CN106634356B - A kind of lower shrinkage antifouling ceramic tile joint trimming agent - Google Patents

A kind of lower shrinkage antifouling ceramic tile joint trimming agent Download PDF

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CN106634356B
CN106634356B CN201710001992.3A CN201710001992A CN106634356B CN 106634356 B CN106634356 B CN 106634356B CN 201710001992 A CN201710001992 A CN 201710001992A CN 106634356 B CN106634356 B CN 106634356B
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polyethylene glycol
ceramic tile
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agent
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CN106634356A (en
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阮潇禾
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Housing doctor (Shanghai) Environmental Protection Technology Co.,Ltd.
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • C08G65/329Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
    • C08G65/3322Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof acyclic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterized by the type of post-polymerisation functionalisation
    • C08G2650/04End-capping
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/38Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of lower shrinkage antifouling ceramic tile joint trimming agents, be grouped as by following parts by weight group: 30-40 parts of silicone acrylic emulsion, 3-6 parts of sodium gluconate, 4-5 parts of polyethylene glycol (PEG) oleate, 1-3 parts of ultraviolet absorber, 20-30 parts of modified Portland, 2-5 parts of dispersing agent, 10-15 parts of pigment and 1-3 parts of defoaming agent, the polyethylene glycol (PEG) oleate the preparation method comprises the following steps: by oleic acid, polyethylene glycol and SO4 2‑/ZrO2Solid super acid catalyst after mixing, reacts at 120 ~ 140 DEG C, and the water of generation is constantly removed in reaction process, until reaction solution is in neutrality, stops reaction, and after being cooled to room temperature, filtering, filtrate distillation is gone after moisture removal up to polyethylene glycol (PEG) oleate.Lower shrinkage antifouling ceramic tile joint trimming agent provided by the present invention has lower shrinking percentage, while being not easy to adhere to dirt and droplet, has preferable anti-fouling effect.

Description

A kind of lower shrinkage antifouling ceramic tile joint trimming agent
Technical field
The invention belongs to technical field of finishing materials, and in particular to a kind of lower shrinkage antifouling ceramic tile joint trimming agent.
Background technique
In modern architecture ceramic tile using very universal, including metope, floor, ceiling, fireplace, wall surface and swimming pool etc. It can be used Deng, indoor and outdoor.Other face bricks include stone face brick other than ceramic tile, compound or artificial stone's face brick also extensive quilt It uses.Modern Residence considers the aesthetics of facade and uses functional requirement, and majority uses joint sealing material joint filling, to avoid conventional method The crack infiltration generated at pointed with cement mortar and accumulation of salt in the surface soil phenomenon, while can obtain and the unified facade effect of finishing material.From vision On, joint trimming agent brings completely new feeling to house fitting-up, the beauty of household will not be influenced because of the gap of ceramic tile, this makes it It especially receives an acclaim on beautification space, exquisite in texture after joint trimming agent is spread in the painting of this shape, and uniform color is secured, there is very strong decoration Effect.It can play a very good protection to building material product especially ceramic tile, and joint trimming agent is applied to after the gap of ceramic tile Swell-shrinking deformation between energy good absorption ground and masonry, extends the service life of facing.
Joint trimming agent is mainly made of polymer and pigment, is a kind of semi-fluid shape liquid, is broadly divided into one-component joint trimming agent, i.e., Daily described aqueous joint trimming agent, another kind is two-component joint trimming agent, and finally a is Self-leveling.Three kinds of joint trimming agents have one Fixed shrinking percentage, therefore secondary joint filling is generally required after constructing, or even will affect the intensity in joint filling face.Existing gap filler simultaneously Antifouling property is limited, greatly reduces its service life.
Summary of the invention
The present invention provides a kind of lower shrinkage antifouling ceramic tile joint trimming agents, have lower shrinking percentage, while it is dirty to be not easy adherency Object and droplet have preferable anti-fouling effect.
The technical proposal for solving the technical problem of the invention are as follows:
A kind of lower shrinkage antifouling ceramic tile joint trimming agent is grouped as by following parts by weight group: 30-40 parts of silicone acrylic emulsion, grape 3-6 parts of sodium saccharate, 4-5 parts of polyethylene glycol (PEG) oleate, 1-3 parts of ultraviolet absorber, 20-30 parts of modified Portland, dispersing agent 2-5 Part, 10-15 parts of pigment and 1-3 parts of defoaming agent, the polyethylene glycol (PEG) oleate the preparation method comprises the following steps: by oleic acid, polyethylene glycol and SO4 2-/ZrO2Solid super acid catalyst after mixing, reacts at 120~140 DEG C, constantly removes and generates in reaction process Water stop reaction until reaction solution is in neutrality, after being cooled to room temperature, filtering, filtrate distillation is gone after moisture removal up to poly- second two Alcohol oleate.
Preferably, the ultraviolet absorber is 2-hydroxy-4-n-octoxybenzophenone, [2- hydroxyl -4- (octyloxy) Phenyl] phenyl ketone, 2- hydroxyl -4- octyloxybenzophenone or 2- hydroxyl -4- n-octyloxy Benzophenone.
Preferably, the dispersing agent is glyceryl monostearate, zinc stearate or calcium stearate.
Preferably, the defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxypropylene polyoxy Ethylene Glycol ether or dimethyl silicone polymer.
Preferably, the mass ratio of the oleic acid and polyethylene glycol is 1:6~10, the solid super acid catalyst Quality is the 0.1~0.15% of polyethylene glycol quality.
Preferably, it is characterized in that, the polyethylene glycol average molecular weight is 600,1000 or 2000.
Preferably, the modified Portland the preparation method comprises the following steps: by silicate be added mass concentration be 20% 12 In sodium alkyl benzene sulfonate-aqueous solution, in 70-80 DEG C stirring 30-50 minutes, stirring gives ultrasonic wave added simultaneously, using filter, filters Cake drying, ground 60 mesh obtain modified Portland.Metal cation in neopelex and silicate occur from Son exchange assigns silicate branched structure to enter the molecule interlayer of silicate in a manner of molecule intercalation.When the third cream of silicon When liquid solidifies, in the branch insertion polymer in modified Portland, to form network structure, the receipts of joint trimming agent are reduced Shrinkage.
Preferably, the silicate and neopelex-aqueous solution mass ratio are 1:20-30.
Modified poly (ethylene glycol) is esterified using oleic acid, obtains branched polymer, the not hydrophilic not oleophylic of polyethylene glycol (PEG) oleate makes It obtains greasy dirt and droplet is not easy be attached to joint trimming agent surface, assign joint trimming agent excellent anti-pollution.Oleic acid and polyethylene glycol Mass ratio determine polyethylene glycol degree of esterification, when the additional amount of oleic acid is too low, esterification degree is not high, and gained joint trimming agent still has Hydrophily;When the additional amount of oleic acid is excessively high, polyethylene glycol is excessively esterified, and lipophilicity increases, the decline of joint trimming agent anti-pollution.
The invention has the benefit that
1, the present invention makees inorganic filler using modified Portland, forms cross-linked network structure with silicone acrylic emulsion, reduces beauty Stitch the shrinking percentage of agent.
2, using oleate polyethylene glycol, keep its highly branched, gained polyethylene glycol (PEG) oleate belongs to not hydrophilic not close Oil substances, so that greasy dirt and droplet are not easy be attached to joint trimming agent surface, to assign joint trimming agent excellent anti-pollution.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments to the present invention It is further elaborated.
Embodiment 1
(1) by 10g oleic acid, 60g PEG1000 and 0.1g SO4 2-/ZrO2Solid super acid catalyst is placed in rotary evaporation It in instrument, after mixing, is reacted at 130 DEG C, and depressurizes and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction, it is cold But to after room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 65.3g;
(2) 30g silicate is added in neopelex-aqueous solution that 600g mass concentration is 20%, in 70 DEG C stirring 50 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 38g modification silicic acid Salt;
(3) 20g modified Portland, 30g silicone acrylic emulsion and 5g sodium gluconate are added in reaction vessel, in 1200r/ After stirring 30 minutes under min, it is stearic to add 4g polyethylene glycol (PEG) oleate, 2g 2-hydroxy-4-n-octoxybenzophenone, 3g Sour zinc, 10g pigment and 1g polyoxyethylene polyoxy propyl alcohol amidogen ether stir 20 minutes under 1000r/min.
Embodiment 2
(1) by 10g oleic acid, 80g PEG6000 and 0.12g SO4 2-/ZrO2Solid super acid catalyst is placed in rotary evaporation It in instrument, after mixing, is reacted at 140 DEG C, and depressurizes and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction, it is cold But to after room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 82.9g;
(2) 30g silicate is added in neopelex-aqueous solution that 800g mass concentration is 20%, in 75 DEG C stirring 40 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 40g modification silicic acid Salt;
(3) 25g modified Portland, 35g silicone acrylic emulsion and 6g sodium gluconate are added in reaction vessel, in 1200r/ After stirring 30 minutes under min, 4g polyethylene glycol (PEG) oleate, 1g 2- hydroxyl -4- n-octyloxy Benzophenone, 2g stearic acid are added Calcium, 12g pigment and 2g polypropylene glycerol aether stir 20 minutes under 1000r/min.
Embodiment 3
(1) by 10g oleic acid, 100g PEG2000 and 0.15g SO4 2-/ZrO2Solid super acid catalyst is placed in rotation and steams It sends out in instrument, after mixing, is reacted at 150 DEG C, and depressurize and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction, After being cooled to room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 104.9g;
(2) 30g silicate is added in neopelex-aqueous solution that 900g mass concentration is 20%, in 80 DEG C stirring 30 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 42g modification silicic acid Salt;
(3) 30g modified Portland, 40g silicone acrylic emulsion and 3g sodium gluconate are added in reaction vessel, in 1200r/ After stirring 30 minutes under min, it is hard to add 5g polyethylene glycol (PEG) oleate, 3g [2- hydroxyl -4- (octyloxy) phenyl] phenyl ketone, 5g Resin acid monoglyceride, 15g pigment and 3g dimethyl silicone polymer stir 20 minutes under 1000r/min.
Comparative example 1
(1) 30g silicate is added in neopelex-aqueous solution that 600g mass concentration is 20%, in 70 DEG C stirring 50 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake drying, ground 60 mesh obtain 38g modification silicic acid Salt;
(2) 20g modified Portland, 30g silicone acrylic emulsion and 5g sodium gluconate are added in reaction vessel, in 1200r/ After stirring 30 minutes under min, it is poly- to add 2g 2-hydroxy-4-n-octoxybenzophenone, 3g zinc stearate, 10g pigment and 1g Ethylene oxide polyoxy propyl alcohol amidogen ether stirs 20 minutes under 1000r/min.
Comparative example 2
(1) by 10g oleic acid, 60g PEG1000 and 0.1g SO4 2-/ZrO2Solid super acid catalyst is placed in rotary evaporation It in instrument, after mixing, is reacted at 130 DEG C, and depressurizes and divide water, after PH test paper detection reaction solution is in neutrality, stop reaction, it is cold But to after room temperature, filtering, filtrate distillation is gone after moisture removal up to modified poly (ethylene glycol) 65.3g;
(2) 20g silicate, 30g silicone acrylic emulsion and 5g sodium gluconate are added in reaction vessel, under 1200r/min Stirring 30 minutes after, add 4g polyethylene glycol (PEG) oleate, 2g 2-hydroxy-4-n-octoxybenzophenone, 3g zinc stearate, 10g pigment and 1g polyoxyethylene polyoxy propyl alcohol amidogen ether stir 20 minutes under 1000r/min.
The test of 4 amphipathic property of embodiment
The ceramic tile joint trimming agent of embodiment 1-3, comparative example 1-2 are squeezed out into curing molding in mold.
Hydrophilicity experiment: using JC2000C1 intravenous infusion contact angle/interfacial tension measuring instrument measurement deionized water in embodiment The contact angle θ on the made automobile adhesive film surface 1-31
Lipophilicity experiment: using JC2000C1 intravenous infusion contact angle/interfacial tension measuring instrument measurement castor oil in embodiment 1-3 The contact angle θ on made automobile adhesive film surface2
Test result is shown in Table 1:
Table 1:
Number θ1(°) θ2(°)
Embodiment 1 135.2 108.6
Embodiment 2 132.9 112.3
Embodiment 3 130.9 109.5
Comparative example 1 65.3 72.5
Comparative example 2 12.5.3 105.3
It can be seen from Table 1 that the hydrophily and lipophilicity of made ceramic tile joint trimming agent are equal after polyethylene glycol (PEG) oleate is added It decreased significantly, to improve the stain resistance of ceramic tile joint trimming agent.
The test of 5 shrinkage of embodiment
Embodiment 1-3, comparative example 1-2 are respectively filled in the ceramic tile gap that depth is 10mm, width is 3mm, observe it Joint filling effect, the results are shown in Table 2:
Table 2:
It can be seen from Table 2 that silicate is after modified, the shrinking percentage of made gap filler is reduced, and is not required to secondary joint filling, greatly It improves work efficiency greatly.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (5)

1. a kind of lower shrinkage antifouling ceramic tile joint trimming agent, which is characterized in that the ceramic tile joint trimming agent is grouped by following parts by weight group At: 30-40 parts of silicone acrylic emulsion, 3-6 parts of sodium gluconate, 4-5 parts of polyethylene glycol (PEG) oleate, 1-3 parts of ultraviolet absorber, modified silicon 20-30 parts of hydrochlorate, 2-5 parts of dispersing agent, 10-15 parts of pigment and 1-3 parts of defoaming agent, the preparation method of the polyethylene glycol (PEG) oleate Are as follows: by oleic acid, polyethylene glycol and SO4 2-/ZrO2Solid super acid catalyst after mixing, reacts, instead at 120 ~ 140 DEG C The water generated should be constantly removed in the process, until reaction solution is in neutrality, stopping reaction, after being cooled to room temperature, filtering, filtrate distillation It goes after moisture removal up to polyethylene glycol (PEG) oleate;
The mass ratio of the oleic acid and polyethylene glycol is 1:6 ~ 10, and the quality of the solid super acid catalyst is polyethylene glycol The 0.1 ~ 0.15% of quality;
The modified Portland the preparation method comprises the following steps: by silicate be added mass concentration be 20% neopelex-water In solution, in 70-80 DEG C stirring 30-50 minutes, stirring simultaneously give ultrasonic wave added, using filter, filter cake dry, ground 60 Mesh obtains modified Portland;
The silicate and neopelex-aqueous solution mass ratio are 1:20-30.
2. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the ultraviolet absorber is 2- hydroxyl Base -4- oxy-octyl benzophenone.
3. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the dispersing agent is that stearic acid list is sweet Grease, zinc stearate or calcium stearate.
4. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the defoaming agent is poly- for polyoxyethylene Oxygen propyl alcohol amidogen ether, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether or dimethyl silicone polymer.
5. lower shrinkage antifouling ceramic tile joint trimming agent as described in claim 1, which is characterized in that the polyethylene glycol average molecular weight It is 600,1000 or 2000.
CN201710001992.3A 2017-01-03 2017-01-03 A kind of lower shrinkage antifouling ceramic tile joint trimming agent Active CN106634356B (en)

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Publication number Priority date Publication date Assignee Title
CN107141904A (en) * 2017-07-10 2017-09-08 张庆珠 A kind of environmentally friendly diatom ceramic tile joint trimming agent and preparation method thereof
CN108707389A (en) * 2018-05-21 2018-10-26 无锡尊丰新材料科技有限公司 A kind of environment-friendly type waterproof and oilproof joint trimming agent
CN111533856B (en) * 2020-06-04 2023-02-03 广州市建筑科学研究院有限公司 Organic shrinkage-reducing agent and preparation method and application thereof

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CN101747192A (en) * 2009-12-15 2010-06-23 浙江合诚化学有限公司 Method for synthesizing polyethylene glycol (PEG) oleate
CN105907339A (en) * 2016-06-30 2016-08-31 广东三和化工科技有限公司 Water-based crack sealer and preparation method thereof
CN105969261A (en) * 2016-06-30 2016-09-28 广东三和控股有限公司 Decorating caulk and preparation method thereof

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CA2697184C (en) * 2007-06-29 2015-10-27 James Hardie Technology Limited Multifunctional primers

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Publication number Priority date Publication date Assignee Title
CN101747192A (en) * 2009-12-15 2010-06-23 浙江合诚化学有限公司 Method for synthesizing polyethylene glycol (PEG) oleate
CN105907339A (en) * 2016-06-30 2016-08-31 广东三和化工科技有限公司 Water-based crack sealer and preparation method thereof
CN105969261A (en) * 2016-06-30 2016-09-28 广东三和控股有限公司 Decorating caulk and preparation method thereof

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Effective date of registration: 20210126

Address after: 200040 room A2301, no.360 hengtongdao, Jing'an District, Shanghai (centralized registration place)

Patentee after: Housing doctor (Shanghai) Environmental Protection Technology Co.,Ltd.

Address before: 325200 unit 1, building 5, Hongrui building, Anyang street, Ruian City, Wenzhou City, Zhejiang Province

Patentee before: Ruan Xiaohe