CN106588048A - Steelmaking tundish guard plate and castable therefor - Google Patents
Steelmaking tundish guard plate and castable therefor Download PDFInfo
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- CN106588048A CN106588048A CN201611145578.1A CN201611145578A CN106588048A CN 106588048 A CN106588048 A CN 106588048A CN 201611145578 A CN201611145578 A CN 201611145578A CN 106588048 A CN106588048 A CN 106588048A
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- magnesite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/003—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like with impact pads
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3826—Silicon carbides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
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- Engineering & Computer Science (AREA)
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Abstract
The invention belongs to the technical field of refractory materials and particularly relates to a steelmaking tundish guard plate and a castable therefor. The castable for the steelmaking tundish guard plate disclosed herein is made by mixing, by weight, 50-70% of wasted magnesia-chrome brick particles, 20-30% of sintered magnesium sand, 2-5% of silica powder, 5-8% of aluminum powder, 2-5% of silicon carbide, and 1-2% of stainless steel fiber. As the recycled wasted magnesia-chrome brick is used as a main material, wasted secondary resources are made full use and good environment-protection benefit is achieved; meanwhile, compared with the same industry where fused magnesite is used directly as main aggregate, the guard plate of the invention has improved slag resistance and prolonged life, and has greatly reduced production cost and significant economic and social benefits.
Description
Technical field
The invention belongs to technical field of refractory materials, and in particular to one kind is made steel tundish backplate and its uses castable.
Background technology
After 20 century 70s, the continuous casting process of iron and steel steel-making enterprise is rapidly developed, and is characterized in process speed
Degree is fast, and investment is concentrated, and technology is gradually improved.Whole world continuous casting ratio is only 5.6% within 1970, and to nineteen ninety global continuous casting
62.4% is reached than, the continuous casting ratio of some industrially developed country has exceeded 95%.In recent years in the world many steel mills are real
Sequence casting production is showed.Compared with traditional steel-making die casting process, continuous casting has raising recovery rate of iron and reduces energy expenditure
Superiority, and reduce metals resources and energy consumption meet sustainable development requirement.The realization of sequence casting makes steel-making
Production process simplifies, and flow process shortens, and production efficiency is significantly improved.
Tundish is the intermediate link of STEELMAKING PRODUCTION flow process, and is the connecting points that continuous operation is turned to by intermittently operated.
Tundish is the important ring for improving output of steel and quality as metallurgical reaction, no matter being smoothed out for continuous casting operation,
Or for guarantee molten steel quality suits the requirements, the effect of tundish is very important.Because bakie working lining directly with
Steel contacts, it is desirable to which bakie working lining can reduce the field trash in molten steel, the degree of purity of raising molten steel, and resistance to molten steel and melt
The erosion of slag, makes the time of continuous-casting steel pouring as long as possible, and tundish reduces labor intensity with rear easy disintegration.
Backplate is to use prefabricated component made by castable refractory, and it is mainly used in, and tundish is spacious to be poured and long-time pouring technology,
Tundish impact and impact zone opposing regions are acted on, plays a part of to protect bakie working lining.Pour opening and pour for a long time
During note, tundish impact area domain and shock zone opposing regions are washed away by molten steel and corrode the most serious with slag.
Traditional backplate is directly compared using fused magnesite for main aggregate, and its slag resistance is poor and the life-span is not high, production
Cost is larger.
The content of the invention
The technical problem to be solved is:There is provided that a kind of slag resistance is good, the life-span is high, the relatively low refining of production cost
Steel tundish backplate and its use castable.
The present invention solves the steel-making tundish backplate castable that its technical problem is adopted, by following percentage by weight
Raw material is mixed:Useless magnesite-chrome brick granule 50%~70%, magnesite clinker 20%~30%, silicon powder 2%~5%, aluminum micropowder
5%~8%, carborundum 2%~5%, stainless steel fibre 1%~2%.
It is further that the grade of the useless magnesite-chrome brick granule is by 1mm≤granularity≤3mm, 3mm < granularities≤5mm, 5mm
< granularities≤tri- kinds of 8mm specifications composition, wherein the weight ratio of the useless magnesite-chrome brick granule of 1mm≤granularity≤3mm are 10~20%,
The weight of useless magnesite-chrome brick granule of the weight of the useless magnesite-chrome brick granule of 3mm < granularities≤5mm than 20~25%, 5mm < granularities≤8mm
Amount ratio 20~25%.
It is further, TFe≤1.4% contained by the useless magnesite-chrome brick granule.
