CN106633588B - A kind of electric automobile charging pile cable material and preparation method thereof - Google Patents
A kind of electric automobile charging pile cable material and preparation method thereof Download PDFInfo
- Publication number
- CN106633588B CN106633588B CN201611138158.0A CN201611138158A CN106633588B CN 106633588 B CN106633588 B CN 106633588B CN 201611138158 A CN201611138158 A CN 201611138158A CN 106633588 B CN106633588 B CN 106633588B
- Authority
- CN
- China
- Prior art keywords
- parts
- charging pile
- electric automobile
- automobile charging
- cable material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Abstract
The invention discloses a kind of electric automobile charging pile elastomer cable materials and preparation method thereof, its component includes: SEBS(styrene series elastomer), nitrile rubber, TPU thermoplastic elastomer (TPE), high density polyethylene (HDPE), equal benzene polyimides, low hydration zinc borate, compatilizer, DMDPB (2,3- dimethyl -2,3- diphenyl butane)；Electric automobile charging pile private cable material of the invention has many advantages, such as that flame retardant property is good, fire retardant additive amount is low, heat-resisting, fire retardant low toxic and environment-friendly and cheap and easy to get, low cigarette, good mechanical property.
Description
Technical field
The present invention relates to a kind of cable materials, and in particular to a kind of electric automobile charging pile cable material and preparation method.
Background technique
Thermoplastic elastomer (TPE), i.e. TPE, not only with the processing performance of thermoplastic, but also it is physical with vulcanized rubber
Can, it is the advantageous combination of plastics and rubber advantage.Thermoplastic elastomer (TPE) is capturing without restraint is pertaining only to vulcanized rubber originally
Manor.In the recent decade, the fast development of electronic apparatus, communication and automobile industry has driven the high speed in thermoplastic elastomer (TPE) city
Development.Thermoplastic elastomer (TPE) (TPE) has the physical mechanical property of vulcanized rubber and the performance of technical process of thermoplastic.By
In being not required to by heat cure, production can be completed using general device of plastic processing.
Since charging pile cable load electric current is larger, conductor is easy fever, while charging pile cable is exposed to the external world for a long time
There is the risk meeting open fire and burning in environment.So needing the insulating materials of charging pile cable has certain anti-flammability.It is complicated
External environment need cable to need better weatherability, and inevitably there is the case where cable circumnutates in application, so phase
The cable answered should have the preferable resistance to performance that circumnutates.And conductor easily causes cable insulation material by the heat that high current generates
Fever and aging, therefore, charging pile cable have higher want with fire-retardant etc. to hot-air aging resistance, weatherability, resistance to circumnutate
It asks.
CN103554814 discloses a kind of TPE material that high temperature resistance is good, it by following parts by weight each component system
At: 80-100 parts of hydrogenated styrene-butadiene-styrene block copolymers, hydrogenation naphthenic oil 80-100 parts, polypropylene 15-20
Part, 15-20 parts of Propylene-ethylene random copolymer, 100-120 parts of calcium carbonate, 0.5-1 parts of calcium stearate, 2- tert-butyl -4,6- two
0.1-0.2 parts of methylphenol, 0.4-0.8 parts of 2,4,6- tri-butyl-phenol.The TPE material heat resistance is good, compressive deformation, bullet
Property the physical property such as restore and will not be remarkably decreased because temperature is excessively high, however its flame retardant property is poor.
CN201410390759 discloses the modification TPE mixing material and its system of a kind of electric automobile charging pile cable
Preparation Method, the TPE mixing material include following component by weight: 50~70 parts of thermoplastic elastomer (TPE), reinforcing agent 10~20
Part, 25~55 parts of fire retardant, 0.2~0.5 part of lubricant, 0.1~0.3 part of coupling agent, 0.1~0.3 part of antioxidant, the material because
Fire retardant additive amount is larger and intensity is lower, and oil resistivity, heat resistance and scratch resistance are poor, limit it and fill in electric car
Application on electric stake cable.
