CN106634356B - A kind of lower shrinkage antifouling ceramic tile joint trimming agent - Google Patents
A kind of lower shrinkage antifouling ceramic tile joint trimming agent Download PDFInfo
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- CN106634356B CN106634356B CN201710001992.3A CN201710001992A CN106634356B CN 106634356 B CN106634356 B CN 106634356B CN 201710001992 A CN201710001992 A CN 201710001992A CN 106634356 B CN106634356 B CN 106634356B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
- C08G65/3322—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof acyclic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterized by the type of post-polymerisation functionalisation
- C08G2650/04—End-capping
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The present invention provides a kind of lower shrinkage antifouling ceramic tile joint trimming agents, be grouped as by following parts by weight group: 30-40 parts of silicone acrylic emulsion, 3-6 parts of sodium gluconate, 4-5 parts of polyethylene glycol (PEG) oleate, 1-3 parts of ultraviolet absorber, 20-30 parts of modified Portland, 2-5 parts of dispersing agent, 10-15 parts of pigment and 1-3 parts of defoaming agent, the polyethylene glycol (PEG) oleate the preparation method comprises the following steps: by oleic acid, polyethylene glycol and SO4 2‑/ZrO2Solid super acid catalyst after mixing, reacts at 120 ~ 140 DEG C, and the water of generation is constantly removed in reaction process, until reaction solution is in neutrality, stops reaction, and after being cooled to room temperature, filtering, filtrate distillation is gone after moisture removal up to polyethylene glycol (PEG) oleate.Lower shrinkage antifouling ceramic tile joint trimming agent provided by the present invention has lower shrinking percentage, while being not easy to adhere to dirt and droplet, has preferable anti-fouling effect.
Description
Technical field
The invention belongs to technical field of finishing materials, and in particular to a kind of lower shrinkage antifouling ceramic tile joint trimming agent.
Background technique
In modern architecture ceramic tile using very universal, including metope, floor, ceiling, fireplace, wall surface and swimming pool etc.
It can be used Deng, indoor and outdoor.Other face bricks include stone face brick other than ceramic tile, compound or artificial stone's face brick also extensive quilt
It uses.Modern Residence considers the aesthetics of facade and uses functional requirement, and majority uses joint sealing material joint filling, to avoid conventional method
The crack infiltration generated at pointed with cement mortar and accumulation of salt in the surface soil phenomenon, while can obtain and the unified facade effect of finishing material.From vision
On, joint trimming agent brings completely new feeling to house fitting-up, the beauty of household will not be influenced because of the gap of ceramic tile, this makes it
It especially receives an acclaim on beautification space, exquisite in texture after joint trimming agent is spread in the painting of this shape, and uniform color is secured, there is very strong decoration
Effect.It can play a very good protection to building material product especially ceramic tile, and joint trimming agent is applied to after the gap of ceramic tile
Swell-shrinking deformation between energy good absorption ground and masonry, extends the service life of facing.
Joint trimming agent is mainly made of polymer and pigment, is a kind of semi-fluid shape liquid, is broadly divided into one-component joint trimming agent, i.e.,
Daily described aqueous joint trimming agent, another kind is two-component joint trimming agent, and finally a is Self-leveling.Three kinds of joint trimming agents have one
Fixed shrinking percentage, therefore secondary joint filling is generally required after constructing, or even will affect the intensity in joint filling face.Existing gap filler simultaneously
Antifouling property is limited, greatly reduces its service life.
Summary of the invention
The present invention provides a kind of lower shrinkage antifouling ceramic tile joint trimming agents, have lower shrinking percentage, while it is dirty to be not easy adherency
Object and droplet have preferable anti-fouling effect.
The technical proposal for solving the technical problem of the invention are as follows:
A kind of lower shrinkage antifouling ceramic tile joint trimming agent is grouped as by following parts by weight group: 30-40 parts of silicone acrylic emulsion, grape
3-6 parts of sodium saccharate, 4-5 parts of polyethylene glycol (PEG) oleate, 1-3 parts of ultraviolet absorber, 20-30 parts of modified Portland, dispersing agent 2-5
Part, 10-15 parts of pigment and 1-3 parts of defoaming agent, the polyethylene glycol (PEG) oleate the preparation method comprises the following steps: by oleic acid, polyethylene glycol and
SO4 2-/ZrO2Solid super acid catalyst after mixing, reacts at 120~140 DEG C, constantly removes and generates in reaction process
Water stop reaction until reaction solution is in neutrality, after being cooled to room temperature, filtering, filtrate distillation is gone after moisture removal up to poly- second two
Alcohol oleate.
