CN106614606A - Cyclaniliprole-containing insecticidal composition - Google Patents
Cyclaniliprole-containing insecticidal composition Download PDFInfo
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- CN106614606A CN106614606A CN201610828763.4A CN201610828763A CN106614606A CN 106614606 A CN106614606 A CN 106614606A CN 201610828763 A CN201610828763 A CN 201610828763A CN 106614606 A CN106614606 A CN 106614606A
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- ring bromine
- insect amide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a cyclaniliprole-containing insecticidal composition. Effective active components comprise a first active component and a second component, wherein the first active component is cyclaniliprole; the second active component is one of biological-source insecticides, namely avermectin, emamectin benzoate and spinosad; the weight ratio of the first active component to the second active component is 1:60 to 60:1; the sum of the contents of the first active component and the second active component is 1-80% of the total weight of the composition. The cyclaniliprole-containing insecticidal composition can be prepared into agriculturally allowable dosage forms, including emulsifiable oil, suspensions, wettable powder, water-dispersible granules, aqueous emulsions, microemulsions, microcapsules, granules and water aqua. The cyclaniliprole-containing insecticidal composition is reasonable in components, and has a good insecticidal effect on lepidoptera, homoptera and thysanoptera pests such as cnaphalocrocis medinalis, plutella xylostella, psylla, thrips and the like; the insecticidal effect of the cyclaniliprole-containing insecticidal composition is not a simple superposition of activities of the components; compared with the conventional single preparation, the cyclaniliprole-containing insecticidal composition has the advantages of significant insecticidal effect, significant synergistic effect, reduced dosage, and good safety to crops.
Description
Technical field
The present invention relates to a kind of Pesticidal combination containing ring bromine insect amide and application thereof, composition is by the first active component
Ring bromine insect amide, the second active ingredients Biogenic source insecticides and auxiliary agent are constituted, and belong to technical field of compounded pesticide.
Background technology
Ring bromine insect amide, English name is cyclaniliprole, and chemical name is：The bromo- N- of 3- [the chloro- 6- of the bromo- 4- of 2-
[[(1- cyclopropylethyls) amine] carbonyl] phenyl] -1- (3- Chloro-2-Pyridyles) -1H- pyrazoles -5- formamides, test code number is IKI-
3106, CAS：1031756-98-5.The bisamide insecticides that Japanese Ishihara Sangyo Kaisha, Ltd. develops.With systemic activity,
Broad-spectrum insecticidal activity, has good prevention effect to insects such as diamondback moth, prodenia litura, aleyrodid, aphid, thrips, liriomyza bryoniaes.
The invention mainly relates to biogenic pesticide mainly have：AVM, emamectin-benzoate,
Multiple killing teichomycin.
AVM, is the detached natural products from edaphon, has to insect and mite class and tags and stomach toxicity work
With and have faint fumigation action, without systemic action.But it has very strong osmosis to blade, subepidermal evil can be killed
Worm, and the longevity of residure is long.Its not ovicidal.Its mechanism of action is interference nervous physiology activity, mite class into, deutonymph and insect and larva and
There is paralysis symptom after medicament contact, inertia does not take food, it is dead after 2～4 days.Because not causing insect rapid dehydration, so
Its lethal effect is slower.
Emamectin-benzoate, efficient, wide spectrum, the longevity of residure are long, and the mechanism of action hinders pest movements nerve letter
Breath is transmitted and makes body paralysis dead.Mode of action action of contace poison based on stomach toxicity, to crop without interior suction performance, but effectively oozes
Enter to apply crop epidermal tissue, thus with the longer longevity of residure.Lepidoptera pest, mite class, coleoptera and homoptera pest have pole
High activity, soil and in degradable noresidue, it is free from environmental pollution, in normal dosage ranges to beneficial insect and natural enemy, people,
Poultry safety.
Multiple killing teichomycin, can be with sustained activation target insect acetylcholine nicotine receptor, it is also possible to affect GABA acceptors.Can
To cause target plant-feed insect dead rapidly.
Applicant Jing tests find, the different ring bromine insect amide of the mechanism of action and biogenic pesticide are compounded, have
Advantages below and beneficial effect：1st, compound scheme is used, to Lepidopteras such as rice leaf roller, diamondback moth, pear sucker, thrips, together
There is notable synergistic to act on for wing mesh, Thysanoptera, significantly improve prevention effect；2nd, dosage and times for spraying, drop are reduced
Low cost accounting；3rd, overcome long-term single using the shortcoming for easily producing resistance, extend the service life of medicament.
The content of the invention
It is an object of the invention to provide a kind of component is reasonable, synergistic effect significantly, good disinsection effect, drug cost it is low,
Agricultural insecticidal composite to crop safety.
Another object of the present invention is to provide the Insecticidal combinations agent containing ring bromine insect amide and biogenic pesticide
Type.
It is still another object of the present invention to provide above-mentioned composition is in preventing and treating rice leaf roller, diamondback moth, pear sucker, thrips
Deng the application on Lepidoptera, Homoptera, Thysanoptera.
For achieving the above object, the technical scheme is that such solution：
A kind of Pesticidal combination containing ring bromine insect amide and biogenic pesticide and application thereof, it is characterised in that
（1）First active component：Ring bromine insect amide；
（2）Second active component：Biogenic pesticide AVM, emamectin-benzoate, kill mould more
One kind in element；
The weight ratio of the first active component and the second active component is 1:60～60:1, content sum is that the composition is total
The 1%～80% of weight, preferably 10%～60%.