Electric automobile charging pile cable material is because the particularity of its use environment will unavoidably use fire retardant, and China is
Become fire retardant big producer, be still leading in many field halogen system flame retardants, although halogen fire proofing is with superior
Anti-flammability, but they burning when generate more smog and toxic, mordant gas (hydrogen halides).These are toxic
Gas has serious harm to human respiratory tract and other organs, hinders the progress of disaster relief work, and their diffusion velocity is remote
It is factor most dangerous in fire greater than the diffusion velocity of flame.Consideration in environmental protection, these years, phosphorus flame retardant is gradually
Halogen system flame retardant being substituted, but there are still some disadvantages for phosphorus flame retardant, such as poor heat resistance, volatility is big, compatibility is undesirable, and
And have dropping generation in burning etc..Nitrogenated flame retardant is related to melamine, melamine cyanurate, melamine methanol
Condensation product, polyamide, polyimides, guanidine salt, guanidine condensation product etc., and based on melamine and melamine cyanurate.
Currently, generally speaking, the flame retardant property of nitrogenated flame retardant is not very well, to need to be used in combination with other fire retardants.Three oxidations two
Antimony because usage amount is low, synergy is widely used in fire retarding synergist fortunately, but the technique of antimony oxide have it is special
Property, the heavy metals such as cadmium are inevitably introduced, have adverse effect to environment, so, exploitation environmental protection, comprehensive performance are preferably fire-retardant
Synergist is also following hot spot.
Summary of the invention
Electric automobile charging pile private cable material of the invention, has that flame retardant property is good, fire retardant additive amount is low, resistance to
The advantages that heat, fire retardant low toxic and environment-friendly and cheap and easy to get, low cigarette, good mechanical property.
A kind of electric automobile charging pile cable material, the material composition calculate by weight, and raw material includes:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
Low hydration zinc borate: 10-15 parts,
Compatilizer: 4 parts,
DMDPB:2-3 parts,
Wherein:
(1) compatilizer is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein the Malaysia
The weight ratio of acid anhydrides Maleated SEBS and maleic anhydride grafting PE are 1:2；
(2) styrene series elastomer is each based block copolymer containing styryl structures unit of hub-and-spoke configuration,
And the weight ratio of the styrene and butadiene that contain in the styrene series elastomer is 3:1.
Preferably, the low hydration zinc borate is 2ZnO3B2O35H2O.
Preferably, Jing≤2 μm Li of the 2ZnO3B2O35H2O.
Preferably, the partial size of the 2ZnO3B2O35H2O is 75nm.
Preferably, the nitrile rubber is the nitrile rubber that hydrogenation degree is greater than 99%.
Preferably, the TPU thermoplastic elastomer (TPE) is polyester-type TPU.
It preferably, further include 0.1-1 parts of antioxidant in material.
Preferably, the antioxidant is the mixture of antioxidant 1010 and irgasfos 168, wherein antioxidant 1010 and antioxygen
The weight ratio of agent 168 is 1:2.
The method for preparing the electric automobile charging pile cable material, includes the following steps:
(1) it is spare that various materials weighing: are accurately weighed according to composition；
(2) it is added the SEBS, nitrile rubber into high-speed mixer, TPU thermoplastic elastomer (TPE), high density polyethylene (HDPE),
Equal benzene polyimides, is stirred 5 minutes at 80 DEG C with 900 revs/min of revolving speed, adds low hydration zinc borate, compatilizer,
DMDPB, to obtain mixed material under conditions of 1000 revs/min of mixing at 100 DEG C；
(3) mixed material obtained in step 2 is put into double screw extruder and carries out melt kneading and squeezes out, squeezed out
Temperature is 220 DEG C, screw speed 550rpm；Water cooling is carried out to the melting output that extruder die head squeezes out again, grain is made
Packaging is completed after material.
Specific embodiment
Below with reference to embodiment, the invention will be further described, and mode of the invention includes but are not limited to following implementation
Example.
