CN106592233A - Preparation process for a fiber - Google Patents
Preparation process for a fiber Download PDFInfo
- Publication number
- CN106592233A CN106592233A CN201611065392.5A CN201611065392A CN106592233A CN 106592233 A CN106592233 A CN 106592233A CN 201611065392 A CN201611065392 A CN 201611065392A CN 106592233 A CN106592233 A CN 106592233A
- Authority
- CN
- China
- Prior art keywords
- parts
- fiber
- finishing agent
- antibacterial finishing
- particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000835 fiber Substances 0.000 title claims abstract description 90
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 47
- 239000002105 nanoparticle Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011787 zinc oxide Substances 0.000 claims abstract description 11
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010457 zeolite Substances 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 238000005516 engineering process Methods 0.000 claims description 19
- LSBDFXRDZJMBSC-UHFFFAOYSA-N 2-phenylacetamide Chemical compound NC(=O)CC1=CC=CC=C1 LSBDFXRDZJMBSC-UHFFFAOYSA-N 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 241000737241 Cocos Species 0.000 claims description 10
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 10
- 229920002494 Zein Polymers 0.000 claims description 10
- 230000003115 biocidal effect Effects 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 235000013336 milk Nutrition 0.000 claims description 10
- 239000008267 milk Substances 0.000 claims description 10
- 210000004080 milk Anatomy 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 10
- 239000004332 silver Substances 0.000 claims description 10
- 239000005019 zein Substances 0.000 claims description 10
- 229940093612 zein Drugs 0.000 claims description 10
- 235000003276 Apios tuberosa Nutrition 0.000 claims description 9
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 9
- 235000010744 Arachis villosulicarpa Nutrition 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 244000105624 Arachis hypogaea Species 0.000 claims description 8
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000004879 dioscorea Nutrition 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- -1 Diol ester Chemical class 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000004902 Softening Agent Substances 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 229960001296 zinc oxide Drugs 0.000 claims 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 2
- 244000133018 Panax trifolius Species 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000004753 textile Substances 0.000 abstract description 7
- 239000000395 magnesium oxide Substances 0.000 abstract description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract description 2
- DEQUKPCANKRTPZ-UHFFFAOYSA-N (2,3-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1O DEQUKPCANKRTPZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000001153 anti-wrinkle effect Effects 0.000 abstract 1
- DKLYDESVXZKCFI-UHFFFAOYSA-N n,n-diphenylacetamide Chemical compound C=1C=CC=CC=1N(C(=O)C)C1=CC=CC=C1 DKLYDESVXZKCFI-UHFFFAOYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 108090000623 proteins and genes Proteins 0.000 description 7
- 241000255925 Diptera Species 0.000 description 6
- 238000001514 detection method Methods 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 230000000843 anti-fungal effect Effects 0.000 description 5
- 229940121375 antifungal agent Drugs 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 230000004224 protection Effects 0.000 description 5
- 230000006750 UV protection Effects 0.000 description 4
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- 241000144210 Culex pipiens pallens Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000003187 abdominal effect Effects 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 230000001846 repelling effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 208000025865 Ulcer Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- JSLMNNPQKHONFW-UHFFFAOYSA-N benzene naphthalene-1-carboxylic acid Chemical compound C1(=CC=CC2=CC=CC=C12)C(=O)O.C1=CC=CC=C1 JSLMNNPQKHONFW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000035617 depilation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 231100000397 ulcer Toxicity 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a preparation process for a fiber, belonging to the field of functional textiles. The preparation process employs the following antibacterial finishing agents by weight: 3 to 8 parts of silica nanoparticles, 10 to 15 parts of zinc oxide nanoparticles, 7 to 13 parts of magnesium oxide nanoparticles, 9 to 19 parts of nanosilver, 2 to 8 parts of zeolite, 11 to 25 parts of 2,3-dihydroxybenzophenone and 15 to 27 parts of N,N-diphenylacetamide. The fiber prepared by the preparation process is comfortable, antibacterial, mosquito-repelling, damp-guiding, perspiration-promoting and warm-keeping and also has good flame resistance, high anti-wrinkle elasticity and high breaking strength.
