CN106625948A - Soaking liquid for moth, crack and fire resistance of wood and preparation method of soaking liquid - Google Patents

Soaking liquid for moth, crack and fire resistance of wood and preparation method of soaking liquid Download PDF

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Publication number
CN106625948A
CN106625948A CN201611094555.2A CN201611094555A CN106625948A CN 106625948 A CN106625948 A CN 106625948A CN 201611094555 A CN201611094555 A CN 201611094555A CN 106625948 A CN106625948 A CN 106625948A
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CN
China
Prior art keywords
soak
anticracking
maring
preservative
bore
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611094555.2A
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Chinese (zh)
Inventor
樊岁新
邹敏
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Panzhihua University
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Panzhihua University
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Filing date
Publication date
Application filed by Panzhihua University filed Critical Panzhihua University
Priority to CN201611094555.2A priority Critical patent/CN106625948A/en
Publication of CN106625948A publication Critical patent/CN106625948A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52Impregnating agents containing mixtures of inorganic and organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/20Removing fungi, molds or insects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/30Fireproofing

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention belongs to the material science field, and particularly relates to soaking liquid for moth, crack and fire resistance of wood and a preparation method of the soaking liquid, aiming to solve the problem that there is no economic and reasonable method for moth, crack and fire resistance of the wood in the prior art. The soaking liquid comprises, by weight, 30-40 parts of moisture-absorbing humectants, 20-30 parts of sterilizing preservatives and 20-30 parts of fire retardants. The preparation method includes making the raw materials into powder, mixing the powder evenly, adding the mixed powder into water, and evenly stirring the water to obtain the soaking liquid. The soaking liquid and the preparation method thereof have the advantages that the selected raw materials are easy to dissolve in the water; after dissolution, solution viscosity is low, odour and poison are not generated, the liquid is basically colorless, and the color of the wood is not contaminated; the soaking liquid has high seepage force and easily permeates into the wood, and the soaked wood is resistant to moth, crack and fire, the effect lasts long, and economic value is high.