A kind of Pesticidal combination containing ring bromine insect amide of the present invention is according to the side well known to those skilled in the art of the present technique
The preparation formulation that method can be prepared is missible oil, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, microcapsules
Agent, granule, aqua.
To missible oil, the auxiliary agent that can be used has：Emulsifying agent is selected from calcium dodecyl benzene sulfonate（Agriculture breast 500#）, Nongru-700 #,
Agriculture breast 2201, this disk -60#, emulsifying agent T-60（Common name：Anhydrous sorbitol single-hard ester acid ester APEO）、TX-10（It is logical
With name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601#, agriculture breast 600#, one or more in agriculture breast 400# etc.；Solvent is selected
From dimethylbenzene, solvent naphtha（S-150、S-180、S-200）, toluene, biodiesel, the one kind or many in methylated vegetable oil etc.
Kind；Cosolvent is selected from one or more in ethyl acetate, methyl alcohol, dimethylformamide, cyclohexanone, acetone, MEK etc.；Surely
Determine one or more of agent in triphenyl phosphite, epoxychloropropane, aceticanhydride etc..
To suspending agent, the auxiliary agent that can be used has：Dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate（Expand
Powder NNO）、TERSPERSE 2020（Huntsman Corporation of the U.S. produces, alkyl naphthalene sulfonic acid salt）In one or more；Emulsifying agent
Such as Nongru-700 #（Common name：Alkyl phenol formaldehyde resin polyoxyethylene ether）, agriculture breast 2201, this disk -60#（Common name：Sorbitan
Alcohol stearate）, Tween-60 #（Common name：Polyoxyethylene sorbitan stearate）, agriculture breast 1601#（Common name：Triphen
Ethyl -phenol polyoxyethylene polyoxypropylene block polymer）、TERSPERSE 4894（Huntsman Corporation of the U.S. produces）In
One or more；Wetting agent such as alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy base ether phosphoric acid
Ester, phenethyl phenol polyoxyethylene groups ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500
（Huntsman Corporation of the U.S. produces）One or more in；Thickener such as xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate
One or more in；One or more in preservative such as formaldehyde, benzoic acid, Sodium Benzoate；Stabilizer such as epoxy is big
One or more in soya-bean oil, epoxychloropropane, triphenyl phosphate etc.；Defoamer such as silicone defoamer；Antifreezing agent such as second
One or more in glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride；Water is deionized water.
To wettable powder, the auxiliary agent that can be used has：Dispersant such as polycarboxylate, lignosulfonates, polyoxyethylene gather
Oxypropylene group ether block copolymers, alkyl naphthalene formaldehyde condensate sulfonates, alkylphenol-polyethenoxy base ether phosphate, poly alkyl alcohol
One or more in oxygen ethene ether phosphate, alkylphenol-polyethenoxy base ether sulfonate etc.；Wetting agent such as alkyl sulfate, alkane
One or more in base sulfonate, alkylnaphthalene sulfonate etc.；Filler such as ammonium sulfate, urea, sucrose, glucose, diatomite, height
One or more in ridge soil, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay etc..
To water dispersible granules, the auxiliary agent that can be used has：Dispersant such as polycarboxylate（TERSPERSE 2700、T36、GY-
D06 etc.）, lignosulfonates, one or more in alkylnaphthalene sulfonate etc.；Wetting agent such as alkyl sulfate, alkyl sulfonic acid
One or more in salt, naphthalene sulfonate etc.；Disintegrant such as ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and its derivative
One or more in thing, bentonite etc.；Binding agent such as starch, glucose, polyvinyl alcohol, polyethylene glycol, carboxymethylcellulose calcium
One or more in sodium, sucrose etc.；Filler such as diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay
One or more in.
To aqueous emulsion, the auxiliary agent that can be used has：Emulsifying agent such as Nonyl pheno（EO=10）Ether phosphate, triphen second
Base phenol polyoxyethylene phosphonate, Nongru-700 #（Common name：Alkyl phenol formaldehyde resin polyoxyethylene ether）, agriculture breast 2201#, this
Disk -60#（Common name：Span60）, Tween-60 #（Common name：Polyoxyethylene sorbitan stearic acid
Ester）、TX-10（Common name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601（Common name：Triphenoethyl benzene phenol polyoxypropylene gathers
Oxygen ethylene block polymer）, agriculture breast 600#, one or more in agriculture breast 400# etc.；Solvent for example dimethylbenzene, toluene, cyclohexanone,
Solvent naphtha（The trade mark：S-150、S-180、S-200）One or more in；Stabilizer such as triphenyl phosphite, epoxy chloropropionate
One or more in alkane, epoxidized soybean oil etc.；Antifreezing agent such as ethylene glycol, propane diols, glycerine, urea, inorganic salts such as chlorination
One or more in sodium etc.；One or more in thickener such as xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate；It is anti-
One or more in rotten agent such as formaldehyde, benzoic acid, Sodium Benzoate, water is deionized water.