Description
Technical field
The present invention relates to function textile field, and in particular to fiber reparation technology.
Background technology
In recent years, people require more and more higher to the comfortableness of garment material, health, safety and feature of environmental protection etc., right
The functional requirement of safe and efficient antibacterial dress ornament is more and more；In life, people inevitably touch various thin
The microorganisms such as bacterium, funguses, these microorganisms can be bred rapidly under suitable external condition, and are propagated by modes such as contacts
Disease, affects healthy and normal work, the studying and living of people.Fiber belongs to porous material, after superposition braiding
The polylayer forest in countless spaces can be formed again, therefore fabric is easier to adsorb mushroom.Antibiotic finish is exactly have fabric to suppress bacterium
The function of class growth, maintains the clothing living environment of health, it is ensured that health.The application of antibacterial originates from second world
During Great War, German army greatly reduced the bacterium infection of the wounded due to wearing antibacterial military uniform at that time.In the sixties in last century, people
Antibacterial fabric is produced using organic antibacterial agent mostly；After inorganic antiseptic is succeeded in developing within 1984, antibiotic finish is obtained
Fast development, makes antibacterial be applied not only to fiber and textile, is also used in the products such as plastics, construction material.At present, Japan exists
Study in terms of antibacterial deodourizing and enliven the most, technological precedence, product have been expanded to fields such as gym suit, carpet, medical supplies.In recent years
Come, the emphasis of antibacterial research is from protecting textile to be transferred to environmental protection from bacteria attack and make user from antibacterial
Invasion and attack.Into 21 century, as the arrival of aging society, bed old man and the person of recuperating that is in gradually increase, the old of decubital ulcer is prevented
The demand of people's nursing materialss is also in increased trend.Due to the Concept Change based on from the society based on production to life, exploitation
Research be conducive to health,
Be conducive to the product of earth environment, therefore antibiotic finish is increasingly subject to the attention of people, at present, in clothes basic training
Can it is constant on the basis of, people constantly research and develop the new material of clothes, using appropriate technique by various effects of different materials
It is added in dress material, increased the feature of clothes.Clothes also has opposing ultraviolet radiation in addition to warming effect, kills
The effects such as bacterium deodorization, anion releasing and infrared emitting.
But the comparison of ingredients of anti-biotic material addition at present is single, the function having is also relatively simple, it is impossible to meet actual
Needs.Chinese patent literature CN103255538 A discloses a kind of UV resistance antibiotic facing material and its preparation technology, the prior art
Obtained fabric lining breathability while with anti-ultraviolet is improved, while the effect with antibacterial anophelifuge.So
In wetness guiding perspiration discharging performance, endurance quality and wrinkle resistance are all not satisfactory for which.
The content of the invention
Therefore, the technical problem to be solved in the present invention is to overcome the fabric lining in prior art obtained by reparation technology
In wetness guiding perspiration discharging performance, all not satisfactory defect of synthesis, fire resistance and wrinkle resistance, so as to provide a kind of fiber
Reparation technology.
For this purpose, the present invention provides following technical scheme：
A kind of reparation technology of fiber, using the antibacterial finishing agent with following weight：Silica dioxide nano particle
Sub- 3-8 parts；Zinc oxide nano-particle 10-15 parts；Bitter earth nano particle 7-13 parts；Nanometer silver 9-19 parts；Zeolite 2-8 parts；2,
3- dihydroxy benaophenonel 11-25 parts；N, N- bis- and phenyl acetamide 15-27 parts.
The antibacterial finishing agent is the titanium dioxide nano-particle 5-7 parts for including following weight portion；Zinc oxide nano-particle
12-14 parts；Bitter earth nano particle 9-11 parts；Nanometer silver 10-16 parts；Zeolite 4-6 parts；2,3- dihydroxy benaophenonel 15-20
Part；N, N- bis- and phenyl acetamide 19-23 parts.
The antibacterial finishing agent is 6 parts of Nano particles of silicon dioxide for including following weight portion；Zinc oxide nano-particle 13
Part；10 parts of bitter earth nano particle；13 parts of nanometer silver；5 parts of zeolite；17 parts of 2,3- dihydroxy benaophenonels；N, N- bis- and benzene
20 parts of acetamide.
The Nano particles of silicon dioxide, zinc oxide nano-particle and bitter earth nano particle, the particle diameter of nanometer silver are equal
For 10-30nm.
The antibacterial finishing agent elder generation and polyethylene terephthalate by weight 1:9 are configured to antibacterial finishing agent mother
Grain, then exercise use.
The antibacterial finishing agent master batch is prepared as follows：Antibacterial finishing agent each component is taken in proportion, and with poly- to benzene
Naphthalate, blending are extruded with screw extruder, pelletizing, and antibacterial matrices are obtained, and standby, wherein blending temperature is
250-270 DEG C, screw rod rotary speed is 100-200rpm.
Described reparation technology, comprises the steps：
(1) by pearl fiber；Milk fibre；Zein fibers；Ground nut fiber；Modal fibre；Coconut palm Carbon fibe；
Folium Camelliae sinensis fibre antibacterial finishing agent adds dispersant, binding agent, softening agent at 40-45 DEG C, adds 100-120 part water, mixing to stir
Mix uniform, then dry in the sun molding；
(2) said mixture is made into functional yams lines through blowing, opener, drafting, rove, spun yarn；
(3) then temperature control rinses half an hour using clear water at 42-44 DEG C；
(4) antibiotic finish master batch is added to be dipped through the functional yams lines 30-70 minutes that step (3) was processed, then
Bake at 70-80 DEG C again, last heat treatment.
Each component weight is：Pearl fiber 10-25 parts；Milk fibre 11-27 parts；Zein fibers 5-15
Part；Ground nut fiber 7-16 parts；Modal fibre 8-17 parts；Coconut palm Carbon fibe 12-33 parts；Folium Camelliae sinensis 8-21 part fibers；Antibacterial is whole
Reason agent 10-19 parts.
Each component weight is：Pearl fiber 15-20 parts；Milk fibre 17-23 parts；Zein fibers 7-10
Part；Ground nut fiber 10-13 parts；Modal fibre 10-15 parts；Coconut palm Carbon fibe 20-30 parts；Folium Camelliae sinensis fiber 11-18 parts；Antibacterial
Finishing agent 13-17 parts.
Each component weight is：17 parts of pearl fiber；20 parts of milk fibre；9 parts of Zein fibers；Semen arachidis hypogaeae protein
11 parts of fiber；13 parts of Modal fibre；25 parts of coconut palm Carbon fibe；15 parts of Folium Camelliae sinensis fiber；15 parts of antibacterial finishing agent.
Technical solution of the present invention, has the advantage that：
1. the fiber each group distribution ratio that the present invention is provided is scientific and reasonable, macromolecular polysaccharide, protein in each fibre composition,
Metal or non pinetallic nano particle, zeolite and macromolecule or small molecular organic compounds in aminoacid and antibacterial finishing agent
Between Synergistic, and macromole conjugate is formed by conjugated effect, so that the novel antibacterial fabric that the present invention is provided
While with the function such as comfortable, antibacterial, anophelifuge, wetness guiding perspiration discharging, warming, also with good anti-flammability and high antifungal gene bullet
Property and high Resisting fractre strength.
2. the present invention provide fiber environmental pollution is little, low cost.
3. the preparation method of the fiber that the present invention is provided is simple, convenient, easy to operate.
Specific embodiment
It is to preferably further understand the present invention to provide following embodiments, it is not limited to the optimal embodiment party
Formula, is not construed as limiting to present disclosure and protection domain, anyone the present invention enlightenment under or by the present invention and its
The feature of his prior art be combined and draw it is any with the present invention it is same or like as product, all fall within the present invention
Within protection domain.
Unreceipted specific experiment step or condition person in embodiment, according to the normal experiment described by document in the art
The operation of step or condition can be carried out.Agents useful for same or the unreceipted production firm person of instrument, be can by city available from
Conventional reagent product.
