One kind is without silicon hydrotherapy element hair care composition
Technical field
The invention belongs to daily cosmetics field, is related to one kind without silicon hydrotherapy element hair care composition.
Background technology
At present, such as send out in film, hair conditioner, hydrotherapy element etc. in hair care product, silicone oil is still the one of most extensive addition
Plant hair conditioner.The silicone oil of higher molecular weight is a kind of extremely soft and smooth material, its have good hydrophobicity and
Extremely low surface tension, can be in the space for being attached to hair hair scale piece and very soft and suitable in one layer of hair surface formation
Sliding thin film, makes the submissive easy comb of hair.However, silicone oil is water insoluble, there is very strong tack, be easily deposited on scalp and block hair
Capsule, the problems such as cause fuel-displaced, alopecia.Additionally, because the characteristics of silicone oil has bio-refractory, for a long time using meeting to environment
Pollute.
At present, part cosmetics company develops the shampoo without silicone oil or hair products.However, big on the market
It is partial without silicone oil hair product, its moisturizing and smooth effect are limited, and such as the shampoo without silicone oil uses puckery sense
Feel, it is dry withered short-tempered using back.
Or, the hair products without silicone oil substitute silicone oil by other greases, get the effect of lubrication.Such as Chinese patent
105380831 moisten hair by the oils and fatss or oils and fatss derivant of the non-silicone oil of addition 1-10%, and for example Chinese patent
105796440 are prepared without silicone oil hair products by extracting natural Ah's glycerol.Add other greases and substitute silicone oil, although have suitable
The effect of sliding moisturizing, however, substantial amounts of grease has used greasy feeling, is not particularly suitable for oily hair, and some is salubrious
Then cost is too high for crude vegetal.
On market, it is difficult to there are a hair products without silicon, can have good moistness, moisture retention, while clearly,
And damaged hair can be repaired.
The content of the invention
One of the object of the invention is to provide a kind of Haircare composition of not silicate-containing oil.
The two of the object of the invention be provide one kind can effectively smooth hair, improve the Haircare composition of Hair setting degree.
The three of the object of the invention are to provide a kind of salubrious Haircare composition.
The present invention also aims to provide a kind of Haircare composition that can repair damaged hair.
The purpose of the present invention is realized by following technological means:
The invention provides a kind of Haircare composition, which contains hydroxypropyl-trimethyl ammonium chloride Mel, trimethyl glycine
With Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein.
Hydroxypropyl-trimethyl ammonium chloride Mel, trimethyl glycine and Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein
Percentage by weight in whole composition system is followed successively by 0.01~10.0%, 0.01~10.0%, 0.01~10.0%;According to
Less preferred 0.1~2.0%, 0.1~2.0%, 0.1~1.0%.
Hydroxypropyl-trimethyl ammonium chloride Mel can bring superior moist soft and smooth effect to hair, and it is contained by disaccharide
The lightweight Mel for having the abnormal smells from the patient of hydroxyl little is formed with hydroxyl trimethyl ammonium chloride derivatives reaction.Hydroxypropyl-trimethyl ammonium chloride honeybee
Honey has following characteristics:1) it is salubrious not sticky:There is hair products addition Mel to moisten conditioning hair, natural Mel contains
75% disaccharidase, it is very sticky, and also the moistening effect wetting agent more common than some such as glycerol, Propylene Glycol etc. is poor.Keeping honey
On the basis of the natural nourishing effect of sugar, which is carried out quaternised modified, connect the quaternary ammonium chain of low-molecular-weight, so as to eliminate Mel
Viscous sense;2) affinity is strong:Hydroxypropyl-trimethyl ammonium chloride Mel contains the quaternary ammonium structure attracting with the negative charge of mankind's skin,
Effectively increase affinity;3) moistening effect is good:Hydroxypropyl-trimethyl ammonium chloride Mel can be bonded the moisture in environment, effectively carry
The high moistening effect to hair, and, the molecular weight of hydroxypropyl-trimethyl ammonium chloride Apiss is little, with good penetrating power,
Prolonged moisturizing is provided for hair, result of study shows, twice of its moistening effect equivalent to glycerol.
Hydroxypropyl-trimethyl ammonium chloride Apiss can be effectively improved the wet comb effect of hair, make hair smooth, improve hair
Gloss, especially for damaged hair, is also either that non-rinse-off products all have obviously effect for washing-off type.
Trimethyl glycine, is a kind of natural, edible aminoacid completely, in beet root, Herba Spinaciae, Broccoli and first
All contain the material in shell class material such as shrimp etc., trimethyl glycine is carried from the molasses of beet root using color analysis isolation technics
Take obtained all-natural product.
Trimethyl glycine has the performance of unique moisturizing and protection cell membrane, and smooth skin sense as silk can be reduced and be matched somebody with somebody
The viscous sense of side, raising spreadability, are widely used in all kinds of cosmetics.
Trimethyl glycine can increase dissolubility of the active ingredient in water so that matching somebody with somebody containing salicylic acid and allantoin
Dissolve at room temperature side.Additionally, trimethyl glycine can also lower fruit acid formula zest.Improve thickened systems and emulsification system
Stability, can as stabilizer be used for formula in.
Trimethyl glycine is easily infiltrated into inside hair, can effectively supplement the part ammonia that keratin is lost in because being damaged
Base acid, improves hair quality microfibre, strengthens hair toughness.
Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein is, with hydrolyzed wheat and quaternary ammonium salt as primary raw material, to pass through
The nutrition used for cosmetic of Modern biochemical technique preparation such as the removal of impurity, decolouring, de- abnormal flavour, quaternized, concentration, allotment, sterilization,
The hair products such as moisturizing, film forming and conditioning.It can form protein protection film in hair surface, protect hair, and preferential in head
Damaged part absorption is sent out, is had good repair to hair, the pulling force tonicity and elasticity of hair fiber can be significantly increased, can be put down
Sliding hair structure, strengthens hair gloss, texture and compliance, hence it is evident that improve that hair is dry, wet cardability.
Used as preferred embodiment, Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein mean molecule quantity is less than
3000Da.The Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein of this molecular weight ranges preferably can be infiltrated into inside hair,
Hair is supplemented because being damaged be lost in keratoprotein, is improved hair quality microfibre, is strengthened hair toughness.
The Haircare composition of the present invention, also contains aqueous carrier, and aqueous carrier contains quaternary ammonium salt and fatty alcohol.
Quaternary ammonium salt is in CTAB, stearyl trimethyl ammonium chloride and behenyl base trimethyl ammonium chloride
One or more combination.Further, percentage by weight of the quaternary ammonium salt in whole composition system is 0.5~2.5%;It is excellent
Select 1.0~2.0%.
One or more combination of the fatty alcohol in spermol, stearyl alcohol and behenyl alcohol.Further, fatty alcohol is whole
Percentage by weight in individual composition system is 1.0~8.0%;It is preferred that 3.0~5.0%.
Aqueous carrier also contains preservative, essence and soda acid blender such as citric acid.Remaining component of aqueous carrier is water.
Described preservative is not particularly limited, the preservative commonly used in being selected from Haircare composition.
In an embodiment of the present invention, described preservative is selected from phenoxyethanol.
The Haircare composition of the present invention can also contain various active composition, such as various extracted form natural plant elite, champignon
Ion, natural moist Moisture factor etc., as long as do not affect the property of our invention Haircare composition add.
Present invention also offers the preparation method of above-mentioned hair care compositions, specifically comprises the steps of:
1) in oil phase pot, quaternary ammonium salt and fatty alcohol is mixed, 70~80 DEG C are heated to;
2) in water phase pot, water is mixed with trimethyl glycine, 70~80 DEG C are heated to;
3) under the conditions of 70~80 DEG C, by step 1) mixture add step 2) mixture in, stir homogenizing;
4) by step 3) mixture when being cooled to 45~50 DEG C, add hydroxypropyl-trimethyl ammonium chloride Apiss and lauryl
Dimethyl Ammonium Hydroxypropyl Hydrolyzed Wheat albumen, stirs;
5) by step 4) mixture when being cooled to 40~45 DEG C, add citric acid, preservative and essence, stir i.e.
Can.
