CN106639236A - Elastic brick used on ground of toilet and manufacturing method of elastic brick - Google Patents

Elastic brick used on ground of toilet and manufacturing method of elastic brick Download PDF

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Publication number
CN106639236A
CN106639236A CN201611065034.4A CN201611065034A CN106639236A CN 106639236 A CN106639236 A CN 106639236A CN 201611065034 A CN201611065034 A CN 201611065034A CN 106639236 A CN106639236 A CN 106639236A
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weight
parts
modified
powder
brick
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CN106639236B (en
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任广鸿
毕文峰
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Henan Tong Wei Building Materials Co Ltd
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Henan Tong Wei Building Materials Co Ltd
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/1305—Organic additives
    • C—CHEMISTRY; METALLURGY
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/135—Combustion residues, e.g. fly ash, incineration waste
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/16—Lean materials, e.g. grog, quartz
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4045—Mixtures of compounds of group C08G18/58 with other macromolecular compounds
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/26—Silicon- containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K7/00—Use of ingredients characterised by shape
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    • C08K9/00—Use of pretreated ingredients
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    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3215—Barium oxides or oxide-forming salts thereof
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract

The invention provides an elastic brick used on the ground of a toilet and a manufacturing method of the elastic brick. The elastic brick comprises a brick body. A plurality of bonding pits are distributed on the upper surface of the brick body. The longitudinal section of each bonding pit is an isosceles trapezoid with the width gradually decreased from the bottom to the top. A polyurethane elastic layer is laid on the upper surface of the brick body. The bonding pits are filled with the polyurethane elastic layer. The surface of the polyurethane elastic layer is a plane densely covered with arc protrusions with a massage effect. According to the elastic brick used on the ground of the toilet and the manufacturing method of the elastic brick, by arranging the polyurethane elastic layer on the surface of the fired brick, the anti-skid effect is achieved, falling-down and injuries caused by falling-down are prevented, and the comfort during walking is improved; the surface of the brick body is provided with the bonding pits with the small bottoms and large tops, accordingly the bonding pits can be filled with the polyurethane elastic layer, and the bonding strength between the polyurethane elastic layer and the bonding pits is improved; and the arc protrusions are distributed on the surface of the polyurethane elastic layer and can achieve the massage and anti-skid effects on the feet.

Description

A kind of elastic brick for accomodation ground and preparation method thereof
Technical field
The present invention relates to the floor tile in building material field, specifically a kind of elastic brick for accomodation ground And preparation method thereof.
Background technology
Floor tile is a kind of floor decorative material, is also floor tile, and most of floor tile is to be fired to form with clay, its chi Very little specification and shape are also varied, have the advantages that matter it is hard, it is pressure it is wear-resisting, can be moistureproof, and some have Jing after glazing treatment Decoration function, is used for the ground and floor of public building and civil buildings.
In actual life, the floor of toilet and wall substantially all enter luggage in finishing using floor tile and face brick Decorations, due to the ground often wet water of toilet, cause ground to be easy to slip, and have the ground of decorative pattern or lines using surface Although brick aesthetic property is relatively good, step on and uncomfortable.
The content of the invention
It is an object of the invention to provide a kind of elastic brick for accomodation ground and preparation method thereof, the floor tile by The tile surface for baking arranges one layer of polyurethane elastomer, not only acts as anti-skidding effect, prevents from falling down and tumble injury, Er Qieti Comfortableness during high walking.
The present invention for realize technical scheme that above-mentioned technical purpose adopted for：A kind of elasticity for accomodation ground Brick, including brick body, are distributed with some bonding pits on the upper surface of brick body, the vertical section of each bonding pit is isosceles ladder Shape, and its width is gradually reduced from bottom to top；A strata urethane elastic layer, and the poly- ammonia are equipped with the upper surface of brick body Ester elastomer layer is filled into bonding pit, and the surface of elastic polyurethane layer is plane, and has been densely covered with the arc of massage effect thereon Shape projection；
The elastic polyurethane layer is mixed by the B component of component A and component A weight 50-60%, wherein, according to weight ratio, A Component is mixed by the triisocyanate of the polyoxypropylene, the polyether-tribasic alcohol of 7-8 parts and 5-6 parts of 12-14 parts, B groups Part by the polyoxypropylene of 7-8 parts, the polyether-tribasic alcohol of 4-5 parts, the polyethyl acrylate of 2-3 parts, 5-6 parts asphalt mixtures modified by epoxy resin The modified filler of fat, the Ludox of 3-4 parts and 5-6 parts is made, the modified filler by 2-3 parts modified abandoned molecular sieve, 4-6 Part modified meerschaum suede powder, the modified hollow glass micropearl of 10-12 parts and 3-5 parts modified manometer silicon dioxide mixing and It is that first by discarded molecular sieve, that to be added to mass concentration be 20-25%, temperature is dilute for 80-90 DEG C into, the modified abandoned molecular sieve Immersion treatment 2h in salpeter solution, then filters and dry under conditions of 350 DEG C and obtain, the modified meerschaum suede powder with change Property hollow glass micropearl refer to the surface modifier I of commercially available sepiolite cashmere powder and hollow glass micropearl and its weight 3-5% respectively Stand to filter to dry after 1-2h after mixing and obtain, surface modifier used I is by KH550, ethanol, acetone and barium hydroxide according to weight Amount compares 3-4:80:2-3:The ratio of 1-2 is mixed；The modified manometer silicon dioxide be by commercially available nano silicon with The surface modifier II of its weight 3-5% is mixed to get, and the surface modifier II is by barium hydroxide, sodium carbonate and KH550 according to weight Amount compares 3-4:1-2:30 ratio is mixed；
Brick body is by major ingredient, the additive of major ingredient weight 5-6%, the enhancing powder of major ingredient weight 3-4% and major ingredient weight 12- 13% and aluminum filament of the diameter less than 1mm fire and form, according to weight ratio, the major ingredient by 12-14 parts colliery powder, The iron ore waste residue composition of the clay of 23-24 parts, the shale powder of 7-8 parts, the slag of 11-12 parts and 5-6 parts, additive is by 4-5 parts Calcium oxide and the montmorillonite powder of 1-2 parts mix, quartz sand, the 2-3 for strengthening powder by 6-7 parts particle diameter less than 1mm The SILICA FUME of part and the modified aluminas micro mist of 1-1.2 parts are obtained after being well mixed；The modified aluminas micro mist is to aoxidize Aluminium micro mist is mixed to get with the surface modifier of its weight 3-5%, and the surface modifier is pressed by barium hydroxide, sodium carbonate and KH550 Compare 3-4 according to weight:1-2:30 ratio is mixed.
The preparation method of the elastic polyurethane layer is comprised the following steps：
1）Component A is prepared, it is standby；
Respectively polyoxypropylene, polyether-tribasic alcohol and triisocyanate are weighed according to above-mentioned ratio, then by polycyclic oxygen third Alkane ether carries out decompression dehydration under conditions of vacuum is 0.096MPa, after its moisture content is less than 0.1%, is cooled to 60 DEG C, Load weighted polyether-tribasic alcohol is added thereto under conditions of stirring, 85-90 DEG C is warming up to, then stirring reaction 2h is cooled to 40 DEG C, then load weighted triisocyanate is added thereto to, it is well mixed and obtain component A；
2）B component is prepared, it is standby；
Weigh polyoxypropylene, polyether-tribasic alcohol, polyethyl acrylate, epoxy resin, silicon according to above-mentioned ratio respectively molten Glue and modified filler, then by polyoxypropylene, decompression dehydration is less than to moisture content under conditions of vacuum is 0.096MPa 0.1%, epoxy resin is then added thereto to, after epoxy resin melts, 50 DEG C are cooled to, then it is added thereto to successively gather Ether trihydroxylic alcohol, polyethyl acrylate, Ludox and modified filler, stirs the B component that obtain；
3）When in use, the B component mixing of component A and its weight 50-60% is obtained into elastic polyurethane layer.
According to weight ratio, the epoxy resin by 3 parts bisphenol A type epoxy resin, 1 part of aliphatic epoxy resin, 0.5 Part polypropylene fibre, 0.5 part of modified manometer silicon dioxide and 0.5 part of modified silicasol make, the modified Nano two Silica is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 3-5%, and surface modifier II is by hydrogen Barium monoxide, sodium carbonate and KH550 compare 3-4 according to weight:1-2:30 ratio is mixed；The modified silicasol is commercially available Silicon powder, the crystal whisker of hexa potassium titanate of Ludox weight 1-2% and the Ludox weight of Ludox weight 2-3% are sequentially added in Ludox The sodium acetate of amount 0.8-1%, then stirs the mixture that 1-2h is obtained under the conditions of 70-80 DEG C.
Also containing 0.4 part of glass fiber in the epoxy resin.
Also containing 0.3 part of nano aluminium oxide in the epoxy resin.
The preparation method of the epoxy resin is comprised the following steps：
1）Modified manometer silicon dioxide and modified silicasol are prepared respectively, it is standby；
The modified manometer silicon dioxide is to mix commercially available nano silicon with the surface modifier II of its weight 3-5% Arrive, surface modifier II compares 3-4 by barium hydroxide, sodium carbonate and KH550 according to weight:1-2:30 ratio is mixed；
The modified silicasol is silicon powder, Ludox weight 1- that Ludox weight 2-3% is sequentially added in commercially available Ludox 2% crystal whisker of hexa potassium titanate and the sodium acetate of Ludox weight 0.8-1%, then stir what 1-2h was obtained under the conditions of 70-80 DEG C Mixture；
2）Each component is weighed according to described ratio, after then bisphenol A type epoxy resin is melted, is added thereto to load weighted Aliphatic epoxy resin and polypropylene fibre, stir after melting completely, then are added thereto to step 1）Obtained modified Nano Silica and modified silicasol, are obtained epoxy resin after stirring.
Talcum powder in the enhancing powder also containing 1-1.2 parts particle diameter less than 300 microns.
Also containing the basalt powder of 1-2 parts in the additive.
The preparation method of the above-mentioned elastic brick for accomodation ground, comprises the following steps：
1）Modified aluminas micro mist is prepared, it is standby；
Alumina powder is mixed to get with the surface modifier of its weight 3-5%, the surface modifier is by barium hydroxide, carbonic acid Sodium and KH550 compare 3-4 according to weight:1-2:30 ratio is mixed；
2）According to above-mentioned requirement weigh respectively composition major ingredient, additive and strengthen powder each raw material mixing and grinding to fineness not It is standby so as to major ingredient powder, additive being obtained and strengthening powder more than 100 microns；
Aluminum filament of the diameter less than 1mm is weighed, it is standby；
3）By step 2）Obtained major ingredient powder, additive and enhancing powder mixing, then sequentially add thereto major ingredient grain weight amount 40- 50% water and the mix liquid of major ingredient grain weight amount 3-5%, mix uniformly obtains pug, and after pug is aged 6-8 days, it is standby；
It is 10 according to weight ratio that the mix liquid is waste oil, starch and glucose:1:1 ratio is mixed；
4）Take step 2）The aluminum filament for weighing mixes rear and step 3）Pug mix after middle ageing is uniform, then makes brick Base, and dry at a temperature of 90-110 DEG C, it is standby；
5）By step 4）Adobe after middle drying is sintered, and brick body is obtained after natural cooling, then lays on the surface of brick body One strata urethane elastic layer, that is, obtain product；
The sintering is divided into preheating section, warming-up section and the part of furnace zone three, wherein, preheating section is to instigate in-furnace temperature to exist from normal temperature 3h is uniformly increased to 350 DEG C, and keeps temperature 1-2h, and in the process, oxygen content is not higher than 4% in holding furnace；
The warming-up section refers to, makes in-furnace temperature uniformly be increased to 950 DEG C in 4h from 350 DEG C, and keeps temperature 1-2h, here During, oxygen content is not less than 45% in holding furnace；
The furnace zone refers to, makes in-furnace temperature uniformly be increased to 1550 DEG C in 2h from 950 DEG C, and keeps temperature 3-4h, During this, oxygen content is not less than 35% in holding furnace.
In the present invention, modified abandoned molecular sieve, modified meerschaum suede powder are contained in the modified filler of elastic polyurethane layer, is changed Property hollow glass micropearl and modified manometer silicon dioxide, this several material can be dispersed in polyurethane matrix, on the one hand, Modified abandoned molecular sieve and modified meerschaum suede powder have very big internal surface area, and it is the micro mist with microcellular structure, these Microcellular structure can effectively cut down the transmission of vibrations and absorb moisture, on the other hand be that hollow glass micropearl table is made in modifying process Face is grafted substantial amounts of silicone hydroxyl, and these groups are coupled together hollow glass micropearl with matrix by chemical reaction, it is ensured that the two With good interface binding power, when by external force, hollow glass micropearl particle is stressed in the material generation shape to material Become, destroy etc., so as to apparatus with shock absorbing, impact property is improved, while crazing can also be caused, terminate crack extension, one Determine the shear yielding for causing matrix under morphosis, so as to consume substantial amounts of impact energy, can preferably transmit what is born again External force, improves compressive strength, bending strength, the impact strength of elastic polyurethane layer；
When making modified manometer silicon dioxide in the present invention, by the use of barium hydroxide and sodium carbonate mixing as catalyst by nanoscale SiO2The hard to bear effect to hydroxyl of surface energy of particle, so as to contain a number of oxygen-containing functional group, increased nanoscale SiO2The relevant surface compatability of particle, in nanoscale SiO2When particle is sufficiently mixed with remaining raw material, because SiO2Particle is very It is little, and specific surface area is big, the structure of granular causes rest materials to increase with its contact area, makes SiO2Particle can be in thing It is dispersed in material, consequently facilitating SiO2There is chemical bonding or physical bond at high temperature with remaining material.Additionally, uniform Scattered nanoscale SiO2Equivalent to " anchor point ", it can make the reinforcing matrix generated under hot environment in connection, be subject to Under external impacts effect, the effect of " stress concentration " can be produced so that some matrixes " surrender " around it simultaneously absorb more Work of deformation, can also produce " pinning-climb up and over " effect in addition, increase the crackle resistance suffered in extension, consume deformation Work(, so that its toughness increases；
Epoxy resin in the elastic polyurethane layer of the present invention is fine by bisphenol A type epoxy resin, aliphatic epoxy resin, polypropylene Dimension, modified manometer silicon dioxide and modified silicasol are made, and improve the toughness of material.Add modified silicasol micro- in system Grain and modified manometer silicon dioxide, can substantially improve the mechanical property and thermal property of material, while also finding that modified silicon is molten Final IPN form of the addition of glue particulate to component mixing, the raising of the tensile property of product and product in preparation process It is favourable；
In the present invention, to fire colliery powder, clay, shale powder, slag and the iron ore waste residue of floor tile as major ingredient, wherein containing SiO2Mullite is generated with oxidation reactive aluminum, so as to form mullite reinforcement in floor tile；In sintering process, aluminum oxide Hercynite structure can be generated with iron oxide, so as to strengthen its intensity；Calcium oxide and montmorillonite powder in additive can Effectively reduce sintering temperature；Mix was carried out before firing with special mix liquid so that its stickiness and plasticity are increased By force；
Strengthen the double ginseng of quartz sand and SILICA FUME in powder, can in improvement system particle it is tightly packed, modified aluminas micro mist is lived Property it is big, even dispersion greatly improves its filling rate in whole system, and three kinds of materials realize compound volcano ash effect, to improving The compression strength of material has very strong effect；
In sintering process, aluminum filament melts and is filled in the hole of part the brick body of the present invention, acts not only as brick body Skeleton strengthen its intensity, and in sintering process, a part of aluminum oxidation forms aluminum oxide so as to combine closely with floor tile, increases The intensity and globality of strong floor tile.
Beneficial effect：Compared with the existing, the present invention has advantages below：
1）The elastic brick not only acts as anti-skidding effect by arranging a strata urethane elastic layer on the brick body surface for baking, Comfortableness when preventing from falling down and resulting tumble injury, and improve walking；The surface of brick body is provided with the little top in bottom Big bonding pit, so that elastic polyurethane layer can be filled into bonding pit, improves both adhesive strengths；Polyurethane Elastic layer surface distributed has arc-shaped protrusions, and the anti-skidding effect of massage can be played to foot；
4）In the present invention, modified abandoned molecular sieve, modified meerschaum suede powder are contained in the modified filler of elastic polyurethane layer, is modified Hollow glass micropearl and modified manometer silicon dioxide, this several material can be dispersed in polyurethane matrix, on the one hand, changed Property discarded molecular sieve and modified meerschaum suede powder there is very big internal surface area, it is the micro mist with microcellular structure, and this is slightly Pore structure can effectively cut down the transmission of vibrations and absorb moisture, on the other hand be that hollow glass micropearl surface is made in modifying process Substantial amounts of silicone hydroxyl is grafted, these groups are coupled together hollow glass micropearl with matrix by chemical reaction, it is ensured that the two tool Have a good interface binding power, material when by external force, hollow glass micropearl particle be stressed in the material deform upon, Destruction etc., so as to apparatus with shock absorbing, improves impact property, while crazing can also be caused, terminates crack extension, in a setting Cause the shear yielding of matrix under state structure, so as to consume substantial amounts of impact energy, born external force can be preferably transmitted again, Improve compressive strength, bending strength, the impact strength of elastic polyurethane layer；
3）The present invention to fire colliery powder, clay, shale powder, slag and the iron ore waste residue of floor tile as major ingredient, wherein containing SiO2Mullite is generated with oxidation reactive aluminum, so as to form mullite reinforcement in floor tile；In sintering process, aluminum oxide Hercynite structure can be generated with iron oxide, so as to strengthen its intensity；Calcium oxide and montmorillonite powder in additive can Effectively reduce sintering temperature；Mix was carried out before firing with special mix liquid so that its stickiness and plasticity are increased By force；
4）In sintering process, aluminum filament melts and is filled in the hole of part the brick body of the present invention, acts not only as brick The skeleton of body strengthens its intensity, and in sintering process, a part of aluminum oxidation forms aluminum oxide so as to combine closely with floor tile, Enhance the intensity and globality of floor tile.
Description of the drawings
Fig. 1 is the structural representation of the present invention；
Reference：1st, brick body, 101, bonding pit, 2, elastic polyurethane layer, 201, arc-shaped protrusions.
Specific embodiment
With reference to specific embodiment, the present invention is further elaborated.
Embodiment 1
As illustrated, a kind of elastic brick for accomodation ground, including brick body 1, it is distributed with the upper surface of brick body 1 some viscous Pit 101 is connect, the vertical section of each bonding pit 101 is isosceles trapezoid, and its width is gradually reduced from bottom to top；Brick A strata urethane elastic layer 2 is equipped with the upper surface of body 1, and the elastic polyurethane layer 2 is filled into bonding pit 101, is gathered The surface of urethane elastic layer 2 is plane, and has been densely covered with the arc-shaped protrusions 201 of massage effect thereon；
