CN106571236A - 一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料 - Google Patents
一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料 Download PDFInfo
- Publication number
- CN106571236A CN106571236A CN201610929776.0A CN201610929776A CN106571236A CN 106571236 A CN106571236 A CN 106571236A CN 201610929776 A CN201610929776 A CN 201610929776A CN 106571236 A CN106571236 A CN 106571236A
- Authority
- CN
- China
- Prior art keywords
- palygorskite
- carbon nano
- parts
- electrode material
- spinning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910052625 palygorskite Inorganic materials 0.000 title claims abstract description 26
- 229920000767 polyaniline Polymers 0.000 title claims abstract description 26
- 239000007772 electrode material Substances 0.000 title claims abstract description 18
- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 239000002041 carbon nanotube Substances 0.000 title claims abstract description 14
- 229910021393 carbon nanotube Inorganic materials 0.000 title claims abstract description 14
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 14
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims abstract description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 7
- MIOPJNTWMNEORI-UHFFFAOYSA-N camphorsulfonic acid Chemical compound C1CC2(CS(O)(=O)=O)C(=O)CC1C2(C)C MIOPJNTWMNEORI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 6
- 239000002048 multi walled nanotube Substances 0.000 claims abstract description 6
- 150000002500 ions Chemical class 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000009987 spinning Methods 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 3
- 239000006227 byproduct Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000005192 partition Methods 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000003990 capacitor Substances 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 6
- 239000003792 electrolyte Substances 0.000 abstract description 5
- 239000012528 membrane Substances 0.000 abstract description 3
- 238000009792 diffusion process Methods 0.000 abstract description 2
- 238000009826 distribution Methods 0.000 abstract description 2
- -1 polyoxyethylene Polymers 0.000 abstract description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- 230000008569 process Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229910021389 graphene Inorganic materials 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 229910003481 amorphous carbon Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000005087 graphitization Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000006396 nitration reaction Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
本发明公开了一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料，由下列重量份的原料制成：多壁碳纳米管10‑12、十二烷基硫酸钠1.5‑1.6、去离子水适量、无水乙醇适量、氯仿适量、聚氧化乙烯14‑15、混旋樟脑磺酸12‑13、坡缕石0.2‑0.3、1mol/L的盐酸溶液适量、苯胺10‑12、过硫酸铵12.6‑1.3。本发明静电纺纤维膜具有优异的孔隙分布，这种结构能为电解质离子的扩散提供良好的通道，具有良好的比电容，用此电极材料制成的超级电容器电化学性能优异。
Description
技术领域
本发明涉及电容器技术领域，尤其涉及一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料。
背景技术
超级电容器又称电化学电容器，具有功率密度大、循环寿命长、维护简便以及成本相对低廉等特点。超级电容器具有比传统介电电容器更大的能量密度和比电池更高的功率密度，在应急电源、混合动力、数码产品、电子通讯等领域有广阔的应用前景。碳纳米管自从1991年被发现以来, 由于具有优异的力学性能、热学性能、 导电性能, 而成为科学家研究的热点。碳纳米管是理想的复合材料添加相, 具有高达1000以上的长径比, 同时由于sp2轨道杂化形成大量离域p电子, 导电性能优异。聚苯胺作为超级电容器导电性聚合物的电极材料，由于易于合成、良好的环境稳定性、高导电性等优点，已被广泛研究应用。然而，聚苯胺因为体积变化大和较差的循环充电/放电能力等缺点，限制了其在超级电容器电极材料方面的应用。这些问题可以通过将聚苯胺与碳基纳米材料合并加以解决，从而实现电化学双层电容器和赝电容电容器的协同作用。因此，大比表面积和良好导电性的纳米碳材料被用作支持材料以获得高性能和长循环寿命的复合电极。
《碳纳米管/聚苯胺/石墨烯复合纳米碳纸及其电化学电容行为》一文中通过真空抽滤的方法制备碳纳米管纸, 并对其进行循环伏安电化学氧化处理，以该电化学氧化处理的碳纳米管纸为基体, 采用电化学聚合沉积聚苯胺, 随后吸附石墨烯, 制备具有三明治夹心结构的碳纳米管/聚苯胺/石墨烯复合纳米碳纸，该复合碳纸具有良好的电容特性、大电流充放电特性以及良好的循环稳定性能。但是操作工艺复杂，难以控制复合纸的结构，以至于难以提高了其比表面积，限制了比电容的提高；而且由于实际生产过程中生产的碳纳米管都会残留一部分的催化剂杂质, 以及一些无定形碳, 这些杂质的存在限制了碳纳米管的使用,文章中采用酸纯化碳纳米管，混酸处理的同时去除了绝大多数的无定形碳及金属颗粒, 但处理过程繁琐, 污染严重, 同时也引入了一些官能团, 这些官能团的存在对碳纳米管的结构造成一定的破坏, 从而对性能会产生一定的影响，限制了其性能；综上所述，需要对工艺手段进行一定的改进，从而能够制得操作可控，导电性强、比表面积大、比电容大的超级电容器电极材料，满足科技发展的需求。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料。
本发明是通过以下技术方案实现的：
一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料，由下列重量份的原料制成：多壁碳纳米管10-12、十二烷基硫酸钠1.5-1.6、去离子水适量、无水乙醇适量、氯仿适量、聚氧化乙烯14-15、混旋樟脑磺酸12-13、坡缕石0.2-0.3、1mol/L的盐酸溶液适量、苯胺10-12、过硫酸铵12.6-1.3。
所述一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料，由下列具体方法制备而成：
（1）将多壁碳纳米管放在石墨坩埚炉，置于石墨化炉中，对其进行抽真空，以10-15℃/min升温至2800℃，保温20-20小时，自然冷却，得到石墨化碳纳米管；将上述石墨化碳纳米管放入球磨机中以200-300转/份的速度球磨90-120分钟，加入溶于25-30倍量的去离子水的十二烷基硫酸钠，超声20-30分钟后喷雾干燥，得到改性碳纳米管；
（2）将坡缕石中加入100-110倍量的1mol/L的盐酸溶液中，滴加苯胺，以500-600转/分搅拌30-40分钟，冰浴条件下，缓慢滴加过硫酸铵，控温0-5℃，搅拌反应8-9小时，抽滤，用去离子水洗涤2-3次，将产物在60下真空干燥，得到坡缕石聚苯胺复合材料；
（3）将步骤（2）得到的坡缕石聚苯胺复合材料溶于100倍量的氯仿中，再加入混旋樟脑磺酸，室温下以300-400转/分的速度搅拌12-14小时，然后加入步骤（1）得到的产物，超声分散20-30分钟后加入其余剩余成分，继续以300-400转/分的速度搅拌10-12小时，得到纺丝液；
（4）将纺丝液吸入到注射器中利用静电纺丝技术将纺丝液收集在集流体金属镍上，控制纺丝液流量为0.2-0.3ml/h，电压为15-20kV，纺丝距离为8-14cm，纺丝过程5-6小时，形成具有一定厚度的网络结构的复合纤维电极材料。
本发明的优点是：本发明首先对碳纳米管进行高温石墨化处理的方法来达到纯化的效果，在石墨化的同时，金属催化剂发生蒸发，碳纳米管不会遭到破坏，同时结晶度和导电性提高；然后利用静电纺丝技术将石墨化后的碳纳米管、聚苯胺、聚氧化乙烯等制成了网络结构的复合纤维膜，通过控制纺丝距离、纺丝流量等使得制备的纤维较细，增强了其比表面积，从而使得电解质离子扩散阻力变小，电荷转移通道越通畅，由此表现出更好的电容性能，提高了比电容，而且利用此电极材料制成的超级电容器表现出良好的循环稳定性，同时工艺简单，便于工业控制。
本发明将坡缕石与苯胺进行原位聚合，由于坡缕石具有良好的吸附性能和大的比表面积，在原位聚合中，可以提高聚苯胺的分散性，以提高聚苯胺和电解液的接触面积， 增大聚苯胺的利用率，从而提高比电容；本发明静电纺纤维膜具有优异的孔隙分布，这种结构能为电解质离子的扩散提供良好的通道，具有良好的比电容，用此电极材料制成的超级电容器电化学性能优异。
具体实施方式
一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料，由下列重量份（公斤）的原料制成：多壁碳纳米管10、十二烷基硫酸钠1.5、去离子水适量、无水乙醇适量、氯仿适量、聚氧化乙烯14、混旋樟脑磺酸12、坡缕石0.2、1mol/L的盐酸溶液适量、苯胺10、过硫酸铵12.6。
所述一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料，由下列具体方法制备而成：
（1）将多壁碳纳米管放在石墨坩埚炉，置于石墨化炉中，对其进行抽真空，以10℃/min升温至2800℃，保温20小时，自然冷却，得到石墨化碳纳米管；将上述石墨化碳纳米管放入球磨机中以200转/份的速度球磨90分钟，加入溶于25倍量的去离子水的十二烷基硫酸钠，超声20分钟后喷雾干燥，得到改性碳纳米管；
（2）将坡缕石中加入100倍量的1mol/L的盐酸溶液中，滴加苯胺，以500转/分搅拌30分钟，冰浴条件下，缓慢滴加过硫酸铵，控温0℃，搅拌反应8小时，抽滤，用去离子水洗涤2次，将产物在60下真空干燥，得到坡缕石聚苯胺复合材料；
（3）将步骤（2）得到的坡缕石聚苯胺复合材料溶于100倍量的氯仿中，再加入混旋樟脑磺酸，室温下以300转/分的速度搅拌12小时，然后加入步骤（1）得到的产物，超声分散20分钟后加入其余剩余成分，继续以300转/分的速度搅拌10小时，得到纺丝液；
（4）将纺丝液吸入到注射器中利用静电纺丝技术将纺丝液收集在集流体金属镍上，控制纺丝液流量为0.2ml/h，电压为15kV，纺丝距离为8cm，纺丝过程5小时，形成具有一定厚度的网络结构的复合纤维电极材料。
将聚四氟乙烯隔膜浸入到聚乙烯醇-硫酸凝胶电解质中，保持 20分钟，取出后在室温下自然蒸发干燥，然后把所述实施例制成的收集复合纤维膜的金属镍作为电极材料与聚乙烯醇-硫酸隔膜按三明治结构叠放在一起，并用聚酯薄膜对其进行封装，得到超级电容器。在扫描速度为 5 mV•s–1、电位区间–0.8-0.2 V 时的循环伏安特性曲线得到超级电容器的比电容为97 F/g，在 1 000 次循环充放电测试后比电容仍能保持大于90%。
Claims (2)
1.一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料，其特征在于，由下列重量份的原料制成：多壁碳纳米管10-12、十二烷基硫酸钠1.5-1.6、去离子水适量、无水乙醇适量、氯仿适量、聚氧化乙烯14-15、混旋樟脑磺酸12-13、坡缕石0.2-0.3、1mol/L的盐酸溶液适量、苯胺10-12、过硫酸铵12.6-1.3。
2.根据权利要求书1所述一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料，其特征在于，由下列具体方法制备而成：
（1）将多壁碳纳米管放在石墨坩埚炉，置于石墨化炉中，对其进行抽真空，以10-15℃/min升温至2800℃，保温20-20小时，自然冷却，得到石墨化碳纳米管；将上述石墨化碳纳米管放入球磨机中以200-300转/份的速度球磨90-120分钟，加入溶于25-30倍量的去离子水的十二烷基硫酸钠，超声20-30分钟后喷雾干燥，得到改性碳纳米管；
（2）将坡缕石中加入100-110倍量的1mol/L的盐酸溶液中，滴加苯胺，以500-600转/分搅拌30-40分钟，冰浴条件下，缓慢滴加过硫酸铵，控温0-5℃，搅拌反应8-9小时，抽滤，用去离子水洗涤2-3次，将产物在60下真空干燥，得到坡缕石聚苯胺复合材料；
（3）将步骤（2）得到的坡缕石聚苯胺复合材料溶于100倍量的氯仿中，再加入混旋樟脑磺酸，室温下以300-400转/分的速度搅拌12-14小时，然后加入步骤（1）得到的产物，超声分散20-30分钟后加入其余剩余成分，继续以300-400转/分的速度搅拌10-12小时，得到纺丝液；
（4）将纺丝液吸入到注射器中利用静电纺丝技术将纺丝液收集在集流体金属镍上，控制纺丝液流量为0.2-0.3ml/h，电压为15-20kV，纺丝距离为8-14cm，纺丝过程5-6小时，形成具有一定厚度的网络结构的复合纤维电极材料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610929776.0A CN106571236A (zh) | 2016-10-31 | 2016-10-31 | 一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610929776.0A CN106571236A (zh) | 2016-10-31 | 2016-10-31 | 一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106571236A true CN106571236A (zh) | 2017-04-19 |
Family
ID=60414467
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610929776.0A Pending CN106571236A (zh) | 2016-10-31 | 2016-10-31 | 一种纳米坡缕石改性聚苯胺碳纳米管复合电极材料 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106571236A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110707326A (zh) * | 2019-04-10 | 2020-01-17 | 中南大学 | 一种水系电池集流体、正极、柔性电池及其制备和应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130431A (zh) * | 2006-08-23 | 2008-02-27 | 中国科学院金属研究所 | 一种纯化多壁碳纳米管/纳米碳纤维的方法 |
-
2016
- 2016-10-31 CN CN201610929776.0A patent/CN106571236A/zh active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101130431A (zh) * | 2006-08-23 | 2008-02-27 | 中国科学院金属研究所 | 一种纯化多壁碳纳米管/纳米碳纤维的方法 |
Non-Patent Citations (3)
| Title |
|---|
| 代涛娟 等: ""纳米结构坡缕石改性聚苯胺超级电容器电极材料的研究"", 《武汉理工大学学报》 * |
| 庞志鹏 等: ""碳纳米管导电纸的制备及改性研究"", 《功能材料》 * |
| 梁军生 等: ""静电纺丝PANI/CNT/PEO超级电容器电极的性能研究"", 《电子元件与材料》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110707326A (zh) * | 2019-04-10 | 2020-01-17 | 中南大学 | 一种水系电池集流体、正极、柔性电池及其制备和应用 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ni et al. | Free-standing and highly conductive PEDOT nanowire films for high-performance all-solid-state supercapacitors | |
| Heme et al. | Recent progress in polyaniline composites for high capacity energy storage: A review | |
| Wu et al. | Carbonaceous hydrogels and aerogels for supercapacitors | |
| Niu et al. | A “skeleton/skin” strategy for preparing ultrathin free-standing single-walled carbon nanotube/polyaniline films for high performance supercapacitor electrodes | |
| Zheng et al. | Graphene-based fibers for the energy devices application: A comprehensive review | |
| Liu et al. | PANI coated microporous graphene fiber capable of subjecting to external mechanical deformation for high performance flexible supercapacitors | |
| Hu et al. | Orderly and highly dense polyaniline nanorod arrays fenced on carbon nanofibers for all-solid-state flexible electrochemical energy storage | |
| CN104240973A (zh) | 一种透明、柔性的超级电容器织物及其制备方法 | |
| Du et al. | Fabrication of hierarchical carbon layer encapsulated polyaniline core-shell structure nanotubes and application in supercapacitors | |
| Luo et al. | Fixing graphene-Mn3O4 nanosheets on carbon cloth by a poles repel-assisted method to prepare flexible binder-free electrodes for supercapacitors | |
| Zhou et al. | A facile approach to improve the electrochemical properties of polyaniline-carbon nanotube composite electrodes for highly flexible solid-state supercapacitors | |
| Liu et al. | Polyaniline-decorated 3D carbon porous network with excellent electrolyte wettability and high energy density for supercapacitors | |
| Ji et al. | Cellulose and poly (vinyl alcohol) composite gels as separators for quasi-solid-state electric double layer capacitors | |
| CN107275116B (zh) | 一种氮掺杂有序多孔高导电石墨烯纤维及其制备方法与应用 | |
| Gopalsamy et al. | Wet-spun poly (ionic liquid)-graphene hybrid fibers for high performance all-solid-state flexible supercapacitors | |
| Malik et al. | Electrochemical behavior of composite electrode based on sulphonated polymeric surfactant (SPEEK/PSS) incorporated polypyrrole for supercapacitor | |
| Chen et al. | Electrochemical capacitance of spherical nanoparticles formed by electrodeposition of intrinsic polypyrrole onto Au electrode | |
| Cao et al. | Redox-active doped polypyrrole microspheres induced by phosphomolybdic acid as supercapacitor electrode materials | |
| Yin et al. | Enhanced performance of flexible dye-sensitized solar cells using flexible Ag@ ZrO2/C nanofiber film as low-cost counter electrode | |
| Malik et al. | Study of supercapacitive pursuance of polypyrrole/sulphonated poly (ether ether ketone)/multi walled carbon nanotubes composites for energy storage | |
| Chen et al. | Characterisations of carbon-fenced conductive silver nanowires-supported hierarchical polyaniline nanowires | |
| Faraji et al. | 2.0-V flexible all-solid-state symmetric supercapacitor device with high electrochemical performance composed of MWCNTs-WO 3-graphite sheet | |
| Li et al. | Robust conductive polymer grafted carbon cloth via solvothermal polymerization for flexible electrochemical devices | |
| CN106683898A (zh) | 超级电容器用复合电极材料及其制备方法和超级电容器 | |
| Li et al. | Graphene-enabled improved supercapacitor performance of polyaniline nanofiber composites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170419 |