The present invention only lists the performance test of the fiber prepared by embodiment 1, and the fiber prepared by embodiment 2-5 also can
Same or like effect is reached, it is numerous to list herein.
Embodiment 1
1. antibacterial finishing agent master batch is prepared：
(1) 6 parts of silicon dioxide is taken by following proportioning；13 parts of Zinc Oxide；10 parts of magnesium oxide；13 parts of nanometer silver；5 parts of zeolite；
17 parts of 2,3- dihydroxy benaophenonels；20 parts of N, N- bis- and phenyl acetamide mix to obtain the first mixture；
(2) polyethylene terephthalate of first 9 times of weight of mixture is taken, is blended with the first mixture, is used screw rod
Extruder is extruded, pelletizing, and antibacterial matrices are obtained, standby, and wherein blending temperature is 250-270 DEG C, and screw rod rotary speed is 100-
200rpm。
2. fiber is prepared：
Take 17 parts of the pearl fiber of following weight portion；20 parts of milk fibre；9 parts of Zein fibers；Ground nut fiber
11 parts；13 parts of Modal fibre；25 parts of coconut palm Carbon fibe；15 parts of Folium Camelliae sinensis fiber；15 parts of antibacterial finishing agent, adds 120 parts of water, mixing
Stir, then dry in the sun molding.
Then said mixture is made into functional yams lines through blowing, opener, drafting, rove, spun yarn；Then control
Temperature rinses half an hour using clear water at 42 DEG C；
It is subsequently adding antibiotic finish master batch and is dipped through the functional yams lines that processed 30 minutes, then again at 70 DEG C
Bake, last heat treatment obtains finished fiber.
Embodiment 2-5
, with embodiment 1, the proportioning of each component is as follows for the preparation method of embodiment 2-5：
The each group distribution ratio of the antibacterial in embodiment 2-5 see the table below 1：
The each group distribution ratio of the antibacterial in 1 embodiment 2-5 of table
| Embodiment/weight portion | 2 | 3 | 4 | 5 |
| Zinc oxide nano-particle (particle diameter 10-30nm) | 10 | 15 | 12 | 14 |
| Nano particles of silicon dioxide (particle diameter 10-30nm) | 8 | 7 | 5 | 3 |
| Bitter earth nano particle (particle diameter 10-30nm) | 13 | 11 | 7 | 9 |
| Nanometer silver (particle diameter 10-30nm) | 10 | 19 | 16 | 9 |
| Zeolite | 8 | 2 | 6 | 4 |
| 2,3- dihydroxy benaophenonels | 20 | 25 | 11 | 15 |
| N, N- bis- and phenyl acetamide | 23 | 15 | 27 | 19 |
The each group distribution ratio of the fiber in embodiment 2-5 see the table below 2：
The each group distribution ratio of the fiber in 2 embodiment 2-5 of table
| Embodiment/weight portion | 2 | 3 | 4 | 5 |
| Pearl fiber | 15 | 10 | 25 | 20 |
| Milk fibre | 11 | 23 | 17 | 27 |
| Zein fibers | 7 | 5 | 15 | 10 |
| Ground nut fiber | 7 | 16 | 10 | 13 |
| Modal fibre | 17 | 10 | 15 | 8 |
| Coconut palm Carbon fibe | 12 | 33 | 30 | 20 |
| Folium Camelliae sinensis fiber | 18 | 11 | 8 | 21 |
| Antibacterial finishing agent | 19 | 10 | 17 | 13 |
Comparative example 1.
According to UV resistance antibacterial face prepared by 103255538 A embodiments of Chinese patent literature CN, 1 disclosure of that
Material, as X1.
Test case 1.
Determine the repelling effect of the product of embodiment 1 and X1
(1) process sample：Fiber or fabric are cut into into 15cm × 8cm.
(2) prepare test worm：By mosquito with plate being put into after ether light anesthesia, be placed on ice cube, select culex pipiens pallens
Female mosquito, is put in mosquito cage for one group per 50.