It is known in the art that hydroxypropyl-trimethyl ammonium chloride Mel, trimethyl glycine are respectively provided with moistening effect, invention Crinis Carbonisatus
Now, when hydroxypropyl-trimethyl ammonium chloride Mel, trimethyl glycine and Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein are multiple
Timing, can significantly increase moistening effect, make hair smooth, hence it is evident that improve the dry of hair, wet cardability.Its moisturizing smoothness can
The hair products of silicate-containing oil on the market are reached, even surmounted, and there can be salubrious property, while impaired hair quality can be repaired.
The beneficial effect that the present invention is obtained:
1) Haircare composition of the invention does not contain silicone oil, by hydroxypropyl-trimethyl ammonium chloride Mel, the sweet ammonia of trimethyl
Acid, the compounding of Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein, effectively collaboration enhance the moisturizing effect of Haircare composition
Really, make the smooth easy combing of hair.
2) hydroxypropyl-trimethyl ammonium chloride Mel, trimethyl glycine, Lauryldimonium Hydroxypropyl base hydrolyzed wheat egg
White compounding, instead of the silicone oil or other oils and fatss in existing hair products, and remaining component is salubrious quality, overcomes
The existing hair products greasy thick and heavy problem that silicone oil are substituted with other oils and fatss.
3) Haircare composition of the invention contains natural amino acid trimethyl glycine and Lauryldimonium Hydroxypropyl base
Hydrolyzed wheat protein, the hair to being damaged have dual repairing effect, can significantly increase the pulling force tonicity and elasticity of hair fiber.
Description of the drawings
The hair state diagram under an electron microscope being damaged after Fig. 1 hair dyeings
Fig. 2 is using the hair state diagram under an electron microscope after the compositionss cleaning once of comparative example of the present invention 4
Fig. 3 is using the hair state diagram under an electron microscope after the combination E cleanings once of the embodiment of the present invention 1
The hair state diagram under an electron microscope that Fig. 4 is cleaned after five times using the combination E of the embodiment of the present invention 1
Specific embodiment
Technical scheme is further illustrated below by way of specific embodiment, specific embodiment is not represented to this
The restriction of bright protection domain.Other people still fall within this according to some nonessential modifications and adjustment that theory of the present invention is made
Bright protection domain.
A kind of 1 Haircare composition of embodiment
Related component count by weight percentage, unless otherwise stated.Additionally, being suitable for composition is trade name or INCI
Title.
Table 1
Preparation method:
1) in oil phase pot, quaternary ammonium salt and fatty alcohol is mixed, 70~80 DEG C are heated to;
2) in water phase pot, water is mixed with trimethyl glycine, 70~80 DEG C are heated to;
3) under the conditions of 70~80 DEG C, by step 1) mixture add step 2) mixture in, stir homogenizing;
4) by step 3) mixture when being cooled to 45~50 DEG C, add hydroxypropyl-trimethyl ammonium chloride Apiss and lauryl
Dimethyl Ammonium Hydroxypropyl Hydrolyzed Wheat albumen, stirs;
5) by step 4) mixture when being cooled to 40~45 DEG C, add citric acid, preservative and essence, stir i.e.
Can.
Comparative example 1-6
Table 2
Preparation method is with embodiment 1.
2 performance test of embodiment
1. moisturizing degree test
Moisturizing degree method of testing:12 beam hair quality identical hairs are taken, each topknot quality is 10g, and length is 30cm, is first used
Hair is cleaned up and is dried by benchmark cleaning solution (10% sodium laureth sulfate solution).Per beam hair respectively with applying
Give the Haircare composition of combination A-F and comparative example 1-6, room temperature to clean up after stopping 15 minutes, 40 are dried in 65 DEG C of drying baker
Weight m of hair is tested after minute1, then hair is positioned over into baking 30 minutes in 180 DEG C of drying baker, test the weight of now hair
Amount m2, by formula:Moisturizing degree=(m1-m2)/m2× 100%, water containing ratio is combined after obtaining different hair washing water process.
2. combing power is determined
Method of testing:
(1) selection of topknot:36 true man's standard topknots are chosen, each topknot quality is 10g, and length is 30cm, standby;
(2) topknot is processed:10% sodium laureth sulfate solution is prepared, whole topknots are repeatedly clear with the solution
Wash three times, suitably dry, it is standby;
(3) initial combing power is determined:The combing power of wet per beam hair is determined using combing instrument:Per beam hair test three
It is secondary, average, record all topknot measurement data, obtain wet combing power WS0, hair natural air drying, then with same method
Determine topknot hair drying comb reason work(WG0;
(3) Compound mixed solution:Collocation method according to the present composition prepare respectively example A in above Tables 1 and 2~
The Haircare composition of F compositionss and comparative example 1-6,45 DEG C of water bath heat preservation;
(4) topknot immersion:36 beam topknots in (3) are separately immersed in the middle of each compositionss of the above, each mixing immersion
3 standard topknots of bubble, soak time are 10 minutes.
(5) after nursing, combing power is determined:Immersion is finished, and topknot is suitably rushed and dries moisture, presses (3) using combing instrument
Method determine wet combing power WS1, hair natural air drying, then topknot hair drying comb reason work(W is determined with same methodG1, by institute
In topknot natural air drying, hair drying comb reason work(W is determined using combing instrumentG1;
Wet combing power reduction=(WS0-WS1)/WS0* 100%
Hair drying comb manages work(reduction=(WG0-WG1)/WG0* 100%
Test result:
Table 3
Combination |
Moisturizing degree (%) |
Wet combing power reduces (%) |
Hair drying comb reason work(reduces (%) |
A |
7.2 |
73.5 |
48.2 |
B |
6.3 |
69.3 |
48.9 |
C |
7.3 |
75.6 |
48.8 |
D |
6.9 |
72.8 |
49.2 |
E |
7.0 |
73.4 |
52.0 |
F |
5.1 |
76.5 |
49.2 |
Comparative example 1 |
4.9 |
56.8 |
45.3 |
Comparative example 2 |
4.5 |
63.4 |
47.9 |
Comparative example 3 |
3.1 |
22.5 |
15.4 |
Comparative example 4 |
2.5 |
20.7 |
11.5 |
Comparative example 5 |
4.5 |
38.6 |
23.2 |
Comparative example 6 |
6.5 |
72.3 |
49.3 |
Experimental result:As known from Table 3, the present invention is containing hydrotherapy element (the sweet ammonia of hydroxypropyl-trimethyl ammonium chloride Mel, trimethyl
Acid, Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein) compositionss are substantially carried for the moisturizing degree and combing power of hair have
Rise, whole structure is compared favourably with siliceous hair conditioner (comparative example 6).Comparative example 1-4 without hydroxypropyl-trimethyl ammonium chloride Mel,
Any one or a few in trimethyl glycine, Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein, even if keeping hydrotherapy
Under the premise of combination F identicals in the percent of total and embodiment 1 of element, which is also remote with the reduction of combing power for moisturizing degree is lifted
Not as the present composition, especially comparative example 3 and comparative example 4.It can be seen that, hydroxypropyl-trimethyl ammonium chloride Mel, trimethyl are sweet
Propylhomoserin is with Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein compounding with collaboration moisturizing, the effect of smooth hair.
3. hair surface microstructure observation
Test object:From same tester, the three beams hair dyeing at same position impaired hair A, B, C.
Method of testing:
Using dye of positive ion B (cationic Rhodamine B) labelling hair, which can be with the cystine two in hair
Sulfide linkage is combined, and makes hair dye redness.
First 3 beam topknots are cleaned with 10% SLES (sodium lauryl ether sulphates) solution, make topknot maintain space state, point
Do not test.
Hair A is cleaned once using the compositionss (without hydrotherapy element) of comparative example of the present invention 4,
Hair B is cleaned once using the combination E (containing hydrotherapy element) of the embodiment of the present invention 1;
Hair C is cleaned once using the combination E (containing hydrotherapy element) of the embodiment of the present invention 1;
Observed under electron microscope is put in respectively.
Experimental result is shown in Fig. 1-Fig. 4.
Only the state under an electron microscope of the impaired topknot after SLES cleanings is shown in Fig. 1, and its hair scale piece is to tilt,
When A, B topknot (is shown in Fig. 2 and Fig. 3) respectively Jing after once cleaning, it can be seen that the iridescent of B is substantially shallow than A, it was demonstrated that present invention combination
Thing more effectively can be adsorbed onto on hair, and hair damaged part is repaired.The color of C is more shallow than B, it was demonstrated that this is used for multiple times
Inventive composition, effect become apparent from.Compositionss prepared by the present invention can effectively repair impaired hair, smooth hair scale piece.