To microemulsion, the auxiliary agent that can be used has：Emulsifying agent is selected from calcium dodecyl benzene sulfonate（Agriculture breast 500#）, agriculture breast
700#, agriculture breast 2201, this disk-60#, polysorbate60-#, TX-10, agriculture breast 1601（Common name：Phenethyl phenol polyoxyethylene polyoxy
Propylene ether）, agriculture breast 600#, one or more in agriculture breast 400# etc.；Assistant for emulsifying agent is selected from methyl alcohol, isopropanol, n-butanol, second
Alcohol；Solvent is selected from cyclohexanone, 1-METHYLPYRROLIDONE, dimethylbenzene, toluene, solvent naphtha（The trade mark：S-150、S-180、S-200）Deng
In one or more；Stabilizer is selected from one or more in triphenyl phosphite, epoxychloropropane etc.；Water is deionization
Water.
To microcapsule formulations, the auxiliary agent that can be used has：Emulsifying dispersant such as Nonyl pheno（EO=10）Ether phosphate,
Triphenoethyl benzene phenol polyethenoxy ether phosphate, Nongru-700 #（Common name：Alkyl phenol formaldehyde resin polyoxyethylene ether）, agriculture breast
2201#, this disk -60#（Common name：Span60）, Tween-60 #（Common name：Polyoxyethylene sorbitan
Stearate）、TX-10（Common name：Octyl phenol polyoxyethylene（10）Ether）, agriculture breast 1601（Common name：Triphenoethyl benzene phenol polyoxy
Propylene polyoxyethylene block polymers）, agriculture breast 600#, one or more in agriculture breast 400# etc.；Antifreezing agent such as ethylene glycol, the third two
One or more in alcohol, glycerine, urea, inorganic salts such as sodium chloride；Thickener for example white carbon, polyvinyl alcohol, bentonite,
One or more in aluminium-magnesium silicate etc.；Defoamer for example silicone oil, silicone compound, C10-20 saturated fat acid compounds,
One or more in C8-10 aliphatic alcohols, hexanol, butanol, octanol etc.；Water is deionized water.
To granule, the auxiliary agent that can be used has：Carrier such as clay, kaolin, talcum, calcium carbonate, cornstarch, alumina silicate
In one or more；One or more in dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate；Wetting
One or more in agent such as alkyl sulfate, alkylsulfonate, naphthalene sulfonate；Adhesive such as polyvinyl alcohol, dextrin, polyethylene
One or more in pyrrolidones etc..
To aqua, the auxiliary agent that can be used has：Emulsifying agent such as calcium dodecyl benzene sulfonate, alkylphenol-formaldehyde resin polyoxyethylene
Ether, agriculture breast 2201#, sorbitan monostearate, sorbitan monostearate APEO, octyl phenol polyoxyethylene
（10）Ether, AEO, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, agriculture breast 600#, agriculture breast 400#, dodecane
One or more in base dimethyl benzyl ammonium chloride etc.；Water is deionized water.
Rationally, good disinsection effect, drug cost is low for instant component, and its activity and insecticidal effect are not each component activity
Simple superposition, but have significant synergistic effect, it is good to crop safety, meet the security requirement of pesticidal preparations.This
It is bright that there is significant prevention effect to the Lepidopteras such as rice leaf roller, diamondback moth, pear sucker, thrips, Homoptera, Thysanoptera.
Specific embodiment
Illustrate ring bromine insect amide with biogenic pesticide mixture to Lepidoptera, same wing below by Toxicity Determination
Whether mesh, Thysanoptera have synergistic effect.
1st, ring bromine insect amide and AVM, emamectin-benzoate, multiple killing teichomycin mixture are to cnaphalocrocis
The synergy of snout moth's larva is determined.
Synergy measure is carried out using leaf dipping method.By ring bromine insect amide active compound, AVM, Affirm (Merck Co.) benzene
Formates, multiple killing teichomycin active compound, are configured to the liquid of 5 series concentrations, standby.
Select the rice leaf roller of indoor feeding（Cnaphalocrocis medinalis）4 instar larvaes are standby.Choose
The consistent rice leaf of growth, makes suitable leaf section.Leaf section is dipped in liquid solution to be measured, taking-up after 10s is dried and is placed in
In culture dish containing 1% water agar, test worm is accessed.Often process 4 repetitions, often repeatedly 10, and set the process without medicament and make
For control.
Test worm after process is placed in into temperature is（25±1）DEG C, humidity be 60%～80%, periodicity of illumination be L:D=（16:8）
Raise under h and observe.48h investigation test worm death condition, records total borer population and dead borer population after process.According to investigation result,
Calculate the death rate of each process.Virulence regression equation, the lethal concentration of 50, coefficient correlation etc. are obtained, and is obtained altogether with the abundant methods of Sun Yun
Malicious coefficient（CTC values）.
The theoretical toxicity index TTI=Σ percentage of the pharmaceutically active ingredient (certain medicine ATI × in mixture)
The Pesticidal combination of the insect amide of bromine containing ring that the present invention is provided is evaluated to rice leaf roller using co-toxicity coefficient method
Synergy, regression equation is sought with the logarithm and medicament of drug concentration to the preventive effect niqueMin of rice leaf roller, and is calculated
The LC of medicament pair50Value, then tries to achieve co-toxicity coefficient.Synergy of the compound drug to rice leaf roller is evaluated with co-toxicity coefficient,
Co-toxicity coefficient>120 are expressed as synergistic effect, and co-toxicity coefficient is expressed as summation action, co-toxicity coefficient between 80～120<80 tables
It is shown as antagonism.
Table 1-1 ring bromine insect amides and toxicity test result of the AVM mixture to rice leaf roller
Table 1-2 ring bromine insect amides and toxicity test result of the emamectin-benzoate mixture to rice leaf roller
Table 1-3 ring bromine insect amides and toxicity test result of the multiple killing teichomycin mixture to rice leaf roller
Toxicity Determination result shows：Ring bromine insect amide and biogenic pesticide AVM, methylamino Avermectin
Plain benzoate, multiple killing teichomycin press 1:60～60:1 uses with, there is higher virulence to rice leaf roller, shows as synergistic effect.
2nd, the joint toxicity measuring of ring bromine insect amide and AVM mixture to pear sucker.
Toxicity Determination is carried out using medicine embrane method.By ring bromine insect amide active compound, the former medicine of AVM, being configured to 5 is
The liquid of row concentration, it is standby.
The pear sucker for selecting indoor culture, age consistent（Psylla chinensis）Nymph.Prepare the culture of diameter 9cm
Ware, the qualitative filter paper for taking diameter 9cm is placed in ware bottom, and the liquid 1mL for having configured is drawn respectively, is equably added dropwise on filter paper, treats
Medicine film is made in solvent volatilization, places standby after 24h.
The consistent test worm 10 of physiological status is chosen with writing brush, immigration is lined with the culture dish of filter paper film, treats it in filter paper
Creep in medicine film after 1h, test worm is transferred in the clean culture dish for be placed with clean feeds and is raised.Often process and be repeated 4 times, with clear
Water process is control.Test worm after process is placed in into temperature is（25±1）DEG C, humidity be 60%～80%, periodicity of illumination be L:D=
（16:8）Raise under h and observe.
Number of dead and live insects is checked after 48h, test of the control group death rate less than 20% is efficiency test.
According to investigation result, the death rate of each process is calculated.Obtain virulence regression equation, the lethal concentration of 50, coefficient correlation
Deng, and obtain co-toxicity coefficient with the abundant methods of Sun Yun（CTC values）.
The theoretical toxicity index TTI=Σ percentage of the pharmaceutically active ingredient (certain medicine ATI × in mixture)
Joint of the Pesticidal combination of the insect amide of bromine containing ring that the present invention is provided to pear sucker is evaluated using co-toxicity coefficient method
Effect, regression equation is sought with the logarithm and medicament of drug concentration to the preventive effect niqueMin of pear sucker, and calculates medicament pair
LC50Value, then tries to achieve co-toxicity coefficient.Synergy of the compound drug to pear sucker, co-toxicity coefficient are evaluated with co-toxicity coefficient>120
Synergistic effect is expressed as, co-toxicity coefficient is expressed as summation action, co-toxicity coefficient between 80～120<80 are expressed as antagonism.
The ring bromine insect amide of table 2 and toxicity test result of the AVM mixture to pear sucker
Toxicity Determination result shows：Ring bromine insect amide presses 1 with AVM:60～60:1 uses with, has to pear sucker
Higher virulence, shows as synergistic effect.
3rd, the joint toxicity measuring of ring bromine insect amide and multiple killing teichomycin mixture to eggplant thrips.
Toxicity Determination is carried out using infusion process.By ring bromine insect amide active compound, multiple killing teichomycin active compound, being configured to 5 is
The liquid of row concentration, it is standby.
The palm thrips for selecting indoor culture, age consistent（Thrips palmi）, test worm is moved into for 20 with pest sucking device
Volume is in the leaching worm box of 50mL, medication immersion worm 10s blots unnecessary liquid in leaching worm box with filter paper.It is put into the section melon of long 3cm
Leaf, sealed membrane will soak the sealing of worm box, after be placed in temperature and be 26 DEG C, cultivate in the illumination box of humidity 70%.Often process and repeat 4
It is secondary, worm 20 is often repeatedly soaked, control is processed as with clear water.Number of dead and live insects is checked after 24h, the control group death rate is less than 20%
Test as efficiency test.
According to investigation result, the death rate of each process is calculated.Obtain virulence regression equation, the lethal concentration of 50, coefficient correlation
Deng, and obtain co-toxicity coefficient with the abundant methods of Sun Yun（CTC values）.
The theoretical toxicity index TTI=Σ percentage of the pharmaceutically active ingredient (certain medicine ATI × in mixture)
Connection of the Pesticidal combination of the insect amide of bromine containing ring that the present invention is provided to eggplant thrips is evaluated using co-toxicity coefficient method
Cooperation is used, and regression equation is sought to the preventive effect niqueMin of eggplant thrips with the logarithm and medicament of drug concentration, and calculates medicament
To LC50Value, then tries to achieve co-toxicity coefficient.Synergy of the compound drug to eggplant thrips is evaluated with co-toxicity coefficient, altogether poison system
Number>120 are expressed as synergistic effect, and co-toxicity coefficient is expressed as summation action, co-toxicity coefficient between 80～120<80 be expressed as it is short of money
Anti- effect.
The ring bromine insect amide of table 3 and toxicity test result of the emamectin-benzoate mixture to eggplant thrips
Toxicity Determination result shows：Ring bromine insect amide presses 1 with emamectin-benzoate:60～60:1 mixes
With, there is higher virulence to eggplant thrips, show as synergistic effect.
