CN106592221A - Preparation method of flame-retardant antistatic fabric - Google Patents

Preparation method of flame-retardant antistatic fabric Download PDF

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Publication number
CN106592221A
CN106592221A CN201611117731.XA CN201611117731A CN106592221A CN 106592221 A CN106592221 A CN 106592221A CN 201611117731 A CN201611117731 A CN 201611117731A CN 106592221 A CN106592221 A CN 106592221A
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CN
China
Prior art keywords
fabric
antistatic
preparation
fire
institute
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611117731.XA
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Chinese (zh)
Inventor
王鸿博
傅佳佳
孟微
陈太球
蒋春燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangnan University
Swoto Protection and Technology Co Ltd
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Jiangnan University
Swoto Protection and Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangnan University, Swoto Protection and Technology Co Ltd filed Critical Jiangnan University
Priority to CN201611117731.XA priority Critical patent/CN106592221A/en
Publication of CN106592221A publication Critical patent/CN106592221A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D06M14/22Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal

Abstract

The invention discloses a preparation method of a flame-retardant antistatic fabric. The preparation method comprises the steps: (1) in a process of weaving the fabric, selecting a proper fabric weave structure, weaving antistatic filaments in the fabric in an embedded weaving manner, and reasonably designing the embedded spacing; (2) soaking the fabric obtained from weaving in a grafting monomer solution for 1-3 hours, followed by, taking out the fabric, rolling to remove excess liquid through a padder, wrapping the fabric with a plastic thin film, putting in a self-seal bag, putting the fabric together with the self-seal bag into a high energy electron beam, and irradiating; and (3) after the irradiation is finished, washing the grafted fabric with deionized water, and removing homopolymers and unreacted monomers on the fabric surface; and then putting the fabric after cleaning in a drying oven, and drying for 24 hours to obtain the product. The fabric has good durability, flame retardancy and antistatic properties, and is a fabric having flame-retardant and antistatic double functions.

Description

A kind of preparation method of fire-resistant antistatic fabric
Technical field
The invention discloses a kind of preparation method of fire-resistant antistatic fabric, belongs to coverstock material technical field.
Background technology
With industrial expansion, people are for the understanding intensification of multiple incidents and progressively carrying for security protection consciousness Height, people are not limited solely to original fundamental characteristics such as warming, comfortable for the requirement of textile, it is also desirable which has The specific functions such as health care, safety, can not meet market demand according to the fabric of simple function, and dual function fabrics are even multi-functional Fabric arises at the historic moment.Wherein, flame-retardant and anti-static fabric is wherein one, and it can be used for protective clothing and indoor decoration Multiple occasions such as cloth, particularly in some inflammable and explosive occasions of the industries such as chemical industry, coal, oil, war industry, flame-retardant and anti-static is knitted Thing has been received more and more attention.
Fire-retardant is one of elementary tactics of disaster reduction and prevention, fire-retardant to can not be underestimated to the social benefit that society brings.Spin The application of fabric spreads all over the various aspects of our lives, therefore, the security performance for improving constantly fabric is manufacturer to consumer Promise be also progress of social civilization mark.Reducing fire casualties and property loss and reducing fire using inflaming retarding fabric Illeffectss of calamity consequence etc. are all very effective.
Electrostatic phenomenon is a kind of physical phenomenon of objective reality, refer on certain surface or produce in a constant volume just, Negative charge, under conditions of electric charge is not revealed, electric charge is in static or slowly varying relatively stably with certain electrical State.The prerequisite that electrostatic phenomenon is produced is that electric charge is generated and assembled.As textile material typically all has very high ratio electricity Resistance, two interfacial contacts that textile material interacts, produces substantial amounts of build-up of static charges after Separate With Friction, causes textile material Electrostatic phenomenon.
The harm of electrostatic phenomenon can't neglect, and electrostatic is that the industries such as chemical industry, petroleum industry cause the things such as fire, blast Therefore one of main predisposing factors, (flammable explosive gas or dust atmosphere) dress in a few thing environment is easy to produce and product During the activity such as poly- electrostatic material fabric production operation, there is static discharge in fabric, produce tiny spark, and its energy just can be made enough Surrounding flammable explosive gas are on fire or even explode, and cause serious accident.Static discharge phenomenon can bury major safety risks.
Inflaming-retarding antistatic fabric can be applied and be related to the industry employee such as oil, coal, chemical industry, microelectronics, war industry, firer Dressing in terms of, above-mentioned working wear dress has a large capacity and a wide range, and service life is shorter, therefore with flame-retardant and anti-static dual-use function There is the very big market demand, remarkable in economical benefits in face.Meanwhile, the application of the fabric with flame-retardant and anti-static dual-use function, Personal safety and the production safety of above-mentioned industry practitioner is can ensure that, the fire-retardant of above-mentioned industry practitioner protective garment is improved Performance and antistatic property are very necessary, therefore research and develop the dual-use function fabric and have important social meaning.
The content of the invention
The invention aims to a kind of preparation method of fire-resistant antistatic fabric is provided, to solve the upper of prior art State problem.
The purpose of the present invention is achieved through the following technical solutions.
A kind of preparation method of fire-resistant antistatic fabric, its step are as follows:
(1) in the weaving process of fabric, appropriate fabric structure is selected, by antistatic long filament using the embedding side knitted Formula is woven in fabric, and the embedded spacing of appropriate design;
(2) weaving gained fabric is immersed in into 1-3 hours in grafted monomers solution, subsequently taking-up shuts out unnecessary through padding machine Liquid, fabric is wrapped with plastic sheeting, is put in valve bag, fabric is put under high-power electron beam together with valve bag to be carried out Irradiation;
(3) after irradiation terminates, the fabric deionized water after grafting is cleaned, removes the homopolymer and not of fabric face The grafted monomers of reaction;Then the fabric after cleaning is put in baking oven and is dried 24 hours, obtain product.
In step (1), described fabric structure includes all tissues that can be used to embedding weaving yarns such as woven, knitting Structure.
In step (1), the embedding spacing of knitting of described electrostatic resistance yarn according to the characteristics of organizational structure of fabric and can be knitted The appearance looks elegant of thing carrys out designed, designed, and anti-static function yarn is >=1 with common yarn proportional spacing scope:0.01.
In step (1), described fabric includes that the spinning such as natural fiber, chemical fibre and various tencels institute is woven Fabric.
In step (1), described antistatic long filament includes metal system conductive fiber, white carbon black system conductive fiber, metal compound One or more in thing type conductive fiber, conductive polymer subtype conductive fiber;Also include by sides such as antistatic additive arrangements The long filament is spun into by antistatic fibre obtained by method.
In step (2), in the grafted monomers solution, solute is acrylamide, Methacrylamide, acrylic acid and methyl One kind in the vinyl monomers such as acrylic acid, its concentration are 0.1-10mol/L;Solvent is water.Or solute is vinyl phosphoric acid two The phosphorus such as methyl ester system grafted monomers, its concentration are 0.1wt%-30wt%;Solvent is water.
In step (2), the high-energy electron beam irradiation reaction condition is:Irradiation dose be 0-100kGy and it is corresponding other Radiation unit's transforming numerical.
In step (2), the atmosphere, the temperature conditionss during electron beam irradiation is not limited, and atmosphere can divide For atmospheric environment, vacuum environment or the inert gas environment containing nitrogen and/or helium.
Described grafted monomers solvent can not affect other functional finishing agents with other functions finishing agent compounding use Effect.
Fabric of the present invention is interwoven by filling yarn, and described warp thread is the yarn of common cellulose fibre spinning, The weft yarn is interweaved by electrostatic resistance yarn and common yarn, and wherein electrostatic resistance yarn can have conducting function for itself Fibre spinning is formed, or is spinned or through the yarn of anti-static function Final finishing by antistatic additive is added in spinning process Line.
It is an advantage of the current invention that:
This is a kind of novel processing step of exploitation with antistatic and fire-retardant dual-use function fabric, on Vehicles Collected from Market simultaneously Very rarely seen with fire-retardant and anti-static function fabric, the invention compensate for the deficiency on this market.Simultaneously as existing Top finish, impregnating flame-retardant finishing method for fabric flame-proof treatment have resistance to persistence, the present invention pass through high energy Electron beam irradiation carries out flame-proof treatment to fabric, and the effect of the flame-retardant and anti-static of durability can be produced to fabric.
Often technological process is long for traditional flame resistant method, and the operation of process equipment is extremely complex, has a lot Uncontrollable factor, is easily caused the undesirable of flame retardant effect.Meanwhile, loaded down with trivial details processor can greatly improve the production of Final finishing Cost.
The present invention first by it is electrostatic resistance yarn embedding be woven in fabric after again by fabric irradiation is carried out with high-power electron beam come Give fabrics flame resistance and anlistatig dual-use function.Fabric after irradiation can have the flame retardant effect of durability and resist Electrostatic efficiency.
The phosphorus such as the vinyl monomers such as acrylamide and vinyl phosphonic dimethyl phthalate system monomer is used to knit by the present invention first The high-energy electron beam irradiation of thing is grafted to make fabric reach the bi-functional fabric with antistatic property Yu fire resistance.This Bright prepared fabric has good fire resistance and antistatic property,
Used in the present invention, high-power electron beam carries out graft reaction to fabric, and high-energy electron beam irradiation is a kind of simple to operate Easy, response speed is fast, it is not necessary to carry out the method for sorting of Final finishing and non-secondary pollution.Need not appoint in the course of reaction What initiator, its ray energy are high, and penetration capacity is strong, and reaction can be deep into the inside of fabric.
The fire-resistant antistatic fabric of the present invention go for the textile fields such as clothing, decoration, home textile and fire-entry suit, The special type wearing fabric such as protective garment field, and there is the flame retardant effect of durability by the fabric prepared by the method and resist quiet Electric effect, comfortable feel.
Specific embodiment
The technical characterstic of the present invention is expanded on further with reference to specific embodiment.
Embodiment 1
Warp thread and weft yarn select purified cotton yarns, will plating silver yarn as embedding yarn and common cotton yarn with 1:60 space ratio It is embedding to be woven in fabric, anti-static fabric is obtained, then by the fabric of weaving gained in the acrylamide monomer that concentration is 2mol/L 2.5h is soaked in solution, then by fabric after an immersing and rolling (padding machine rotating speed 1m/min, pressure 0.1Mpa), high energy electricity is put into Irradiation is carried out under beamlet, irradiation dose is 22kGy, after completion of the reaction, fabric is taken out into deionized water cleaning, to remove fabric The homopolymer on surface and unreacted grafted monomers, are finally dried in an oven to constant weight.The percent grafting of fabric of gained is 11.15%, testing vertical flammability shows that after flame time and smoldering time are respectively 4.5s and 4s, and limited oxygen index is 29%;Its It is 934V to be charged by friction voltage, and surface resistivity is 1 × 109Ω。
Embodiment 2
Warp thread and weft yarn select purified cotton yarns, will plating silver yarn as embedding yarn and common cotton yarn with 1:40 space ratios are embedding It is woven in fabric, obtains anti-static fabric, then will be the fabric of weaving gained molten for the acrylamide monomer of 2mol/L in concentration 2.5h is soaked in liquid, fabric is put into into high energy electron after an immersing and rolling (padding machine rotating speed 1m/min, pressure 0.1Mpa) then Irradiation is carried out under beam, irradiation dose is 43kGy, after completion of the reaction, fabric is taken out into deionized water cleaning, to remove fabric table The homopolymer in face and unreacted grafted monomers, are finally dried in an oven to constant weight.The percent grafting of fabric of gained is 23.25%, testing vertical flammability shows that after flame time and smoldering time are respectively 4s and 3.5s, and limited oxygen index is 32%;Its It is 876V to be charged by friction voltage, and surface resistivity is 4 × 108Ω。
Embodiment 3
Warp thread and weft yarn select purified cotton yarns, will plating silver yarn as embedding yarn and common cotton yarn with 1:20 space ratios are embedding It is woven in fabric, obtains anti-static fabric, then will be the fabric of weaving gained molten for the acrylamide monomer of 2mol/L in concentration 2.5h is soaked in liquid, fabric is put into into high energy electron after an immersing and rolling (padding machine rotating speed 1m/min, pressure 0.1Mpa) then Irradiation is carried out under beam, irradiation dose is 65kGy, after completion of the reaction, fabric is taken out into deionized water cleaning, to remove fabric table The homopolymer in face and unreacted grafted monomers, are finally dried in an oven to constant weight.The percent grafting of fabric of gained is 11.15%, testing vertical flammability shows that after flame time and smoldering time are respectively 3s and 3s, and limited oxygen index is 36%;Which rubs Wiping electrified voltage is 783V, and surface resistivity is 3 × 108Ω。
Embodiment 4
Warp thread and weft yarn select purified cotton yarns, will plating silver yarn as embedding yarn and common cotton yarn with 1:10 space ratios are embedding It is woven in fabric, obtains anti-static fabric, then will be the fabric of weaving gained molten for the acrylamide monomer of 3mol/L in concentration 2.5h is soaked in liquid, fabric is put into into high energy electron after an immersing and rolling (padding machine rotating speed 1m/min, pressure 0.1Mpa) then Irradiation is carried out under beam, irradiation dose is 65kGy, after completion of the reaction, fabric is taken out into deionized water cleaning, to remove fabric table The homopolymer in face and unreacted grafted monomers, are finally dried in an oven to constant weight.The percent grafting of fabric of gained is 11.15%, testing vertical flammability shows that after flame time and smoldering time are respectively 2.5s and 3s, and limited oxygen index is 37%;Its It is 698V to be charged by friction voltage, and surface resistivity is 2 × 108Ω。
Embodiment 5
Warp thread and weft yarn select purified cotton yarns, will plating silver yarn as embedding yarn and common cotton yarn with 1:1 space ratio It is embedding to be woven in fabric, anti-static fabric is obtained, then by the fabric of weaving gained in the acrylamide monomer that concentration is 3mol/L 2.5h is soaked in solution, then by fabric after an immersing and rolling (padding machine rotating speed 1m/min, pressure 0.1Mpa), high energy electricity is put into Irradiation is carried out under beamlet, irradiation dose is 65kGy, after completion of the reaction, fabric is taken out into deionized water cleaning, to remove fabric The homopolymer on surface and unreacted grafted monomers, are finally dried in an oven to constant weight.The percent grafting of fabric of gained is 11.15%, testing vertical flammability shows that after flame time and smoldering time are respectively 2s and 2s, and limited oxygen index is 39%;Which rubs Wiping electrified voltage is 595V, and surface resistivity is 5 × 107Ω。
, merely for purpose of explanation, each reacting substance and reaction condition are in each technique for example cited by the present invention The bound value of parameter can realize the present invention, and here no longer distinguishes illustrative example.
Those skilled in the art directly derive without departing from the spirit and concept in the present invention or associate its He improves and changes, and is considered as within protection scope of the present invention.

Claims (9)

1. a kind of preparation method of fire-resistant antistatic fabric, it is characterised in that:Its step is as follows:
(1) in the weaving process of fabric, appropriate fabric structure is selected, antistatic long filament is knitted by the way of embedding knitting In fabric, and the embedded spacing of appropriate design;
(2) weaving gained fabric is immersed in into 1-3 hours in grafted monomers solution, subsequently take out and unnecessary liquid is shut out through padding machine Body, fabric is wrapped with plastic sheeting, is put in valve bag, and fabric is put under high-power electron beam together with valve bag carries out spoke According to;
(3) after irradiation terminates, the fabric deionized water after grafting is cleaned, removes the homopolymer and unreacted of fabric face Grafted monomers;Then the fabric after cleaning is put in baking oven and is dried 24 hours, obtain product.
2. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (1), institute The fabric structure stated includes all organizational structuries that can be used to embedding weaving yarns such as woven, knitting.
3. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (1), institute The embedding spacing of knitting of the electrostatic resistance yarn stated can be voluntarily set according to the appearance looks elegant of the characteristics of organizational structure of fabric and fabric Meter, anti-static function yarn are >=1 with common yarn proportional spacing scope:0.01.
4. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (1), institute The fabric stated includes the woven fabric of natural fiber, chemical fibre and various tencels spinning institute.
5. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (1), institute The antistatic long filament stated includes metal system conductive fiber, white carbon black system conductive fiber, metallic compound type conductive fiber, conductive polymer One or more in subtype conductive fiber.
6. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (1), institute The antistatic long filament stated includes the long filament is spun into by the antistatic fibre as obtained by antistatic additive method for sorting.
7. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (2), institute State in grafted monomers solution, solute is acrylamide, Methacrylamide, acrylic acid and methacrylic acid grafting vinyl monomers In one kind, its concentration be 0.1-10mol/L;Solvent is water.
8. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (2), institute State in grafted monomers solution, solute is vinyl phosphoric acid dimethyl ester grafted monomers, and its concentration is 0.1wt%-30wt%;Solvent is Water.
9. the preparation method of a kind of fire-resistant antistatic fabric according to claim 1, it is characterised in that:In step (2), institute Stating high-energy electron beam irradiation reaction condition is:Irradiation dose is 0-100kGy and corresponding other radiation unit's transforming numericals.
CN201611117731.XA 2016-12-07 2016-12-07 Preparation method of flame-retardant antistatic fabric Pending CN106592221A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107201654A (en) * 2017-06-30 2017-09-26 四川东方绝缘材料股份有限公司 A kind of washable fire-retardant polyester cotton and preparation method thereof
CN110512419A (en) * 2019-08-08 2019-11-29 东华大学 A kind of antibacterial flame-retardant cellulose and its preparation and application
CN112813685A (en) * 2020-06-30 2021-05-18 应急管理部四川消防研究所 Durable flame-retardant after-finishing fabric and preparation method thereof
CN114318869A (en) * 2020-10-10 2022-04-12 上海水星家用纺织品股份有限公司 Method for preparing flame-retardant fabric fiber based on electron beam radiation
CN116595761A (en) * 2023-05-17 2023-08-15 东莞市弘伟应急科技有限公司 Production method and device of antistatic firefighter uniform fabric

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CN2255435Y (en) * 1996-06-07 1997-06-04 西北纺织工学院 Composite compatible fire-retardant anti-static synthetic fiber textile
CN1554817A (en) * 2003-12-24 2004-12-15 ��˹�����ն��Ƽ��ɷ����޹�˾ Method for producing anti-static flame retardant, water-proof and oil-proof natural fibrous fabric
CN104757718A (en) * 2015-03-27 2015-07-08 陕西锦澜科技有限公司 Anti-flaming anti-static jean fabric and preparing method thereof
CN105133285A (en) * 2015-09-18 2015-12-09 江南大学 Method for performing durable flame-retardant grafting modification on fabric through cooperation of low-temperature plasma with electron beam irradiation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2255435Y (en) * 1996-06-07 1997-06-04 西北纺织工学院 Composite compatible fire-retardant anti-static synthetic fiber textile
CN1554817A (en) * 2003-12-24 2004-12-15 ��˹�����ն��Ƽ��ɷ����޹�˾ Method for producing anti-static flame retardant, water-proof and oil-proof natural fibrous fabric
CN104757718A (en) * 2015-03-27 2015-07-08 陕西锦澜科技有限公司 Anti-flaming anti-static jean fabric and preparing method thereof
CN105133285A (en) * 2015-09-18 2015-12-09 江南大学 Method for performing durable flame-retardant grafting modification on fabric through cooperation of low-temperature plasma with electron beam irradiation

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107201654A (en) * 2017-06-30 2017-09-26 四川东方绝缘材料股份有限公司 A kind of washable fire-retardant polyester cotton and preparation method thereof
CN110512419A (en) * 2019-08-08 2019-11-29 东华大学 A kind of antibacterial flame-retardant cellulose and its preparation and application
CN110512419B (en) * 2019-08-08 2021-11-02 东华大学 Antibacterial flame-retardant cellulose and preparation and application thereof
CN112813685A (en) * 2020-06-30 2021-05-18 应急管理部四川消防研究所 Durable flame-retardant after-finishing fabric and preparation method thereof
CN114318869A (en) * 2020-10-10 2022-04-12 上海水星家用纺织品股份有限公司 Method for preparing flame-retardant fabric fiber based on electron beam radiation
CN116595761A (en) * 2023-05-17 2023-08-15 东莞市弘伟应急科技有限公司 Production method and device of antistatic firefighter uniform fabric
CN116595761B (en) * 2023-05-17 2024-01-19 东莞市弘伟应急科技有限公司 Production method and device of antistatic firefighter uniform fabric

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Application publication date: 20170426