CN106590396A - Environment-friendly wall decoration fireproof coating and preparation method thereof - Google Patents
Environment-friendly wall decoration fireproof coating and preparation method thereof Download PDFInfo
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- CN106590396A CN106590396A CN201611072737.XA CN201611072737A CN106590396A CN 106590396 A CN106590396 A CN 106590396A CN 201611072737 A CN201611072737 A CN 201611072737A CN 106590396 A CN106590396 A CN 106590396A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Building Environments (AREA)
- Finishing Walls (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses an environment-friendly wall decoration fireproof coating, comprising ceramic fiber, vermiculite, perlite, fine asbestos, borax, mica powder, aliphatic waterborne polyurethane, a film-forming agent, a foaming agent and deionized water, wherein the foaming agent consists of a thermoplastic acrylic resin type polymer, sodium dodecyl benzene sulfonate, ammonium borate, ammonium polyphosphate and deionized water. The raw materials for preparing the coating disclosed by the invention are environment-friendly, have good fireproof performance, cannot deform easily, are high in strength, and cannot fall off and bulk; and preferably, the foaming agent is environment-friendly and nontoxic and has a reasonable formula, so that in the case of fire, the foaming agent expands to generate foams quickly to form a compact sponge-shaped expansion foam layer with a good heat-insulating property, combustible base materials can be protected more effectively, black smoke cannot be generated, and the concentration of organic volatiles is extremely low, which is beneficial for the health of sufferers and rescuers in the fire disaster. The preparation method disclosed by the invention is simple and is easy to operate, and the environment-friendly wall decoration fireproof coating is convenient in construction and firm in adhesion, and cannot crack to ensure that a wall body has a long service life.
Description
Technical field
The invention belongs to building coating and its preparing technical field, more particularly to a kind of environment-friendly type for being suitable for wall decoration is prevented
Fiery coating.
Background technology
Fireproof coating is, for flammable substrates surface, to reduce by the combustibility of painting material surface, block the fast of fire
Speed spreads, to improve by a kind of sapecial coating of painting material fire endurance.Can be divided into by purposes and using the difference of object：Decorations
Face type fireproof coating, cable fire-refractory coating, fire-resistant coating for steel structure, prestressed concrete floor slab fireproof coating etc..Wherein facing
Type fireproof coating is increasingly paid attention in building coating industry.But focusing on decoration effect decorated wall surface fireproof coating at present more
Really, flameproof effect is not ideal.
At home in building decoration regulation, the requirement to wall covering is only to specify that interior wall is applied in GB/T9756-2001
Material physical and chemical index, does not refer to fire protection requirement；And requirement of the domestic fire codes to finishing fire retardant paint is
GB12441-1998 also specify only fire protecting performance index, and its physical and chemical index refers to items specified in GB/T9756-2001
Mark greatly differs from each other.So cause fire prevention Finishing coating physical and chemical index on the market and the fire line can not be all good, and
And part coatings are raw materials used not environmentally, meeting fire burning can more produce the organic volatile (VOCs) of high concentration, or even emerge black
Cigarette, this is very unfavorable to the victim and rescue personnel in fire.How wall covering is accomplished the effect of fire protection flame retarding
Not losing the decorative effect and environment protection health of wall covering again simultaneously becomes the design concept and design key of the present invention.
The content of the invention
The invention mainly solves the technical problem of providing a kind of environment protection type wall covering decorative fireproof coating, the environment protection type wall covering
Decorative fireproof coating is unlikely to deform, and is not afraid of extruding, collides, and intensity is high, does not fall off, plays drum, and long service life, fire protecting performance is good,
Pernicious gas, more safety and environmental protection are not produced at high operating temperatures.
To solve above-mentioned technical problem, one aspect of the present invention is：A kind of environment protection type wall covering decoration is provided
Fireproof coating, including the raw material of following weight portion：Ceramic fibre is 15-25 parts, and vermiculite is 20-30 parts, and perlite is 5-15 parts,
Thin essence asbestos are 20-30 parts, and borax is 5-10 parts, and mica powder is 15-20 parts, and aliphatic water-based polyurethane is 10-20 parts, film forming
Agent is 5-10 parts, and foaming agent is 15-20 parts and deionized water is 40-50 parts；
The aliphatic water-based polyurethane is PPG or PEPA, the PPG or polyester polyols
The molecular weight of alcohol is 1800-2000；
The granularity of the ceramic fibre is 900-1000 mesh；The granularity of the vermiculite is 300-500 mesh；It is described perlitic
Granularity is 800-900 mesh；The granularity of the thin smart asbestos is 400-500 mesh.
