CN106633381A - A color master batch used for highly anti-shock PP - Google Patents
A color master batch used for highly anti-shock PP Download PDFInfo
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- CN106633381A CN106633381A CN201610909738.9A CN201610909738A CN106633381A CN 106633381 A CN106633381 A CN 106633381A CN 201610909738 A CN201610909738 A CN 201610909738A CN 106633381 A CN106633381 A CN 106633381A
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- parts
- master batch
- color master
- impact
- masterbatch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
A color master batch used for highly anti-shock PP is disclosed. The color master batch is prepared from, by weight, 140-150 parts of PP, 20-30 parts of polybutylene terephthalate, 5-14 parts of N,N'-ethylenebis(stearamide), 3-5 parts of oleamide, 2-4 parts of alkylphenol polyoxyethylene, 12-15 parts of hydroxy silicone oil, 13-15 parts of acrylic resin, 8-12 parts of diphenylthiourea, 10-15 parts of ethyl acetate, 2-6 parts of dibasic lead phosphite, 5-9 parts of o-phthalic anhydride, 1-5 parts of methyltin and 6-14 parts of nanometer coconut oil monoethanolamide. The color master batch has high anti-shock performance and wear resistance, a processing cost is low, and a preparing process is simple. When the color master batch is used for PP product coloring, the color master batch has advantages of improved color stability and low chromatic aberration, and problems that color is unstable, chromatic aberration is large, and the like during coloring using present PP color master batches are overcome.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of high-impact PP Masterbatch.
Background technology
With the raising of living standards of the people, people not only pay close attention to the performance of the product used in various lives, same to time
Its is attractive in appearance for benefit pursuit, and wishes that product of its purchase has good outward appearance.Because plastic products have abundant raw material source, valency
Lattice are cheap, nontoxic, be easy to processing and forming, higher rigidity and toughness, and mechanical strength is good, so being flooded with people's life now
Plastic products miscellaneous, and Masterbatch coloring is the coloring plastic method for most generally adopting now.Masterbatch is 20th century 60
A kind of plastics, the coloring new product of fiber of age exploitation, it is pigment super quantity to be uniformly attached in resin and is obtained
Polymer compound.With the progress of technology, in plastic processes, by adding Masterbatch, so as to play beautification, dress
Adorn, be easy to recognize, improve weatherability, improve mechanical property, improve the effect such as optical property.When being coloured using Masterbatch, pigment
Through pre-processing and it is dispersed in vector resin, the dispersive property and coloration efficiency of pigment is substantially increased, with operation
Simply, the advantages of with low cost, environmentally safe.
Polypropylene（PP）It is that a kind of proportion is low, corrosion-resistant, widely used polymer, as non-polar polymeric material,
With very high insulating properties, specific insulation can reach 1016-1020 Ω cm, but often also easily produce electrostatic, absorption
Dust, have impact on the application in fields such as electronic apparatus, dangerous material storages.
At present, the variety of raw material such as the higher country of external PP Masterbatch technical merit, pigment, dispersant are complete, shape
Into seriation and specialized product structure.But domestic PP Masterbatch product structure is single, the former material item such as pigment, dispersant
Plant collocation complete, there is some difference to cause color and luster, and this is totally unfavorable for the coloring of product.When being coloured with Masterbatch,
Because carrier flow performance is poor, the problems such as easily there is flow liner, color and luster uneven, wayward aberration and single function.Therefore,
How to solve easily to be produced when PP Masterbatch is coloured the problems such as flow liner, color and luster be uneven, aberration is larger and shock resistance is deteriorated, be
The problem that PP need to be solved urgently when colouring.For this purpose, we set about from the formula of product, new Masterbatch is developed, there is provided Yi Zhonggao
Anti-impact PP Masterbatch.
The content of the invention
It is an object of the invention to provide a kind of high-impact PP Masterbatch.
To achieve these goals, the invention provides a kind of high-impact PP Masterbatch, by the raw material of following weight portion
It is obtained：PP 140-150 parts, polybutylene terephthalate (PBT) 20-30 parts, ethylene bis stearamide 5-14 parts, oleamide 3-5
Part, APES 2-4 parts, hydroxy silicon oil 12-15 parts, acrylic resin 13-15 parts, rhenocure CA 8-12 parts,
Ethyl acetate 10-15 parts, dibasic lead phosphite 2-6 parts, phthalic acid diformazan acid anhydride 5-9 parts, methyl tin 1-5 parts, nano coconut
Sub- oleic monoethanolamide 6-14 parts.
It also includes Graphene 3-8 parts.
It also includes polyaniline 8-23 parts.
It also includes barium titanate 3-7 parts.
Beneficial effect：The high-impact PP that the present invention is provided has higher shock resistance and anti-wear performance with Masterbatch,
Processing cost is low, preparation process is simple, less with colour stability raising, aberration when the coloring of PP products is applied to
Advantage, overcomes the problems such as color is unstable, aberration is larger when existing PP Masterbatch is coloured.
Specific embodiment
Embodiment 1
A kind of high-impact PP Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 140 parts of PP, poly- to benzene
20 parts of dioctyl phthalate butanediol ester, 5 parts of ethylene bis stearamide, 3 parts of oleamide, 2 parts of APES, hydroxy silicon oil 12
Part, 13 parts of acrylic resin, 8 parts of rhenocure CA, 10 parts of ethyl acetate, 2 parts of dibasic lead phosphite, phthalic acid diformazan
5 parts of acid anhydride, 6 parts of 1 part, nanometer coconut monoethanolamide of methyl tin.