The elastic polyurethane layer 2 is mixed by the B component of component A and component A weight 50%, wherein, according to weight ratio, A groups Part by 12 parts polyoxypropylene, 7 parts of polyether-tribasic alcohol and 5 parts of triisocyanate be mixed, B component is by 7 parts Polyoxypropylene, 4 parts of polyether-tribasic alcohol, 2 parts of polyethyl acrylate, 5 parts of epoxy resin, 3 parts of Ludox and 5 parts Modified filler make, the modified filler by 2 parts modified abandoned molecular sieve, 4 parts of modified meerschaum suede powder, 10 parts change Property hollow glass micropearl and 3 parts of modified manometer silicon dioxide mix, the modified abandoned molecular sieve is first will discarded point It is immersion treatment 2h in the dilute nitric acid solution that 20%, temperature is 80 DEG C that son sieve is added to mass concentration, is then filtered and at 350 DEG C Under conditions of dry and obtain, the modified meerschaum suede powder and modified hollow glass micropearl refer to commercially available sepiolite cashmere powder respectively Stand to filter to dry after 1h after mixing with the surface modifier I of its weight 3% with hollow glass micropearl and obtain, surface used is modified Agent I compares 3 by KH550, ethanol, acetone and barium hydroxide according to weight:80:2:1 ratio is mixed；The modified Nano two Silica is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 3%, the surface modifier II by Barium hydroxide, sodium carbonate and KH550 compare 3 according to weight:1:30 ratio is mixed；
Brick body 1 is by major ingredient, the additive of major ingredient weight 5%, the enhancing powder of major ingredient weight 3% and major ingredient weight 12% and straight Aluminum filament of the footpath less than 1mm is fired and formed, according to weight ratio, the major ingredient by 12 parts colliery powder, 23 parts of clay, 7 parts of shale powder, 11 parts of slag and 5 parts of iron ore waste residue composition, calcium oxide and 1 part of montmorillonite powder of the additive by 4 parts Mix, the quartz sand for strengthening powder by 6 parts of particle diameters less than 1mm, 2 parts of SILICA FUME and 1 part of modified aluminas are micro- Powder is obtained after being well mixed；The modified aluminas micro mist is to mix alumina powder with the surface modifier of its weight 3% Arrive, the surface modifier compares 3 by barium hydroxide, sodium carbonate and KH550 according to weight:1:30 ratio is mixed；
The preparation method of the above-mentioned elastic brick for accomodation ground, comprises the following steps：
1）Modified aluminas micro mist is prepared, it is standby；
Alumina powder is mixed to get with the surface modifier of its weight 3%, the surface modifier is by barium hydroxide, sodium carbonate Compare 3 according to weight with KH550:1:30 ratio is mixed；
2）According to above-mentioned requirement weigh respectively composition major ingredient, additive and strengthen powder each raw material mixing and grinding to fineness not It is standby so as to major ingredient powder, additive being obtained and strengthening powder more than 100 microns；
Aluminum filament of the diameter less than 1mm is weighed, it is standby；
3）By step 2）Obtained major ingredient powder, additive and enhancing powder mixing, then sequentially add thereto major ingredient grain weight amount 40% Water and major ingredient grain weight amount 3% mix liquid, mix uniformly obtains pug, and after pug is aged 6 days, standby；
It is 10 according to weight ratio that the mix liquid is waste oil, starch and glucose:1:1 ratio is mixed；
4）Take step 2）The aluminum filament for weighing mixes rear and step 3）Pug mix after middle ageing is uniform, then makes brick Base, and dry at a temperature of 90 DEG C, it is standby；
5）By step 4）Adobe after middle drying is sintered, and brick body 1 is obtained after natural cooling, then spreads on the surface of brick body 1 If a strata urethane elastic layer 2, that is, obtain product；
The sintering is divided into preheating section, warming-up section and the part of furnace zone three, wherein, preheating section is to instigate in-furnace temperature to exist from normal temperature 3h is uniformly increased to 350 DEG C, and keeps temperature 1h, and in the process, oxygen content is not higher than 4% in holding furnace；
The warming-up section refers to, makes in-furnace temperature uniformly be increased to 950 DEG C in 4h from 350 DEG C, and keeps temperature 1h, here mistake Cheng Zhong, oxygen content is not less than 45% in holding furnace；
The furnace zone refers to, makes in-furnace temperature uniformly be increased to 1550 DEG C in 2h from 950 DEG C, and keeps temperature 3h, here During, oxygen content is not less than 35% in holding furnace.
Above for the present embodiment basic embodiment, can more than on the basis of be further optimized, improve and limit：
Such as, the preparation method of the elastic polyurethane layer 2 is comprised the following steps：
1）Component A is prepared, it is standby；
Respectively polyoxypropylene, polyether-tribasic alcohol and triisocyanate are weighed according to above-mentioned ratio, then by polycyclic oxygen third Alkane ether carries out decompression dehydration under conditions of vacuum is 0.096MPa, after its moisture content is less than 0.1%, is cooled to 60 DEG C, Load weighted polyether-tribasic alcohol is added thereto under conditions of stirring, 85 DEG C are warming up to, then stirring reaction 2h is cooled to 40 DEG C, then load weighted triisocyanate is added thereto to, it is well mixed and obtain component A；
2）B component is prepared, it is standby；
Weigh polyoxypropylene, polyether-tribasic alcohol, polyethyl acrylate, epoxy resin, silicon according to above-mentioned ratio respectively molten Glue and modified filler, then by polyoxypropylene, decompression dehydration is less than to moisture content under conditions of vacuum is 0.096MPa 0.1%, epoxy resin is then added thereto to, after epoxy resin melts, 50 DEG C are cooled to, then it is added thereto to successively gather Ether trihydroxylic alcohol, polyethyl acrylate, Ludox and modified filler, stirs the B component that obtain；
3）When in use, the B component mixing of component A and its weight 50% is obtained into elastic polyurethane layer 2；
And for example, according to weight ratio, the epoxy resin by 3 parts bisphenol A type epoxy resin, 1 part of aliphatic epoxy resin, 0.5 part of polypropylene fibre, 0.5 part of modified manometer silicon dioxide and 0.5 part of modified silicasol are made, the modified Nano Silica is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 3%, and surface modifier II is by hydrogen Barium monoxide, sodium carbonate and KH550 compare 3 according to weight:1:30 ratio is mixed；The modified silicasol is molten in commercially available silicon Silicon powder, the crystal whisker of hexa potassium titanate of Ludox weight 1% and the Ludox weight 0.8% of Ludox weight 2% are sequentially added in glue Sodium acetate, then stirs the mixture that 1h is obtained under the conditions of 70 DEG C；
Further, the preparation method of the epoxy resin is comprised the following steps：
1）Modified manometer silicon dioxide and modified silicasol are prepared respectively, it is standby；
The modified manometer silicon dioxide is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 3%, Surface modifier II compares 3 by barium hydroxide, sodium carbonate and KH550 according to weight:1:30 ratio is mixed；
The modified silicasol is silicon powder, the Ludox weight 1% that Ludox weight 2% is sequentially added in commercially available Ludox The sodium acetate of crystal whisker of hexa potassium titanate and Ludox weight 0.8%, then stirs the mixture that 1h is obtained under the conditions of 70 DEG C；
2）Each component is weighed according to described ratio, after then bisphenol A type epoxy resin is melted, is added thereto to load weighted Aliphatic epoxy resin and polypropylene fibre, stir after melting completely, then are added thereto to step 1）Obtained modified Nano Silica and modified silicasol, are obtained epoxy resin after stirring.
Further, also containing 0.4 part of glass fiber in the epoxy resin；
Further, also containing 0.3 part of nano aluminium oxide in the epoxy resin；
For another example, the talcum powder strengthened in powder also containing 1 part of particle diameter less than 300 microns；
Finally, also containing 1 part of basalt powder in the additive.
