CN106566635A - Corrosion-resistant, high-wear-resistant, environment-friendly and energy-saving engine lubricating oil and preparation method therefor - Google Patents
Corrosion-resistant, high-wear-resistant, environment-friendly and energy-saving engine lubricating oil and preparation method therefor Download PDFInfo
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/043—Sulfur; Selenenium; Tellurium
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/05—Metals; Alloys
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
- C10M2201/103—Clays; Mica; Zeolites
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
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Abstract
The invention discloses corrosion-resistant, high-wear-resistant, environment-friendly and energy-saving engine lubricating oil and a preparation method therefor. The engine lubricating oil is prepared from the following raw materials in parts by weight: 2-3 parts of sodium polyacrylate, 40-80 parts of rapeseed oil, 1-3 parts of barium petroleum sulfonate, 15-25 parts of poly alpha olefin PAO6, 5-15 parts of polyol ester PriEco3000, 4-8 parts of sulfur powder, 1-2 parts of butyl triphosphinate, 0.5-1 part of tungsten powder, 5-10 parts of zeolite ZIF-8, 2-3 parts of linoleic acid, 15-20 parts of dimethyl sulfoxide, 5-10 parts of pour point depressant LZL803B, 4-7 parts of ethylene-propylene copolymer T618, 15-20 parts of deionized water and a proper volume of anhydrous ethanol. According to the engine lubricating oil and the preparation method therefor, the hydrophobic and lipophilic material, i.e., the zeolite ZIF-8 is introduced, so that the zeolite ZIF-8 can serve as a carrier for tungsten disulfide particles, and the fusion of the tungsten disulfide particles with base oil is further improved; meanwhile, the zeolite ZIF-8 can serve as a lubricant additive; and petroleum sodium sulfonate and the like are added in a matched manner, so that the corrosion resistance of the lubricating oil is improved.
Description
Technical field
The present invention relates to a kind of engine lubricating oil and its preparation, more particularly to a kind of antiseptical, high abrasion-resistant environmental protection energy-conservation
Engine lubricating oil and preparation method thereof.
Background technology
Lubricating oil also has pole in industries such as aviation, automobile, machining, transportation, metallurgy, coal, building, light industrys
To be widely applied.With the high speed development of industry, the demand of lubricating oil rises year by year.And it is traditional based on mineral oil
The lubricant of oil, not only pollutes environment, while also exacerbating lack of energy.While it is widely used, unavoidably
Ground can by transport, reveal, sputtering, overflow or it is inappropriate discharge etc. number of ways flow into environment, severe contamination soil and
Water resource, destruction ecological environment and ecological balance.Green Lubricants are also called environmentally friendly or environmental compatible type lubricating oil, its
Including both sides implication:One is that its performance must is fulfilled for working condition requirement;Two is ecological effect, i.e., itself and its decompose
Product will not work the mischief to ecological environment, or be to a certain extent friendly to environment in certain limit.
Shi Chen is in its Ph.D. Dissertation《Nanometer WS2The development and its performance study of environmental protection energy-saving engine lubricating oil》
In, using Oleum Brassicae campestriss, polyalphaolefin PAO6, polyol ester PriEco3000 and WS2A kind of engine lubricating oil is prepared for, but
Its bearing capacity, abrasion-resistance need to be improved.
The content of the invention
Thinking based on more than, the present invention is intended to provide a kind of environmental protection and energy saving with high-mechanic performance, high-wear resistance
Engine lubricating oil and preparation method thereof.
The technical problem to be solved is realized using following technical scheme:
A kind of antiseptical, high abrasion-resistant environmental protection energy-saving engine lubricating oil, it is characterised in that be made up of the raw material of following weight portion:
Sodium polyacrylate 2-3, Oleum Brassicae campestriss 40-80, barium mahogany sulfonate 1-3, polyalphaolefin PAO6 15-25, polyol ester
PriEco3000 5-15, sulphur powder 4-8, the fat 1-2 of phosphorous acid fourth three, tungsten powder 0.5-1, zeolite ZIF-8 5-10, linoleic acid 2-3, two
Methyl sulfoxide 15-20, pour-point depressant LZL803B 5-10, ethylene-propylene copolymer T618 4-7, deionized water 15-20, dehydrated alcohol is fitted
Amount.
