CN106633821A - Long glass fiber reinforced nylon composite material - Google Patents
Long glass fiber reinforced nylon composite material Download PDFInfo
- Publication number
- CN106633821A CN106633821A CN201510409737.3A CN201510409737A CN106633821A CN 106633821 A CN106633821 A CN 106633821A CN 201510409737 A CN201510409737 A CN 201510409737A CN 106633821 A CN106633821 A CN 106633821A
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- CN
- China
- Prior art keywords
- parts
- glass fiber
- roving glass
- composite material
- long glass
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of composite materials, specifically to a long glass fiber reinforced nylon composite material. The long glass fiber reinforced nylon composite material comprises the following components in parts by mass: 65 to 80 parts of polyamide resin, 35 to 50 parts of long glass fiber, 15 to 20 parts of methacrylic acid, 10 to 15 parts of polybutyl succinate, 30 to 40 parts of calcium stearate, 20 to 30 parts of zinc stearate, 5 to 15 parts of polyvinyl chloride, 10 to 15 parts of sodium dodecyl benzene sulfonate, 5 to 9 parts of polyol, 12 to 18 parts of calcium carbonate and 3 to 8 parts of polyester resin. By adopting the above-mentioned formula, the long glass fiber reinforced nylon composite material has the following advantages: by controlling the usage amount of each material, and through modification of the long glass fiber reinforced nylon composite material, the complexing coordination action between an amide group in nylon and an metal ion in metal salt or a metal complex can be formed, so the composite material is improved in tensile properties and is convenient for popularization and application.
Description
Technical field
The present invention relates to technical field of composite materials, particularly a kind of roving glass fiber nylon enhancing composite.
Background technology
Polyamide, is a kind of high comprehensive performance, applies more extensive industrial chemicals.Due to itself
With good mechanical property, heat resistance, abrasion resistance properties, chemical resistance and self-lubricating property,
And coefficient of friction is low, have certain anti-flammability and easy to process, nylon material be suitable for use with glass fibre and/
Or other filler fillings carry out strengthening modified, so as to be widely used in electronics, machinery, automobile and weaving
In industry.
The content of the invention
The technical problem to be solved in the invention is to provide a kind of roving glass fiber nylon strengthens composite.
To solve above-mentioned technical problem, a kind of roving glass fiber nylon of the present invention strengthens composite, according to quality
Number meter includes following components：Polyamide 65-80 parts, roving glass fiber 35-50 parts, methacrylic acid 15-20
Part, polybutyl succinate 10-15 parts, calcium stearate 30-40 parts, zinc stearate 20-30 parts, polychlorostyrene second
Alkene 5-15 parts, neopelex 10-15 parts, polyalcohol 5-9 parts, calcium carbonate 12-18 parts are gathered
Ester resin 3-8 parts.
Further, following components is included according to mass fraction meter：65 parts of polyamide, 35 parts of roving glass fiber,
15 parts of methacrylic acid, 10 parts of polybutyl succinate, 30 parts of calcium stearate, 20 parts of zinc stearate gathers
5 parts of vinyl chloride, 10 parts of neopelex, 5 parts of polyalcohol, 12 parts of calcium carbonate, polyester resin 3
Part.
Further, following components is included according to mass fraction meter：80 parts of polyamide, 50 parts of roving glass fiber,
20 parts of methacrylic acid, 15 parts of polybutyl succinate, 40 parts of calcium stearate, 30 parts of zinc stearate gathers
15 parts of vinyl chloride, 15 parts of neopelex, 9 parts of polyalcohol, 18 parts of calcium carbonate, polyester resin
8 parts.
Further, following components is included according to mass fraction meter：70 parts of polyamide, 40 parts of roving glass fiber,
17 parts of methacrylic acid, 11 parts of polybutyl succinate, 33 parts of calcium stearate, 22 parts of zinc stearate gathers
8 parts of vinyl chloride, 13 parts of neopelex, 6 parts of polyalcohol, 13 parts of calcium carbonate, polyester resin 5
Part.
Further, following components is included according to mass fraction meter：75 parts of polyamide, 45 parts of roving glass fiber,
19 parts of methacrylic acid, 12 parts of polybutyl succinate, 38 parts of calcium stearate, 26 parts of zinc stearate gathers
10 parts of vinyl chloride, 14 parts of neopelex, 8 parts of polyalcohol, 15 parts of calcium carbonate, polyester resin
6 parts.
After above-mentioned formula, the roving glass fiber nylon of the present invention strengthens composite, controls the consumption of each material,
Long glass fiber reinforced nylon composite materials are modified, the acid amides group in nylon and slaine or metal network is made
Complex coordination effect can be formed between metal ion in compound, the tensile property of composite is lifted, just
In popularization and application.
Specific embodiment
A kind of roving glass fiber nylon of the present invention strengthens composite, and according to mass fraction meter following components is included：It is poly-
Amide resin 65-80 parts, roving glass fiber 35-50 parts, methacrylic acid 15-20 parts, polybutyl succinate 10-15
Part, calcium stearate 30-40 parts, zinc stearate 20-30 parts, polyvinyl chloride 5-15 parts, detergent alkylate sulphur
Sour sodium 10-15 parts, polyalcohol 5-9 parts, calcium carbonate 12-18 parts, polyester resin 3-8 parts.
Embodiment one：
Include following components according to mass fraction meter：65 parts of polyamide, 35 parts of roving glass fiber, metering system
15 parts of acid, 10 parts of polybutyl succinate, 30 parts of calcium stearate, 20 parts of zinc stearate, polyvinyl chloride 5
Part, 10 parts of neopelex, 5 parts of polyalcohol, 12 parts of calcium carbonate, 3 parts of polyester resin.
Embodiment two：
Include following components according to mass fraction meter：80 parts of polyamide, 50 parts of roving glass fiber, metering system
20 parts of acid, 15 parts of polybutyl succinate, 40 parts of calcium stearate, 30 parts of zinc stearate, polyvinyl chloride 15
Part, 15 parts of neopelex, 9 parts of polyalcohol, 18 parts of calcium carbonate, 8 parts of polyester resin.
Embodiment three：
Include following components according to mass fraction meter：70 parts of polyamide, 40 parts of roving glass fiber, metering system
17 parts of acid, 11 parts of polybutyl succinate, 33 parts of calcium stearate, 22 parts of zinc stearate, polyvinyl chloride 8
Part, 13 parts of neopelex, 6 parts of polyalcohol, 13 parts of calcium carbonate, 5 parts of polyester resin.
Embodiment four：
Include following components according to mass fraction meter：75 parts of polyamide, 45 parts of roving glass fiber, metering system
19 parts of acid, 12 parts of polybutyl succinate, 38 parts of calcium stearate, 26 parts of zinc stearate, polyvinyl chloride 10
Part, 14 parts of neopelex, 8 parts of polyalcohol, 15 parts of calcium carbonate, 6 parts of polyester resin.
Although the foregoing describing the specific embodiment of the present invention, those skilled in the art should manage
Solution, these are merely illustrative of, and can make various changes or modifications to present embodiment, without departing from send out
Bright principle and essence, protection scope of the present invention is only limited by the claims that follow.
Claims (5)
1. a kind of roving glass fiber nylon strengthens composite, it is characterised in that include following components according to mass fraction meter：
Polyamide 65-80 parts, roving glass fiber 35-50 parts, methacrylic acid 15-20 parts, polybutyl succinate
10-15 parts, calcium stearate 30-40 parts, zinc stearate 20-30 parts, polyvinyl chloride 5-15 parts, dodecane
Base benzene sulfonic acid sodium salt 10-15 parts, polyalcohol 5-9 parts, calcium carbonate 12-18 parts, polyester resin 3-8 parts.
2. composite is strengthened according to a kind of roving glass fiber nylon described in claim 1, it is characterised in that according to matter
Amount number meter includes following components：65 parts of polyamide, 35 parts of roving glass fiber, 15 parts of methacrylic acid,
10 parts of polybutyl succinate, 30 parts of calcium stearate, 20 parts of zinc stearate, 5 parts of polyvinyl chloride, dodecane
10 parts of base benzene sulfonic acid sodium salt, 5 parts of polyalcohol, 12 parts of calcium carbonate, 3 parts of polyester resin.
3. composite is strengthened according to a kind of roving glass fiber nylon described in claim 1, it is characterised in that according to matter
Amount number meter includes following components：80 parts of polyamide, 50 parts of roving glass fiber, 20 parts of methacrylic acid,
15 parts of polybutyl succinate, 40 parts of calcium stearate, 30 parts of zinc stearate, 15 parts of polyvinyl chloride, 12
15 parts of sodium alkyl benzene sulfonate, 9 parts of polyalcohol, 18 parts of calcium carbonate, 8 parts of polyester resin.
4. composite is strengthened according to a kind of roving glass fiber nylon described in claim 1, it is characterised in that according to matter
Amount number meter includes following components：70 parts of polyamide, 40 parts of roving glass fiber, 17 parts of methacrylic acid,
11 parts of polybutyl succinate, 33 parts of calcium stearate, 22 parts of zinc stearate, 8 parts of polyvinyl chloride, dodecane
13 parts of base benzene sulfonic acid sodium salt, 6 parts of polyalcohol, 13 parts of calcium carbonate, 5 parts of polyester resin.
5. composite is strengthened according to a kind of roving glass fiber nylon described in claim 1, it is characterised in that according to matter
Amount number meter includes following components：75 parts of polyamide, 45 parts of roving glass fiber, 19 parts of methacrylic acid,
12 parts of polybutyl succinate, 38 parts of calcium stearate, 26 parts of zinc stearate, 10 parts of polyvinyl chloride, 12
14 parts of sodium alkyl benzene sulfonate, 8 parts of polyalcohol, 15 parts of calcium carbonate, 6 parts of polyester resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510409737.3A CN106633821A (en) | 2015-07-13 | 2015-07-13 | Long glass fiber reinforced nylon composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510409737.3A CN106633821A (en) | 2015-07-13 | 2015-07-13 | Long glass fiber reinforced nylon composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633821A true CN106633821A (en) | 2017-05-10 |
Family
ID=58815187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510409737.3A Pending CN106633821A (en) | 2015-07-13 | 2015-07-13 | Long glass fiber reinforced nylon composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106633821A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108659400A (en) * | 2018-05-29 | 2018-10-16 | 芜湖创科新材料科技有限公司 | A kind of modified automobile engineering plastics and preparation method thereof |
| CN108727810A (en) * | 2018-05-23 | 2018-11-02 | 江苏金发科技新材料有限公司 | Long glass fiber reinforced daiamid composition and preparation method thereof |
| CN109081612A (en) * | 2018-07-27 | 2018-12-25 | 苏州华龙化工有限公司 | A kind of enhancing nylon glass fiber size and preparation method thereof |
-
2015
- 2015-07-13 CN CN201510409737.3A patent/CN106633821A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727810A (en) * | 2018-05-23 | 2018-11-02 | 江苏金发科技新材料有限公司 | Long glass fiber reinforced daiamid composition and preparation method thereof |
| CN108659400A (en) * | 2018-05-29 | 2018-10-16 | 芜湖创科新材料科技有限公司 | A kind of modified automobile engineering plastics and preparation method thereof |
| CN109081612A (en) * | 2018-07-27 | 2018-12-25 | 苏州华龙化工有限公司 | A kind of enhancing nylon glass fiber size and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170510 |
|
| WD01 | Invention patent application deemed withdrawn after publication |