Present invention is described further with reference to embodiment.
Example of formulations 1
Weigh 300 grams of ring bromine insect amides, 50 grams of AVMs, 60 grams of agriculture breasts 400#, 40 grams of agriculture breasts 600#, 250 grams of diformazans
Base formamide, dimethylbenzene adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and stirring and dissolving is obtained afterwards completely 35% ring bromine worm acyl
Amine abamectin emulsifiable concentrate.
Example of formulations 2
Weigh 200 grams of ring bromine insect amides, 80 grams of emamectin-benzoates, 30 grams of agriculture breasts 1601#, 40 grams of agriculture breasts
500#, 40 grams of TX-10,120 grams of ethyl acetate, biodiesel adds to 1000 gram weight parts.Above-mentioned raw materials are blended, stirring and dissolving
Prepared 28% ring bromine insect amide emamectin-benzoate missible oil after completely.
Example of formulations 3
Weigh 40 grams of ring bromine insect amides, 120 grams of multiple killing teichomycins, 60 grams of agriculture breasts 1601#, 30 grams of agriculture breasts 500#, 40 grams of TX-
10th, 150 grams of ethyl acetate, biodiesel adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and stirring and dissolving is obtained afterwards completely
16% ring bromine insect amide multiple killing teichomycin missible oil.
Example of formulations 4
Weigh 100 grams of ring bromine insect amides, 100 grams of AVMs, 40 grams of agriculture breasts, 2201,40 grams of phenethyl phenol polyoxyethylene groups
Ether phosphate, 50 grams of sodium lignin sulfonates, 30 grams of bentonites, 20 grams of xanthans, 40 grams of urea, 12 grams of benzoic acid, 10 grams it is organic
Silicon defoaming agent（Trade name：S-29 Nanjing "four news" (new ideas applied chemistry product company produces）, deionized water adds to 1000 gram weight parts.It is above-mentioned
Raw material is blended, high speed shear dispersion 30min, is suspended with 20% ring bromine insect amide AVM is obtained after sand mill sand milling
Agent.
Example of formulations 5
Weigh 150 grams of ring bromine insect amides, 100 grams of emamectin-benzoates, 50 grams of TERSPERSE2020（It is beautiful
Huntsman Corporation of state produces）, 30 grams of agriculture breast 1601#, 20 grams of sodium naphthalene sulfonates, 10 grams of aluminium-magnesium silicates, 12 grams of aluminium-magnesium silicates, 14 grams of second
Glycol, 12 grams of benzoic acid, 10 grams of organic silicon defoamers（Trade name：S-29 Nanjing "four news" (new ideas applied chemistry product company produces）, 12 grams
Epoxychloropropane, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, high speed shear dispersion 30min, use sand mill
25% ring bromine insect amide emamectin benzoate suspending agent is made after sand milling.
Example of formulations 6
Weigh 120 grams of ring bromine insect amides, 60 grams of multiple killing teichomycins, 50 grams of agriculture breasts 1601#, 40 grams of TERSPERSE2020（The U.S.
Huntsman Corporation produces）, 15 grams of sodium naphthalene sulfonates, 20 grams of aluminium-magnesium silicates, 10 grams of aluminium-magnesium silicates, 15 grams of ethylene glycol, 10 grams of benzoic acid,
5 grams of organic silicon defoamer s-29（Nanjing "four news" (new ideas applied chemistry product company produces）, 10 grams of epoxychloropropane, deionized water adds to
1000 gram weight parts.Above-mentioned raw materials are blended, high speed shear dispersion 30min, with prepared 18% ring bromine worm acyl after sand mill sand milling
Amine multiple killing teichomycin suspending agent.
Example of formulations 7
Weigh 240 grams of ring bromine insect amides, 160 grams of AVMs, 40 grams of alkylphenol-polyethenoxy base ether sulfonic acid calcium, 50 grams of alkane
Base naphthalenesulfonate formaldehyde condensation compound, 40 grams of Negels, potter's clay is filled up to 1000 grams of weight portion.Above-mentioned raw materials Jing is mixed
Conjunction, ultra micro air-flow crushing, hybrid technique step are prepared into 40% ring bromine insect amide AVM wettable powder.
Example of formulations 8
Weigh 120 grams of ring bromine insect amides, 180 grams of emamectin-benzoates, 30 grams of alkyl naphthalene formaldehyde condensation products
Sodium sulfonate, 50 grams of calcium lignosulfonates, 45 grams of sodium alkyl sulfonates, talcum powder is filled up to 1000 grams of weight portion.Above-mentioned raw materials Jing
Mixing, ultra micro air-flow crushing, hybrid technique step are prepared into 30% ring bromine insect amide emamectin-benzoate can
WP.
Example of formulations 9
Weigh 100 grams of ring bromine insect amides, 150 grams of multiple killing teichomycins, 50 grams of polycarboxylic acids sodium, 40 grams of alkyl naphthalene formaldehyde condensation product sulphurs
Sour sodium, 28 grams of lauryl sodium sulfate, attapulgite is filled up to 1000 grams of weight portion.Above-mentioned raw materials are blended, ultra micro air-flow
Crush, hybrid technique step is prepared into 25% ring bromine insect amide multiple killing teichomycin wettable powder.