Embodiment 1, the composition and weight of the electric automobile charging pile cable material of the present embodiment are as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 75nm): 10 parts,
Compatilizer: 4 parts,
DMDPB:1 parts,
Antioxidant: 0.2 part,
Wherein:
(1) compatilizer is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein the Malaysia
The weight ratio of acid anhydrides Maleated SEBS and maleic anhydride grafting PE are 1:2；
(2) antioxidant is the mixture for being antioxidant 1010 and irgasfos 168, wherein antioxidant 1010 and antioxidant
168 weight ratio is 1:2.
(3) styrene series elastomer (SEBS) is that all kinds of blocks containing styryl structures unit of hub-and-spoke configuration are total
Polymers, and the weight ratio of the styrene and butadiene contained in the styrene series elastomer is 3:1.
(4) nitrile rubber is the nitrile rubber that hydrogenation degree is greater than 99%, and the TPU thermoplastic elastomer (TPE) is polyester-type
TPU。
The method for preparing electric automobile charging pile cable material using above-mentioned material, includes the following steps:
(1) it is spare that various materials weighing: are accurately weighed according to composition；
(2) it is added the SEBS, nitrile rubber into high-speed mixer, TPU thermoplastic elastomer (TPE), high density polyethylene (HDPE),
Equal benzene polyimides, is stirred 5 minutes at 80 DEG C with 900 revs/min of revolving speed, adds low hydration zinc borate, compatilizer,
DMDPB, antioxidant, to obtain mixed material under conditions of 1000 revs/min of mixing at 100 DEG C；
(3) mixed material obtained in step 2 is put into double screw extruder and carries out melt kneading and squeezes out, squeezed out
Temperature is 220 DEG C, screw speed 550rpm；Water cooling is carried out to the melting output that extruder die head squeezes out again, grain is made
Packaging is completed after material.
Embodiment 2, the preparation method of the electric automobile charging pile cable material of the present embodiment such as embodiment 1 are different
It is that composition and weight are as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 75nm): 10 parts,
Compatilizer: 4 parts,
DMDPB:2 parts,
Antioxidant: 0.2 part.
Embodiment 3, the preparation method of the electric automobile charging pile cable material of the present embodiment such as embodiment 1 are different
It is that composition and weight are as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 75nm): 10 parts,
Compatilizer: 4 parts,
DMDPB:3 parts,
Antioxidant: 0.2 part.
Embodiment 4, the preparation method of the electric automobile charging pile cable material of the present embodiment such as embodiment 1 are different
It is that composition and weight are as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 75nm): 5 parts,
Compatilizer: 4 parts,
DMDPB:3 parts,
Antioxidant: 0.2 part.
Embodiment 5, the present embodiment electric automobile charging pile cable material preparation method such as embodiment 1, it is different
It is that composition and weight are as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 75nm): 15 parts,
Compatilizer: 4 parts,
DMDPB:2 parts,
Antioxidant: 0.2 part.
Embodiment 6, the present embodiment electric automobile charging pile cable material preparation method such as embodiment 1, it is different
It is that composition and weight are as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 75nm): 15 parts,
Compatilizer: 4 parts,
DMDPB:1 parts,
Antioxidant: 0.2 part.
The preparation method of the electric automobile charging pile cable material of comparative example 1, this comparative example such as embodiment 1 is different
It is that composition and weight are as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
The mixture (1:1) of poly cyanamid cyanurate and diethyl hypophosphites: 40 parts,
Silicone master batch: 3 parts,
Compatilizer: 4 parts,
Antioxidant: 0.2 part,
Smoke suppressant: 4 parts.
(1) smoke suppressant described in is zinc borate.
The preparation method of the electric automobile charging pile cable material of comparative example 2, this comparative example such as embodiment 1, composition
And weight is as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 2 μm): 10 parts,
Compatilizer: 4 parts,
DMDPB:2 parts,
Antioxidant: 0.2 part.
The preparation method of the electric automobile charging pile cable material of comparative example 3, this comparative example such as embodiment 1, composition
And weight is as follows:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
2ZnO3B2O35H2O (partial size, 75nm): 10 parts,
Compatilizer: 4 parts,
Sb2O3:2 parts,
Antioxidant: 1 part.
