CN106667847A - Magnetic graphene composite material mask rich in hydrogen water - Google Patents

Magnetic graphene composite material mask rich in hydrogen water Download PDF

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Publication number
CN106667847A
CN106667847A CN201710098040.8A CN201710098040A CN106667847A CN 106667847 A CN106667847 A CN 106667847A CN 201710098040 A CN201710098040 A CN 201710098040A CN 106667847 A CN106667847 A CN 106667847A
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Prior art keywords
graphene composite
magnetic graphene
rich water
facial film
film containing
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CN201710098040.8A
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Chinese (zh)
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不公告发明人
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Guangzhou Poly Green Chemical Technology Research Institute Co Ltd
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Guangzhou Poly Green Chemical Technology Research Institute Co Ltd
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Priority to CN201710098040.8A priority Critical patent/CN106667847A/en
Publication of CN106667847A publication Critical patent/CN106667847A/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/735Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90Block copolymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/08Anti-ageing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Gerontology & Geriatric Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)

Abstract

The invention relates to a magnetic graphene composite material mask rich in hydrogen water. The magnetic graphene composite material mask rich in the hydrogen water is prepared from the following components by weight percent: 5-25% of a humectant, 1-15% of a plant extract, 0.5-5% of a magnetic graphene composite material, 0.1-3% of a thickener, 0.1-3% of an emulsifier, 0.1-0.5% of an amendment, 0.01-0.1% of EDTA disodium, 0.01-0.5% of a preservative and the balance of hydrogen water. The adopted hydrogen water can play roles in removing free radicals of a human body and delaying senescence. The magnetic graphene composite material has a good adsorption characteristic and a unique magnetic function, is capable of adsorbing dirt on the skin surface, promoting permeation of the humectant and the plant extract towards the inside of the skin; and nutrients contained in the mask are introduced to play roles in cleaning the skin and inhibiting the growth of pathogenic bacteria.

