aluminium from steel, due to battery outside
Draw extreme general using electric conductivity and all preferable pure nickel material of corrosion resistance, the welding thus brought between nickel material and aluminium is asked
Topic.Preferable method is drawn outside between extreme nickel material and shell aluminium using a kind of aluminium/nickel bimetal composite band as welding
Transition zone.
At present, the preparation method of bimetallic composite band has various, such as roll-bonding method, extrusion cladding method, explosion composite method,
Reverse solidification method, casting and roll process etc., but it is roll-bonding method to be obtained in actual production wide variety of.In order to realize the first of interface
With reference to, a large deformation more than 50% is generally required during Rolling compund, this can cause compound constituent element to produce serious processing hard
Change, for aluminium/nickel complex system, the fusing point of two constituent elements, recrystallization temperature and mechanical property difference are larger, therefore roll
Diffusion annealing after system is compound is difficult to realize both and softens completely simultaneously, meanwhile, aluminium nickel compound interface is changed between easily generating metal
Compound, the conflicting property for causing combined strength bination to be controlled with nickel layer hardness seems especially prominent.Therefore, using traditional rolling work
During skill production aluminium nickel double metal composite band, the bond strength of composite bed and the hardness control difficulty of composite band are big.
The content of the invention:
The purpose of the present invention is, during for producing aluminium nickel double metal composite band using traditional rolling mill practice, composite bed
The hardness of bond strength and composite band controls the big technical barrier of difficulty, there is provided a kind of preparation of aluminium nickel double metal composite strip
Method, the preparation of the aluminium nickel double metal composite strip for making lithium battery pole ear, the method by will heat aluminium strip with it is soft
Nickel strap after annealing carries out Rolling compund, obtains aluminium nickel compound belt blank, is then diffused annealing and room temperature rolling obtains aluminium
The method of nickel double metal composite strip finished product.
To achieve the above object, the present invention uses following technical scheme:
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
After nickel strap is carried out into soft annealing, the nickel strap after soft annealing is formed;Wherein, the temperature of soft annealing be 700~
800 DEG C, soft annealing soaking time is 20~30min;
It is prepared by step 2, aluminium nickel compound belt blank
Take after aluminium strip is heated to 300~500 DEG C, with the nickel strap after soft annealing, Rolling compund is carried out at room temperature, obtain
Aluminium nickel compound belt blank;Wherein, Rolling compund deflection is 20~45%;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, the aluminium nickel compound belt blank of interfacial bonding property improvement is obtained;Wherein, spread
Annealing temperature is 300~550 DEG C, and diffusion annealing soaking time is 5~180min;
Step 4, hardness control
The aluminium nickel compound belt blank that interfacial bonding property is improved is carried out into room temperature rolling, aluminium nickel double metal composite strip, institute is obtained
Aluminium nickel double metal composite strip thickness is stated for 0.12~0.8mm, hardness is HV80~230;Wherein, room temperature rolling deflection is 0
~60%.
In described step 1, purity >=99.9% of nickel strap, the thickness of nickel strap is 0.1~1mm.
In described step 1, the nickel strap surface after soft annealing through over cleaning oil removing and grinding process, wherein, polishing side
Formula is that belt sanding or wire brush are polished.
In described step 2, purity >=99.5% of aluminium strip, the thickness of aluminium strip is 0.1~1mm.
In described step 1 and step 2, the thickness of raw material aluminium and raw material nickel material, the double gold of aluminium nickel according to required preparation
Belong to the thickness of composite strip, and aluminium nickel thickness ratio determines in aluminium nickel double metal composite strip.
In described step 2, before heating, surface is through over cleaning oil removing and grinding process for aluminium strip;Described polishing mode
It is that belt sanding or wire brush are polished.
In described step 4, the hardness of the aluminium nickel double metal composite strip that room temperature rolling deflection is prepared according to needed for will
Determination is asked, when the aluminium nickel compound belt blank hardness that the interfacial bonding property that step 3 is obtained is improved meets finished product aluminium nickel double metal composite band
During material requirement, then it is 0% that need not carry out the room temperature rolling operation of step 4, i.e. room temperature rolling deflection;The interface that step 3 is obtained
The aluminium nickel compound belt blank of associativity improvement, as finished product aluminium nickel double metal composite strip.
The preparation method of aluminium nickel double metal composite strip of the invention, heats aluminium strip in Rolling compund, it is possible to decrease roll
The first pass deformation of compound tense processed, reduces the deformation (the processing hardening of very little occurs) of soft state nickel strap, after such Rolling compund
The aluminium nickel compound belt blank of formation is substantially at soft state, therefore, the diffusion annealing of the aluminium nickel compound belt blank after Rolling compund is only needed
The intensity of compound interface is controlled, and the room temperature that the hardness of finished product aluminium nickel double metal composite strip can be after controlling diffusion annealing is rolled
Deflection processed is easily realized.