The composition of table 1, embodiment 1-6 and comparative example 1-3
| SEBS | Fourth Nitrile Rubber Glue | TPU | It is highly dense Degree is poly- Ethylene | Equal benzene Polyamides Amine | 2ZnO· 3B2O3· 5H2O (grain Diameter, 75nm) | Phase Hold Agent | DMDPB | It is anti- Oxygen Agent | Poly cyanamid cyanuric acid Salt and diethyl Phosphatic mixing Object (1:1) | 2ZnO· 3B2O3· 5H2O (grain Diameter, 2 μm) | Silicone master batch | Smoke suppressant | Sb2O3 | |
| Embodiment 1 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 1 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 2 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 2 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 3 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 3 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 4 | 20 | 10 | 15 | 15 | 15 | 5 | 4 | 3 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 5 | 20 | 10 | 15 | 15 | 15 | 15 | 4 | 2 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 6 | 20 | 10 | 15 | 15 | 15 | 15 | 4 | 1 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Comparative example 1 | 20 | 10 | 15 | 15 | 15 | 0 | 4 | 0 | 0.2 | 40 | 0 | 3 | 4 | 0 |
| Comparative example 2 | 20 | 10 | 15 | 15 | 15 | 0 | 4 | 2 | 0.2 | 0 | 10 | 0 | 0 | 0 |
| Comparative example 3 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 0 | 1 | 0 | 0 | 0 | 0 | 2 |
The explanation of a part of content of table:
(1) compatilizer described in table is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein described
The weight ratio of maleic anhydride-g-SBS and maleic anhydride grafting PE are 1:2；
(2) antioxidant described in table is the mixture for being antioxidant 1010 and irgasfos 168, wherein antioxidant 1010 and anti-
The weight ratio of oxygen agent 168 is 1:2.
(3) styrene series elastomer described in table (SEBS) contains all kinds of embedding of styryl structures unit for hub-and-spoke configuration
Section copolymer, and the weight ratio of the styrene and butadiene contained in the styrene series elastomer is 3:1.
(4) nitrile rubber described in table is the nitrile rubber that hydrogenation degree is greater than 99%, and the TPU thermoplastic elastomer (TPE) is poly-
Ester type TPU.
(5) smoke suppressant described in table is zinc borate.
The indices and comparing result of table 2, embodiment 1-6 and comparative example 1-3
Relative to immediate documents CN201510516682, the beneficial effects of the present invention are:
Documents are using phosphorus flame retardant diethyl hypophosphites and nitrogen system as composite flame-retardant agent, diethyl hypophosphorous acid
Salt belongs to small molecule phosphorus flame retardant, volatile, not only processing environment is made to be deteriorated, but also be easily precipitated, and pollutes mold, price
Also more expensive.The present invention is using low hydration zinc borate as fire retardant, especially 2ZnOB2O3H2O, it is only necessary to add
Lower amount can reach the flame retardant effect of CN201510516682 preferred embodiment.
Fire retarding synergist is 2,3- dimethyl -2,3- diphenyl butane (DMDPB), with fire retardant in certain proportional region
The dosage of fire retardant can be effectively reduced in interior combination, very small on the influence of cable material mechanical performance, and overcomes existing height
Imitate the high disadvantage of the raw smoke of synergist Sb2O3.
Hydration zinc borate and DMDPB not only have fire retardation, while also having suppression cigarette effect, and cable material of the invention does not add
Add smoke suppressant, just reaches the smoke suppressing effect of CN201510516682 preferred embodiment.Form relatively easy, reduction technique step
Suddenly.In a certain range, we compared influence of the 2ZnOB2O3H2O partial size difference to smoke suppressing effect and other indexs.
It was found that the 2ZnOB2O3H2O smoke suppressing effect for selecting partial size small is more preferable.
