CN1065881A - 浓缩型灭菌洗衣粉配方及工艺 - Google Patents
浓缩型灭菌洗衣粉配方及工艺 Download PDFInfo
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- CN1065881A CN1065881A CN 92108124 CN92108124A CN1065881A CN 1065881 A CN1065881 A CN 1065881A CN 92108124 CN92108124 CN 92108124 CN 92108124 A CN92108124 A CN 92108124A CN 1065881 A CN1065881 A CN 1065881A
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- 238000005406 washing Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 11
- 230000001954 sterilising effect Effects 0.000 title claims abstract description 11
- 235000020610 powder formula Nutrition 0.000 title 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 11
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 9
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000003599 detergent Substances 0.000 claims abstract description 7
- 239000000645 desinfectant Substances 0.000 claims abstract description 6
- 238000005187 foaming Methods 0.000 claims abstract description 5
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 5
- 238000010521 absorption reaction Methods 0.000 claims abstract description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 8
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 8
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 229940056729 sodium sulfate anhydrous Drugs 0.000 claims description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000032683 aging Effects 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000003206 sterilizing agent Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- 238000005054 agglomeration Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 abstract 1
- 230000007794 irritation Effects 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical group [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000295644 Staphylococcaceae Species 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000003559 chemosterilizing effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
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Abstract
本发明是集消毒剂和洗涤剂为一体的洗衣粉,该
商品取名为“消洗灵洗衣粉”,配方的特征是:灭菌剂
采用氯化磷酸三钠,表面活性剂是由十二烷基苯磺酸
和壬基酚聚氧乙烯醚组成,抗再沉积剂采用羧甲基纤
维素,助剂由三聚磷酸钠,水合硅酸钠以及无水碳酸
钠混合反应而成。其工艺特征是:将中和、发泡、吸
收、附聚成型和混合等反应过程集中在一个反应设备
中完成。该产品灭菌效果达99%,对人体无害,对皮
肤无刺激,不损坏衣物。
Description
本发明涉及一种灭菌洗衣粉的配方及生产工艺。在日常生活中人们使用的普通洗衣粉往往只起洗涤作用,而使用的卫生防疫用品又只能起消毒作用,这样经常造成洗涤和消毒需分别进行的重复工作。
本发明的目的在于制造一种集卫生防疫用品和洗涤剂为一体的洗衣粉。该商品取名为“消洗灵洗衣粉”,意即为消毒皆洗涤都灵。
为了达到上述目的,本发明的配方特征是:灭菌剂采用氯化磷酸三钠,表面活性剂是由十二烷基苯磺酸和壬基酚聚氧乙烯醚组成,抗再沉积剂是采用羧甲基纤维素,洗涤助剂由三聚磷酸钠,水合硅酸钠以及无水碳酸钠混合反应而成。
本发明的生产工艺特征是:将中和、发泡、吸收、附聚成型、混合五个反应过程集中在一个反应设备中完成。
由以上配方和工艺制成的产品与化学消毒剂(即氯化磷酸三钠)一样具有广谱、高效和速效的灭菌功能及用途,而在稳定性好,不吸潮、不结块等方面则优于氯化磷酸三钠及其它无机氯消毒剂,它与一般洗衣粉相比除增加消毒灭菌功能外还具有去污力强、易漂洗的特点,因而克服了以往需分别进行洗涤和消毒的重复工作。
下面结合实施例对本发明进行详细说明。
实施例1:灭菌剂采用氯化磷酸三钠,表面活性剂是由阴离子型活性剂十二烷基苯磺酸和非离子型活性剂壬基酚聚氧乙烯醚组成,抗再沉积剂是采用羧甲基纤维素,洗涤助剂由三聚磷酸钠,水合硅酸钠以及无水碳酸钠混合而成,其余为元明粉。以上配方中各组份比如下:(重量百分比)氯化磷酸三钠15%,三聚磷酸钠20%,十二烷基苯磺酸4%,壬基酚聚氧乙烯醚8%,无水碳酸钠20%,元明粉31.9%,水合硅酸钠1%,羧甲基纤维素0.1%。
其生产工艺是:在一台混料机中首先放入无水碳酸钠后喷入液体的十二烷基苯磺酸(即中和,时间大约为15分钟)此时产生十二烷基磺酸钠、二氧化碳和水,其中二氧化碳和水部分被吸收,部分挥发时起泡(即发泡)然后加入三聚磷酸钠,元明粉,羧甲基纤维素、水合硅酸钠,在喷入液体的壬基酚聚氧乙烯醚的同时搅拌大约30分钟即形成以液滴为核心粘结成细小粒状物亦即附聚成型,最后加入氯化磷酸三钠进行混合约30分钟后陈化至温室即可包装
实施例2:配方用料同实施例1,各组份比如下:(重量百分比)氯化磷酸三钠20%,三聚磷酸钠15%,十二烷基苯磺酸6%,壬基酚聚氧乙烯醚6%,无水碳酸钠25%,元明粉24.8%,水合硅酸钠1%,羧甲基纤维素0.2%。
生产工艺同实施例1。
在以上两种配方比例中,以实施例1为最佳,本配方使用的化学灭菌剂为氯化磷酸三钠,它不同于次氯酸钠,二氯异氰尿酸钠等含氯消毒剂,由此配方制成的洗衣粉具有稳定性好,常温水溶性好,灭菌活性好(即不需另加活化剂)的优点。
本发明的生产工艺吸取了附聚成型法和湿混法的优点,采用了中和吸收-附聚成型法的新工艺,即在一台设备中完成所有反应过程,因而具有操作简单,无污染、投资少,效益高,能耗低等优点。
本产品是将消毒、灭菌、洗涤、去污一次完成的新型洗涤剂,经四川省防疫站检测,对大肠杆菌,金色葡萄球菌等细菌的灭菌效果达99%(参见附件1和2),对人体无毒无害,对皮肤无刺激性,对衣物无破坏性(参见附件3)。用于家庭洗涤,省时省力,洗后衣物色彩鲜艳、洁白如新。用于浴池、游泳池等场所可防止各种疾病的传染,所以尤其适合医院和宾馆等单位使用。
Claims (4)
1、一种由表面活性剂、抗再沉积剂、洗涤助剂及元明粉配合而成的浓缩型灭菌洗衣粉,其特征是:灭菌剂采用氯化磷酸三钠,表面活性剂是十二烷基苯磺酸和壬基酚聚氧乙烯醚组成,抗再沉积剂采用羧甲基纤维素,洗涤助剂由三聚磷酸钠、水合硅酸钠以及无水碳酸混合反应而成。
2、如权利要求1所述的洗衣粉,其特征是:配方中各组份的配比如下:(重量百分比)氯化磷酸三钠15-20%,三聚磷酸钠15-20%,十二烷基苯磺酸4-6%,壬基酚聚氧乙烯醚6-8%,无水碳酸钠20-25%,水合硅酸钠1%,羧甲基纤维素0.1%-0.2%,其余为元明粉。
3、一种浓缩型灭菌洗衣粉的生产工艺,其特征是:将中和、发泡、吸收、附聚成型、混合五个反应过程集中在一个反应设备中完成。
4、如权利要求3所述的生产工艺,其特征是:在一台混料机中先将无水碳酸钠和十二烷基苯磺酸中和后加入三聚磷酸钠、羧甲基纤维素、水合硅酸钠和壬基酚聚氧乙烯醚附聚成型再加入氯化磷酸三钠进行混合,最后陈化至室温即可包装。
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CN 92108124 CN1065881A (zh) | 1992-05-08 | 1992-05-08 | 浓缩型灭菌洗衣粉配方及工艺 |
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CN 92108124 CN1065881A (zh) | 1992-05-08 | 1992-05-08 | 浓缩型灭菌洗衣粉配方及工艺 |
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CN1065881A true CN1065881A (zh) | 1992-11-04 |
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CN 92108124 Pending CN1065881A (zh) | 1992-05-08 | 1992-05-08 | 浓缩型灭菌洗衣粉配方及工艺 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1038344C (zh) * | 1993-04-24 | 1998-05-13 | 娄熙南 | 高效消毒灭菌洗衣粉 |
CN1052751C (zh) * | 1995-06-16 | 2000-05-24 | 杨国林 | 清真洗衣粉 |
CN1059074C (zh) * | 1996-10-21 | 2000-12-06 | 谢体生 | 洗涤消毒剂 |
CN102796625A (zh) * | 2012-07-13 | 2012-11-28 | 湖北海力化工科技有限公司 | 一种光学玻璃镀膜前的水基清洗剂 |
-
1992
- 1992-05-08 CN CN 92108124 patent/CN1065881A/zh active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1038344C (zh) * | 1993-04-24 | 1998-05-13 | 娄熙南 | 高效消毒灭菌洗衣粉 |
CN1052751C (zh) * | 1995-06-16 | 2000-05-24 | 杨国林 | 清真洗衣粉 |
CN1059074C (zh) * | 1996-10-21 | 2000-12-06 | 谢体生 | 洗涤消毒剂 |
CN102796625A (zh) * | 2012-07-13 | 2012-11-28 | 湖北海力化工科技有限公司 | 一种光学玻璃镀膜前的水基清洗剂 |
CN102796625B (zh) * | 2012-07-13 | 2013-09-11 | 湖北海力化工科技有限公司 | 一种光学玻璃镀膜前的水基清洗剂 |
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