Example of formulations 10
Weigh 400 grams of ring bromine insect amides, 60 grams of AVMs, 40 grams of sodium lignin sulfonates, 50 grams of GY-D06（Polycarboxylic acids
Salt, Huntsman Corporation of the U.S. produces）, 40 grams of lauryl sodium sulfate, 35 grams of alkylsulfonate sodium, talcum powder adds to 1000 grammes per square metres
Amount part.Above-mentioned raw materials Jing routinely produces that the method for water dispersible granules mixes, ultra micro air-flow crushing, mixing, granulation step are produced
46% ring bromine insect amide AVM water dispersible granules.
Example of formulations 11
Weigh 80 grams of ring bromine insect amides, 260 grams of emamectin-benzoates, 40 grams of sodium lignin sulfonates, 20 grams
GY-D06,30 grams of Nekal BXs（Nekal）, 25 grams of K-12（Lauryl sodium sulfate）, fine particle calcium carbonate adds to 1000 grammes per square metres
Amount part.Above-mentioned raw materials Jing routinely produces that the method for water dispersible granules mixes, ultra micro air-flow crushing, mixing, granulation step are produced
34% ring bromine insect amide emamectin-benzoate water dispersible granules.
Example of formulations 12
Weigh 200 grams of ring bromine insect amides, 160 grams of multiple killing teichomycins, 30 grams of sodium lignin sulfonates, 30 grams of GY-D06,25 carats
Open powder BX（Nekal）, 20 grams of K-12（Lauryl sodium sulfate）, fine particle calcium carbonate adds to 1000 gram weight parts.Above-mentioned raw materials
Jing routinely produces that the method for water dispersible granules mixes, ultra micro air-flow crushing, mixing, granulation step produce 36% ring bromine worm acyl
Amine spinosad water dispersible granule.
Example of formulations 13
Weigh 120 grams of ring bromine insect amides, 80 grams of AVMs, 40 grams of triphenoethyl benzene phenol polyethenoxy ether phosphates, 30
Ke Si disk -60#, 20 grams of Tween-60 #, 40 grams of Nongru-700 #, 50 grams of glycerine, 70 grams of solvent naphtha S-200,30 grams of toluene, 4 grams it is swollen
Profit soil, 3 grams of Sodium Benzoates, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and high speed shearing emulsification is obtained 20%
Ring bromine insect amide abamectin aqueous emulsion.
Example of formulations 14
Weigh 300 grams of ring bromine insect amides, 40 grams of emamectin-benzoates, 15 grams of Nongru-700 #, 40 grams of nonyls
Phenol polyethenoxy（EO=10）Ether phosphate, 30 grams of agriculture breasts, 1601,40 grams of Tween-60 #, 20 grams of epoxidized soybean oils, 30 grams of glycerine,
40 grams of cyclohexanone, 5 grams of bentonites, 5 grams of Sodium Benzoates, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, at a high speed
Emulsification pretreatment is obtained 34% ring bromine insect amide emamectin-benzoate aqueous emulsion.
Example of formulations 15
Weigh 220 grams of ring bromine insect amides, 60 grams of multiple killing teichomycins, 50 grams of Nongru-700 #, 30 grams of Nonyl phenos（EO=
10）Ether phosphate, 30 grams of agriculture breasts, 1601,20 grams of Tween-60 #, 20 grams of epoxidized soybean oils, 20 grams of glycerine, 30 grams of cyclohexanone, 3 grams
Bentonite, 4 grams of Sodium Benzoates, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and high speed shearing emulsification is obtained
28% ring bromine insect amide spinosad aqueous emulsion.
Example of formulations 16
Weigh 80 grams of ring bromine insect amides, 60 grams of AVMs, 60 grams of agriculture breasts, 1601,40 grams of agriculture breasts 400#, 50 grams of toluene,
130 grams of cyclohexanone, 50 grams of isopropanols, 10 grams of triphenyl phosphites, Jing dissolvings are complete and are well mixed, and deionized water adds to 1000
Gram weight part, is obtained 14% ring bromine insect amide avermectin micro-emulsion after stirring.
Example of formulations 17
Weigh 70 grams of ring bromine insect amides, 50 grams of emamectin-benzoates, 60 grams of agriculture breasts, 2201,50 grams of this disks-
60#, 50 grams of 1-METHYLPYRROLIDONEs, 120 grams of cyclohexanone, 40 grams of n-butanols, 30 grams of epoxychloropropane, Jing dissolvings are complete and mix
Uniformly, deionized water adds to 1000 gram weight parts, and 12% ring bromine insect amide emamectin-benzoate is obtained after stirring
Microemulsion.
Example of formulations 18
Weigh 40 grams of ring bromine insect amides, 30 grams of multiple killing teichomycins, 30 grams of polysorbate60-#, 40 grams of agriculture breasts, 2201,25 grams of this disks-
60#, 60 grams of 1-METHYLPYRROLIDONEs, 130 grams of cyclohexanone, 50 grams of n-butanols, 20 grams of epoxychloropropane, Jing dissolvings are complete and mix
Uniformly, deionized water adds to 1000 gram weight parts, and 7% ring bromine insect amide spinosad microemulsion is obtained after stirring.