Preferably, the ultraviolet absorber is 2-hydroxy-4-n-octoxybenzophenone, [2- hydroxyl -4- (octyloxy)
Phenyl] phenyl ketone, 2- hydroxyl -4- octyloxybenzophenone or 2- hydroxyl -4- n-octyloxy Benzophenone.
Preferably, the dispersing agent is glyceryl monostearate, zinc stearate or calcium stearate.
Preferably, the defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxypropylene polyoxy
Ethylene Glycol ether or dimethyl silicone polymer.
Preferably, the mass ratio of the oleic acid and polyethylene glycol is 1:6~10, the solid super acid catalyst
Quality is the 0.1~0.15% of polyethylene glycol quality.
Preferably, it is characterized in that, the polyethylene glycol average molecular weight is 600,1000 or 2000.
Preferably, the modified Portland the preparation method comprises the following steps: by silicate be added mass concentration be 20% 12
In sodium alkyl benzene sulfonate-aqueous solution, in 70-80 DEG C stirring 30-50 minutes, stirring gives ultrasonic wave added simultaneously, using filter, filters
Cake drying, ground 60 mesh obtain modified Portland.Metal cation in neopelex and silicate occur from
Son exchange assigns silicate branched structure to enter the molecule interlayer of silicate in a manner of molecule intercalation.When the third cream of silicon
When liquid solidifies, in the branch insertion polymer in modified Portland, to form network structure, the receipts of joint trimming agent are reduced
Shrinkage.
Preferably, the silicate and neopelex-aqueous solution mass ratio are 1:20-30.
Modified poly (ethylene glycol) is esterified using oleic acid, obtains branched polymer, the not hydrophilic not oleophylic of polyethylene glycol (PEG) oleate makes
It obtains greasy dirt and droplet is not easy be attached to joint trimming agent surface, assign joint trimming agent excellent anti-pollution.Oleic acid and polyethylene glycol
Mass ratio determine polyethylene glycol degree of esterification, when the additional amount of oleic acid is too low, esterification degree is not high, and gained joint trimming agent still has
Hydrophily；When the additional amount of oleic acid is excessively high, polyethylene glycol is excessively esterified, and lipophilicity increases, the decline of joint trimming agent anti-pollution.
The invention has the benefit that
1, the present invention makees inorganic filler using modified Portland, forms cross-linked network structure with silicone acrylic emulsion, reduces beauty
Stitch the shrinking percentage of agent.
2, using oleate polyethylene glycol, keep its highly branched, gained polyethylene glycol (PEG) oleate belongs to not hydrophilic not close
Oil substances, so that greasy dirt and droplet are not easy be attached to joint trimming agent surface, to assign joint trimming agent excellent anti-pollution.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments to the present invention
It is further elaborated.
Embodiment 1
(1) by 10g oleic acid, 60g PEG1000 and 0.1g SO4 2-/ZrO2Solid super acid catalyst is placed in rotary evaporation
It in instrument, after mixing, is reacted at 130 DEG C, and depressurizes and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction, it is cold
But to after room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 65.3g；
(2) 30g silicate is added in neopelex-aqueous solution that 600g mass concentration is 20%, in 70
DEG C stirring 50 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 38g modification silicic acid
Salt；
(3) 20g modified Portland, 30g silicone acrylic emulsion and 5g sodium gluconate are added in reaction vessel, in 1200r/
After stirring 30 minutes under min, it is stearic to add 4g polyethylene glycol (PEG) oleate, 2g 2-hydroxy-4-n-octoxybenzophenone, 3g
Sour zinc, 10g pigment and 1g polyoxyethylene polyoxy propyl alcohol amidogen ether stir 20 minutes under 1000r/min.