Description

Wood treated with maring bore preservative anticracking fire prevention soak and preparation method thereof
Technical field
The invention belongs to material science, specifically related to a kind of wood treated with maring bore preservative anticracking fire prevention soak and its preparation side Method.
Background technology
Over the past thousands of years people build house using timber, do furniture or woodenware jewelry.Either resplendent and magnificent palace Those carved beams and painted rafter and the through-carved work artwork decoration of life-like character animal flowers and plants, or the local-style dwelling houses of common people among the people Private residence and apparatus, all employ size timber.Through the abundant imagination and superb wisdom of craftsman, dab hand skill, wonderful workmanship excelling nature Works, succession culture, brought life endless spiritual enjoyment.But as time goes by, have experienced various vicissitudes of life, timber The cross beam and upright post made and the ornaments for decorateeing house all wrecked fineness then with it is complete:Moth erosion is rotten, and ftracture weak point. The beautiful appearance that virtuosity then is decorateeed out has not existed, and more notably because a variety of causes catches fire one burns tool, ash Winged cigarette goes out.
People once make great efforts to explore the methods for changing wood characteristicses, and it is mothproof to try out various paint anti-corrosions, such as uses Tung oil is coated in wood surface, or mixes lime with pig blood and apply and scrape, or raw lacquer is scraped and smeared, or using various paint sprayings, or adopt plate The measures such as material parcel timber, but these methods respectively have shortcoming, and tung oil, paint do not prevent fires not fire-retardant, combustion-supporting on the contrary;Raw lacquer price is too It is expensive, and in operation personnel are too big by its murder by poisoning, serious harm health of people;Pig blood lime, scrapes and smears thickness, expense of taking a lot of work When, and surface has no aesthetic feeling, also needs to coat paint to decorate, and cost increases;Sheet material parcel cost is too high, and produces trouble, Also do not prevent fires, it is combustion-supporting on the contrary.
Said method is all makeshift, it is impossible to fundamentally solve the problems, such as that inflammable easily the splitting of timber is easily damaged by worms.
The content of the invention
The technical problem to be solved in the present invention is:Prior art does not have the wood treated with maring bore preservative anticracking fireproof side of economical rationality Method.
The present invention solves the technical scheme of technical problem:A kind of wood treated with maring bore preservative anticracking fire prevention soak is provided.The immersion Liquid constitutive material includes:Count by weight, 30~40 parts of moisture-absorption humectant, 20~30 parts of sterilization antiseptic, fire retardant 20~ 30 parts.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described moisture-absorption humectant is urea, ammonium hydrogencarbonate, unit In bright powder or calcium chloride at least two.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described sterilization antiseptic be boric acid, borax, sodium chloride, In Sodium Benzoate or alum at least two.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described fire retardant is sodium metasilicate, sodium tripolyphosphate or phosphorus In sour trisodium at least two.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described moisture-absorption humectant, sterilization antiseptic, fire retardant All it is the powder of granularity≤200 mesh.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, its composition also includes 10~15 parts of dispersant;It is preferred that , the dispersant is calgon.
The present invention also provides the preparation method that a kind of above-mentioned wood treated with maring bore preservative anticracking prevents fires soak, comprises the following steps:
A, moisture-absorption humectant, sterilization antiseptic, fire retardant are made into powder, it is standby after being well mixed;
B, by the step of 10~15% a gained mixed-powder add 85~90% water in, stir 10~20min, be obtained Wood treated with maring bore preservative anticracking fireproof soak.
Wherein, in the preparation method of above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, mixed-powder is added to the water in step b Afterwards, dispersant is added.
The present invention also provides the using method that a kind of above-mentioned wood treated with maring bore preservative anticracking prevents fires soak, it would be desirable to which mothproof anticracking is prevented The timber of fire is completely soaked in the soak, soaks 12~24h.
Beneficial effects of the present invention are:The present invention selects suitable moisture-absorption humectant, sterilization antiseptic and fire-retardant powder, Be prepared into soak, for soaking timber after mothproof anticracking fire prevention.The raw material that the present invention is selected is soluble in water, after dissolving Solution viscosity is little, odorlessness, nonhazardous, it is substantially colorless, the color and luster of timber itself will not be polluted;Also, the soak penetration By force, easily it is soaked into timber, the wood treated with maring bore preservative anticracking fire prevention after immersion, and effect is persistently, and economic worth is high.
Specific embodiment
The present invention provides a kind of wood treated with maring bore preservative anticracking fire prevention soak, and its constitutive material includes:Count by weight, moisture absorption 30~40 parts of NMF, 20~30 parts of sterilization antiseptic, 20~30 parts of fire retardant.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described moisture-absorption humectant is urea, ammonium hydrogencarbonate, unit In bright powder or calcium chloride at least two.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described sterilization antiseptic be boric acid, borax, sodium chloride, In Sodium Benzoate or alum at least two.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described fire retardant is sodium metasilicate, sodium tripolyphosphate or phosphorus In sour trisodium at least two.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, described moisture-absorption humectant, sterilization antiseptic, fire retardant All it is the powder of granularity≤200 mesh.
Wherein, in above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, its composition also includes 10~15 parts of dispersant;It is preferred that , the dispersant is calgon.
The present invention also provides the preparation method that a kind of above-mentioned wood treated with maring bore preservative anticracking prevents fires soak, comprises the following steps:
A, moisture-absorption humectant, sterilization antiseptic, fire retardant are made into powder, it is standby after being well mixed;
B, by the step of 10~15% a gained mixed-powder add 85~90% water in, stir 10~20min, be obtained Wood treated with maring bore preservative anticracking fireproof soak.