Example of formulations 19
Weigh 20 grams of ring bromine insect amides, 40 grams of AVMs, 40 grams of glycerine, 50 grams of agriculture breasts 2201#, 30 grams of bentonites, 30
Gram octanol, deionized water is filled up to 1000 grams of weight portion.6% ring bromine is obtained after the blended stirring of above-mentioned raw materials, polymerisation
Insect amide avermectin microcapsule agent.
Example of formulations 20
Weigh 60 grams of ring bromine insect amides, 20 grams of emamectin-benzoates, 50 grams of ethylene glycol, 50 grams of tweens-
60#, 25 grams of aluminium-magnesium silicates, 30 grams of silicone oil, deionized water is filled up to 1000 grams of weight portion.It is the blended stirring of above-mentioned raw materials, poly-
Close and be obtained after reaction 8% ring bromine insect amide emamectin-benzoate microcapsule formulations.
Example of formulations 21
Weigh 20 grams of ring bromine insect amides, 30 grams of multiple killing teichomycins, 50 grams of propane diols, 60 grams of agriculture breasts 600#, 20 grams of white carbons, 25
Gram butanol, deionized water is filled up to 1000 grams of weight portion.5% ring bromine is obtained after the blended stirring of above-mentioned raw materials, polymerisation
Insect amide multiple killing teichomycin microcapsule formulations.
Example of formulations 22
Weigh 50 grams of ring bromine insect amides, 10 grams of AVMs, 60 grams of Negels, 30 grams of sodium alkyl sulfonates, 30 grams
Polyvinylpyrrolidone, talcum powder adds to 1000 gram weight parts.Above-mentioned raw materials are well mixed in mixed cylinder, through extruding, making
Grain, drying, and screened step is obtained 6% ring bromine insect amide Abamectin.
Example of formulations 23
Weigh 30 grams of ring bromine insect amides, 20 grams of emamectin-benzoates, 40 grams of polycarboxylic acids sodium, 30 grams of naphthalene sulfonic acids
Sodium, 30 grams of polyvinyl alcohol, calcium carbonate adds to 1000 gram weight parts.Above-mentioned raw materials are well mixed in mixed cylinder, through extruding, making
Grain, drying, and screened step is obtained 5% ring bromine insect amide emamectin-benzoate granule.
Example of formulations 24
Weigh 10 grams of ring bromine insect amides, 20 grams of multiple killing teichomycins, 40 grams of polycarboxylic acids sodium, 40 grams of sodium naphthalene sulfonates, 35 grams of polyethylene
Alcohol, calcium carbonate adds to 1000 gram weight parts.Above-mentioned raw materials are well mixed in mixed cylinder, through extruding, granulation, are dried, and Jing
Screening step is obtained 3% ring bromine insect amide multiple killing teichomycin granule.
Example of formulations 25
80 grams of ring bromine insect amides, 40 grams of AVMs, 60 grams of agriculture breasts 2201# are weighed, deionized water adds to 1000 gram weights
Part.Above-mentioned raw materials are blended, and stirring and dissolving is obtained afterwards completely 12% ring bromine insect amide AVM aqua.
Example of formulations 26
Weigh 60 grams of ring bromine insect amides, 40 grams of emamectin-benzoates, 50 grams of agriculture breasts 2201#, 50 grams of agriculture breasts
700#, deionized water adds to 1000 gram weight parts.Above-mentioned raw materials are blended, and stirring and dissolving is obtained afterwards completely 10% ring bromine worm acyl
Amine emamectin-benzoate aqua.
Example of formulations 27
40 grams of ring bromine insect amides, 20 grams of multiple killing teichomycins, 50 grams of sorbitan monostearates are weighed, deionized water is added to
1000 gram weight parts.Above-mentioned raw materials are blended, and stirring and dissolving is obtained afterwards completely 6% ring bromine insect amide multiple killing teichomycin aqua.
Biological Examples 1：Preventing and treating rice leaf roller field control effectiveness test.
Inventor has carried out example of formulations 1 in Junichiro Koizumi village of the county of xiangtan, hunan province in 2016（35% ring bromine insect amide AVM hereinafter
Rhzomorph missible oil）, example of formulations 5（25% ring bromine insect amide emamectin benzoate suspending agent）, example of formulations
9（25% ring bromine insect amide multiple killing teichomycin wettable powder）Preventing and treating rice leaf roller field control effectiveness test, demonstrates the medicament pair
The prevention effect of rice leaf roller and the security to paddy rice.
Trial crops are paddy rice, and controlling object is rice leaf roller, in the spraying of the instar larvae occurance peak of rice leaf roller 2.
Experimental plot physical features is flat, and soil is sandy loam, and middle fertility, irrigation and drainage are facilitated.Test medicine and dosage refer to table 4.Separately set blank
Compare, often 4 repetitions of process, every ㎡ of cell 40, totally 32 cells, the random district's groups arrangement of cell.
25 clumps of rice are investigated altogether per 5 points of samplings of cell.Statistics leaf roll rate, compares with check plot leaf roll rate, calculates relative control effect,
Investigating in leaf roll simultaneously has worm rate.