Embodiment 2
As illustrated, a kind of elastic brick for accomodation ground, including brick body 1, it is distributed with the upper surface of brick body 1 some viscous Pit 101 is connect, the vertical section of each bonding pit 101 is isosceles trapezoid, and its width is gradually reduced from bottom to top；Brick A strata urethane elastic layer 2 is equipped with the upper surface of body 1, and the elastic polyurethane layer 2 is filled into bonding pit 101, is gathered The surface of urethane elastic layer 2 is plane, and has been densely covered with the arc-shaped protrusions 201 of massage effect thereon；
The elastic polyurethane layer 2 is mixed by the B component of component A and component A weight 60%, wherein, according to weight ratio, A groups Part by 14 parts polyoxypropylene, 8 parts of polyether-tribasic alcohol and 6 parts of triisocyanate be mixed, B component is by 8 parts Polyoxypropylene, 5 parts of polyether-tribasic alcohol, 3 parts of polyethyl acrylate, 6 parts of epoxy resin, 4 parts of Ludox and 6 parts Modified filler make, the modified filler by 3 parts modified abandoned molecular sieve, 6 parts of modified meerschaum suede powder, 12 parts change Property hollow glass micropearl and 5 parts of modified manometer silicon dioxide mix, the modified abandoned molecular sieve is first will discarded point It is immersion treatment 2h in the dilute nitric acid solution that 25%, temperature is 90 DEG C that son sieve is added to mass concentration, is then filtered and at 350 DEG C Under conditions of dry and obtain, the modified meerschaum suede powder and modified hollow glass micropearl refer to commercially available sepiolite cashmere powder respectively Stand to filter to dry after 2h after mixing with the surface modifier I of its weight 5% with hollow glass micropearl and obtain, surface used is modified Agent I compares 4 by KH550, ethanol, acetone and barium hydroxide according to weight:80:3:2 ratio is mixed；The modified Nano two Silica is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 5%, the surface modifier II by Barium hydroxide, sodium carbonate and KH550 compare 4 according to weight:2:30 ratio is mixed；
Brick body 1 is by major ingredient, the additive of major ingredient weight 6%, the enhancing powder of major ingredient weight 4% and major ingredient weight 13% and straight Aluminum filament of the footpath less than 1mm is fired and formed, according to weight ratio, the major ingredient by 14 parts colliery powder, 24 parts of clay, 8 parts of shale powder, 12 parts of slag and 6 parts of iron ore waste residue composition, calcium oxide and 2 part of montmorillonite powder of the additive by 5 parts Mix, the quartz sand for strengthening powder by 7 parts of particle diameters less than 1mm, 3 parts of SILICA FUME and 1.2 parts of modified aluminas Micro mist is obtained after being well mixed；The modified aluminas micro mist is to mix alumina powder with the surface modifier of its weight 5% Obtain, the surface modifier compares 4 by barium hydroxide, sodium carbonate and KH550 according to weight:2:30 ratio is mixed；
The preparation method of the above-mentioned elastic brick for accomodation ground, comprises the following steps：
1）Modified aluminas micro mist is prepared, it is standby；
Alumina powder is mixed to get with the surface modifier of its weight 5%, the surface modifier is by barium hydroxide, sodium carbonate Compare 4 according to weight with KH550:2:30 ratio is mixed；
2）According to above-mentioned requirement weigh respectively composition major ingredient, additive and strengthen powder each raw material mixing and grinding to fineness not It is standby so as to major ingredient powder, additive being obtained and strengthening powder more than 100 microns；
Aluminum filament of the diameter less than 1mm is weighed, it is standby；
3）By step 2）Obtained major ingredient powder, additive and enhancing powder mixing, then sequentially add thereto major ingredient grain weight amount 50% Water and major ingredient grain weight amount 5% mix liquid, mix uniformly obtains pug, and after pug is aged 8 days, standby；
It is 10 according to weight ratio that the mix liquid is waste oil, starch and glucose:1:1 ratio is mixed；
4）Take step 2）The aluminum filament for weighing mixes rear and step 3）Pug mix after middle ageing is uniform, then makes brick Base, and dry at a temperature of 110 DEG C, it is standby；
5）By step 4）Adobe after middle drying is sintered, and brick body 1 is obtained after natural cooling, then spreads on the surface of brick body 1 If a strata urethane elastic layer 2, that is, obtain product；
The sintering is divided into preheating section, warming-up section and the part of furnace zone three, wherein, preheating section is to instigate in-furnace temperature to exist from normal temperature 3h is uniformly increased to 350 DEG C, and keeps temperature 2h, and in the process, oxygen content is not higher than 4% in holding furnace；
The warming-up section refers to, makes in-furnace temperature uniformly be increased to 950 DEG C in 4h from 350 DEG C, and keeps temperature 2h, here mistake Cheng Zhong, oxygen content is not less than 45% in holding furnace；
The furnace zone refers to, makes in-furnace temperature uniformly be increased to 1550 DEG C in 2h from 950 DEG C, and keeps temperature 4h, here During, oxygen content is not less than 35% in holding furnace.
Above for the present embodiment basic embodiment, can more than on the basis of be further optimized, improve and limit：
Such as, the preparation method of the elastic polyurethane layer 2 is comprised the following steps：
1）Component A is prepared, it is standby；
Respectively polyoxypropylene, polyether-tribasic alcohol and triisocyanate are weighed according to above-mentioned ratio, then by polycyclic oxygen third Alkane ether carries out decompression dehydration under conditions of vacuum is 0.096MPa, after its moisture content is less than 0.1%, is cooled to 60 DEG C, Load weighted polyether-tribasic alcohol is added thereto under conditions of stirring, 90 DEG C are warming up to, then stirring reaction 2h is cooled to 40 DEG C, then load weighted triisocyanate is added thereto to, it is well mixed and obtain component A；
2）B component is prepared, it is standby；
Weigh polyoxypropylene, polyether-tribasic alcohol, polyethyl acrylate, epoxy resin, silicon according to above-mentioned ratio respectively molten Glue and modified filler, then by polyoxypropylene, decompression dehydration is less than to moisture content under conditions of vacuum is 0.096MPa 0.1%, epoxy resin is then added thereto to, after epoxy resin melts, 50 DEG C are cooled to, then it is added thereto to successively gather Ether trihydroxylic alcohol, polyethyl acrylate, Ludox and modified filler, stirs the B component that obtain；
3）When in use, the B component mixing of component A and its weight 60% is obtained into elastic polyurethane layer 2；
And for example, according to weight ratio, the epoxy resin by 3 parts bisphenol A type epoxy resin, 1 part of aliphatic epoxy resin, 0.5 part of polypropylene fibre, 0.5 part of modified manometer silicon dioxide and 0.5 part of modified silicasol are made, the modified Nano Silica is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 5%, and surface modifier II is by hydrogen Barium monoxide, sodium carbonate and KH550 compare 4 according to weight:2:30 ratio is mixed；The modified silicasol is molten in commercially available silicon The second of the silicon powder, the crystal whisker of hexa potassium titanate of Ludox weight 2% and Ludox weight 1% of Ludox weight 3% is sequentially added in glue Sour sodium, then stirs the mixture that 2h is obtained under the conditions of 80 DEG C；
Further, the preparation method of the epoxy resin is comprised the following steps：
1）Modified manometer silicon dioxide and modified silicasol are prepared respectively, it is standby；
The modified manometer silicon dioxide is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 5%, Surface modifier II compares 4 by barium hydroxide, sodium carbonate and KH550 according to weight:2:30 ratio is mixed；
The modified silicasol is silicon powder, the Ludox weight 2% that Ludox weight 3% is sequentially added in commercially available Ludox The sodium acetate of crystal whisker of hexa potassium titanate and Ludox weight 1%, then stirs the mixture that 2h is obtained under the conditions of 80 DEG C；
2）Each component is weighed according to described ratio, after then bisphenol A type epoxy resin is melted, is added thereto to load weighted Aliphatic epoxy resin and polypropylene fibre, stir after melting completely, then are added thereto to step 1）Obtained modified Nano Silica and modified silicasol, are obtained epoxy resin after stirring.
Further, also containing 0.4 part of glass fiber in the epoxy resin；
Further, also containing 0.3 part of nano aluminium oxide in the epoxy resin；
For another example, the talcum powder strengthened in powder also containing 1.2 parts of particle diameters less than 300 microns；
Finally, also containing 2 parts of basalt powder in the additive.
Embodiment 3
As illustrated, a kind of elastic brick for accomodation ground, including brick body 1, it is distributed with the upper surface of brick body 1 some viscous Pit 101 is connect, the vertical section of each bonding pit 101 is isosceles trapezoid, and its width is gradually reduced from bottom to top；Brick A strata urethane elastic layer 2 is equipped with the upper surface of body 1, and the elastic polyurethane layer 2 is filled into bonding pit 101, is gathered The surface of urethane elastic layer 2 is plane, and has been densely covered with the arc-shaped protrusions 201 of massage effect thereon；
The elastic polyurethane layer 2 is mixed by the B component of component A and component A weight 55%, wherein, according to weight ratio, A groups Part by 13 parts polyoxypropylene, 7.5 parts of polyether-tribasic alcohol and 5.5 parts of triisocyanate be mixed, B component by 7.5 parts of polyoxypropylene, 4.5 parts of polyether-tribasic alcohol, 2.5 parts of polyethyl acrylate, 5.5 parts of epoxy resin, 3.5 Part Ludox and 5.5 parts of modified filler make, modified abandoned molecular sieve, 5 part modified of the modified filler by 2.5 parts Sepiolite cashmere powder, 11 parts of modified hollow glass micropearl and 4 parts of modified manometer silicon dioxide are mixed, described modified abandoned Molecular sieve is that first discarded molecular sieve to be added into mass concentration be immersion treatment in the dilute nitric acid solution that 22.5%, temperature is 85 DEG C 2h, then filters and dries under conditions of 350 DEG C and obtain, and the modified meerschaum suede powder and modified hollow glass micropearl refer to point Stand after not mixing commercially available sepiolite cashmere powder and hollow glass micropearl with the surface modifier I of its weight 4% after 1.5h and filter Dry and obtain, surface modifier used I compares 3.5 by KH550, ethanol, acetone and barium hydroxide according to weight:80:2.5:1.5 Ratio is mixed；The modified manometer silicon dioxide is the surface modifier by commercially available nano silicon and its weight 4% II is mixed to get, and the surface modifier II compares 3.5 by barium hydroxide, sodium carbonate and KH550 according to weight:1.5:30 ratio is mixed Conjunction is formed；
Brick body 1 is by major ingredient, the additive of major ingredient weight 5.5%, the enhancing powder of major ingredient weight 3.5% and major ingredient weight 12.5% and aluminum filament of the diameter less than 1mm fire and form, according to weight ratio, the major ingredient by 13 parts colliery powder, 23.5 parts of clay, 7.5 parts of shale powder, 11.5 parts of slag and 5.5 parts of iron ore waste residue composition, additive is by 4.5 parts Calcium oxide and 1.5 parts of montmorillonite powder are mixed, it is described strengthen powder by 6.5 parts of particle diameters less than 1mm quartz sand, 2.5 parts SILICA FUME and 1.1 parts of modified aluminas micro mist be well mixed after obtain；The modified aluminas micro mist is that aluminum oxide is micro- Powder is mixed to get with the surface modifier of its weight 4%, and the surface modifier is by barium hydroxide, sodium carbonate and KH550 according to weight Than 3.5:1.5:30 ratio is mixed；
The preparation method of the above-mentioned elastic brick for accomodation ground, comprises the following steps：
1）Modified aluminas micro mist is prepared, it is standby；
Alumina powder is mixed to get with the surface modifier of its weight 4%, the surface modifier is by barium hydroxide, sodium carbonate Compare 3.5 according to weight with KH550:1.5:30 ratio is mixed；
2）According to above-mentioned requirement weigh respectively composition major ingredient, additive and strengthen powder each raw material mixing and grinding to fineness not It is standby so as to major ingredient powder, additive being obtained and strengthening powder more than 100 microns；
Aluminum filament of the diameter less than 1mm is weighed, it is standby；
3）By step 2）Obtained major ingredient powder, additive and enhancing powder mixing, then sequentially add thereto major ingredient grain weight amount 45% Water and major ingredient grain weight amount 4% mix liquid, mix uniformly obtains pug, and after pug is aged 7 days, standby；
It is 10 according to weight ratio that the mix liquid is waste oil, starch and glucose:1:1 ratio is mixed；
4）Take step 2）The aluminum filament for weighing mixes rear and step 3）Pug mix after middle ageing is uniform, then makes brick Base, and dry at a temperature of 100 DEG C, it is standby；
5）By step 4）Adobe after middle drying is sintered, and brick body 1 is obtained after natural cooling, then spreads on the surface of brick body 1 If a strata urethane elastic layer 2, that is, obtain product；
The sintering is divided into preheating section, warming-up section and the part of furnace zone three, wherein, preheating section is to instigate in-furnace temperature to exist from normal temperature 3h is uniformly increased to 350 DEG C, and keeps temperature 1.5h, and in the process, oxygen content is not higher than 4% in holding furnace；
The warming-up section refers to, makes in-furnace temperature uniformly be increased to 950 DEG C in 4h from 350 DEG C, and keeps temperature 1.5h, here During, oxygen content is not less than 45% in holding furnace；
The furnace zone refers to, makes in-furnace temperature uniformly be increased to 1550 DEG C in 2h from 950 DEG C, and keeps temperature 3.5h, During this, oxygen content is not less than 35% in holding furnace.
Above for the present embodiment basic embodiment, can more than on the basis of be further optimized, improve and limit：
Such as, the preparation method of the elastic polyurethane layer 2 is comprised the following steps：
1）Component A is prepared, it is standby；
Respectively polyoxypropylene, polyether-tribasic alcohol and triisocyanate are weighed according to above-mentioned ratio, then by polycyclic oxygen third Alkane ether carries out decompression dehydration under conditions of vacuum is 0.096MPa, after its moisture content is less than 0.1%, is cooled to 60 DEG C, Load weighted polyether-tribasic alcohol is added thereto under conditions of stirring, 88 DEG C are warming up to, then stirring reaction 2h is cooled to 40 DEG C, then load weighted triisocyanate is added thereto to, it is well mixed and obtain component A；
2）B component is prepared, it is standby；
Weigh polyoxypropylene, polyether-tribasic alcohol, polyethyl acrylate, epoxy resin, silicon according to above-mentioned ratio respectively molten Glue and modified filler, then by polyoxypropylene, decompression dehydration is less than to moisture content under conditions of vacuum is 0.096MPa 0.1%, epoxy resin is then added thereto to, after epoxy resin melts, 50 DEG C are cooled to, then it is added thereto to successively gather Ether trihydroxylic alcohol, polyethyl acrylate, Ludox and modified filler, stirs the B component that obtain；
3）When in use, the B component mixing of component A and its weight 55% is obtained into elastic polyurethane layer 2；
And for example, according to weight ratio, the epoxy resin by 3 parts bisphenol A type epoxy resin, 1 part of aliphatic epoxy resin, 0.5 part of polypropylene fibre, 0.5 part of modified manometer silicon dioxide and 0.5 part of modified silicasol are made, the modified Nano Silica is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 4%, and surface modifier II is by hydrogen Barium monoxide, sodium carbonate and KH550 compare 3.5 according to weight:1.5:30 ratio is mixed；The modified silicasol is commercially available Silicon powder, the crystal whisker of hexa potassium titanate of Ludox weight 1.5% and the Ludox weight of Ludox weight 2.5% are sequentially added in Ludox The sodium acetate of amount 0.9%, then stirs the mixture that 1.5h is obtained under the conditions of 75 DEG C；
Further, the preparation method of the epoxy resin is comprised the following steps：
1）Modified manometer silicon dioxide and modified silicasol are prepared respectively, it is standby；
The modified manometer silicon dioxide is to be mixed to get commercially available nano silicon with the surface modifier II of its weight 4%, Surface modifier II compares 3.5 by barium hydroxide, sodium carbonate and KH550 according to weight:1.5:30 ratio is mixed；
The modified silicasol is silicon powder, the Ludox weight that Ludox weight 2.5% is sequentially added in commercially available Ludox 1.5% crystal whisker of hexa potassium titanate and the sodium acetate of Ludox weight 0.9%, then stir the mixing that 1.5h is obtained under the conditions of 75 DEG C Thing；
2）Each component is weighed according to described ratio, after then bisphenol A type epoxy resin is melted, is added thereto to load weighted Aliphatic epoxy resin and polypropylene fibre, stir after melting completely, then are added thereto to step 1）Obtained modified Nano Silica and modified silicasol, are obtained epoxy resin after stirring.
Further, also containing 0.4 part of glass fiber in the epoxy resin；
Further, also containing 0.3 part of nano aluminium oxide in the epoxy resin；
For another example, the talcum powder strengthened in powder also containing 1.1 parts of particle diameters less than 300 microns；
Finally, also containing 1.5 parts of basalt powder in the additive.

Claims (9)

1. a kind of elastic brick for accomodation ground, it is characterised in that：Including brick body（1）, brick body（1）Upper surface on be distributed There are some bonding pits（101）, each bonding pit（101）Vertical section be isosceles trapezoid, and its width is from bottom to top Portion is gradually reduced；Brick body（1）Upper surface on be equipped with a strata urethane elastic layer（2）, and the elastic polyurethane layer（2）Filling Enter bonding pit（101）It is interior, elastic polyurethane layer（2）Surface be plane, and it is prominent to be densely covered with the arc of massage effect thereon Rise（201）；
The elastic polyurethane layer（2）Mixed by the B component of component A and component A weight 50-60%, wherein, according to weight Than, component A is mixed by the triisocyanate of the polyoxypropylene, the polyether-tribasic alcohol of 7-8 parts and 5-6 parts of 12-14 parts, B component by the polyoxypropylene of 7-8 parts, the polyether-tribasic alcohol of 4-5 parts, the polyethyl acrylate of 2-3 parts, 5-6 parts epoxy The modified filler of resin, the Ludox of 3-4 parts and 5-6 parts is made, the modified filler by 2-3 parts modified abandoned molecular sieve, The modified manometer silicon dioxide mixing of the modified meerschaum suede powder, the modified hollow glass micropearl of 10-12 parts and 3-5 parts of 4-6 parts Form, the modified abandoned molecular sieve be first by discarded molecular sieve be added to mass concentration for 20-25%, temperature be 80-90 DEG C Immersion treatment 2h in dilute nitric acid solution, then filters and dry under conditions of 350 DEG C and obtain, the modified meerschaum suede powder with Modified hollow glass micropearl refers to commercially available sepiolite cashmere powder and hollow glass micropearl are modified with the surface of its weight 3-5% respectively Agent I stands to filter to dry after 1-2h after mixing and obtains, and surface modifier used I is pressed by KH550, ethanol, acetone and barium hydroxide Compare 3-4 according to weight:80:2-3:The ratio of 1-2 is mixed；The modified manometer silicon dioxide is by commercially available nanometer titanium dioxide Silicon is mixed to get with the surface modifier II of its weight 3-5%, and the surface modifier II is pressed by barium hydroxide, sodium carbonate and KH550 Compare 3-4 according to weight:1-2:30 ratio is mixed；
Brick body（1）By major ingredient, the additive of major ingredient weight 5-6%, the enhancing powder of major ingredient weight 3-4% and major ingredient weight The aluminum filament of 12-13% and diameter less than 1mm is fired and formed, according to weight ratio, the major ingredient by 12-14 parts gangue The iron ore waste residue composition of powder, the clay of 23-24 parts, the shale powder of 7-8 parts, the slag of 11-12 parts and 5-6 parts, additive is by 4-5 The calcium oxide of part and the montmorillonite powder of 1-2 parts are mixed, quartz sand, the 2- for strengthening powder by 6-7 parts particle diameter less than 1mm 3 parts of SILICA FUME and the modified aluminas micro mist of 1-1.2 parts are obtained after being well mixed；The modified aluminas micro mist is to aoxidize Aluminium micro mist is mixed to get with the surface modifier of its weight 3-5%, and the surface modifier is pressed by barium hydroxide, sodium carbonate and KH550 Compare 3-4 according to weight:1-2:30 ratio is mixed.
2. a kind of elastic brick for accomodation ground according to claim 1, it is characterised in that：The elastic polyurethane The preparation method of layer is comprised the following steps：
1）Component A is prepared, it is standby；
Respectively polyoxypropylene, polyether-tribasic alcohol and triisocyanate are weighed according to the ratio described in claim 1, then will Polyoxypropylene carries out decompression dehydration under conditions of vacuum is 0.096MPa, after its moisture content is less than 0.1%, cooling To 60 DEG C, load weighted polyether-tribasic alcohol is added thereto under conditions of stirring, is warming up to 85-90 DEG C, stirring reaction 2h, so After be cooled to 40 DEG C, then be added thereto to load weighted triisocyanate, be well mixed and obtain component A；
2）B component is prepared, it is standby；
Respectively according to the ratio of claim 1 weigh polyoxypropylene, polyether-tribasic alcohol, polyethyl acrylate, epoxy resin, Ludox and modified filler, then by polyoxypropylene vacuum be 0.096MPa under conditions of decompression dehydration to moisture content Less than 0.1%, epoxy resin is then added thereto to, after epoxy resin melts, is cooled to 50 DEG C, then added thereto successively Enter polyether-tribasic alcohol, polyethyl acrylate, Ludox and modified filler, stirs the B component that obtain；
3）When in use, the B component mixing of component A and its weight 50-60% is obtained into elastic polyurethane layer（2）.