Wherein, in the preparation method of above-mentioned wood treated with maring bore preservative anticracking fire prevention soak, mixed-powder is added to the water in step b Afterwards, dispersant is added.
The present invention also provides the using method that a kind of above-mentioned wood treated with maring bore preservative anticracking prevents fires soak, it would be desirable to which mothproof anticracking is prevented The timber of fire is completely soaked in the soak, soaks 12~24h.
Moisture-absorption humectant, sterilization antiseptic, the fire retardant adopted in the present invention all to be highly soluble in the powdered substance of water, Good water solubility, dispersiveness is high, just can be completely dispersed in water body, and then is entered in timber by action of soaking.Can be with leaching Add a certain proportion of dispersant in bubble formula of liquid so that more preferably, the wood effect after immersion is more preferable for dispersion effect.
Moisture-absorption humectant, sterilization antiseptic, fire retardant powder used by the present invention is white or colourless substance, and melts Point is high, and itself is nonflammable, after being soaked into timber, improves the fusing point of timber, makes timber become nonflammable;Meanwhile, the moisture absorption of addition NMF so that timber has moisture retention, not easy to crack.The sterilization antiseptic of addition can kill the worm's ovum in timber, make timber It is difficult to be damaged by worms.The inventive method is simple, the wiring solution-forming after by above-mentioned several raw material mixing, obtains final product timber immersion Liquid, in immersion, various functions composition is all entered in timber together with moisture, reaches mothproof anticracking fireproof effect.
It is widely present in life in view of the timber after immersion, with human contact closely, the mothproof anticracking of the present invention is prevented Fiery soak also has the feature of environmental protection, and selected advantages of nontoxic raw materials is harmless and substantially colorless, and the color of timber itself can be kept after immersion Pool.And raw material will not form film in water, stickum will not be also formed, active ingredient can be effectively promoted and uniformly immersed In timber, stablize the wood performance after immersion.
Timber in use, cracking phenomenon most serious, next to that damage by worms, the phenomenon of rare baked wheaten cake occurs, Therefore, the moisture-absorbing moisture-keeping agent content highest that the present invention is added in soak, is 30~40 parts, sterilization antiseptic and fire retardant Addition is 20~30 parts.
Explanation is further explained to the specific embodiment of the present invention below by embodiment, but is not indicated that and will be protected Scope is limited in scope described in embodiment.
The wood treated with maring bore preservative anticracking of embodiment 1~4 fire prevention soak and preparation method thereof
Wood treated with maring bore preservative anticracking fire prevention soak 1 is prepared, raw material is:30 parts of moisture-absorption humectant, 20 parts of sterilization antiseptic is fire-retardant 30 parts of agent;Described moisture-absorption humectant is the mixture of urea and ammonium hydrogencarbonate;Described sterilization antiseptic be boric acid, borax and The mixture of sodium chloride;Described fire retardant is the mixture of sodium metasilicate, sodium tripolyphosphate and tertiary sodium phosphate.
Wood treated with maring bore preservative anticracking fire prevention soak 2 is prepared, raw material is:40 parts of moisture-absorption humectant, 20 parts of sterilization antiseptic is fire-retardant 20 parts of agent;Described moisture-absorption humectant is the mixture of glauber salt and calcium chloride;Described sterilization antiseptic be Sodium Benzoate and The mixture of alum;Described fire retardant is the mixture of sodium metasilicate and sodium tripolyphosphate.
Wood treated with maring bore preservative anticracking fire prevention soak 3 is prepared, raw material is:40 parts of moisture-absorption humectant, 30 parts of sterilization antiseptic is fire-retardant 30 parts of agent;Described moisture-absorption humectant is the mixture of urea, ammonium hydrogencarbonate, glauber salt and calcium chloride;Described sterilization and anticorrosion Agent is the mixture of boric acid, borax, sodium chloride and Sodium Benzoate;Described fire retardant is the mixing of sodium metasilicate and tertiary sodium phosphate Thing.
The preparation method of embodiment 1~3 is:
A, moisture-absorption humectant, sterilization antiseptic, fire retardant are made into powder, it is standby after being well mixed;
B, a gained mixed-powder will add in 85% water the step of 15%, stir 20min, wood treated with maring bore preservative anticracking will be obtained Fireproof soak.
Wood treated with maring bore preservative anticracking fire prevention soak 4 is prepared, raw material is:35 parts of moisture-absorption humectant, 25 parts of sterilization antiseptic is fire-retardant 25 parts of agent, 15 parts of dispersant (calgon).Described moisture-absorption humectant is urea, ammonium hydrogencarbonate, glauber salt and calcium chloride Mixture;Described sterilization antiseptic is the mixture of boric acid, borax, sodium chloride, Sodium Benzoate and alum;Described is fire-retardant Agent is the mixture of sodium metasilicate, sodium tripolyphosphate and tertiary sodium phosphate.
The preparation method of embodiment 4 is:
A, moisture-absorption humectant, sterilization antiseptic, fire retardant are made into powder, it is standby after being well mixed;
B, by the step of 15% a gained mixed-powder add 85% water in, add dispersant (calgon), stirring 20min, is obtained wood treated with maring bore preservative anticracking fireproof soak.
Timber of 500 block specifications for 40 × 20 × 10 (cm) is soaked using the soak that embodiment 1~4 is prepared, Timber submerges completely in soak, and soak time 24h dries wood surface;The timber of 500 pieces of same sizes is taken, is not done and is soaked Bubble process is as a comparison case.
The timber of embodiment and comparative example is placed under normal temperature and pressure, monitors time, the time of damaging by worms that crackle occurs in its surface, Obtain such as table 1 below result.
The wood treated with maring bore preservative anticracking fire protecting performance measurement result of table 1
Cracking ratio % Ratio % that appearance is damaged by worms 100 DEG C of combustibilities
Embodiment 1 2.2 1.6 It is non-combustible
Embodiment 2 3.4 1.4 It is non-combustible
Embodiment 3 2.4 1.2 It is non-combustible
Embodiment 4 1 0.6 It is non-combustible
Comparative example 17 13 It is flammable
As seen from the experiment, after using the soak immersion timber of the present invention, can reduce that timber is cracking, damage by worms Ratio, the cracking time of prolonging wood is greatly increased with the time for occurring damaging by worms, wood using life, and can not at 100 DEG C Combustion, the timber after immersion has fire line.