Insect population investigation is carried out before dispenser, when blank it is aggrieved substantially, or the present age to cause harm and carry out drug effect tune after sizing
Look into.Drug effect is calculated：
Table 4 prevents and treats rice leaf roller field control effectiveness test result
Field control effectiveness test result shows, complex preparation preventive effect has exceeded 90%, the preventive effect of single dose is respectively 72.1%,
66.8%th, 73.5% and 66.9%, illustrate ring bromine insect amide and AVM, emamectin-benzoate, multiple killing teichomycin point
After not in different ratio compoundings, the preventive effect of complex preparation is obvious apparently higher than the preventive effect of two single doses, synergistic effect.
Security survey, observes during test, and all reagent agents occur to paddy growth safety without poisoning phenomenon.
Biological Examples 2：Preventing and treating eggplant thrips field control effectiveness test.
Inventor has carried out example of formulations 10 in 2016 in Hainan Province Sanya precipice city（46% ring bromine insect amide
AVM water dispersible granules）, example of formulations 14（34% ring bromine insect amide emamectin-benzoate water and milk
Agent）, example of formulations 18（7% ring bromine insect amide spinosad microemulsion）Preventing and treating eggplant thrips field control effectiveness test, demonstrates
Security of the medicament to the prevention effect of eggplant thrips and to saving melon.
Trial crops are section melon, and controlling object is eggplant thrips, in the spraying of eggplant thrips 2 age nymph occurance peak.Test
Field gesture is flat, and soil is sandy loam, and middle fertility, irrigation and drainage are facilitated.Test medicine and dosage refer to table 5.Blank is separately set,
4 repetitions are often processed, often the ㎡ of cell 30, totally 32 cells, the random district's groups arrangement of cell.
Fix in section melon middle and upper part per cell and choose 20 leaves, insect population investigation is carried out before dispenser, 5 days and 10 after dispenser
Its investigation residual borer population living.Calculate larval mortality and prevention effect.
CK0：Borer population living before blank district dispenser, unit is head；
CK1：Borer population living after blank district dispenser, unit is head；
PT0：Borer population living before chemicals treatment district dispenser, unit is head；
PT1：Borer population living after chemicals treatment district dispenser, unit is head.
Table 5 prevents and treats eggplant thrips field control effectiveness test result
Field control effectiveness test result shows, preventive effect of the complex preparation after medicine after 5 days and 10 days has exceeded 90%, and two
The preventive effect of individual single dose is respectively less than 70%, illustrates ring bromine insect amide and AVM, emamectin-benzoate, kills mould more
Element is obvious apparently higher than the preventive effect of two single doses, synergistic effect in the preventive effect after different ratio compoundings respectively.
Security survey, observes during test, and all reagent agents occur to saving melon growth safety without poisoning phenomenon.
Example of formulations 19, example of formulations 23 and example of formulations 27, preventing and treating pear sucker, diamondback moth field test results
Show, 10 days preventive effects reach more than 90% after medicine, hence it is evident that better than the preventive effect of each single dose single dose, synergistic effect is obvious.
From above example, ring bromine insect amide and biogenic pesticide AVM, Affirm (Merck Co.)
Benzoate, multiple killing teichomycin are 1 according to weight ratio:60～60:1 is compounded, can be made into missible oil, suspending agent, wettable powder,
Water dispersible granules, aqueous emulsion, microemulsion, microcapsule formulations, granule, aqua, to rice leaf roller, diamondback moth, pear sucker, thrips
Have a significant prevention effect Deng Lepidoptera, Homoptera, Thysanoptera, synergistic effect substantially, reduce dosage and medication into
This, and be the same Lepidoptera of preventing and treating, Homoptera, the favourable agents of Thysanoptera to crop safety, therefore have extensive on producing
Application prospect.
In sum, composition of the invention is that, using two kinds of active components compound scheme, its activity and insecticidal effect are not
It is the simple superposition of each component activity, compared with existing unitary agent, in addition to obvious insecticidal effect, and has significantly
Synergistic effect, cost accounting reduce, to crop safety, meet the security requirement of pesticidal preparations.
Claims (5)
1. a kind of Pesticidal combination containing ring bromine insect amide, it is characterised in that effective active composition is by the first active component ring
Bromine insect amide and the second active ingredients Biogenic source insecticides AVM, emamectin-benzoate, multiple killing teichomycin
In a kind of composition, the first active component is 1 with the weight ratio of the second active component:60～60:1, content sum is described group
The 1%～80% of compound gross weight.
2. according to claim 1 containing the Pesticidal combination of ring bromine insect amide, it is characterised in that the first active component and
Two active component weight ratios are 1:30～30:1, content sum is the 10%～60% of the composition total weight.
3. according to claim 1 containing the Pesticidal combination of ring bromine insect amide, it is characterised in that the combination dosage form is
Missible oil, suspending agent, wettable powder, water dispersible granules, aqueous emulsion, microemulsion, microcapsule formulations, granule, aqua.
4. the Pesticidal combination according to claim 1 containing ring bromine insect amide is in preventing and treating Lepidoptera, Homoptera, Thysanoptera evil
Purposes on worm.
5. the Pesticidal combination according to claim 5 containing ring bromine insect amide is in preventing and treating rice leaf roller, diamondback moth, pear wood
Purposes on lice, thrips.
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| US10897902B2 (en) * | 2016-12-27 | 2021-01-26 | Ishihara Sangyo Kaisha, Ltd. | Pesticidal solid composition containing cyclaniliprole or its salt |
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