3. a kind of elastic brick for accomodation ground according to claim 1, it is characterised in that：According to weight ratio, institute State epoxy resin by 3 parts bisphenol A type epoxy resin, 1 part of aliphatic epoxy resin, 0.5 part of polypropylene fibre, 0.5 part Modified manometer silicon dioxide and 0.5 part of modified silicasol make, the modified manometer silicon dioxide is by commercially available nanometer two Silica is mixed to get with the surface modifier II of its weight 3-5%, and surface modifier II is by barium hydroxide, sodium carbonate and KH550 Compare 3-4 according to weight:1-2:30 ratio is mixed；The modified silicasol is that to sequentially add silicon in commercially available Ludox molten The sodium acetate of the silicon powder, the crystal whisker of hexa potassium titanate of Ludox weight 1-2% and Ludox weight 0.8-1% of glue weight 2-3%, and Stir the mixture that 1-2h is obtained under the conditions of 70-80 DEG C afterwards.
4. a kind of elastic brick for accomodation ground according to claim 3, it is characterised in that：In the epoxy resin Also containing 0.4 part of glass fiber.
5. a kind of elastic brick for accomodation ground according to claim 3, it is characterised in that：In the epoxy resin Also containing 0.3 part of nano aluminium oxide.
6. a kind of elastic brick for accomodation ground according to claim 3, it is characterised in that the epoxy resin Preparation method is comprised the following steps：
1）Modified manometer silicon dioxide and modified silicasol are prepared respectively, it is standby；
The modified manometer silicon dioxide is to mix commercially available nano silicon with the surface modifier II of its weight 3-5% Arrive, surface modifier II compares 3-4 by barium hydroxide, sodium carbonate and KH550 according to weight:1-2:30 ratio is mixed；
The modified silicasol is silicon powder, Ludox weight 1- that Ludox weight 2-3% is sequentially added in commercially available Ludox 2% crystal whisker of hexa potassium titanate and the sodium acetate of Ludox weight 0.8-1%, then stir what 1-2h was obtained under the conditions of 70-80 DEG C Mixture；
2）Each component is weighed according to the ratio described in claim 3, after then bisphenol A type epoxy resin is melted, is added thereto Enter load weighted aliphatic epoxy resin and polypropylene fibre, stir after melting completely, then be added thereto to step 1）It is obtained Modified manometer silicon dioxide and modified silicasol, after stirring i.e. be obtained epoxy resin.
7. a kind of elastic brick for accomodation ground according to claim 1, it is characterised in that：In the enhancing powder also Containing talcum powder of 1-1.2 parts particle diameter less than 300 microns.
8. a kind of elastic brick for accomodation ground according to claim 1, it is characterised in that：In the additive also Basalt powder containing 1-2 parts.
9. the preparation method of a kind of elastic brick for accomodation ground according to claim 1, it is characterised in that include Following steps：
1）Modified aluminas micro mist is prepared, it is standby；
Alumina powder is mixed to get with the surface modifier of its weight 3-5%, the surface modifier is by barium hydroxide, carbonic acid Sodium and KH550 compare 3-4 according to weight:1-2:30 ratio is mixed；
2）Requirement according to claim 1 weigh respectively composition major ingredient, additive and strengthen powder each raw material mixing and grinding extremely Fineness is less than 100 microns, standby so as to major ingredient powder, additive being obtained and strengthening powder；
Aluminum filament of the diameter less than 1mm is weighed, it is standby；
3）By step 2）Obtained major ingredient powder, additive and enhancing powder mixing, then sequentially add thereto major ingredient grain weight amount 40- 50% water and the mix liquid of major ingredient grain weight amount 3-5%, mix uniformly obtains pug, and after pug is aged 6-8 days, it is standby；
It is 10 according to weight ratio that the mix liquid is waste oil, starch and glucose:1:1 ratio is mixed；
4）Take step 2）The aluminum filament for weighing mixes rear and step 3）Pug mix after middle ageing is uniform, then makes brick Base, and dry at a temperature of 90-110 DEG C, it is standby；
5）By step 4）Adobe after middle drying is sintered, and brick body is obtained after natural cooling（1）, then in brick body（1）Table Lay a strata urethane elastic layer in face（2）, that is, obtain product；
The sintering is divided into preheating section, warming-up section and the part of furnace zone three, wherein, preheating section is to instigate in-furnace temperature to exist from normal temperature 3h is uniformly increased to 350 DEG C, and keeps temperature 1-2h, and in the process, oxygen content is not higher than 4% in holding furnace；
The warming-up section refers to, makes in-furnace temperature uniformly be increased to 950 DEG C in 4h from 350 DEG C, and keeps temperature 1-2h, here During, oxygen content is not less than 45% in holding furnace；
The furnace zone refers to, makes in-furnace temperature uniformly be increased to 1550 DEG C in 2h from 950 DEG C, and keeps temperature 3-4h, During this, oxygen content is not less than 35% in holding furnace.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111517829A (en) * 2020-05-27 2020-08-11 广西欧神诺陶瓷有限公司 Anti-skid antibacterial ceramic tile and preparation method thereof
CN115849944A (en) * 2022-12-21 2023-03-28 江苏恒尚节能科技股份有限公司 Aerated concrete block for building curtain wall and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120189845A1 (en) * 2005-02-21 2012-07-26 Sadahito Misumi Semiconductor device manufacturing method
CN103387649A (en) * 2013-08-08 2013-11-13 常熟市中腾塑胶有限公司 Method for preparing all plastic polyurethane plastic floor
CN104211895A (en) * 2014-09-18 2014-12-17 东莞市雄林新材料科技股份有限公司 Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof
CN105176366A (en) * 2015-07-17 2015-12-23 河南科技大学 Preparation method of wear-resistant anti-microbial coating for sports equipment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120189845A1 (en) * 2005-02-21 2012-07-26 Sadahito Misumi Semiconductor device manufacturing method
CN103387649A (en) * 2013-08-08 2013-11-13 常熟市中腾塑胶有限公司 Method for preparing all plastic polyurethane plastic floor
CN104211895A (en) * 2014-09-18 2014-12-17 东莞市雄林新材料科技股份有限公司 Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof
CN105176366A (en) * 2015-07-17 2015-12-23 河南科技大学 Preparation method of wear-resistant anti-microbial coating for sports equipment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111517829A (en) * 2020-05-27 2020-08-11 广西欧神诺陶瓷有限公司 Anti-skid antibacterial ceramic tile and preparation method thereof
CN115849944A (en) * 2022-12-21 2023-03-28 江苏恒尚节能科技股份有限公司 Aerated concrete block for building curtain wall and preparation method thereof
CN115849944B (en) * 2022-12-21 2023-08-11 江苏恒尚节能科技股份有限公司 Aerated concrete block for building curtain wall and preparation method thereof

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