To solve above-mentioned technical problem, one aspect of the present invention is：
The foaming agent is comprised the following raw materials by weight percent：The thermoplastic acrylic resin of 16%-20% is birdsed of the same feather flock together
Compound, the neopelex of 16%-22%, the ammonium borate of 24%-30%, the APP of 3%-7%, it is balance of to go
Ionized water.
Further say, the film forming agent is pure acrylic latex or polyvinyl acetate emulsion.
Further say, including the raw material of following weight portion：Ceramic fibre be 20-25 parts, vermiculite be 22-28 parts, pearl
Rock is 8-12 parts, and thin essence asbestos are 22-28 parts, and borax is 6-9 parts, and mica powder is 15-18 parts, and aliphatic water-based polyurethane is
12-18 parts, film forming agent is 5-8 parts, and foaming agent is 18-20 parts and deionized water is 42-48 parts；
The molecular weight of the PPG or PEPA is 1900-2000；
The granularity of the ceramic fibre is 900-950 mesh；The granularity of the vermiculite is 400-500 mesh；It is described perlitic
Granularity is 800-850 mesh；The granularity of the thin smart asbestos is 450-500 mesh.
Further say that the preparation method of described environment protection type wall covering decorative fireproof coating is carried out as steps described below：
Step one：Respectively by ceramic fibre, vermiculite, perlite, thin essence asbestos, borax and mica powder, crushing is sequentially passed through
Machine is crushed, and grinder grinding and dispersion machine disperse, and obtains required granularity, standby；
Step 2：Each raw material that step one is prepared is sent in mixer, is stirred with 500-800 rev/min of rotating speed,
Time is 1-2 hours so as to is well mixed, obtains mixture A；
Step 3：By thermoplastic acrylic resin birds of the same feather flock together compound, neopelex, ammonium borate, APP and
Deionized water adds mixer, is stirred with 300-500 rev/min of rotating speed, and the time is 0.5-1 hours so as to is well mixed, obtains
To mixture B；
Step 4：Mixture A, aliphatic water-based polyurethane, film forming agent, deionized water and mixture B are added simultaneously and is stirred
Machine is mixed, is stirred with 500-600 rev/min of rotating speed, the time is 1-1.5 hours so as to is well mixed, is cooled to room temperature, obtains final product
Finished product coating.
The invention has the beneficial effects as follows：The environment protection type wall covering decorative fireproof coating that the present invention is provided, from natural inorganic
Material, it is tasteless, pollution-free, nonirritant, and fire protecting performance is good, is unlikely to deform, and is not afraid of extruding, collides, and intensity is high, does not take off
Fall, play drum, it is environmentally friendly and safe and applicable；For environment-friendly materials, the ratio of addition rationally, makes system to the aliphatic water-based polyurethane for being adopted
Product color inhibition, it is resistance to it is tortuous, do not play drum；More preferably, the foaming agent of employing selects raw material environment-protecting asepsis, and formula is reasonable,
It is rapid expanded foamed during so that fire occurring, the fine and close spongy expanded foam layer with good heat-proof quality is formed, can be more
Flammable substrates are effectively protected, and black smoke will not be produced, organic volatile concentration is extremely low, be conducive to aggrieved in fire
Person and the health of rescue personnel.The environment protection type wall covering decorative fireproof coating provided in the present invention, preparation method is simple, it is easy to grasp
Make, be easy to construction, it is not necessary to which binding agent can be directly applied to all kinds of base course walls, be firmly bonded, do not ftracture, body of wall makes
Use life-span length.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of specification, described in detail as after with presently preferred embodiments of the present invention below.
Specific embodiment
The specific embodiment of the present invention is illustrated below by way of particular specific embodiment, those skilled in the art can be by this
Content disclosed in specification understands easily advantages of the present invention and effect.The present invention can also other different modes give
Implement, i.e. without departing substantially from different modifications under the scope of disclosed, being given and changed.