Embodiment 2
A kind of high-impact PP Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 150 parts of PP, poly- to benzene
30 parts of dioctyl phthalate butanediol ester, 14 parts of ethylene bis stearamide, 5 parts of oleamide, 4 parts of APES, hydroxy silicon oil
15 parts, 15 parts of acrylic resin, 12 parts of rhenocure CA, 15 parts of ethyl acetate, 6 parts of dibasic lead phosphite, phthalic acid
9 parts of diformazan acid anhydride, 14 parts of 5 part, nanometer coconut monoethanolamide of methyl tin, 8 parts of Graphene.
Embodiment 3
A kind of high-impact PP Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 140 parts of PP, poly- to benzene
20 parts of dioctyl phthalate butanediol ester, 5 parts of ethylene bis stearamide, 3 parts of oleamide, 2 parts of APES, hydroxy silicon oil 12
Part, 13 parts of acrylic resin, 8 parts of rhenocure CA, 10 parts of ethyl acetate, 2 parts of dibasic lead phosphite, phthalic acid diformazan
5 parts of acid anhydride, 6 parts of 1 part, nanometer coconut monoethanolamide of methyl tin, 3 parts of Graphene, 8 parts of polyaniline.
Embodiment 4
A kind of high-impact PP Masterbatch that the present embodiment is provided, is obtained by the raw material of following weight portion：It is 150 parts of PP, poly- to benzene
30 parts of dioctyl phthalate butanediol ester, 14 parts of ethylene bis stearamide, 5 parts of oleamide, 4 parts of APES, hydroxy silicon oil
15 parts, 15 parts of acrylic resin, 12 parts of rhenocure CA, 15 parts of ethyl acetate, 6 parts of dibasic lead phosphite, phthalic acid
9 parts of diformazan acid anhydride, 14 parts of 5 part, nanometer coconut monoethanolamide of methyl tin, 8 parts of Graphene, 23 parts of polyaniline, barium titanate 7
Part.
The production technology that above-described embodiment 1-4 is used is conventional production process, and its step is：First weigh respectively by said ratio
In raw material input homogenizer, stirring mixing；Then the material being well mixed is added to into melting in double screw extruder, modeling
Change, extrude, granulate, obtain final product.
Claims (4)
1. a kind of high-impact PP Masterbatch, it is characterised in that be made up of the raw material of following weight portion：It is PP 140-150 parts, poly- right
Benzene dicarboxylic acid butanediol ester 20-30 parts, ethylene bis stearamide 5-14 parts, oleamide 3-5 part, APES 2-4
Part, hydroxy silicon oil 12-15 parts, acrylic resin 13-15 parts, rhenocure CA 8-12 parts, ethyl acetate 10-15 parts, dibasic
Lead phosphite 2-6 parts, phthalic acid diformazan acid anhydride 5-9 parts, methyl tin 1-5 parts, nanometer coconut monoethanolamide 6-14 parts.
2. a kind of high-impact PP Masterbatch according to claim 1, it is characterised in that：It also includes Graphene 3-8 parts.
3. a kind of high-impact PP Masterbatch according to claim 2, it is characterised in that：It also includes polyaniline 8-23
Part.
4. a kind of high-impact PP Masterbatch according to claim 3, it is characterised in that：It also includes barium titanate 3-7 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909738.9A CN106633381A (en) | 2016-10-19 | 2016-10-19 | A color master batch used for highly anti-shock PP |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610909738.9A CN106633381A (en) | 2016-10-19 | 2016-10-19 | A color master batch used for highly anti-shock PP |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106633381A true CN106633381A (en) | 2017-05-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610909738.9A Pending CN106633381A (en) | 2016-10-19 | 2016-10-19 | A color master batch used for highly anti-shock PP |
Country Status (1)
| Country | Link |
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| CN (1) | CN106633381A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129633A (en) * | 2017-06-13 | 2017-09-05 | 浙江金彩新材料有限公司 | A kind of polypropylene graphene Masterbatch of high fade resistance and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557870A (en) * | 2004-02-11 | 2004-12-29 | 广东盛恒昌化学工业有限公司 | Natural-like multifunctional color batch and use thereof |
| CN102485791A (en) * | 2010-12-02 | 2012-06-06 | 池建平 | Masterbatch |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
| CN103709497A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | Color master batch for plastic cement and preparation method thereof |
| CN104004300A (en) * | 2014-06-13 | 2014-08-27 | 滁州市宏源喷涂有限公司 | Color masterbatch |
-
2016
- 2016-10-19 CN CN201610909738.9A patent/CN106633381A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557870A (en) * | 2004-02-11 | 2004-12-29 | 广东盛恒昌化学工业有限公司 | Natural-like multifunctional color batch and use thereof |
| CN102485791A (en) * | 2010-12-02 | 2012-06-06 | 池建平 | Masterbatch |
| CN103709497A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | Color master batch for plastic cement and preparation method thereof |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
| CN104004300A (en) * | 2014-06-13 | 2014-08-27 | 滁州市宏源喷涂有限公司 | Color masterbatch |
Non-Patent Citations (1)
| Title |
|---|
| 卓昌明: "《塑料应用技术手册》", 31 May 2013, 机械工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129633A (en) * | 2017-06-13 | 2017-09-05 | 浙江金彩新材料有限公司 | A kind of polypropylene graphene Masterbatch of high fade resistance and preparation method thereof |
| CN107129633B (en) * | 2017-06-13 | 2020-11-24 | 浙江金彩新材料有限公司 | Polypropylene-graphene color master batch with high fading resistance and preparation method thereof |
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