Described a kind of antiseptical, high abrasion-resistant environmental protection energy-saving engine lubricating oil and preparation method thereof, it is characterised in that by
Following steps are made:
A. sulphur powder and tungsten powder are mixed, forms mixture, the mixture is reacted at a temperature of 110-260 DEG C, then
Reactant is crystallized at a temperature of 500-700 DEG C in nonoxidizing atmosphere, that is, is obtained tungsten disulphide powder and remaining
Sulphur powder mixture;
B. step a gained mixture is mixed with deionized water, adds linoleic acid, the fat of phosphorous acid fourth three, obtain suspension,
Feeding after suspension 8-12h is processed using ball grinding stirring in strong ultrasonic field, lyophilization obtains ultra-fine tungsten disulfide and mixes with sulfur
Thing powder;
C. by step b gained mix powder be scattered in dimethyl sulfoxide solvent, and be added thereto to zeolite ZIF-8, poly- third
Olefin(e) acid sodium, proceeds in ptfe autoclave after stirring, and after placing 5-10 days under the conditions of 80-120 DEG C, filters and is used in combination
Absolute ethanol washing 2-4 time, after drying at room temperature, obtains adsorbing ultra-fine tungsten disulfide and sulfur powder, and has dimethyl sulfoxide to fill
Zeolite ZIF-8 mixture;
D. by Oleum Brassicae campestriss, polyalphaolefin PAO6, polyol ester PriEco3004 mixing, pour-point depressant LZL803B, mahogany acid are added
Barium, ethylene-propylene copolymer T618, step c gained mixture, proceed to stirring 30-90min in blender.
Described a kind of antiseptical, high abrasion-resistant environmental protection energy-saving engine lubricating oil and preparation method thereof, it is characterised in that stir
The rotating speed for mixing machine is 200-400r/min.
The invention has the beneficial effects as follows:The present invention hangs tungsten disulfide using strong ultrasound and the compound action of ball grinding stirring
The close nano tungsten disulfide grain graininess of floating particles granularity, then moditied processing is carried out to particle surface by linoleic acid, it is effectively anti-
Stopped it is intergranular reunite again so that tungsten disulfide granule keeps stable dispersion in base oil, improve its stability;
Hydrophobic lipophilic material zeolite ZIF-8 is introduced, and is soaked with dimethyl sulfoxide, not only can be using zeolite ZIF-8 as tungsten disulfide
The carrier of granule, further improves its amalgamation with base oil, at the same zeolite ZIF-8 can as excellent lubricating additive,
With tungsten disulfide together to strengthen the bearing capacity and antiwear and antifriction ability of lubricating oil, and dimethyl sulfoxide then promotes zeolite
The fusion faculty of ZIF-8 carriers and lubricating oil.It is used as subjective basis oil by Oleum Brassicae campestriss, improves the feature of environmental protection of the lubricating oil
Can, environmental friendliness;Cooperation with the addition of petroleum sodium sulfonate etc., improve the antiseptic property of lubricating oil.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.
Embodiment
A kind of antiseptical, high abrasion-resistant environmental protection energy-saving engine lubricating oil, it is characterised in that by the raw material system of following weight portion
Into:
Sodium polyacrylate 3, Oleum Brassicae campestriss 80, barium mahogany sulfonate 3, polyalphaolefin PAO6 25, polyol ester PriEco3000 15, sulfur
Powder 8, the fat 2 of phosphorous acid fourth three, tungsten powder 1, zeolite ZIF-8 10, linoleic acid 3, dimethyl sulfoxide 20, pour-point depressant LZL803B 10, second
Propylene copolymer T618 7, deionized water 20, appropriate dehydrated alcohol.
Described a kind of antiseptical, high abrasion-resistant environmental protection energy-saving engine lubricating oil and preparation method thereof, it is characterised in that by
Following steps are made:
A. sulphur powder and tungsten powder are mixed, forms mixture, the mixture is reacted at a temperature of 110-260 DEG C, then
Reactant is crystallized at a temperature of 500-700 DEG C in nonoxidizing atmosphere, that is, is obtained tungsten disulphide powder and remaining
Sulphur powder mixture;
B. step a gained mixture is mixed with deionized water, adds linoleic acid, the fat of phosphorous acid fourth three, obtain suspension,
Feeding after suspension 8-12h is processed using ball grinding stirring in strong ultrasonic field, lyophilization obtains ultra-fine tungsten disulfide and mixes with sulfur
Thing powder;
C. by step b gained mix powder be scattered in dimethyl sulfoxide solvent, and be added thereto to zeolite ZIF-8, poly- third
Olefin(e) acid sodium, proceeds in ptfe autoclave after stirring, and after placing 5-10 days under the conditions of 80-120 DEG C, filters and is used in combination
Absolute ethanol washing 2-4 time, after drying at room temperature, obtains adsorbing ultra-fine tungsten disulfide and sulfur powder, and has dimethyl sulfoxide to fill
Zeolite ZIF-8 mixture;
D. by Oleum Brassicae campestriss, polyalphaolefin PAO6, polyol ester PriEco3004 mixing, pour-point depressant LZL803B, mahogany acid are added
Barium, ethylene-propylene copolymer T618, step c gained mixture, proceed to stirring 30-90min in blender.
Described a kind of antiseptical, high abrasion-resistant environmental protection energy-saving engine lubricating oil and preparation method thereof, it is characterised in that stir
The rotating speed for mixing machine is 200-400r/min.
The present invention technical parameter be:Average friction coefficient >=0.62;The addition of tungsten disulphide powder makes engine piston
The wear extent of ring reduces >=27.6%.
Claims (3)
1. a kind of antiseptical, high abrasion-resistant environmental protection energy-saving engine lubricating oil, it is characterised in that by the raw material system of following weight portion
Into:
Sodium polyacrylate 2-3, Oleum Brassicae campestriss 40-80, barium mahogany sulfonate 1-3, polyalphaolefin PAO6 15-25, polyol ester
PriEco3000 5-15, sulphur powder 4-8, the fat 1-2 of phosphorous acid fourth three, tungsten powder 0.5-1, zeolite ZIF-8 5-10, linoleic acid 2-3, two
Methyl sulfoxide 15-20, pour-point depressant LZL803B 5-10, ethylene-propylene copolymer T618 4-7, deionized water 15-20, dehydrated alcohol is fitted
Amount.
2. a kind of antiseptical according to claim 1, high abrasion-resistant environmental protection energy-saving engine lubricating oil and preparation method thereof, its
It is characterised by, is made up of following steps:
A. sulphur powder and tungsten powder are mixed, forms mixture, the mixture is reacted at a temperature of 110-260 DEG C, then
Reactant is crystallized at a temperature of 500-700 DEG C in nonoxidizing atmosphere, that is, is obtained tungsten disulphide powder and remaining
Sulphur powder mixture;
B. step a gained mixture is mixed with deionized water, adds linoleic acid, the fat of phosphorous acid fourth three, obtain suspension,
Feeding after suspension 8-12h is processed using ball grinding stirring in strong ultrasonic field, lyophilization obtains ultra-fine tungsten disulfide and mixes with sulfur
Thing powder;
C. by step b gained mix powder be scattered in dimethyl sulfoxide solvent, and be added thereto to zeolite ZIF-8, poly- third
Olefin(e) acid sodium, proceeds in ptfe autoclave after stirring, and after placing 5-10 days under the conditions of 80-120 DEG C, filters and is used in combination
Absolute ethanol washing 2-4 time, after drying at room temperature, obtains adsorbing ultra-fine tungsten disulfide and sulfur powder, and has dimethyl sulfoxide to fill
Zeolite ZIF-8 mixture;
D. by Oleum Brassicae campestriss, polyalphaolefin PAO6, polyol ester PriEco3004 mixing, pour-point depressant LZL803B, mahogany acid are added
Barium, ethylene-propylene copolymer T618, step c gained mixture, proceed to stirring 30-90min in blender.
3. a kind of antiseptical according to claim 2, high abrasion-resistant environmental protection energy-saving engine lubricating oil and preparation method thereof, its
It is characterised by, the rotating speed of blender is 200-400r/min.
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Citations (1)
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CN105038905A (en) * | 2015-07-09 | 2015-11-11 | 太原理工大学 | Lubricating oil, lubricating oil additive and preparation method therefor |
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CN105038905A (en) * | 2015-07-09 | 2015-11-11 | 太原理工大学 | Lubricating oil, lubricating oil additive and preparation method therefor |
Non-Patent Citations (4)
Title |
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