(3) observing effect：White mice is fixed after abdominal part depilation, abdominal part is overlayed on process sample, and uses plastic wraps, cruelly
Expose 2cm × 4cm areas, control is equally processed as with untreated samples.In temperature control laboratory, examination Mus are put in cage, are observed
Culex pipiens pallens 15min stops the mosquito number for falling on sample.
(4) data processing：Calculate mosquito and stop the frequency that falls (average every mosquito stops the number of times that falls).
The repelling effect table of the fiber of 3 embodiment 1 of table
Test case 2
Determine fire resistance, uvioresistant performance and the anti-microbial property of the product of embodiment 1 and X1
Detection unit：Test center of China Textile Academy：Center is superintended and directed in National Textile quality supervision.
Detection functional parameter：
(1) fire resistance
Fire retardancy test：Specimen size mm (mm) 150 is multiplied by 58, and salt index OI (%) is 34.
(2) uv resistance energy and anti-microbial property
A. uv resistance can be with anti-microbial property (routinely microorganism detection method detection)：Specific experiment result such as 4 institute of table
Show：
The uvioresistant of the fiber of 4 embodiment of table, anti-microbial property testing result
Antibacterial experiment result shown in table 4 shows that the fiber of present invention offer has preferable antibacterial effect, wherein to gold
The fungistatic effect of Staphylococcus aureus (ATCC6358), pneumobacilluses and Candida albicans (ATCC10231) is respectively reached
99%th, 99% and ＞ 98%, and test result indicate that the fiber that the present invention is provided has good fire-retardant and UVResistant effect, symbol
Close the requirement of national standard.
B. wet transmitting performance detection, wet transmitting performance testing result such as table 4
The wet transmitting performance detection of 4 embodiment of table, 1 fiber
Test case 3
Determine the creasy recovery angle of embodiment 1 and product
Test is with reference to GB/T3819-1997《The restorative measure of textile fabric folding line replys horn cupping》Test.Warp-wise delays
Elastic recovery angle is elastic with the antifungal gene of the slow elastic recovery angle sum reflection fabric of broadwise.Test result is shown in Table 5
The fiber of 5 embodiment 1 of table and the antibiotic facing material antifungal gene Performance comparision of comparative example
As can be seen from Table 5, the antifungal gene elasticity of fiber of the invention is far superior to the antibiotic facing material of comparative example X1.And
Stoving temperature and time of baking and banking up with earth are little to the antifungal gene elasticity effect of the fiber of the present invention.
Other quality standards for the fiber that reparation technology of the present invention is provided are：Fracture strength is stretched in 2.5CN/tdex, fracture
It is long 130%, line density coefficient of variation CVb1.8% (FZ/T54003-2004), line density deviation ratio (FZ/ between 2.5%
T54003-2004), dye uniformity, (gray card) level >=4 (GB/T6508-2001), 4.5 grades of color fastness ＞.
Obviously, above-described embodiment is only intended to clearly illustrate example, and the not restriction to embodiment.It is right
For those of ordinary skill in the art, can also make on the basis of the above description other multi-forms change or
Change.There is no need to be exhaustive to all of embodiment.And thus it is extended obvious change or
Among changing still in the protection domain of the invention.
Claims (10)
1. a kind of reparation technology of fiber, it is characterised in that using the antibacterial finishing agent with following weight：Titanium dioxide
Silicon nano 3-8 parts；Zinc oxide nano-particle 10-15 parts；Bitter earth nano particle 7-13 parts；Nanometer silver 9-19 parts；Zeolite
2-8 parts；2,3- dihydroxy benaophenonel 11-25 parts；N, N- bis- and phenyl acetamide 15-27 parts.
2. reparation technology according to claim 1, it is characterised in that the antibacterial finishing agent is to include following weight portion
Titanium dioxide nano-particle 5-7 parts；Zinc oxide nano-particle 12-14 parts；Bitter earth nano particle 9-11 parts；Nanometer silver 10-16
Part；Zeolite 4-6 parts；2,3- dihydroxy benaophenonel 15-20 parts；N, N- bis- and phenyl acetamide 19-23 parts.