Beneficial effects of the present invention:
(1) nickel strap of soft state after the aluminium strip of heating and soft annealing is carried out room temperature rolling and is combined by the present invention, reduces head
The deflection of the compound deflection of passes and nickel strap, can obtain the aluminium nickel compound belt blank substantially without hardening, solve expansion
The contradiction that the intensity of compound interface again softens nickel strap layer should be ensured when dissipating annealing;
(2) in aluminium nickel double metal composite strip preparation process of the invention, the compound belt blank after diffusion annealing is carried out not
With the room temperature rolling of deflection, it is convenient to the hardness of control targe product.
Brief description of the drawings:
Fig. 1 is the structural representation of aluminium nickel double metal composite strip of the invention, wherein, 1- aluminium strips, 2- nickel straps;
Fig. 2 is aluminium nickel double metal composite strip case of bending of the invention with reference to figure;
Fig. 3 is the SEM photograph of aluminium nickel double metal composite strip compound interface prepared by the embodiment of the present invention 1;
Fig. 4 is the SEM photograph of aluminium nickel double metal composite strip compound interface prepared by the embodiment of the present invention 2;
Fig. 5 is the SEM photograph of aluminium nickel double metal composite strip compound interface prepared by the embodiment of the present invention 3.
Specific embodiment:
With reference to embodiment, the present invention is described in further detail.
The structural representation of aluminium nickel double metal composite strip prepared by embodiment 1~7, as shown in Figure 1;Wherein, 1- aluminium strips,
2- nickel straps;
The case of bending of aluminium nickel double metal composite strip prepared by embodiment 1~7 with reference to figure, as shown in Figure 2.
Embodiment 1
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
Purity >=99.9% is taken, thickness is the nickel strap of 0.1mm, and nickel strap is carried out into soft annealing, and the temperature of soft annealing is
700 DEG C, anneal 30min, forms the nickel strap after soft annealing, and carries out cleaning oil removing to the nickel strap surface after soft annealing, and
Belt sanding treatment;
It is prepared by step 2, aluminium nickel compound belt blank
Purity >=99.5% is taken, thickness is the aluminium strip of 0.1mm, after surface is through over cleaning oil removing, and belt sanding treatment, plus
After hot to 500 DEG C, the nickel strap with after soft annealing polishing carries out Rolling compund at room temperature, and deflection is 20%, obtains aluminium nickel
Compound belt blank;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, diffusion annealing temperature is 300 DEG C, and soaking time is 180min, is obtained
Thickness is the aluminium nickel double metal composite strip of 0.16mm, and hardness is HV90, the SEM of the compound interface of aluminium nickel double metal composite strip
Photo, as shown in figure 3, interface compound is discontinuous.
Embodiment 2
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
Purity >=99.9% is taken, thickness is the nickel strap of 0.5mm, and nickel strap is carried out into soft annealing, and the temperature of soft annealing is
750 DEG C, anneal 25min, forms the nickel strap after soft annealing, and carries out cleaning oil removing to the nickel strap surface after soft annealing, and
Belt sanding treatment;
It is prepared by step 2, aluminium nickel compound belt blank
Purity >=99.5% is taken, thickness is the aluminium strip of 0.5mm, and surface is processed through over cleaning oil removing and belt sanding, heating
To after 400 DEG C, the nickel strap with after soft annealing polishing carries out Rolling compund at room temperature, and deflection is 30%, obtains thickness and is
The aluminium nickel compound belt blank of 0.7mm;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, diffusion annealing temperature is 400 DEG C, and diffusion annealing soaking time is
120min, obtains the aluminium nickel compound belt blank of interfacial bonding property improvement, the SEM photograph of compound interface, as shown in figure 4, interface is formed
About 0.5 μ thick compound;
Step 4, hardness control
The aluminium nickel compound belt blank that interfacial bonding property is improved is carried out into room temperature rolling, deflection is 30%, obtaining thickness is
The aluminium nickel double metal composite strip of 0.49mm, hardness is HV135.