Claims (10)

1. wood treated with maring bore preservative anticracking fire prevention soak, it is characterised in that constitutive material includes:Count by weight, moisture-absorption humectant 30~40 parts, 20~30 parts of sterilization antiseptic, 20~30 parts of fire retardant.
2. wood treated with maring bore preservative anticracking according to claim 1 is prevented fires soak, it is characterised in that:Described moisture-absorption humectant is In urea, ammonium hydrogencarbonate, glauber salt or calcium chloride at least two.
3. wood treated with maring bore preservative anticracking according to claim 1 is prevented fires soak, it is characterised in that:Described sterilization antiseptic is In boric acid, borax, sodium chloride, Sodium Benzoate or alum at least two.
4. wood treated with maring bore preservative anticracking according to claim 1 is prevented fires soak, it is characterised in that:Described fire retardant is silicic acid In sodium, sodium tripolyphosphate or tertiary sodium phosphate at least two.
5. wood treated with maring bore preservative anticracking according to claim 1 is prevented fires soak, it is characterised in that:Described moisture-absorption humectant, Sterilization antiseptic, fire retardant are all the powder of granularity≤200 mesh.
6. wood treated with maring bore preservative anticracking according to claim 1 is prevented fires soak, it is characterised in that:Its composition also includes 10~15 The dispersant of part.
7. wood treated with maring bore preservative anticracking according to claim 6 is prevented fires soak, it is characterised in that:Described dispersant is six inclined Sodium phosphate.
8. wood treated with maring bore preservative anticracking described in any one of claim 1~7 is prevented fires the preparation method of soak, it is characterised in that bag Include following steps:
A, moisture-absorption humectant, sterilization antiseptic, fire retardant are made into powder, it is standby after being well mixed;
B, will the step of 10~15% a gained mixed-powder add 85~90% water in, stir 10~20min, be obtained timber Mothproof anticracking fireproof soak.
9. wood treated with maring bore preservative anticracking according to claim 8 is prevented fires the preparation method of soak, it is characterised in that:In step b After mixed-powder is added to the water, dispersant is added.
10. wood treated with maring bore preservative anticracking described in any one of claim 1~7 is prevented fires the using method of soak, it is characterised in that:Will Need mothproof anticracking fireproof timber to be completely soaked in the soak, soak 12~24h.
CN201611094555.2A 2016-12-02 2016-12-02 Soaking liquid for moth, crack and fire resistance of wood and preparation method of soaking liquid Pending CN106625948A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107433661A (en) * 2017-09-19 2017-12-05 安徽嘉美工艺品有限公司 A kind of solid wood furniture anticracking bending method
CN109235029A (en) * 2018-09-03 2019-01-18 常熟华尚新材料科技有限公司 Cotton fabric category fire retardant
CN109822702A (en) * 2019-02-25 2019-05-31 王金华 A kind of high steady wood fire retardant

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3247059A (en) * 1962-02-06 1966-04-19 Bayer Ag Wood protection agents
CN1781687A (en) * 2004-11-30 2006-06-07 吴子良 Method for synthesizing wood flame retardant, anti-corrosion and reinforcing modifier
CN101134331A (en) * 2007-09-28 2008-03-05 东北林业大学 Multiple-effect wood fire retardant and method for preparing the same
CN101623886A (en) * 2009-08-03 2010-01-13 河北大学 Loss-resistance and high-efficiency flame-retarding wood and processing method thereof
CN102975251A (en) * 2012-11-22 2013-03-20 北京林业大学 Flame retardant for wood as well as preparation method and applications of flame retardant for wood

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3247059A (en) * 1962-02-06 1966-04-19 Bayer Ag Wood protection agents
CN1781687A (en) * 2004-11-30 2006-06-07 吴子良 Method for synthesizing wood flame retardant, anti-corrosion and reinforcing modifier
CN101134331A (en) * 2007-09-28 2008-03-05 东北林业大学 Multiple-effect wood fire retardant and method for preparing the same
CN101623886A (en) * 2009-08-03 2010-01-13 河北大学 Loss-resistance and high-efficiency flame-retarding wood and processing method thereof
CN102975251A (en) * 2012-11-22 2013-03-20 北京林业大学 Flame retardant for wood as well as preparation method and applications of flame retardant for wood

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107433661A (en) * 2017-09-19 2017-12-05 安徽嘉美工艺品有限公司 A kind of solid wood furniture anticracking bending method
CN109235029A (en) * 2018-09-03 2019-01-18 常熟华尚新材料科技有限公司 Cotton fabric category fire retardant
CN109822702A (en) * 2019-02-25 2019-05-31 王金华 A kind of high steady wood fire retardant

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