Embodiment 2
(1) by 10g oleic acid, 80g PEG6000 and 0.12g SO4 2-/ZrO2Solid super acid catalyst is placed in rotary evaporation
It in instrument, after mixing, is reacted at 140 DEG C, and depressurizes and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction, it is cold
But to after room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 82.9g；
(2) 30g silicate is added in neopelex-aqueous solution that 800g mass concentration is 20%, in 75
DEG C stirring 40 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 40g modification silicic acid
Salt；
(3) 25g modified Portland, 35g silicone acrylic emulsion and 6g sodium gluconate are added in reaction vessel, in 1200r/
After stirring 30 minutes under min, 4g polyethylene glycol (PEG) oleate, 1g 2- hydroxyl -4- n-octyloxy Benzophenone, 2g stearic acid are added
Calcium, 12g pigment and 2g polypropylene glycerol aether stir 20 minutes under 1000r/min.
Embodiment 3
(1) by 10g oleic acid, 100g PEG2000 and 0.15g SO4 2-/ZrO2Solid super acid catalyst is placed in rotation and steams
It sends out in instrument, after mixing, is reacted at 150 DEG C, and depressurize and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction,
After being cooled to room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 104.9g；
(2) 30g silicate is added in neopelex-aqueous solution that 900g mass concentration is 20%, in 80
DEG C stirring 30 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 42g modification silicic acid
Salt；
(3) 30g modified Portland, 40g silicone acrylic emulsion and 3g sodium gluconate are added in reaction vessel, in 1200r/
After stirring 30 minutes under min, it is hard to add 5g polyethylene glycol (PEG) oleate, 3g [2- hydroxyl -4- (octyloxy) phenyl] phenyl ketone, 5g
Resin acid monoglyceride, 15g pigment and 3g dimethyl silicone polymer stir 20 minutes under 1000r/min.
Comparative example 1
(1) 30g silicate is added in neopelex-aqueous solution that 600g mass concentration is 20%, in 70
DEG C stirring 50 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 38g modification silicic acid
Salt；
(2) 20g modified Portland, 30g silicone acrylic emulsion and 5g sodium gluconate are added in reaction vessel, in 1200r/
After stirring 30 minutes under min, it is poly- to add 2g 2-hydroxy-4-n-octoxybenzophenone, 3g zinc stearate, 10g pigment and 1g
Ethylene oxide polyoxy propyl alcohol amidogen ether stirs 20 minutes under 1000r/min.
Comparative example 2
(1) by 10g oleic acid, 60g PEG1000 and 0.1g SO4 2-/ZrO2Solid super acid catalyst is placed in rotary evaporation
It in instrument, after mixing, is reacted at 130 DEG C, and depressurizes and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction, it is cold
But to after room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 65.3g；
(2) 20g silicate, 30g silicone acrylic emulsion and 5g sodium gluconate are added in reaction vessel, under 1200r/min
Stirring 30 minutes after, add 4g polyethylene glycol (PEG) oleate, 2g 2-hydroxy-4-n-octoxybenzophenone, 3g zinc stearate,
10g pigment and 1g polyoxyethylene polyoxy propyl alcohol amidogen ether stir 20 minutes under 1000r/min.
The test of 4 amphipathic property of embodiment
The ceramic tile joint trimming agent of embodiment 1-3, comparative example 1-2 are squeezed out into curing molding in mold.
Hydrophilicity experiment: using JC2000C1 intravenous infusion contact angle/interfacial tension measuring instrument measurement deionized water in embodiment
The contact angle θ on the made automobile adhesive film surface 1-31。
Lipophilicity experiment: using JC2000C1 intravenous infusion contact angle/interfacial tension measuring instrument measurement castor oil in embodiment 1-3
The contact angle θ on made automobile adhesive film surface2。
Test result is shown in Table 1:
Table 1:
| Number | θ1(°) | θ2(°) |
| Embodiment 1 | 135.2 | 108.6 |
| Embodiment 2 | 132.9 | 112.3 |
| Embodiment 3 | 130.9 | 109.5 |
| Comparative example 1 | 65.3 | 72.5 |
| Comparative example 2 | 12.5.3 | 105.3 |
It can be seen from Table 1 that the hydrophily and lipophilicity of made ceramic tile joint trimming agent are equal after polyethylene glycol (PEG) oleate is added
It decreased significantly, to improve the stain resistance of ceramic tile joint trimming agent.
The test of 5 shrinkage of embodiment
Embodiment 1-3, comparative example 1-2 are respectively filled in the ceramic tile gap that depth is 10mm, width is 3mm, observe it
Joint filling effect, the results are shown in Table 2:
Table 2:
It can be seen from Table 2 that silicate is after modified, the shrinking percentage of made gap filler is reduced, and is not required to secondary joint filling, greatly
It improves work efficiency greatly.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (5)
1. a kind of lower shrinkage antifouling ceramic tile joint trimming agent, which is characterized in that the ceramic tile joint trimming agent is grouped by following parts by weight group
At: 30-40 parts of silicone acrylic emulsion, 3-6 parts of sodium gluconate, 4-5 parts of polyethylene glycol (PEG) oleate, 1-3 parts of ultraviolet absorber, modified silicon
20-30 parts of hydrochlorate, 2-5 parts of dispersing agent, 10-15 parts of pigment and 1-3 parts of defoaming agent, the preparation method of the polyethylene glycol (PEG) oleate
Are as follows: by oleic acid, polyethylene glycol and SO4 2-/ZrO2Solid super acid catalyst after mixing, reacts, instead at 120 ~ 140 DEG C
The water generated should be constantly removed in the process, until reaction solution is in neutrality, stopping reaction, after being cooled to room temperature, filtering, filtrate distillation
It goes after moisture removal up to polyethylene glycol (PEG) oleate；
The mass ratio of the oleic acid and polyethylene glycol is 1:6 ~ 10, and the quality of the solid super acid catalyst is polyethylene glycol
The 0.1 ~ 0.15% of quality；
The modified Portland the preparation method comprises the following steps: by silicate be added mass concentration be 20% neopelex-water
In solution, in 70-80 DEG C stirring 30-50 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake dry, ground 60
Mesh obtains modified Portland；
The silicate and neopelex-aqueous solution mass ratio are 1:20-30.
2. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the ultraviolet absorber is 2- hydroxyl
Base -4- oxy-octyl benzophenone.
3. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the dispersing agent is that stearic acid list is sweet
Grease, zinc stearate or calcium stearate.
4. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the defoaming agent is poly- for polyoxyethylene
Oxygen propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether or dimethyl silicone polymer.
5. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the polyethylene glycol average molecular weight
It is 600,1000 or 2000.
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| CN107141904A (en) * | 2017-07-10 | 2017-09-08 | 张庆珠 | A kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof |
| CN108707389A (en) * | 2018-05-21 | 2018-10-26 | 无锡尊丰新材料科技有限公司 | A kind of environment-friendly type waterproof and oilproof joint trimming agent |
| CN111533856B (en) * | 2020-06-04 | 2023-02-03 | 广州市建筑科学研究院有限公司 | Organic shrinkage-reducing agent and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747192A (en) * | 2009-12-15 | 2010-06-23 | 浙江合诚化学有限公司 | Method for synthesizing polyethylene glycol (PEG) oleate |
| CN105907339A (en) * | 2016-06-30 | 2016-08-31 | 广东三和化工科技有限公司 | Water-based crack sealer and preparation method thereof |
| CN105969261A (en) * | 2016-06-30 | 2016-09-28 | 广东三和控股有限公司 | Decorating caulk and preparation method thereof |
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| NZ582054A (en) * | 2007-06-29 | 2012-06-29 | Hardie James Technology Ltd | Multifunctional primers for composite building materials |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747192A (en) * | 2009-12-15 | 2010-06-23 | 浙江合诚化学有限公司 | Method for synthesizing polyethylene glycol (PEG) oleate |
| CN105907339A (en) * | 2016-06-30 | 2016-08-31 | 广东三和化工科技有限公司 | Water-based crack sealer and preparation method thereof |
| CN105969261A (en) * | 2016-06-30 | 2016-09-28 | 广东三和控股有限公司 | Decorating caulk and preparation method thereof |
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Effective date of registration: 20210126 Address after: 200040 room A2301, no.360 hengtongdao, Jing'an District, Shanghai (centralized registration place) Patentee after: Housing doctor (Shanghai) Environmental Protection Technology Co.,Ltd. Address before: 325200 unit 1, building 5, Hongrui building, Anyang street, Ruian City, Wenzhou City, Zhejiang Province Patentee before: Ruan Xiaohe |