Description

A kind of magnetic graphene composite facial film containing hydrogen rich water
Technical field
The present invention relates to cosmetic field, is specifically related to a kind of magnetic graphene composite facial film containing hydrogen rich water.
Background technology
China State of Air pollution is extremely serious.If the dust suspended material carried in air pollution does not note clearly It is clean, pore may be slowly collected in, causes clogging of pores and acne to occur.After atmospheric pollution, printing opacity degree meeting in air Reduce, the ultraviolet of Near Ground is weakened, various viruses in near-earth air, antibacterial and funguses become to be not easy to be killed by ultraviolet Extremely, various viruses are easily caused, antibacterial, funguses reach skin with the dust granules of air, and adhere to skin surface, cause The infection of skin.
Hydrogen is minimum molecule in nature, is colourless, tasteless, odorless, the diatomic gas with certain reproducibility. Hydrogen is colourless, tasteless, and the minimum flammable diatomic gas of density, is mainly used in diving field in the past, in recent years crowd Many researchs find that hydrogen has good selective antioxidation, and the organ injury such as heart, brain, liver, kidney to animal all has guarantor Shield is acted on.
British scientist has been prepared by carbon atom first with sp within 20042It is new that the monoatomic layer of hydridization connection is constituted Two-dimensional atomic crystal-Graphene, its thickness only have 0.3354nm, are to find most thin material in the world at present.Graphene oxide With low cost, raw material is easy to get, with good process based prediction model, such as higher specific surface energy, good hydrophilic, good Absorption property, and have preferable dispersibility in water and organic solvent, be a kind of excellent composite filler.
Composite, is by two or more material of different nature, by method physically or chemically, in macroscopic view Material of the composition with new capability on (microcosmic).Various materials make up for each other's deficiencies and learn from each other in performance, produce cooperative effect, make to be combined The combination property of material meets a variety of requirements better than former composition material.
Chinese patent application 105287248A, discloses a kind of graphene oxide facial film and preparation method thereof.The invention is first It is secondary that Graphene is applied in facial film, and elaborate that Graphene kills acarid and deep layer removes the effect of acarid, but do not have The derivative effect of further investigation graphene composite material.
The content of the invention
Present invention aim at a kind of magnetic graphene composite facial film containing hydrogen rich water is provided, can be clear from hydrogen rich water Except the harmful free radicals of skin surface, delay skin aging, absorption skin surface is reached from magnetic graphene composite Pollutant, the effect for promoting absorption of nutrient ingredients, suppressing pathogenic bacteria growing.
For achieving the above object, the present invention is adopted the following technical scheme that:
A kind of magnetic graphene composite facial film containing hydrogen rich water of the present invention, including following mass percent component:
Wetting agent:5-25%;
Plant extract:1-15%;
Magnetic graphene composite:0.5-5%;
Thickening agent:0.1-3%;
Emulsifying agent:0.1-3%;
Conditioner:0.1-0.5%;
EDETATE SODIUM:0.01-0.1%;
Preservative:0.01-0.5%;
Hydrogen-rich water surplus;
Preferably, in a preferred embodiment of the invention, a kind of described magnetic graphene containing hydrogen rich water is combined Material facial film, including following mass percent component:
Wetting agent:10-15%;
Plant extract:5-10%;
Magnetic graphene composite:1-4%;
Thickening agent:1-2%;
Emulsifying agent:1-2%;
Conditioner:0.2-0.4%;
EDETATE SODIUM:0.04-0.08%;
Preservative:0.2-0.4%;
Hydrogen-rich water surplus;
In a preferred embodiment of the invention, the wetting agent is Propylene Glycol, butanediol, glycerol polymethylacrylic acid Ester/Propylene Glycol/(Gantrez AN-119), the mixture of hyaluronate sodium.Glycerol polymethacrylates/Propylene Glycol/(PVM/MA Copolymer) with unique cage structure, hydrone is incorporated into into polyglycerolmethacrylate by hydrogen bond and Fan De meetings power In the cage structure of formation, when product contacts skin, changed due to the presence of salt, pH value, strong electrolyte or skin temperature change Change causes the slow destruction of cage structure, causes water release, so as to provide skin with gloss and moistening effect.Hyaluronate sodium Aqueous solution is a kind of non-Newtonian fluid, has good viscoelasticity and rheology shape.Based on the special performance of hyaluronate sodium, its Can be widely used in the middle of medicine, cosmetics and health food.
In a preferred embodiment of the invention, the plant extract is Aloe vulgariss leaf extract, North America gold The mixture of thread prunus mume extract.Aloe vulgariss leaf extract has eliminating toxin and beautifying the skin, and heat-clearing and toxic substances removing excludes vivotoxin, to powder Thorn and comedo have sterilization, clear up the effect of poison, are now widely used as medicine, cosmetic material.Hamamelis virginiana extracts owner Want composition to have tannic acid, catechin, procyanidin etc., sebum secretion can be adjusted, with moisturizing and Milk Protein, promote lymph Blood circulation, relaxes the skin such as stimulated and anaphylaxis, fully restrains enlarged pores, prevents blackhead and acne from producing.