Embodiment 1：A kind of environment protection type wall covering decorative fireproof coating of the present invention, including the raw material of following weight portion：Ceramics
Fiber is 15 parts, and vermiculite is 25 parts, and perlite is 5 parts, and thin essence asbestos are 25 parts, and borax is 10 parts, and mica powder is 18 parts, fat
Race's water-based polyurethane is 10 parts, and film forming agent is 5 parts, and foaming agent is 20 parts and deionized water is 45 parts；The film forming agent is pure third
Olefin(e) acid emulsion, the aliphatic water-based polyurethane is PPG.
The foaming agent is comprised the following raw materials by weight percent：16% thermoplastic acrylic resin birds of the same feather flock together compound,
18% neopelex, 28% ammonium borate, 7% APP, balance of deionized water.
Embodiment 2：A kind of environment protection type wall covering decorative fireproof coating of the present invention, including the raw material of following weight portion：Ceramics
Fiber is 20 parts, and vermiculite is 30 parts, and perlite is 10 parts, and thin essence asbestos are 20 parts, and borax is 8 parts, and mica powder is 15 parts, fat
Race's water-based polyurethane is 15 parts, and film forming agent is 8 parts, and foaming agent is 18 parts and deionized water is 40 parts；The film forming agent is pure third
Olefin(e) acid emulsion, the aliphatic water-based polyurethane is polyether polyols ether.
The foaming agent is comprised the following raw materials by weight percent：18% thermoplastic acrylic resin birds of the same feather flock together compound,
16% neopelex, 24% ammonium borate, 5% APP, balance of deionized water.
Embodiment 3：A kind of environment protection type wall covering decorative fireproof coating of the present invention, including the raw material of following weight portion：Ceramics
Fiber is 25 parts, and vermiculite is 20 parts, and perlite is 8 parts, and thin essence asbestos are 30 parts, and borax is 5 parts, and mica powder is 20 parts, fat
Race's water-based polyurethane is 20 parts, and film forming agent is 10 parts, and foaming agent is 15 parts and deionized water is 50 parts；The film forming agent is pure poly-
Acetate emulsion, the aliphatic water-based polyurethane is PPG.
The foaming agent is comprised the following raw materials by weight percent：20% thermoplastic acrylic resin birds of the same feather flock together compound,
22% neopelex, 30% ammonium borate, 3% APP, balance of deionized water.
Embodiment 4：A kind of environment protection type wall covering decorative fireproof coating of the present invention, including the raw material of following weight portion：Ceramics
23 parts of fiber, vermiculite is 28 parts, and perlite is 9 parts, and thin essence asbestos are 22 parts, and borax is 7 parts, and mica powder is 19 parts, aliphatic
Water-based polyurethane is 18 parts, and film forming agent is 7 parts, and foaming agent is 19 parts and deionized water is 48 parts；The film forming agent is poly-vinegar acid
Vac emulsion, the aliphatic water-based polyurethane is polyether polyols ether.
The foaming agent is comprised the following raw materials by weight percent：17% thermoplastic acrylic resin birds of the same feather flock together compound,
20% neopelex, 26% ammonium borate, 6% APP, balance of deionized water.
Embodiment 5：A kind of environment protection type wall covering decorative fireproof coating of the present invention, including the raw material of following weight portion：Ceramics
Fiber is 18 parts, and vermiculite is 22 parts, and perlite is 15 parts, and thin essence asbestos are 23 parts, and borax is 9 parts, and mica powder is 17 parts, fat
Race's water-based polyurethane is 16 parts, and film forming agent is 6 parts, and foaming agent is 17 parts and deionized water is 42 parts；The film forming agent is poly-vinegar
Sour vac emulsion, the aliphatic water-based polyurethane is PPG.
The foaming agent is comprised the following raw materials by weight percent：19% thermoplastic acrylic resin birds of the same feather flock together compound,
21% neopelex, 27% ammonium borate, 4% APP, balance of deionized water.
To in embodiment 5, the molecular weight of the PPG or PEPA is 1800-2000 to embodiment 1；It is described
The granularity of ceramic fibre is 900-1000 mesh；The granularity of the vermiculite is 300-500 mesh；The perlitic granularity is 800-
900 mesh；The granularity of the thin smart asbestos is 400-500 mesh.
Preferably, the molecular weight of the PPG or PEPA is 1900-2000；The grain of the ceramic fibre
Spend for 900-950 mesh；The granularity of the vermiculite is 400-500 mesh；The perlitic granularity is 800-850 mesh；The thin essence
The granularity of asbestos is 450-500 mesh.
The preparation method of described environment protection type wall covering decorative fireproof coating, is carried out in accordance with the following steps：
Step one：Respectively by ceramic fibre, vermiculite, perlite, thin essence asbestos, borax and mica powder, crushing is sequentially passed through
Machine is crushed, and grinder grinding and dispersion machine disperse, and obtains required granularity, standby；
Step 2：Each raw material that step one is prepared is sent in mixer, is stirred with 500-800 rev/min of rotating speed,
Time is 1-2 hours so as to is well mixed, obtains mixture A；
Step 3：By thermoplastic acrylic resin birds of the same feather flock together compound, neopelex, ammonium borate, APP and
Deionized water adds mixer, is stirred with 300-500 rev/min of rotating speed, and the time is 0.5-1 hours so as to is well mixed, obtains
To mixture B；
Step 4：Mixture A, aliphatic water-based polyurethane, film forming agent, deionized water and mixture B are added simultaneously and is stirred
Machine is mixed, is stirred with 500-600 rev/min of rotating speed, the time is 1-1.5 hours so as to is well mixed, is cooled to room temperature, obtains final product
Finished product coating.
Testing performance index is carried out to embodiment, main performance index is as follows：The resistance to combustion time be 25-28 minutes (one-level,
GB12441-1998)；Alkali resistance is 18 hours (GB/T9756-2001) without exception；Abrasion resistance >=1000 time (top grade product, GB/
T9756-2001)；Organic volatile VOCs is 5-10g/L (meeting GB18582-2001).
From in terms of testing result, the environment protection type wall covering decorative fireproof coating of the present invention can meet the fire prevention of GB12441-1998
Require, GB/T9756-2001 performance indications can be met again.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this
The equivalent structure that bright specification is made, or other related technical fields are directly or indirectly used in, this is included in the same manner
In bright scope of patent protection.
Claims (5)
1. a kind of environment protection type wall covering decorative fireproof coating, it is characterised in that：Including the raw material of following weight portion：Ceramic fibre is
15-25 parts, vermiculite is 20-30 parts, and perlite is 5-15 parts, and thin essence asbestos are 20-30 parts, and borax is 5-10 parts, and mica powder is
15-20 parts, aliphatic water-based polyurethane is 10-20 parts, and film forming agent is 5-10 parts, and foaming agent is that 15-20 parts and deionized water are
40-50 parts；
The aliphatic water-based polyurethane is PPG or PEPA, the PPG or PEPA
Molecular weight is 1800-2000；
The granularity of the ceramic fibre is 900-1000 mesh；The granularity of the vermiculite is 300-500 mesh；The perlitic granularity
For 800-900 mesh；The granularity of the thin smart asbestos is 400-500 mesh.
2. environment protection type wall covering decorative fireproof coating according to claim 1, it is characterised in that：The foaming agent is by following heavy
The raw material composition of amount percentage：The thermoplastic acrylic resin of 16%-20% is birdsed of the same feather flock together the detergent alkylate of compound, 16%-22%
Sodium sulfonate, the ammonium borate of 24%-30%, the APP of 3%-7%, balance of deionized water.
3. environment protection type wall covering decorative fireproof coating according to claim 1, it is characterised in that：The film forming agent is pure propylene
Yogurt liquid or polyvinyl acetate emulsion.
4. environment protection type wall covering decorative fireproof coating according to claim 1, it is characterised in that：Including the original of following weight portion
Material：Ceramic fibre is 20-25 parts, and vermiculite is 22-28 parts, and perlite is 8-12 parts, and thin essence asbestos are 22-28 parts, and borax is 6-9
Part, mica powder be 15-18 parts, aliphatic water-based polyurethane be 12-18 parts, film forming agent be 5-8 parts, foaming agent be 18-20 parts and
Deionized water is 42-48 parts；
The molecular weight of the PPG or PEPA is 1900-2000；
The granularity of the ceramic fibre is 900-950 mesh；The granularity of the vermiculite is 400-500 mesh；The perlitic granularity
For 800-850 mesh；The granularity of the thin smart asbestos is 450-500 mesh.