Embodiment 3
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
Purity >=99.9% is taken, thickness is the nickel strap of 1mm, nickel strap is carried out into soft annealing, the temperature of soft annealing is 800
DEG C, the time is 20min, forms the nickel strap after soft annealing, and carry out cleaning oil removing, and steel to the nickel strap surface after soft annealing
Wire brush grinding process;
It is prepared by step 2, aluminium nickel compound belt blank
Take purity >=99.5%, thickness is the aluminium strip of 1mm, surface through over cleaning oil removing, and or wire brush grinding process after,
After being heated to 300 DEG C, the nickel strap with after soft annealing polishing carries out Rolling compund at room temperature, and deflection is 45%, obtains thick
Spend the aluminium nickel compound belt blank for 1.1mm;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, diffusion annealing temperature is 550 DEG C, and diffusion annealing soaking time is
5min, obtains the aluminium nickel compound belt blank of interfacial bonding property improvement, the SEM photograph of compound interface, as shown in figure 5, interface compound
Discontinuously;
Step 4, hardness control
The aluminium nickel compound belt blank that interfacial bonding property is improved is carried out into room temperature rolling, deflection is 60%, obtaining thickness is
The aluminium nickel double metal composite strip of 0.44mm, hardness is HV225.
Embodiment 4
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
Purity >=99.9% is taken, thickness is the nickel strap of 0.5mm, and nickel strap is carried out into soft annealing, and the temperature of soft annealing is
750 DEG C, anneal 25min, forms the nickel strap after soft annealing, and carries out cleaning oil removing to the nickel strap surface after soft annealing, and
Belt sanding treatment;
It is prepared by step 2, aluminium nickel compound belt blank
Purity >=99.5% is taken, thickness is the aluminium strip of 0.5mm, and surface is processed through over cleaning oil removing and belt sanding, heating
To after 400 DEG C, the nickel strap with after soft annealing polishing carries out Rolling compund at room temperature, and deflection is 30%, obtains thickness and is
The aluminium nickel compound belt blank of 0.7mm;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, diffusion annealing temperature is 400 DEG C, and diffusion annealing soaking time is
120min, it is the aluminium nickel double metal composite strip of 0.7mm to obtain thickness, and hardness is HV80.
Embodiment 5
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
Purity >=99.9% is taken, thickness is the nickel strap of 1mm, nickel strap is carried out into soft annealing, the temperature of soft annealing is 710
DEG C, anneal 30min, forms the nickel strap after soft annealing, and carry out cleaning oil removing, and abrasive band to the nickel strap surface after soft annealing
Grinding process;
It is prepared by step 2, aluminium nickel compound belt blank
Purity >=99.5% is taken, thickness is the aluminium strip of 1mm, after surface is through over cleaning oil removing, and belt sanding treatment, heating
To after 500 DEG C, the nickel strap with after soft annealing polishing carries out Rolling compund at room temperature, and deflection is 20%, obtains aluminium nickel and answers
Crossed belt base;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, diffusion annealing temperature is 350 DEG C, and soaking time is 150min, is obtained
The aluminium nickel compound belt blank of interfacial bonding property improvement;
Step 4, hardness control
The aluminium nickel compound belt blank that interfacial bonding property is improved is carried out into room temperature rolling, deflection is 60%, obtaining thickness is
The aluminium nickel double metal composite strip of 0.64mm, hardness is HV230.
Embodiment 6
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
Purity >=99.9% is taken, thickness is the nickel strap of 0.1mm, and nickel strap is carried out into soft annealing, and the temperature of soft annealing is
700 DEG C, anneal 30min, forms the nickel strap after soft annealing, and carries out cleaning oil removing to the nickel strap surface after soft annealing, and
Belt sanding treatment;
It is prepared by step 2, aluminium nickel compound belt blank
Purity >=99.5% is taken, thickness is the aluminium strip of 0.1mm, after surface is through over cleaning oil removing, and belt sanding treatment, plus
After hot to 500 DEG C, the nickel strap with after soft annealing polishing carries out Rolling compund at room temperature, and deflection is 20%, obtains thickness
It is the aluminium nickel compound belt blank of 0.16mm;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, diffusion annealing temperature is 300 DEG C, and soaking time is 180min, is obtained
The aluminium nickel compound belt blank of interfacial bonding property improvement;
Step 4, hardness control
The aluminium nickel compound belt blank that interfacial bonding property is improved is carried out into room temperature rolling, deflection is 25%, obtaining thickness is
The aluminium nickel double metal composite strip of 0.12mm, hardness is HV125.
Embodiment 7
A kind of preparation method of aluminium nickel double metal composite strip, comprises the following steps:
Step 1, nickel strap softens
Purity >=99.9% is taken, thickness is the nickel strap of 1mm, nickel strap is carried out into soft annealing, the temperature of soft annealing is 780
DEG C, anneal 28min, forms the nickel strap after soft annealing, and carry out cleaning oil removing, and abrasive band to the nickel strap surface after soft annealing
Grinding process;
It is prepared by step 2, aluminium nickel compound belt blank
Purity >=99.5% is taken, thickness is the aluminium strip of 1mm, and surface processes through over cleaning oil removing and belt sanding, is heated to
After 450 DEG C, the nickel strap with after soft annealing polishing carries out Rolling compund at room temperature, and deflection is 20%, obtains thickness and is
The aluminium nickel compound belt blank of 1.6mm;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, diffusion annealing temperature is 400 DEG C, and diffusion annealing soaking time is
160min, obtains the aluminium nickel compound belt blank of interfacial bonding property improvement;
Step 4, hardness control
The aluminium nickel compound belt blank that interfacial bonding property is improved is carried out into room temperature rolling, deflection is 50%, obtaining thickness is
The aluminium nickel double metal composite strip of 0.8mm, hardness is HV210.