In a preferred embodiment of the invention, the thickening agent is carbomer.Carbomer be with tetramethylolmethane etc. with The acrylic acid crosslinked resin that acrylic acid crosslinking is obtained, is the very important rheology control agent of a class, and the card ripple after neutralization is outstanding Gel-type vehicle, have the important uses such as thickening, suspension, process is simple, good stability are widely used in emulsion, cream, gel In.
In a preferred embodiment of the invention, the conditioner is allantoin.Allantoin is skin conditioner, skin Protective agent, extracts from Radix Arnebiae (Radix Lithospermi) and forms, and with antiinflammatory, the function of releiving and help skin tissue's regeneration, is common in except acne, day Shine in the product composition of maintenance class.
In a preferred embodiment of the invention, the emulsifying agent is triethanolamine.During triethanolamine is cream preparation Conventional emulsifying agent, has mastic fine and smooth with the cream products of triethanolamine emulsifying, the characteristics of mastic brilliant white.
In a preferred embodiment of the invention, the preservative is phenoxyethanol/Sensiva SC50.
Hydrogen rich water of the present invention can neutralize the pernicious oxygen-derived free radicals of skin surface as solvent.Free radical be referred to as all kinds of diseases and ailments it Source, is the arch-criminal of mankind aging, and keeps the balance of free radical to be only most healthy state.In the mistake for keeping this balance Cheng Zhong, hydrogen molecule act as key player.Hydrogen molecule in hydrogen rich water can strengthen the oxidation resistance of human body, delaying senility speed Degree.
Magnetic graphene composite of the present invention has good characterization of adsorption and distinctive magnetic function, can adsorb skin The dirt on skin surface, promotes wetting agent and plant extract to permeate into skin, contained nutritional labeling in facial film is imported, is played The effect of cleaning skin.As magnetic graphene composite belongs to nanometer materials, easily swallowed in abdomen by antibacterial, pathogenic bacteria, Cause the death of antibacterial, pathogenic bacteria, thus can play a part of to suppress the bacteria growing that causes a disease.
Beneficial effects of the present invention:Compared with prior art, a kind of magnetic graphene containing hydrogen rich water of the invention is combined Material facial film has the advantage that:1. skin surface can be neutralized as solvent using the conventional deionized water of hydrogen rich water replacement pernicious Oxygen-derived free radicals, strengthen the oxidation resistance of skin, slowing down skin aging speed.2. magnetic graphene composite has good Characterization of adsorption and distinctive magnetic function, can adsorb the dirt of skin surface, promote wetting agent and plant extract to skin Interior infiltration, contained nutritional labeling in facial film is imported, and is played a part of to clean skin, is suppressed the bacteria growing that causes a disease.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1~5
5 that a kind of magnetic graphene composite facial film containing hydrogen rich water of the present invention is listed in table 1 are concrete Embodiment.
Table 1
3 that a kind of magnetic graphene composite facial film containing hydrogen rich water of the present invention is listed in table 2 are concrete Comparative example.
Table 2
Evaluation test on probation
Preferably to prove that it is excellent that a kind of magnetic graphene composite facial film containing hydrogen rich water provided by the present invention has (selected reference examples 3,4 are commercially available domestic and international well-known product for different effect, selection embodiment 1,2,3,4,5 and reference examples 1,2,3,4 Board product facial film) carry out further investigation on probation and evaluation test.Embodiment is as follows:Choose 50 special volunteers, year Age is distributed as 18-58 year.Wherein 20 people of male, 30 people of women.Evaluation test is carried out to embodiment, each sampling phase is one Individual month, it was facial acne, long pox, aging crowd to try out object.Table 3 is test index and result.
Table 3
As a result show:
For facial acne, long pox, aging crowd, life-time service magnetic graphene composite of the present invention containing hydrogen rich water Facial film, the effect for improving significantly and alleviating.And embodiment 5 has the best effect for being obviously improved and alleviating, implement Example 5 is optimization formula of the present invention.Comparative example 1 has the effect for being preferably obviously improved and alleviating relative to comparative example 2, shows richness The addition of hydrogen water is for improving and alleviate skin acne, long pox and aging serve facilitation.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope of present disclosure, the change or replacement that can be readily occurred in, Should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims Scope.