3. reparation technology according to claim 1, it is characterised in that the antibacterial finishing agent is to include following weight portion
6 parts of Nano particles of silicon dioxide；13 parts of zinc oxide nano-particle；10 parts of bitter earth nano particle；13 parts of nanometer silver；5 parts of zeolite；
17 parts of 2,3- dihydroxy benaophenonels；20 parts of N, N- bis- and phenyl acetamide.
4. reparation technology according to claim 3, it is characterised in that the Nano particles of silicon dioxide, zinc-oxide nano
Particle and bitter earth nano particle, the particle diameter of nanometer silver are 10-30nm.
5. reparation technology according to claim 4, it is characterised in that the antibacterial finishing agent first with poly terephthalic acid second
Diol ester by weight 1:9 are configured to antibacterial finishing agent master batch, then exercise use.
6. reparation technology according to claim 5, it is characterised in that the antibacterial finishing agent master batch is made as follows
It is standby：Take antibacterial finishing agent each component in proportion, and and polyethylene terephthalate, blending, extruded with screw extruder, cut
Grain, is obtained antibacterial matrices, standby, and wherein blending temperature is 250-270 DEG C, and screw rod rotary speed is 100-200rpm.
7. reparation technology according to claim 1, it is characterised in that comprise the steps：
(1) by pearl fiber；Milk fibre；Zein fibers；Ground nut fiber；Modal fibre；Coconut palm Carbon fibe；Folium Camelliae sinensis
Fibre antibacterial finishing agent adds dispersant, binding agent, softening agent at 40-45 DEG C, adds 100-120 part water, mixes equal
It is even, then dry in the sun molding；
(2) said mixture is made into functional yams lines through blowing, opener, drafting, rove, spun yarn；
(3) then temperature control rinses half an hour using clear water at 42-44 DEG C；
(4) add antibiotic finish master batch to be dipped through the functional yams lines 30-70 minutes that step (3) was processed, then exist again
Bake at 70-80 DEG C, last heat treatment.
8. reparation technology according to claim 7, it is characterised in that each component weight is：Pearl fiber 10-25
Part；Milk fibre 11-27 parts；Zein fibers 5-15 parts；Ground nut fiber 7-16 parts；Modal fibre 8-17 parts；Coconut palm
Carbon fibe 12-33 parts；Folium Camelliae sinensis 8-21 part fibers；Antibacterial finishing agent 10-19 parts.
9. reparation technology according to claim 8, it is characterised in that each component weight is：Pearl fiber 15-20
Part；Milk fibre 17-23 parts；Zein fibers 7-10 parts；Ground nut fiber 10-13 parts；Modal fibre 10-15 parts；
Coconut palm Carbon fibe 20-30 parts；Folium Camelliae sinensis fiber 11-18 parts；Antibacterial finishing agent 13-17 parts.
10. reparation technology according to claim 9, it is characterised in that each component weight is：Pearl fiber 17
Part；20 parts of milk fibre；9 parts of Zein fibers；11 parts of ground nut fiber；13 parts of Modal fibre；25 parts of coconut palm Carbon fibe；
15 parts of Folium Camelliae sinensis fiber；15 parts of antibacterial finishing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611065392.5A CN106592233A (en) | 2016-11-28 | 2016-11-28 | Preparation process for a fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611065392.5A CN106592233A (en) | 2016-11-28 | 2016-11-28 | Preparation process for a fiber |
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| CN106592233A true CN106592233A (en) | 2017-04-26 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611065392.5A Pending CN106592233A (en) | 2016-11-28 | 2016-11-28 | Preparation process for a fiber |
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| CN (1) | CN106592233A (en) |
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| CN108978185A (en) * | 2018-08-09 | 2018-12-11 | 福建樱幼佳科技有限公司 | A kind of dedicated antibacterial textile fabric of baby and preparation method thereof |
| CN113338040A (en) * | 2021-06-04 | 2021-09-03 | 江苏新世嘉家纺高新科技股份有限公司 | Antibacterial fabric with high linear structure strength and good air permeability and production process |
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Application publication date: 20170426 |