5. the preparation method of environment protection type wall covering decorative fireproof coating according to claim 1, it is characterised in that：According to following
Step is carried out：
Step one：Respectively by ceramic fibre, vermiculite, perlite, thin essence asbestos, borax and mica powder, pulverizer powder is sequentially passed through
Broken, grinder grinding and dispersion machine disperse, and obtain required granularity, standby；
Step 2：Each raw material that step one is prepared is sent in mixer, is stirred with 500-800 rev/min of rotating speed, the time
For 1-2 hours so as to be well mixed, mixture A is obtained；
Step 3：By thermoplastic acrylic resin birds of the same feather flock together compound, neopelex, ammonium borate, APP and go from
Sub- water adds mixer, is stirred with 300-500 rev/min of rotating speed, and the time is 0.5-1 hours so as to is well mixed, is mixed
Compound B；
Step 4：Mixture A, aliphatic water-based polyurethane, film forming agent, deionized water and mixture B are added into mixer simultaneously,
Stirred with 500-600 rev/min of rotating speed, the time is 1-1.5 hours so as to is well mixed, is cooled to room temperature, gets product painting
Material.
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| CN201611072737.XA CN106590396B (en) | 2016-11-29 | 2016-11-29 | Environment protection type wall covering decorative fireproof coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611072737.XA CN106590396B (en) | 2016-11-29 | 2016-11-29 | Environment protection type wall covering decorative fireproof coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN106590396A true CN106590396A (en) | 2017-04-26 |
| CN106590396B CN106590396B (en) | 2018-10-30 |
Family
ID=58593663
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722793A (en) * | 2017-11-21 | 2018-02-23 | 马鞍山松鹤信息科技有限公司 | A kind of nano fire-retardant coating and preparation method thereof |
| CN111019419A (en) * | 2019-12-21 | 2020-04-17 | 民发现代建设工程集团有限公司 | Environment-friendly building construction and decoration coating and preparation method thereof |
| CN113683931A (en) * | 2021-08-31 | 2021-11-23 | 江苏冠军科技集团股份有限公司 | Finishing type fireproof coating and preparation method thereof |
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| CN1948404A (en) * | 2006-11-15 | 2007-04-18 | 公安部四川消防研究所 | Non expansion type steel structure fire retarding anticorrosion paint |
| CN101386719A (en) * | 2008-08-28 | 2009-03-18 | 冯守中 | Multifunctional coatings and preparation method thereof |
| CN102993884A (en) * | 2012-11-02 | 2013-03-27 | 马建林 | Flame retardant coating for internal decoration of buildings and production process of flame retardant coating |
| CN104725957A (en) * | 2015-03-18 | 2015-06-24 | 山西省交通科学研究院 | Self-crosslinking steel structure fire retardant coating and preparation method thereof |
| CN105086689A (en) * | 2015-08-28 | 2015-11-25 | 重庆佐恩家具有限公司 | Environmental-protection woodwork furniture coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1948404A (en) * | 2006-11-15 | 2007-04-18 | 公安部四川消防研究所 | Non expansion type steel structure fire retarding anticorrosion paint |
| CN101386719A (en) * | 2008-08-28 | 2009-03-18 | 冯守中 | Multifunctional coatings and preparation method thereof |
| CN102993884A (en) * | 2012-11-02 | 2013-03-27 | 马建林 | Flame retardant coating for internal decoration of buildings and production process of flame retardant coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107722793A (en) * | 2017-11-21 | 2018-02-23 | 马鞍山松鹤信息科技有限公司 | A kind of nano fire-retardant coating and preparation method thereof |
| CN111019419A (en) * | 2019-12-21 | 2020-04-17 | 民发现代建设工程集团有限公司 | Environment-friendly building construction and decoration coating and preparation method thereof |
| CN113683931A (en) * | 2021-08-31 | 2021-11-23 | 江苏冠军科技集团股份有限公司 | Finishing type fireproof coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106590396B (en) | 2018-10-30 |
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