Claims (5)
1. a kind of preparation method of aluminium nickel double metal composite strip, it is characterised in that comprise the following steps:
Step 1, nickel strap softens
After nickel strap is carried out into soft annealing, the nickel strap after soft annealing is formed;Wherein, the temperature of soft annealing is 700~800
DEG C, soft annealing soaking time is 20~30min;
It is prepared by step 2, aluminium nickel compound belt blank
Take after aluminium strip is heated to 300~500 DEG C, with the nickel strap after soft annealing, Rolling compund is carried out at room temperature, obtain aluminium nickel
Compound belt blank;Wherein, Rolling compund deflection is 20~45%;
Step 3, interface improved treatment
Aluminium nickel compound belt blank is diffused annealing, the aluminium nickel compound belt blank of interfacial bonding property improvement is obtained;Wherein, diffusion annealing
Temperature is 300~550 DEG C, and diffusion annealing soaking time is 5~180min;
Step 4, hardness control
The aluminium nickel compound belt blank that interfacial bonding property is improved is carried out into room temperature rolling, aluminium nickel double metal composite strip, the aluminium is obtained
Nickel double metal composite strip thickness is 0.12~0.8mm, and hardness is HV80~230;Wherein, room temperature rolling deflection be 0~
60%.
2. the preparation method of aluminium nickel double metal composite strip according to claim 1, it is characterised in that described step 1
In, purity >=99.9% of nickel strap, the thickness of nickel strap is 0.1~1mm.
3. the preparation method of aluminium nickel double metal composite strip according to claim 1, it is characterised in that described step 1
In, the nickel strap surface after soft annealing is through over cleaning oil removing and grinding process;Wherein, described polishing mode be belt sanding or
Wire brush is polished.
4. the preparation method of aluminium nickel double metal composite strip according to claim 1, it is characterised in that described step 2
In, purity >=99.5% of aluminium strip, the thickness of aluminium strip is 0.1~1mm.
5. the preparation method of aluminium nickel double metal composite strip according to claim 1, it is characterised in that described step 2
In, before heating, surface is through over cleaning oil removing and grinding process for aluminium strip;Wherein, described polishing mode is belt sanding or steel
Wire brush is polished.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114082958A (en) * | 2021-11-23 | 2022-02-25 | 无锡市东杨新材料股份有限公司 | Preparation method of nickel-copper bimetal composite strip |
CN115647035A (en) * | 2022-09-19 | 2023-01-31 | 江苏中色复合材料有限公司 | Nickel-aluminum-nickel composite material, composite process and application |
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CN2873487Y (en) * | 2005-11-09 | 2007-02-28 | 余鹏 | Aluminum-nickel bimetal composite strip |
CN1962255A (en) * | 2005-11-09 | 2007-05-16 | 余鹏 | Aluminium nickel double metal composite strip and its production process |
CN101402100A (en) * | 2008-11-04 | 2009-04-08 | 安徽省鑫源达有色金属材料有限公司 | Method for producing nickel-aluminum composite belt |
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2016
- 2016-12-13 CN CN201611148165.9A patent/CN106670231B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2873487Y (en) * | 2005-11-09 | 2007-02-28 | 余鹏 | Aluminum-nickel bimetal composite strip |
CN1962255A (en) * | 2005-11-09 | 2007-05-16 | 余鹏 | Aluminium nickel double metal composite strip and its production process |
CN101402100A (en) * | 2008-11-04 | 2009-04-08 | 安徽省鑫源达有色金属材料有限公司 | Method for producing nickel-aluminum composite belt |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114082958A (en) * | 2021-11-23 | 2022-02-25 | 无锡市东杨新材料股份有限公司 | Preparation method of nickel-copper bimetal composite strip |
CN114082958B (en) * | 2021-11-23 | 2024-04-19 | 无锡市东杨新材料股份有限公司 | Preparation method of nickel-copper bimetal composite strip |
CN115647035A (en) * | 2022-09-19 | 2023-01-31 | 江苏中色复合材料有限公司 | Nickel-aluminum-nickel composite material, composite process and application |
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