Claims (8)

1. a kind of magnetic graphene composite facial film containing hydrogen rich water, including following mass percent component:Wetting agent:5- 25%th, plant extract:1-15%, magnetic graphene composite:0.5-5%, thickening agent:0.1-3%, emulsifying agent:0.1- 3%th, conditioner:0.1-0.5%, EDETATE SODIUM:0.01-0.1%, preservative:0.01-0.5%, hydrogen-rich water surplus.
2. a kind of magnetic graphene composite facial film containing hydrogen rich water according to claim 1, including following quality hundred Divide and compare component:Wetting agent:10-15%, plant extract:5-10%, magnetic graphene composite:1-4%, thickening agent:1- 2%th, emulsifying agent:1-2%, conditioner:0.2-0.4%, EDETATE SODIUM:0.04-0.08%, preservative:0.2-0.4%, hydrogen-rich Water surplus.
3. a kind of magnetic graphene composite facial film containing hydrogen rich water according to claim 1 and 2, it is characterised in that The wetting agent is Propylene Glycol, butanediol, glycerol polymethacrylates/Propylene Glycol/(Gantrez AN-119), hyalomitome The mixture of sour sodium.
4. a kind of magnetic graphene composite facial film containing hydrogen rich water according to claim 1 and 2, it is characterised in that The plant extract is Aloe vulgariss leaf extract, the mixture of Hamamelis virginiana extract.
5. a kind of magnetic graphene composite facial film containing hydrogen rich water according to claim 1 and 2, it is characterised in that The thickening agent is carbomer.
6. a kind of magnetic graphene composite facial film containing hydrogen rich water according to claim 1 and 2, it is characterised in that The conditioner is allantoin.
7. a kind of magnetic graphene composite facial film containing hydrogen rich water according to claim 1 and 2, it is characterised in that The emulsifying agent is triethanolamine.
8. a kind of magnetic graphene composite facial film containing hydrogen rich water according to claim 1 and 2, it is characterised in that The preservative is phenoxyethanol/Sensiva SC50.
CN201710098040.8A 2017-02-22 2017-02-22 Magnetic graphene composite material mask rich in hydrogen water Pending CN106667847A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107157654A (en) * 2017-05-27 2017-09-15 中山市创思泰新材料科技股份有限公司 Device and a kind of antibiotic skin-care film that a kind of humidity regulation and antibacterial for skin is nursed
CN107260589A (en) * 2017-07-06 2017-10-20 深圳市研成创意设计有限公司 A kind of edible hydrogeneous surfactant
CN107375104A (en) * 2017-08-25 2017-11-24 北京中氢源工程科技有限公司 A kind of production method of the anti-oxidant anti-ageing facial mask of hydrogen-rich
CN108125801A (en) * 2018-01-03 2018-06-08 中山市天图精细化工有限公司 Hydrogen rich water is releived aerosol
CN108567578A (en) * 2018-07-25 2018-09-25 四川大学 It is used to prepare the lotion and preparation method thereof of facial mask
CN110384626A (en) * 2019-08-09 2019-10-29 汉西(厦门)科技有限公司 A kind of facial mask cloth and preparation method based on graphene
CN112315848A (en) * 2020-12-10 2021-02-05 哈工大机器人(中山)无人装备与人工智能研究院 Graphene mask and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103417462A (en) * 2013-07-23 2013-12-04 陈俊杰 Facial mask for treating whelk and pigment patch and whitening skin
CN103947675A (en) * 2014-04-11 2014-07-30 湖南大学 Magnetic graphene oxide nanometer compound, preparation method and application thereof
CN103976916A (en) * 2014-05-30 2014-08-13 广州丹奇日用化工厂有限公司 Berberis julianae schneid extracting solution and preparation method and application thereof
CN105287248A (en) * 2015-11-18 2016-02-03 张建刚 Graphene oxide mask and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103417462A (en) * 2013-07-23 2013-12-04 陈俊杰 Facial mask for treating whelk and pigment patch and whitening skin
CN103947675A (en) * 2014-04-11 2014-07-30 湖南大学 Magnetic graphene oxide nanometer compound, preparation method and application thereof
CN103976916A (en) * 2014-05-30 2014-08-13 广州丹奇日用化工厂有限公司 Berberis julianae schneid extracting solution and preparation method and application thereof
CN105287248A (en) * 2015-11-18 2016-02-03 张建刚 Graphene oxide mask and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107157654A (en) * 2017-05-27 2017-09-15 中山市创思泰新材料科技股份有限公司 Device and a kind of antibiotic skin-care film that a kind of humidity regulation and antibacterial for skin is nursed
CN107260589A (en) * 2017-07-06 2017-10-20 深圳市研成创意设计有限公司 A kind of edible hydrogeneous surfactant
CN107375104A (en) * 2017-08-25 2017-11-24 北京中氢源工程科技有限公司 A kind of production method of the anti-oxidant anti-ageing facial mask of hydrogen-rich
CN107375104B (en) * 2017-08-25 2021-02-02 北京中氢源工程科技有限公司 Production method of hydrogen-rich antioxidant anti-aging mask
CN108125801A (en) * 2018-01-03 2018-06-08 中山市天图精细化工有限公司 Hydrogen rich water is releived aerosol
CN108567578A (en) * 2018-07-25 2018-09-25 四川大学 It is used to prepare the lotion and preparation method thereof of facial mask
CN110384626A (en) * 2019-08-09 2019-10-29 汉西(厦门)科技有限公司 A kind of facial mask cloth and preparation method based on graphene
CN112315848A (en) * 2020-12-10 2021-02-05 哈工大机器人(中山)无人装备与人工智能研究院 Graphene mask and preparation method thereof

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Application publication date: 20170517