It is further that the key component of the useless magnesite-chrome brick granule is MgO >=60%, Cr2O3>=20%, C >=12%,
SiO2≤ 1.2%.
It is further that the magnesite clinker main component is MgO >=80%;The silicon powder main component is SiO2≥
94%;The aluminum micropowder main component is Al2O3>=99%;The carborundum main component is SiC >=94%.
It is further that the steel-making tundish backplate castable is mixed by the raw material of following percentage by weight:
The useless magnesite-chrome brick granule 15% of 1mm≤granularity≤3mm, the useless magnesite-chrome brick granule 20% of 3mm < granularities≤5mm, 5mm < granularities≤
The useless magnesite-chrome brick granule 25% of 8mm, magnesite clinker 27%, silicon powder 3%, aluminum micropowder 5%, carborundum 4%, stainless steel fibre
1%.
It is further that the steel-making tundish backplate castable is mixed by the raw material of following percentage by weight:
The useless magnesite-chrome brick granule 20% of 1mm≤granularity≤3mm, the useless magnesite-chrome brick granule 20% of 3mm < granularities≤5mm, 5mm < granularities≤
The useless magnesite-chrome brick granule 20% of 8mm, magnesite clinker 25%, silicon powder 3%, aluminum micropowder 6%, carborundum 5%, stainless steel fibre
1%.
It is further that the steel-making tundish backplate castable is mixed by the raw material of following percentage by weight:
The useless magnesite-chrome brick granule 18% of 1mm≤granularity≤3mm, the useless magnesite-chrome brick granule 22% of 3mm < granularities≤5mm, grade is 5mm <
The useless magnesite-chrome brick granule 25% of granularity≤8mm, magnesite clinker 23%, silicon powder 2%, aluminum micropowder 5%, carborundum 4%, rustless steel
Fiber 1%.
The present invention solves a kind of steel-making tundish backplate that its technical problem is adopted, and is used by above-mentioned steel-making tundish backplate
Castable is prepared from.
The invention has the beneficial effects as follows:Due to adopting the useless magnesite-chrome brick for reclaiming for primary raw material, make full use of discarded secondary
Resource, serves good environmental benefit, meanwhile, directly use fused magnesite to be main bone in the backplate and the same industry of the present invention
Material is compared, and its slag resistance and life-span also increase, and production cost is greatly lowered, and economic benefit and social benefit are notable.
Specific embodiment
For the defect existing for existing steel-making tundish backplate castable, the present inventor takes full advantage of secondary resource
Useless magnesite-chrome brick granule, so as to provide a kind of new steel-making tundish backplate castable, this castable is mainly by following heavy
The raw material of amount percentage ratio is mixed:Useless magnesite-chrome brick granule 50%~70%, magnesite clinker 20%~30%, silicon powder 2%~
5%th, aluminum micropowder 5%~8%, carborundum 2%~5%, stainless steel fibre 1%~2%.
Specifically, in order that tundish backplate has more preferable effect, the grade of the useless magnesite-chrome brick granule is by 1mm≤grain
Degree≤3mm, 3mm < granularities≤5mm, 5mm < granularities≤tri- kinds of 8mm specifications composition, the wherein useless magnesium chromium of 1mm≤granularity≤3mm
The weight ratio of brick granule is the weight of the useless magnesite-chrome brick granule of 10~20%, 3mm < granularities≤5mm than 20~25%, 5mm < grains
The weight of the useless magnesite-chrome brick granule of degree≤8mm is than 20~25%.
Specifically, because the presence of ferrum can affect the performance of tundish backplate, so the useless magnesite-chrome brick granule for using is being picked
Need that the removal of slag iron part will be contained when selecting, the iron compound being wherein mingled with need to be removed through magnetic separation operation when each grade is processed into,
It is final to control TFe≤1.4% contained by useless magnesite-chrome brick granule.
Specifically, the key component of the useless magnesite-chrome brick granule be MgO >=60%, Cr2O3>=20%, C >=12%, SiO2
≤ 1.2%;The main component of magnesite clinker is MgO >=80%, it is preferred that the main component of magnesite clinker is MgO >=90%;Silicon
The main component of micropowder is SiO2>=94%;The main component of aluminum micropowder is Al2O3>=99%;The main component of carborundum is SiC
>=94%.
In product of the present invention, the component content of each raw material represents percentage by weight.
Aluminum micropowder and magnesite clinker can generate under certain conditions magnesium aluminate spinel, can play good anti-slag effect.
The technological process of preparation of steel-making tundish backplate is:
Raw material selection is carried out first, and raw material selection carries out dispensing, the material for preparing sent in blender and is stirred after completing,
The raw material being stirred is packed, is shipped after packaging to using scene, and be stirred, vibration moulding, the step such as baking.
Useless magnesite-chrome brick used in the present invention needs that slag iron position will be contained in selection and removes, being processed into each grade, plus
The good grade of work need to remove the iron compound being wherein mingled with through magnetic separation operation.
Embodiment 1
Steel-making tundish backplate castable, is mixed by the raw material of following percentage by weight:1mm≤granularity≤3mm
Useless magnesite-chrome brick granule 15%, the useless magnesite-chrome brick granule 20% of 3mm < granularities≤5mm, the useless magnesite-chrome brick of 5mm < granularities≤8mm
Granule 25%, magnesite clinker 27%, silicon powder 3%, aluminum micropowder 5%, carborundum 4%, stainless steel fibre 1%.
The above-mentioned castable for mixing prepares steel-making tundish backplate using conventional method.
This product during tundish use, using temperature up to more than 1500 DEG C, more than use time 800min, valency
Lattice are low compared with like product by 10%.
Properties of product:110 DEG C of bulk densities are more than 2.68g/cm3, and 110 DEG C of drying compressive resistances are more than 35Mpa, 1500 DEG C
Under the conditions of insulation 3 hours after compressive resistance be more than 85Mpa;110 DEG C of drying rupture strengths are more than 5.5Mpa, protect under the conditions of 1500 DEG C
Rupture strength is more than 7.8Mpa after warm 3 hours, and refractoriness is more than 1790 DEG C.
Embodiment 2
Steel-making tundish backplate castable, is mixed by the raw material of following percentage by weight:1mm≤granularity≤3mm
Useless magnesite-chrome brick granule 20%, the useless magnesite-chrome brick granule 20% of 3mm < granularities≤5mm, the useless magnesite-chrome brick of 5mm < granularities≤8mm
Granule 20%, magnesite clinker 25%, silicon powder 3%, aluminum micropowder 6%, carborundum 5%, stainless steel fibre 1%.
The above-mentioned castable for mixing prepares steel-making tundish backplate using conventional method.
This product during tundish use, using temperature up to more than 1500 DEG C, more than use time 800min, valency
Lattice are low compared with like product by 10%.
Properties of product:110 DEG C of bulk densities are more than 2.72g/cm3, and 110 DEG C of drying compressive resistances are more than 40Mpa, 1500 DEG C
Under the conditions of insulation 3 hours after compressive resistance be more than 80Mpa;110 DEG C of drying rupture strengths are more than 4.5Mpa, protect under the conditions of 1500 DEG C
Rupture strength is more than 8Mpa after warm 3 hours, and refractoriness is more than 1790 DEG C.
Embodiment 3
Steel-making tundish backplate castable, is mixed by the raw material of following percentage by weight:1mm≤granularity≤3mm
Useless magnesite-chrome brick granule 18%, the useless magnesite-chrome brick granule 22% of 3mm < granularities≤5mm, grade is useless for 5mm < granularities≤8mm's
Magnesite-chrome brick granule 25%, magnesite clinker 23%, silicon powder 2%, aluminum micropowder 5%, carborundum 4%, stainless steel fibre 1%.
The above-mentioned castable for mixing prepares steel-making tundish backplate using conventional method.
This product during tundish use, using temperature up to more than 1500 DEG C, more than use time 800min, valency
Lattice are low compared with like product by 30%.
Properties of product:110 DEG C of bulk densities are more than 2.85g/cm3, and 110 DEG C of drying compressive resistances are more than 48Mpa, 1500 DEG C
Under the conditions of insulation 3 hours after compressive resistance be more than 95Mpa;110 DEG C of drying rupture strengths are more than 6Mpa, are incubated under the conditions of 1500 DEG C
Rupture strength is more than 9.5Mpa after 3 hours, and refractoriness is more than 1790 DEG C.
Claims (9)
1. tundish backplate castable is made steel, it is characterised in that mixed by the raw material of following percentage by weight:Useless magnesium chromium
Brick granule 50%~70%, magnesite clinker 20%~30%, silicon powder 2%~5%, aluminum micropowder 5%~8%, carborundum 2%~
5%, stainless steel fibre 1%~2%.
2. it is according to claim 1 to make steel tundish backplate castable, it is characterised in that the useless magnesite-chrome brick granule
Grade is made up of 1mm≤granularity≤3mm, 3mm < granularities≤5mm, 5mm < granularities≤tri- kinds of 8mm specifications, wherein 1mm≤granularity
The weight ratio of the useless magnesite-chrome brick granule of≤3mm compares 20 for the weight of the useless magnesite-chrome brick granule of 10~20%, 3mm < granularities≤5mm
The weight of the useless magnesite-chrome brick granule of~25%, 5mm < granularities≤8mm is than 20~25%.
3. it is according to claim 1 to make steel tundish backplate castable, it is characterised in that the useless magnesite-chrome brick granule institute
Containing TFe≤1.4%.
4. it is according to claim 3 to make steel tundish backplate castable, it is characterised in that the useless magnesite-chrome brick granule
Key component be MgO >=60%, Cr2O3>=20%, C >=12%, SiO2≤ 1.2%.
5. it is according to claim 1 steel-making tundish backplate castable, it is characterised in that the magnesite clinker mainly into
It is divided into MgO >=80%;The silicon powder main component is SiO2>=94%;The aluminum micropowder main component is Al2O3>=99%;
The carborundum main component is SiC >=94%.
6. it is according to claim 2 to make steel tundish backplate castable, it is characterised in that by following percentage by weight
Raw material is mixed:The useless magnesite-chrome brick granule 15% of 1mm≤granularity≤3mm, the useless magnesite-chrome brick granule of 3mm < granularities≤5mm
The useless magnesite-chrome brick granule 25% of 20%, 5mm < granularities≤8mm, magnesite clinker 27%, silicon powder 3%, aluminum micropowder 5%, carborundum
4%, stainless steel fibre 1%.
7. it is according to claim 2 to make steel tundish backplate castable, it is characterised in that by following percentage by weight
Raw material is mixed:The useless magnesite-chrome brick granule 20% of 1mm≤granularity≤3mm, the useless magnesite-chrome brick granule of 3mm < granularities≤5mm
The useless magnesite-chrome brick granule 20% of 20%, 5mm < granularities≤8mm, magnesite clinker 25%, silicon powder 3%, aluminum micropowder 6%, carborundum
5%, stainless steel fibre 1%.
8. it is according to claim 2 to make steel tundish backplate castable, it is characterised in that by following percentage by weight
Raw material is mixed:The useless magnesite-chrome brick granule 18% of 1mm≤granularity≤3mm, the useless magnesite-chrome brick granule of 3mm < granularities≤5mm
22%, grade for 5mm < granularities≤8mm useless magnesite-chrome brick granule 25%, magnesite clinker 23%, silicon powder 2%, aluminum micropowder 5%,
Carborundum 4%, stainless steel fibre 1%.
9. it is a kind of to make steel tundish backplate, it is characterised in that in the steel-making by described in any claim in claim 1 to 8
Between bag backplate be prepared from castable.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107892580A (en) * | 2017-12-08 | 2018-04-10 | 攀枝花钢城集团有限公司 | A kind of tundish slag wall castable and its application method |
CN110105074A (en) * | 2019-06-26 | 2019-08-09 | 洛阳科创新材料股份有限公司 | A kind of blowhole inlays magnesium carbonaceous ladle slide gate brick of zirconium plate and preparation method thereof |
CN113416063A (en) * | 2021-06-01 | 2021-09-21 | 海城利尔麦格西塔材料有限公司 | High-temperature-resistant magnesium-chromium castable prepared from magnesium-chromium waste bricks |
CN113860895A (en) * | 2021-11-02 | 2021-12-31 | 江苏嘉耐高温材料股份有限公司 | Circular economy type slag stopping wall and preparation method thereof |
CN115650703A (en) * | 2022-11-04 | 2023-01-31 | 辽宁利尔镁质合成材料股份有限公司 | Magnesium castable and preparation method thereof |
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钟黎声 等: ""废镁铬砖加入量对镁质浇注料性能的影响"", 《硅酸盐学报》 * |
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CN110105074A (en) * | 2019-06-26 | 2019-08-09 | 洛阳科创新材料股份有限公司 | A kind of blowhole inlays magnesium carbonaceous ladle slide gate brick of zirconium plate and preparation method thereof |
CN113416063A (en) * | 2021-06-01 | 2021-09-21 | 海城利尔麦格西塔材料有限公司 | High-temperature-resistant magnesium-chromium castable prepared from magnesium-chromium waste bricks |
CN113860895A (en) * | 2021-11-02 | 2021-12-31 | 江苏嘉耐高温材料股份有限公司 | Circular economy type slag stopping wall and preparation method thereof |
CN115650703A (en) * | 2022-11-04 | 2023-01-31 | 辽宁利尔镁质合成材料股份有限公司 | Magnesium castable and preparation method thereof |
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Application publication date: 20170426 |