Claims (7)
1. a kind of electric automobile charging pile cable material, which is characterized in that by weight, which includes:
SEBS:20 parts,
Nitrile rubber: 10 parts,
TPU thermoplastic elastomer (TPE): 15 parts,
High density polyethylene (HDPE): 15 parts,
Equal benzene polyimides: 15 parts,
Low hydration zinc borate: 10-15 parts,
Compatilizer: 4 parts,
DMDPB:2-3 parts,
Wherein:
The compatilizer is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein the maleic anhydride is grafted
The weight ratio of SEBS and maleic anhydride grafting PE are 1:2；
The SEBS is each based block copolymer containing styryl structures unit of hub-and-spoke configuration, and contains in the SEBS
The weight ratio of some styrene and butadiene is 3:1；
The low hydration zinc borate is 2ZnO3B2O3·5H2O；
The 2ZnO3B2O3·5H2Jing≤2 μm Li of O.
2. electric automobile charging pile cable material as described in claim 1, it is characterised in that: the 2ZnO3B2O3·
5H2The partial size of O is 75nm.
3. electric automobile charging pile cable material as described in claim 1, it is characterised in that: the nitrile rubber is hydrogenation
Degree is greater than 99% nitrile rubber.
4. electric automobile charging pile cable material as described in claim 1, it is characterised in that: the TPU thermoplastic elastic
Body is polyester-type TPU.
5. electric automobile charging pile cable material as claimed in claim 4, it is characterised in that: further include 0.1-1 in material
The antioxidant of part.
6. electric automobile charging pile cable material as claimed in claim 5, it is characterised in that: the antioxidant is antioxidant
1010 with the mixture of irgasfos 168, wherein the weight ratio of antioxidant 1010 and irgasfos 168 is 1:2.
7. the method for preparing the electric automobile charging pile cable material as described in claim any one of 1-6, which is characterized in that packet
Include following steps:
(1) it is spare that various materials weighing: are accurately weighed according to composition；
(2) SEBS, nitrile rubber, TPU thermoplastic elastomer (TPE), high density polyethylene (HDPE), equal benzene are added into high-speed mixer
Polyimides is stirred 5 minutes at 80 DEG C with 900 revs/min of revolving speed, adds low hydration zinc borate, compatilizer, DMDPB,
To obtain mixed material under conditions of 1000 revs/min of mixing at 100 DEG C；
(3) mixed material obtained in step 2 is put into double screw extruder and carries out melt kneading and squeezes out, extrusion temperature
It is 220 DEG C, screw speed 550rpm；Water cooling is carried out to the melting output that extruder die head squeezes out again, after pellet is made
Packaging is completed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611138158.0A CN106633588B (en) | 2016-12-12 | 2016-12-12 | A kind of electric automobile charging pile cable material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611138158.0A CN106633588B (en) | 2016-12-12 | 2016-12-12 | A kind of electric automobile charging pile cable material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106633588A CN106633588A (en) | 2017-05-10 |
| CN106633588B true CN106633588B (en) | 2019-03-08 |
Family
ID=58824180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611138158.0A Active CN106633588B (en) | 2016-12-12 | 2016-12-12 | A kind of electric automobile charging pile cable material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106633588B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102356123A (en) * | 2009-04-28 | 2012-02-15 | 第一工业制药株式会社 | Flame-retardant expandable styrene resin composition |
| CN105038088A (en) * | 2015-08-21 | 2015-11-11 | 中广核三角洲（苏州）高聚物有限公司 | Elastomer cable material for oil-resistant cold-resistant high-temperature-resistant electric automobile charge piles and preparation method thereof |
| CN105556028A (en) * | 2013-09-12 | 2016-05-04 | 溴化合物有限公司 | Brominated epoxy polymers as textile-finishing flame retardant formulations |
| CN105980467A (en) * | 2013-12-16 | 2016-09-28 | 科莱恩国际有限公司 | Polymeric Foam |
-
2016
- 2016-12-12 CN CN201611138158.0A patent/CN106633588B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102356123A (en) * | 2009-04-28 | 2012-02-15 | 第一工业制药株式会社 | Flame-retardant expandable styrene resin composition |
| CN105556028A (en) * | 2013-09-12 | 2016-05-04 | 溴化合物有限公司 | Brominated epoxy polymers as textile-finishing flame retardant formulations |
| CN105980467A (en) * | 2013-12-16 | 2016-09-28 | 科莱恩国际有限公司 | Polymeric Foam |
| CN105038088A (en) * | 2015-08-21 | 2015-11-11 | 中广核三角洲（苏州）高聚物有限公司 | Elastomer cable material for oil-resistant cold-resistant high-temperature-resistant electric automobile charge piles and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106633588A (en) | 2017-05-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103059374B (en) | High-temperature-resistant silane-crosslinked flame-retardation insulating material for automobile wires and preparation method thereof | |
| CN112250935B (en) | High-flame-retardant-grade low-smoke halogen-free material and preparation method and application thereof | |
| CN112063048B (en) | Low-dielectric high-melt-strength flame-retardant polypropylene material and preparation method thereof | |
| KR101601286B1 (en) | Highly flame-resistant polymer composition for electrical wire insulation and electrical wire produced therewith | |
| SA110310827B1 (en) | Clean flame retardant insulation compositions to enhance mechanical properties and flame retardancy for wires and cables | |
| CN102070821A (en) | Irradiation cross-linking oil resistance type soft low smoke zero halogen flame-retardant cable material | |
| CN100374497C (en) | Smokeless and halogen-free expanding fire-retardant electric wire materials with thermoplastic elastomer and production thereof | |
| EP2355111A2 (en) | Cross-linked clean flame retardant wire and cable insulation compositions for enhancing mechanical properties and flame retardancy | |
| CN102485782A (en) | Crosslinked, oil-resistant, low temperature-resistant, low-smoke, halogen-free and flame-retardant cable material and its preparation method | |
| CN105038087A (en) | Halogen-free flame retardant high-tear-resistance wire and cable compound for electric vehicles and wire and cable production method | |
| CN106633420A (en) | Halogen-free flame-retardation thermoplastic dynamic sulfurated ethylene-propylene-diene monomer rubber/polypropylene composition and preparation method thereof | |
| CN103613900B (en) | halogen-free flame-retardant ABS resin and preparation method thereof | |
| CN105348630B (en) | A kind of electric wire high oxygen index (OI), strong self-extinguishing thermoplastic LSOH anti-flaming material and preparation method thereof | |
| CN103224681B (en) | Silicane self-crosslinked halogen-free flame retardant polyolefin foamed composite and preparation method thereof | |
| CN102295818B (en) | Zero-halogen, low-smoke and flame-retardant TPE (Thermoplastic Elastomer) cable material and preparation method thereof | |
| CN101649113B (en) | IE-grade KI-type heat-shrinkable material for nuclear power and preparation technology thereof | |
| CN100363415C (en) | Low smoke non-halogen fire retarding expansive polyolefins electronic wire material and preparation process thereof | |
| CN103849133A (en) | High-temperature-resisting irradiation-free cross-linked halogen-free flame-retardant wire-cable material | |
| CN108239315A (en) | A kind of electric automobile charging pile cable halogen-free type thermoplastic elastomer cable material and preparation method thereof | |
| CN109627568A (en) | Polyolefine cable sheath material and preparation method thereof | |
| CN105199167B (en) | Environment-friendly high and low temperature resistant and oil resistant flame-retardant nano-composite thermoplastic elastomer and preparation process thereof | |
| CN102070836B (en) | Low-smoke flame-retardant thermoplastic vulcanized rubber and preparation method thereof | |
| WO2012127463A1 (en) | Flame retardant composition and flame retarded high impact polypropylene | |
| CN105801990B (en) | A kind of Halogen no red phosphorus high fire-retardance heat-shrinkable T bush and preparation method thereof | |
| CN104356538A (en) | Flame-retardant smoke-eliminating polyvinyl chloride wire and cable material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190129 Address after: 224041 Tongyu North Road, Wuyou Street, South New District, Yancheng City, Jiangsu Province Applicant after: Yancheng Qing Da New Material Co., Ltd. Address before: 610041 No. 1, 8 floor, No. 1, Tianfu Avenue, 1388 middle and high tech Zone, Chengdu, Sichuan. Applicant before: CHENGDU YUYA SCIENCE & TECHNOLOGY CO., LTD. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |