CN106587598B - A kind of coloring production method of bluish grey glass - Google Patents

A kind of coloring production method of bluish grey glass Download PDF

Info

Publication number
CN106587598B
CN106587598B CN201611266565.XA CN201611266565A CN106587598B CN 106587598 B CN106587598 B CN 106587598B CN 201611266565 A CN201611266565 A CN 201611266565A CN 106587598 B CN106587598 B CN 106587598B
Authority
CN
China
Prior art keywords
glass
weight
parts
bluish grey
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201611266565.XA
Other languages
Chinese (zh)
Other versions
CN106587598A (en
Inventor
刘柏辉
张建辉
谭果纯
赵海东
吴信军
袁丽娜
周红
何成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGXING KIBING GLASS Co Ltd
Original Assignee
CHANGXING KIBING GLASS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGXING KIBING GLASS Co Ltd filed Critical CHANGXING KIBING GLASS Co Ltd
Priority to CN201611266565.XA priority Critical patent/CN106587598B/en
Publication of CN106587598A publication Critical patent/CN106587598A/en
Application granted granted Critical
Publication of CN106587598B publication Critical patent/CN106587598B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/02—Compositions for glass with special properties for coloured glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of coloring production methods of bluish grey glass, it include: 1) to be added to the raw material of colorant after mixing in the raw material of parent glass, it stirs evenly, then it puts into melting furnaces, fusing atmosphere before controlling melting furnaces hot spot is weak oxide atmosphere, and it is micro- reducing atmosphere that fusing atmosphere is kept after hot spot, and controlling its clarifying temp is 1500 DEG C~1525 DEG C, 950 DEG C -1000 DEG C of cooling temperature, obtain pewter glass metal；2) pewter glass metal is sent into tin groove forming, obtains bluish grey glass.The present invention designs bluish grey glass by ion coloring and colour mixture principle, due to new colorant formulations, design by formula with combine, improve certain colorants in formula anomalous trichromatism problem so that bluish grey glass of the invention has the bluish grey tone of more beautiful.

Description

A kind of coloring production method of bluish grey glass
Technical field
The present invention relates to a kind of coloring production methods of bluish grey glass.
Background technique
Glass is as daily construction material, with the development of society, people require to grow to even greater heights to it.In addition to common glass Glass, the glass product of many high-tech contents also appear in daily life one after another.The glass product of various colors is also continuous Meets the needs of designer's inspiration, the glass product for having both color and function is also to need to produce by the continuous research and development of producer It is raw.
The common coloring element of body-tinted glass has iron, cobalt, chromium, selenium, manganese, titanium etc., glass can be presented certain Color.For example, ferrous iron can make glass that blue be presented, ferric iron is yellow, and chromium is then green etc., usual group of these coloring elements Close use so that its respectively color mutually compensates, and be finally reached expected tone.And coloured glass is in use, except that need to consider it Outside tone and appearance, it is often more important that need to consider its optical property, such as visible light transmittance, infrared and ultraviolet absorptivity.Coloring The selection of agent and ratio collocation, glass component itself, technology for making glass etc. are the weights for influencing glass color and optical property Want factor.
In the prior art, blue tinted glass and smoked glass are all classical glass color all the time, in order to obtain allusion quotation The pewter glass of refined beauty, we carry out entire pewter glass whole by the research to its body-tinted glass formula Body combines design, while the output for realizing product is controlled by production technology, then obtains with graceful bluish grey color Glass.
Summary of the invention
In view of the above-mentioned problems, the present invention provides a kind of coloring production method of bluish grey glass, make glass have both blue with The graceful color of the classics of grey.
The technical solution adopted by the present invention is that:
A kind of coloring production method of bluish grey glass, the raw material that it is used is parent glass and colorant, the basis Glass includes the raw material of following parts by weight: the SiO of 72.2-73.0 parts by weight2, 0.1-1.0 parts by weight Al2O3, 13.3-14.5 weight Measure the Na of part2The K of O, 0.02-1.2 parts by weight2The MgO of the CaO of O, 7.0-9.0 parts by weight, 3.0-5.0 parts by weight, 0.1-0.5 weight Measure the SO of part3；The colorant includes the raw material of following parts by weight: the Fe of 0.11-0.70 parts by weight2O3, 0.0001-0.05 The TiO of parts by weight2, no more than the Co of 0.1 parts by weight3O4, no more than the Se of 0.1 parts by weight；
This method comprises:
1) raw material of colorant is added in the raw material of parent glass after mixing, is stirred evenly, then investment is molten In kiln, the fusing atmosphere before controlling melting furnaces hot spot is weak oxide atmosphere, and it is micro- reducing atmosphere that fusing atmosphere is kept after hot spot, and And controlling its clarifying temp is 1500 DEG C~1525 DEG C, 950 DEG C -1000 DEG C of cooling temperature, obtains pewter glass metal；
2) pewter glass metal is sent into tin groove forming, obtains bluish grey glass.
Preferably, the compressed air oxygen content in port before the hot spot of the melting furnaces is 5-6%, the melting furnaces hot spot Preceding fusion temperature is 1500 DEG C~1550 DEG C.
Preferably, the clarifying temp in the melting furnaces is 1505 DEG C, cooling temperature is 978 DEG C, fusion temperature 1528 ℃。
Beneficial effects of the present invention:
1, bluish grey glass is designed by ion coloring and colour mixture principle and passes through formula due to new colorant formulations Design with combine, improve certain colorants in being formulated anomalous trichromatism problem so that bluish grey glass of the invention is with more beautiful Bluish grey tone；
2, Na in parent glass2O content is 13.3-14.5, and parts by weight are equivalent to the Na in simple glass component2O+K2O two The total content of 13%~15% parts by weight of person, the Na of bluish grey glass2Ratio shared by O content is higher, promotes glass metal Fe3+Contain Amount also increases；
3, the fusing atmosphere before melting process control melting furnaces hot spot is weak oxide atmosphere, i.e., the compression of port before control hot spot Oxygen content in air is 5%~6%, while controlling fusion temperature before its hot spot is 1500 DEG C~1550 DEG C, to increase in glass metal Fe3+Content, and guarantee simple substance Se pure purples is colored as to glass metal；
4, it is micro- reducing atmosphere that fusing atmosphere is kept after melting process control melting furnaces hot spot, and controls its clarifying temp It is 1500 DEG C~1525 DEG C, 950 DEG C -1000 DEG C of cooling temperature, Co3O4There is [CoO in glass metal4] group, high temperature melting with And be conducive to the generation of the group under reducing atmosphere；
5, when in glass metal ferric ion content increase, weaker coloring so that glass metal be in chartreuse, it is another Kind colouring material TiO2Addition, ferric ion and Co can be improved3O4Pigmentation；
6, pass through the Se and Fe in control colorant2O3Can make glass metal purple respectively and yellow green, the two it is mutual Complementary color recalls Dark grey；And control colorant Co3O4There is [CoO in glass metal4] group is blue, by molten in glass Kiln obtains pewter glass metal after carrying out fusing colour mixture.
Specific embodiment
The present invention is described in further detail below by specific embodiment.
Embodiment 1
The bluish grey glass of 6mm thickness is produced, the raw material of use is parent glass and colorant, and the raw material of parent glass is by as follows Parts by weight weigh:
The raw material of colorant is weighed by following parts by weight:
The raw material of above-mentioned colorant is added in the raw material of parent glass after mixing, is stirred evenly, then put into In melting furnaces, fusing atmosphere is weak oxide atmosphere before controlling melting furnaces hot spot, i.e., the compressed air oxygen content of port is 5% before hot spot, Fusion temperature before melting furnaces hot spot is 1500 DEG C~1550 DEG C, after glass melter carries out fusing colour mixture, is kept after melting furnaces hot spot Fusing atmosphere is micro- reducing atmosphere, and controlling its clarifying temp is 1500 DEG C~1525 DEG C, 950 DEG C -1000 of cooling temperature DEG C, Co3O4There is [CoO in glass metal4] group, high temperature melting and the generation for being conducive to the group under reducing atmosphere, Obtained pewter glass metal is bluish grey glass, light transmittance 44.9% by tin groove forming.
Embodiment 2
The bluish grey glass of 4mm thickness is produced, the raw material of use is parent glass and colorant, and the raw material of parent glass is by as follows Parts by weight weigh:
The raw material of colorant is weighed by following parts by weight:
The raw material of above-mentioned colorant is added in the raw material of parent glass after mixing, is stirred evenly, then put into In melting furnaces, fusing atmosphere is weak oxide atmosphere before controlling melting furnaces hot spot, i.e., the compressed air oxygen content of port is 6% before hot spot, Fusion temperature before melting furnaces hot spot is 1500 DEG C~1550 DEG C, after glass melter carries out fusing colour mixture, is kept after melting furnaces hot spot Fusing atmosphere is micro- reducing atmosphere, and controlling its clarifying temp is 1500 DEG C~1525 DEG C, 950 DEG C -1000 of cooling temperature DEG C, Co3O4There is [CoO in glass metal4] group, high temperature melting and the generation for being conducive to the group under reducing atmosphere, Obtained pewter glass metal is bluish grey glass, light transmittance 52.9% by tin groove forming.
The bluish grey glass as made from embodiment 1 and embodiment 2 has following optical performance data:
As can be seen from the above table, bluish grey glass coloration produced by the present invention is uniform, and color is graceful, and optical electivity range is wide, Various colors increase aesthetic feeling.

Claims (3)

1. a kind of coloring production method of bluish grey glass, which is characterized in that the raw material that it is used is parent glass and colorant, institute The parent glass stated includes the raw material of following parts by weight: the SiO of 72.2-73.0 parts by weight2, 0.1-1.0 parts by weight Al2O3, The Na of 13.3-14.5 parts by weight2The K of O, 0.02-1.2 parts by weight2The CaO of O, 7.0-9.0 parts by weight, 3.0-5.0 parts by weight The SO of MgO, 0.1-0.5 parts by weight3；The colorant includes the raw material of following parts by weight: 0.11-0.70 parts by weight Fe2O3, the TiO of 0.0001-0.05 parts by weight2, no more than the Co of 0.1 parts by weight3O4, no more than the Se of 0.1 parts by weight；
This method comprises:
1) raw material of colorant is added in the raw material of parent glass after mixing, is stirred evenly, then put into melting furnaces, Fusing atmosphere before controlling melting furnaces hot spot is weak oxide atmosphere, and it is micro- reducing atmosphere that fusing atmosphere is kept after hot spot, and is controlled Making its clarifying temp is 1500 DEG C~1525 DEG C, 950 DEG C -1000 DEG C of cooling temperature, obtains pewter glass metal；
2) pewter glass metal is sent into tin groove forming, obtains bluish grey glass.
2. a kind of coloring production method of bluish grey glass according to claim 1, which is characterized in that the hot spot of the melting furnaces Compressed air oxygen content in preceding port is 5-6%, and the fusion temperature before the melting furnaces hot spot is 1500 DEG C~1550 DEG C.
3. a kind of coloring production method of bluish grey glass according to claim 2, which is characterized in that clear in the melting furnaces Clear temperature is 1505 DEG C, and cooling temperature is 978 DEG C, and fusion temperature is 1528 DEG C.
CN201611266565.XA 2016-12-31 2016-12-31 A kind of coloring production method of bluish grey glass Active CN106587598B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611266565.XA CN106587598B (en) 2016-12-31 2016-12-31 A kind of coloring production method of bluish grey glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611266565.XA CN106587598B (en) 2016-12-31 2016-12-31 A kind of coloring production method of bluish grey glass

Publications (2)

Publication Number Publication Date
CN106587598A CN106587598A (en) 2017-04-26
CN106587598B true CN106587598B (en) 2019-07-12

Family

ID=58581868

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611266565.XA Active CN106587598B (en) 2016-12-31 2016-12-31 A kind of coloring production method of bluish grey glass

Country Status (1)

Country Link
CN (1) CN106587598B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108017278B (en) * 2017-12-15 2019-04-09 长兴旗滨玻璃有限公司 A kind of bluish grey coated glass and its manufacturing method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0452207A1 (en) * 1990-04-13 1991-10-16 Saint-Gobain Vitrage Coloured glass composition and glazing produced therewith
US5089444A (en) * 1988-05-31 1992-02-18 Ngk Spark Plug Co., Ltd. Method of producing colored crystallized glass
EP0536049A1 (en) * 1991-10-03 1993-04-07 Saint-Gobain Vitrage International Colored glass composition for the manufacture of glazing
WO2014013242A1 (en) * 2012-07-16 2014-01-23 Pilkington Group Limited Tinted float glass
CN103819088A (en) * 2014-01-09 2014-05-28 株洲醴陵旗滨玻璃有限公司 Gray glass and preparation method thereof as well as equipment for preparing gray glass
CN105753317A (en) * 2015-12-30 2016-07-13 中国建材国际工程集团有限公司 Batch for ocean blue aluminosilicate glass and method for manufacturing same by aid of batch

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5089444A (en) * 1988-05-31 1992-02-18 Ngk Spark Plug Co., Ltd. Method of producing colored crystallized glass
EP0452207A1 (en) * 1990-04-13 1991-10-16 Saint-Gobain Vitrage Coloured glass composition and glazing produced therewith
EP0536049A1 (en) * 1991-10-03 1993-04-07 Saint-Gobain Vitrage International Colored glass composition for the manufacture of glazing
WO2014013242A1 (en) * 2012-07-16 2014-01-23 Pilkington Group Limited Tinted float glass
CN103819088A (en) * 2014-01-09 2014-05-28 株洲醴陵旗滨玻璃有限公司 Gray glass and preparation method thereof as well as equipment for preparing gray glass
CN105753317A (en) * 2015-12-30 2016-07-13 中国建材国际工程集团有限公司 Batch for ocean blue aluminosilicate glass and method for manufacturing same by aid of batch

Also Published As

Publication number Publication date
CN106587598A (en) 2017-04-26

Similar Documents

Publication Publication Date Title
JP5183600B2 (en) Blue green glass
CN102503122B (en) Leadless, cadmium-free and strontium-free glass and manufacture process thereof
JPS6344696B2 (en)
CN106186697A (en) A kind of stove an ancient unit of weight glaze
CN108409139A (en) A kind of stove chun glaze and preparation method thereof
CN105985018A (en) Aluminosilicate glass, and preparation method and application thereof
CN112624618B (en) Colored glass ceramics and preparation method thereof
CN107572822A (en) A kind of pottery plum green glaze and preparation method thereof
CN105271733B (en) Khaki glass that a kind of chromium manganese is co-doped with and its preparation method and application
US5070044A (en) Brightly colored canasite glass-ceramics
CN106587598B (en) A kind of coloring production method of bluish grey glass
TW201431816A (en) Color-strikable glass containers
JPH05193983A (en) Transparent glass and glass goods
CN105686955B (en) A kind of zirconium oxide all-ceramic crown porcelain powders and preparation method thereof
CN106746618A (en) A kind of ecru devitrified glass and its preparation method and application
WO2017185288A1 (en) Aluminosilicate glass and preparation method therefor, and glass plate
CN109592902A (en) A kind of pottery moon white glaze and preparation method thereof
CN106587612A (en) Glass composition and preparation method thereof
CN109704573A (en) Red glass product and preparation method thereof
CN109502974A (en) Blue tinted glass product
CN114057394A (en) Green jade glass and preparation method thereof
CN109293243A (en) A kind of your lavender grey glaze of an ancient unit of weight
JP7060969B2 (en) Yellow-green glass and yellow-green glass container
US4235634A (en) Colored soda-lime glassware
CN103395986B (en) Manufacturing process of high-brightness chromium-containing glass

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant