CN106566089A - Irradiation-resistant, low-smoke, halogen-free and flame-retardant sheath material for nuclear-grade cables - Google Patents
Irradiation-resistant, low-smoke, halogen-free and flame-retardant sheath material for nuclear-grade cables Download PDFInfo
- Publication number
- CN106566089A CN106566089A CN201610563379.6A CN201610563379A CN106566089A CN 106566089 A CN106566089 A CN 106566089A CN 201610563379 A CN201610563379 A CN 201610563379A CN 106566089 A CN106566089 A CN 106566089A
- Authority
- CN
- China
- Prior art keywords
- parts
- sheath material
- low
- oxide
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
Abstract
The invention relates to an irradiation-resistant, low-smoke, halogen-free and flame-retardant sheath material for nuclear-grade cables. The low-smoke, halogen-free and flame-retardant sheath material is prepared from the following ingredients in parts by weight: a ternary ethylene-propylene copolymer, polyimide, magnesium hydroxide, silicon dioxide, antimony trioxide, aluminum oxide, zinc oxide, dicumyl peroxide, ferric oxide, calcium oxide, magnesium oxide, a 2,2,4-trimethyl-1,2-dihydroquinoline polymer, 2-mercaptobenzimidazole, vinyl tri(beta-methoxyethoxyl)silane and a lubricant, wherein the mean particle size of the polyimide is 10 to 20 microns, and the mean particle size of the magnesium hydroxide is 0.8 to 1.5 microns. The sheath material has good flame retardance, oil resistance, electrical properties and mechanical properties and meanwhile has excellent irradiation resistance.
Description
Technical field
The present invention relates to nuclear grade cable low-smoke halogen-free flame-retardant sheath material, more particularly to resistance to irradiation nuclear grade cable with low cigarette without
Halogen flame-retardant sheath material.
Background technology
Nuclear power is a kind of safe and clean, reliable energy, greatly develops nuclear power and has with environmental protection to solving energy crisis
There is very important meaning.According to the ENERGY PLANNING that China is newest, nuclear power station will become one of mainstay of electric structure.In advance
Counting the proportion in the year two thousand twenty nuclear power China total power generating capacity will rise to 4% from current 1.8%.Premier of the State Council Li Keqiang in
Point out when August holds Executive Meeting of the State Council on 27th within 2014, to greatly develop clean energy resource, and go into operation in this year and next year
Build a collection of coastal new nuclear power projects.August in 2014 afternoon on the 22nd, Chinese Guang He groups and China National Nuclear Corporation are successively at it
Official website issues " news of victory ", claims nuclear power authorities to agree to " No. Hua Longyi " nuclear power technology that Liang great nuclear powers group jointly makes
The decision of integration program." No. Hua Longyi " is considered the milestone of China's Generation Ⅲ autonomy-oriented, realizes that nuclear power is exported
A trump.The core requirement life-span of three generations's nuclear power technology reaches 60 years, and two generations for designing originally or the cable of two generation half
Life-span is 40 years, therefore the projected life of cable material is badly in need of improving.
China's nuclear grade cable research and development ability disconnects with growth requirement, and particularly, nuclear grade cable and the excessive foreign countries that rely on of material enter
Mouthful, the formula and production technology of China K3 class CABLE MATERIALSs are still rested in minority cable factory and CABLE MATERIALS manufacturer's hand.But receive
The restriction of its production capacity and wish the strong will held monopoly position, the production domesticization for limiting nuclear grade cable and material is entered
Journey.For K1 class CABLE MATERIALSs, existing producer of the country has carried out researching and developing and having applied some patents successively, but actually can criticize
Amount production provides the producer of K1 class CABLE MATERIALSs almost not to be had, and product variety is also extremely limited.
The content of the invention
It is an object of the invention to provide a kind of resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material, the low smoke and zero halogen resistance
Combustion protective cover material had both improve insulating properties while improve fire resistance, also improved the radiation resistance of base material itself, heat-resisting
The combination properties such as performance, high flame resistance, high insulating property, the insulation core wire for making cables of nuclear power just can using single layer structure
Excellent requirement is realized, cable working technology is simplified.
To achieve the above object of the invention, the technical solution used in the present invention is：A kind of resistance to irradiation nuclear grade cable with low cigarette without
Halogen flame-retardant sheath material, it is characterised in that：The low-smoke halogen-free flame-retardant sheath material is made up of the component of following weight portion：
100 parts of ternary ethylene-propylene copolymer,
5 ~ 20 parts of polyimides,
35 ~ 50 parts of magnesium hydroxide,
24 ~ 32 parts of silica,
18 ~ 26 parts of antimony oxide,
4 ~ 9 parts of alundum (Al2O3),
8 ~ 10 parts of zinc oxide,
2 ~ 3.5 parts of cumyl peroxide,
1.5 ~ 3.5 parts of di-iron trioxide,
0.4 ~ 0.8 part of calcium oxide,
0.6 ~ 1 part of magnesia,
2,2,4- trimethyl -1,2.4 ~ 2.6 parts of 2- dihyaroquinolines condensate,
2 ~ 3 parts of 2-mercaptobenzimidazole,
Vinyl three（'beta '-methoxy ethyoxyl）1 ~ 3 part of silane,
0.5 ~ 5 part of lubricant；
The average grain diameter of the polyimides is 10 ~ 20 μm, and the average grain diameter of the magnesium hydroxide is 0.8 ~ 1.5 μm.
The further improved technical scheme of technical scheme of above-mentioned low-smoke halogen-free flame-retardant isolating material is as follows：
1. in such scheme, the lubricant is PE waxes either silicone or stearic acid.
2. in such scheme, ethylene contents >=60% of the ternary ethylene-propylene copolymer.
3. in such scheme, the Mooney viscosity ML of the ternary ethylene-propylene copolymer（1+4）125℃≤45.
Due to the utilization of above-mentioned technical proposal, the present invention has compared with prior art following advantages：
1. resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material of the invention, it is in 100 parts of ternary ethylene-propylene copolymer, peroxide
Change in 2 ~ 3.5 parts of diisopropylbenzene (DIPB), 8 ~ 10 parts of zinc oxide, magnesium hydroxide and antimony oxide formula by adding polyimides, carry
The combination properties such as high radiation resistance, heat resistance, high flame resistance, the high insulating property of base material itself, also reduce hydrogen-oxygen
Change magnesium and antimony oxide usage amount, improve insulating properties；Secondly, vinyl three is added in formula（'beta '-methoxy ethyoxyl）
1 ~ 3 part of silane, 0.5 ~ 5 part of lubricant, 0.4 ~ 0.8 part of calcium oxide, the tight ness rating of 0.6 ~ 1 part of raising product of magnesia, exclude material
Material micropore, improves immersion, resistance to steam performance, meets the requirement of nuclear power Insulation Material combination property.
2. resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material of the invention, its 100 parts of ternary ethylene-propylene copolymer,
It is sub- by addition polyamides in 2 ~ 3.5 parts of cumyl peroxide, 8 ~ 10 parts of zinc oxide, magnesium hydroxide and antimony oxide formula
Amine, 2,2,4- trimethyl -1,2.4 ~ 2.6 parts of 2- dihyaroquinolines condensate, 2 ~ 3 parts of 2-mercaptobenzimidazole improves insulation
Performance improves fire resistance simultaneously, also；Secondly, 24 ~ 32 parts of silica, 4 ~ 9 parts of alundum (Al2O3), three oxidations are added in formula
Two 1.5 ~ 3.5 parts of iron, can improve insulaion resistance and improve two powers to Insulation Material, not reduce fire resistance, make nuclear power station
The insulation core wire of cable just disclosure satisfy that the requirement of cable using single layer structure, simplify cable working technology.
3. resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material of the invention, the average grain diameter of its polyimides is 10 ~
20 μm, the average grain diameter of magnesium hydroxide is 0.8 ~ 1.5 μm, and the average grain diameter of the antimony oxide is 0.5 ~ 2.5 μm, calcining pottery
Native average grain diameter is 1 ~ 2 μm, if above-mentioned modifying agent and filler particle diameter are meticulous, the elongation of final mixture is low, stream
Dynamic property is deteriorated, and is unfavorable for the processing technology that cable is extruded, if particle diameter is excessive, the tensile strength of mixture is low, and resistance
Combustion property, the combination property such as light transmittance can be deteriorated and affect any surface finish exquisiteness degree.
Specific embodiment
With reference to embodiment, the invention will be further described：
Embodiment 1：A kind of resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material, the fire-retardant high insulated cable material is by following
The component composition of weight portion：
100 parts of ternary ethylene-propylene copolymer,
12 parts of polyimides,
48 parts of magnesium hydroxide,
32 parts of silica,
20 parts of antimony oxide,
5 parts of alundum (Al2O3),
10 parts of zinc oxide,
2.5 parts of cumyl peroxide,
1.6 parts of di-iron trioxide,
0.7 part of calcium oxide,
0.9 part of magnesia,
2,2,4- trimethyl -1,2.4 parts of 2- dihyaroquinolines condensate,
2.6 parts of 2-mercaptobenzimidazole,
Vinyl three（'beta '-methoxy ethyoxyl）1 part of silane,
4 parts of PE waxes；
The Mooney viscosity ML of above-mentioned copolymer（1+4）125 DEG C≤45, ethylene contents >=60% of the copolymer；
Above-mentioned polyimide modified dose of average grain diameter is 10 ~ 20 μm, and the average grain diameter of above-mentioned magnesium hydroxide is 0.8 ~ 1.5 μm,
The average grain diameter of the antimony oxide is 0.5 ~ 2.5 μm.
2nd, preparation technology
The first step：By 100 parts of ternary ethylene-propylene copolymer, 12 parts of polyimides, 48 parts of magnesium hydroxide, 32 parts of silica, three oxygen
Change 20 parts of two antimony, 5 parts of alundum (Al2O3), 10 parts of zinc oxide, 1.6 parts of di-iron trioxide, 0.7 part of calcium oxide, 0.9 part of magnesia,
2.4 parts of 2,2,4- trimethyl -1,2- dihyaroquinolines condensate, 2.6 parts of 2-mercaptobenzimidazole, vinyl three（'beta '-methoxy
Ethyoxyl）1 part of silane, 4 parts of all raw materials of PE waxes are mixed by formula metering, internal mixing and plasticizing 3 minutes in banbury, and material temperature reaches
Discharge when 150 DEG C；
Second step：Then slice after triangle bag turns refining uniformly is beaten in the mill of 120 DEG C of temperature, Jing after filtering rubber machine and filter,
Be again to add be well mixed slice under 2.5 parts of cumyl peroxide in 100 DEG C of mills in temperature, packaging be Insulation Material into
Product.
3rd step：Insulation Material is connected on sulphur line production line in electric wire rubber extruding machine, to extrude at a temperature of 90 ~ 110 DEG C,
It is coated on conductor thread core, and vulcanizes in the curing tube of 170 ~ 200 DEG C of temperature, becomes the insulated electro of nuclear power station K1 class cables
Indices are detected by line according to cable standard.
3rd, technical indicator
Embodiment 2：A kind of resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material, the fire-retardant high insulated cable material is by following
The component composition of weight portion：
100 parts of ternary ethylene-propylene copolymer,
10 parts of polyimides,
43 parts of magnesium hydroxide,
28 parts of silica,
23 parts of antimony oxide,
6 parts of alundum (Al2O3),
8 parts of zinc oxide,
3 parts of cumyl peroxide,
2.2 parts of di-iron trioxide,
0.6 part of calcium oxide,
0.8 part of magnesia,
2,2,4- trimethyl -1,2.6 parts of 2- dihyaroquinolines condensate,
2.4 parts of 2-mercaptobenzimidazole,
Vinyl three（'beta '-methoxy ethyoxyl）2 parts of silane,
2 parts of stearic acid；
The Mooney viscosity ML of above-mentioned copolymer（1+4）125 DEG C≤45, ethylene contents >=60% of the copolymer；
Above-mentioned polyimide modified dose of average grain diameter is 10 ~ 20 μm, and the average grain diameter of above-mentioned magnesium hydroxide is 0.8 ~ 1.5 μm,
The average grain diameter of the antimony oxide is 0.5 ~ 2.5 μm, and above-mentioned calcinated argil average grain diameter is 1 ~ 2 μm.
2nd, preparation technology
The first step：By 100 parts of ternary ethylene-propylene copolymer, 10 parts of polyimides, 43 parts of magnesium hydroxide, 28 parts of silica, three oxygen
Change 23 parts of two antimony, 6 parts of alundum (Al2O3), 8 parts of zinc oxide, 2.2 parts of di-iron trioxide, 0.6 part of calcium oxide, 0.8 part of magnesia, 2,
2.6 parts of 2,4- trimethyl -1,2- dihyaroquinolines condensate, 2.4 parts of 2-mercaptobenzimidazole, vinyl three（'beta '-methoxy second
Epoxide）2 parts of silane, all raw materials of 2 parts of stearic acid are mixed by formula metering, internal mixing and plasticizing 3 minutes in banbury, and material temperature reaches
To discharge when 150 DEG C；
Second step：Then slice after triangle bag turns refining uniformly is beaten in the mill of 120 DEG C of temperature, Jing after filtering rubber machine and filter,
Be again to add be well mixed slice under 3 parts of cumyl peroxide in 100 DEG C of mills in temperature, packaging be Insulation Material into
Product.
3rd step：Insulation Material is connected on sulphur line production line in electric wire rubber extruding machine, to extrude at a temperature of 90 ~ 110 DEG C,
It is coated on conductor thread core, and vulcanizes in the curing tube of 170 ~ 200 DEG C of temperature, becomes the insulated electro of nuclear power station K1 class cables
Indices are detected by line according to cable standard.
3rd, technical indicator
Embodiment 3：A kind of resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material, the fire-retardant high insulated cable material is by following
The component composition of weight portion：
100 parts of ternary ethylene-propylene copolymer,
15 parts of polyimides,
40 parts of magnesium hydroxide,
25 parts of silica,
18 parts of antimony oxide,
9 parts of alundum (Al2O3),
9 parts of zinc oxide,
2.5 parts of cumyl peroxide,
3.2 parts of di-iron trioxide,
0.45 part of calcium oxide,
0.65 part of magnesia,
2,2,4- trimethyl -1,2.5 parts of 2- dihyaroquinolines condensate,
2.5 parts of 2-mercaptobenzimidazole,
Vinyl three（'beta '-methoxy ethyoxyl）2.5 parts of silane,
3 parts of PE waxes；
The Mooney viscosity ML of above-mentioned copolymer（1+4）125 DEG C≤45, ethylene contents >=60% of the copolymer；
Above-mentioned polyimide modified dose of average grain diameter is 10 ~ 20 μm, and the average grain diameter of above-mentioned magnesium hydroxide is 0.8 ~ 1.5 μm,
The average grain diameter of the antimony oxide is 0.5 ~ 2.5 μm, and above-mentioned calcinated argil average grain diameter is 1 ~ 2 μm.
2nd, preparation technology
The first step：By 100 parts of ternary ethylene-propylene copolymer, 15 parts of polyimides, 40 parts of magnesium hydroxide, 25 parts of silica, three oxygen
Change 18 parts of two antimony, 9 parts of alundum (Al2O3), 9 parts of zinc oxide, 3.2 parts of di-iron trioxide, 0.45 part of calcium oxide, 0.65 part of magnesia,
2.5 parts of 2,2,4- trimethyl -1,2- dihyaroquinolines condensate, 2.5 parts of 2-mercaptobenzimidazole, vinyl three（'beta '-methoxy
Ethyoxyl）2.5 parts of silane, all raw materials of 3 parts of PE waxes are mixed by formula metering, internal mixing and plasticizing 3 minutes, material temperature in banbury
Discharge when reaching 150 DEG C；
Second step：Then slice after triangle bag turns refining uniformly is beaten in the mill of 120 DEG C of temperature, Jing after filtering rubber machine and filter,
Be again to add be well mixed slice under 2.5 parts of cumyl peroxide in 100 DEG C of mills in temperature, packaging be Insulation Material into
Product.
3rd step：Insulation Material is connected on sulphur line production line in electric wire rubber extruding machine, to extrude at a temperature of 90 ~ 110 DEG C,
It is coated on conductor thread core, and vulcanizes in the curing tube of 170 ~ 200 DEG C of temperature, becomes the insulated electro of nuclear power station K1 class cables
Indices are detected by line according to cable standard.
To sum up, resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material of the invention, improves the radiation hardness of base material itself
The combination properties such as performance, heat resistance, high flame resistance, high insulating property, can improve insulaion resistance two to Insulation Material
Side, does not reduce fire resistance, and the insulation core wire for making cables of nuclear power just disclosure satisfy that the requirement of cable using single layer structure, letter
Cable working technology is changed；Secondly, insulating properties are improve simultaneously, also improves fire resistance；Again, the tight of product is improved
Degree, excludes material micropore, improves immersion, resistance to steam performance, meets the requirement of nuclear power Insulation Material combination property.
Above-described embodiment technology design only to illustrate the invention and feature, its object is to allow person skilled in the art
Scholar will appreciate that present disclosure and implement according to this, can not be limited the scope of the invention with this.It is all according to the present invention
Equivalence changes or modification that Spirit Essence is made, all should be included within the scope of the present invention.
Claims (4)
1. a kind of resistance to irradiation nuclear grade cable low-smoke halogen-free flame-retardant sheath material, it is characterised in that：The low-smoke halogen-free flame-retardant sheath
Material is made up of the component of following weight portion：
100 parts of ternary ethylene-propylene copolymer,
5 ~ 20 parts of polyimides,
35 ~ 50 parts of magnesium hydroxide,
24 ~ 32 parts of silica,
18 ~ 26 parts of antimony oxide,
4 ~ 9 parts of alundum (Al2O3),
8 ~ 10 parts of zinc oxide,
2 ~ 3.5 parts of cumyl peroxide,
1.5 ~ 3.5 parts of di-iron trioxide,
0.4 ~ 0.8 part of calcium oxide,
0.6 ~ 1 part of magnesia,
2,2,4- trimethyl -1,2.4 ~ 2.6 parts of 2- dihyaroquinolines condensate,
2 ~ 3 parts of 2-mercaptobenzimidazole,
Vinyl three（'beta '-methoxy ethyoxyl）1 ~ 3 part of silane,
0.5 ~ 5 part of lubricant；
The average grain diameter of the polyimides is 10 ~ 20 μm, and the average grain diameter of the magnesium hydroxide is 0.8 ~ 1.5 μm.
2. fire-retardant high insulated cable material according to claim 1, it is characterised in that：The lubricant is PE waxes or silicone
Or stearic acid.
3. fire-retardant high insulated cable material according to claim 1, it is characterised in that：The ethene of the ternary ethylene-propylene copolymer
Content >=60%.
4. fire-retardant high insulated cable material according to claim 1, it is characterised in that：The Mooney of the ternary ethylene-propylene copolymer
Viscosity ML（1+4）125℃≤45.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610563379.6A CN106566089A (en) | 2014-02-26 | 2014-02-26 | Irradiation-resistant, low-smoke, halogen-free and flame-retardant sheath material for nuclear-grade cables |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410066061.8A CN103992567B (en) | 2014-02-26 | 2014-02-26 | There is the fire-retardant high insulated cable material of used in nuclear power station of radiation resistance |
| CN201610563379.6A CN106566089A (en) | 2014-02-26 | 2014-02-26 | Irradiation-resistant, low-smoke, halogen-free and flame-retardant sheath material for nuclear-grade cables |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410066061.8A Division CN103992567B (en) | 2014-02-26 | 2014-02-26 | There is the fire-retardant high insulated cable material of used in nuclear power station of radiation resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106566089A true CN106566089A (en) | 2017-04-19 |
Family
ID=51306921
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610563379.6A Pending CN106566089A (en) | 2014-02-26 | 2014-02-26 | Irradiation-resistant, low-smoke, halogen-free and flame-retardant sheath material for nuclear-grade cables |
| CN201610564012.6A Pending CN106566090A (en) | 2014-02-26 | 2014-02-26 | Nuclear-grade radiation-resistant cable sheath material with high flame resistance |
| CN201410066061.8A Active CN103992567B (en) | 2014-02-26 | 2014-02-26 | There is the fire-retardant high insulated cable material of used in nuclear power station of radiation resistance |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610564012.6A Pending CN106566090A (en) | 2014-02-26 | 2014-02-26 | Nuclear-grade radiation-resistant cable sheath material with high flame resistance |
| CN201410066061.8A Active CN103992567B (en) | 2014-02-26 | 2014-02-26 | There is the fire-retardant high insulated cable material of used in nuclear power station of radiation resistance |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN106566089A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109651718A (en) * | 2018-12-25 | 2019-04-19 | 佛山科学技术学院 | A kind of EPT rubber cable material that calcinated argil is modified |
| CN111825981A (en) * | 2020-07-20 | 2020-10-27 | 中广核高新核材科技（苏州）有限公司 | Radiation-resistant nuclear-grade thermoplastic low-smoke halogen-free flame-retardant cable sheath material and preparation method thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105860384A (en) * | 2016-06-12 | 2016-08-17 | 安徽天元电缆有限公司 | Environment-friendly light aviation cable material and preparation method thereof |
| CN105924809A (en) * | 2016-06-12 | 2016-09-07 | 安徽天元电缆有限公司 | Radiation-resistant cable material for nuclear power |
| CN109627537A (en) * | 2017-10-09 | 2019-04-16 | 中广核三角洲（江苏）塑化有限公司 | Preparation process for the resistance to electric track resistant jacket material of aerial optical cable creep resistant |
| CN109627538A (en) * | 2017-10-09 | 2019-04-16 | 中广核三角洲（江苏）塑化有限公司 | The resistance to electric track resistant jacket material of All Dielectric Self-Supporting Aerial Optical Fiber Cable creep resistant |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531789A (en) * | 2009-04-20 | 2009-09-16 | 宝胜科技创新股份有限公司 | Radiation-resistant halogen-free low smoke flame retardant insulating material for cables of nuclear power plants and preparation method |
| CN102816393A (en) * | 2012-07-28 | 2012-12-12 | 安徽弘博电缆有限公司 | Low-smoke low-halogen flame-retardant crosslinked polyolefin insulated cable material and preparation method thereof |
| CN103275401A (en) * | 2013-05-23 | 2013-09-04 | 宝胜科技创新股份有限公司 | Halogen-free low-smoke flame retardant double-layer insulating outer layer material for area-1 cable of AP1000 nuclear power station and preparation method thereof |
| CN103467819A (en) * | 2013-08-26 | 2013-12-25 | 晶锋集团股份有限公司 | High-temperature-resistant and flame-retardant cable material and preparation method thereof |
| CN103589076A (en) * | 2013-11-11 | 2014-02-19 | 江苏大学 | Radiation-resistant halogen-free flame-retardant cable material and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898709B (en) * | 2011-07-27 | 2014-12-31 | 上海凯波特种电缆料厂有限公司 | 150DEG C irradiation crosslinking low-smoke halogen-free flame retardant polyolefin material for automobile wires and preparation thereof |
| US9640300B2 (en) * | 2012-07-13 | 2017-05-02 | Rockbestos Surprenant Cable Corp. | Cable having a thin film material and methods of preventing discoloration damage to a cable having a thin film material |
| CN103483670A (en) * | 2013-10-10 | 2014-01-01 | 长园集团股份有限公司 | 150 DEG C high-flame-retardant halogen-free red phosphorus-free modified material |
-
2014
- 2014-02-26 CN CN201610563379.6A patent/CN106566089A/en active Pending
- 2014-02-26 CN CN201610564012.6A patent/CN106566090A/en active Pending
- 2014-02-26 CN CN201410066061.8A patent/CN103992567B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101531789A (en) * | 2009-04-20 | 2009-09-16 | 宝胜科技创新股份有限公司 | Radiation-resistant halogen-free low smoke flame retardant insulating material for cables of nuclear power plants and preparation method |
| CN102816393A (en) * | 2012-07-28 | 2012-12-12 | 安徽弘博电缆有限公司 | Low-smoke low-halogen flame-retardant crosslinked polyolefin insulated cable material and preparation method thereof |
| CN103275401A (en) * | 2013-05-23 | 2013-09-04 | 宝胜科技创新股份有限公司 | Halogen-free low-smoke flame retardant double-layer insulating outer layer material for area-1 cable of AP1000 nuclear power station and preparation method thereof |
| CN103467819A (en) * | 2013-08-26 | 2013-12-25 | 晶锋集团股份有限公司 | High-temperature-resistant and flame-retardant cable material and preparation method thereof |
| CN103589076A (en) * | 2013-11-11 | 2014-02-19 | 江苏大学 | Radiation-resistant halogen-free flame-retardant cable material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘大华主编: "《合成橡胶工业手册》", 31 December 1991, 化学工业出版社 * |
| 李永河编: "《橡胶硫化技术》", 31 May 2012, 黄河水利出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109651718A (en) * | 2018-12-25 | 2019-04-19 | 佛山科学技术学院 | A kind of EPT rubber cable material that calcinated argil is modified |
| CN111825981A (en) * | 2020-07-20 | 2020-10-27 | 中广核高新核材科技（苏州）有限公司 | Radiation-resistant nuclear-grade thermoplastic low-smoke halogen-free flame-retardant cable sheath material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103992567A (en) | 2014-08-20 |
| CN103992567B (en) | 2016-06-29 |
| CN106566090A (en) | 2017-04-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106566089A (en) | Irradiation-resistant, low-smoke, halogen-free and flame-retardant sheath material for nuclear-grade cables | |
| CN107163585B (en) | It is a kind of can low-temp ceramics silicon rubber and preparation method thereof | |
| CN102977605B (en) | A kind of silicone rubber crosslinking fire-resistant cable material and preparation method thereof | |
| CN101221836B (en) | Low temperature resistant anti-crack rubber sleeve flexible cable used for wind power generation | |
| CN102382358A (en) | Halogen-free flame-retardant cable sheath material for railway locomotive and manufacturing method for halogen-free flame-retardant cable sheath material | |
| CN103642244B (en) | A kind of Fire retardation fireproof material and preparation method | |
| CN101580610B (en) | Insulating crosslinking polyethylene for winding cable | |
| CN104231420B (en) | 105 DEG C of temperature resistant grade irradiated crosslinking low-smoke halogen-free flame-retardant isolating material and preparation method thereof | |
| CN104008807A (en) | Low-smoke power cable for ship | |
| CN107698906A (en) | Undersea detection steady phase high-strength composite cable and preparation method thereof | |
| CN103980619A (en) | Low-smoke halogen-free flame-retardation insulation material for class 1E category K1 cables of nuclear power station | |
| CN104177692A (en) | Cross-linking material for electric cable of battery charge interface of electric vehicle as well as preparation method and use of cross-linking material | |
| CN102746671A (en) | Environmental-crack-resistant low-temperature compensation cable material and its preparation method | |
| CN110041607A (en) | A kind of metal hydroxides-boron nitride hydridization filler/blend rubber nuclear power cable Insulation Material and preparation method | |
| CN103483829A (en) | High-temperature-resistant and flame-retardant silicone rubber and preparation method thereof | |
| CN108203546B (en) | Chemically-crosslinked elastomer cable material for new energy automobile high-voltage wire capable of being used at 175 ℃ for long time, preparation method of chemically-crosslinked elastomer cable material and cable | |
| CN103525072B (en) | A kind of halogen-free flame-retardant polyphenylether cable | |
| CN103985472B (en) | The flat power cable that skeleton connects | |
| CN103468000B (en) | Insulating rubber for high carrying capacity low surface temperature rise cables for ships and preparation method thereof | |
| CN103289282B (en) | A kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof | |
| CN104761832A (en) | Mesoporous silica nano-composite nuclear cable insulation material and preparation method | |
| CN105348617B (en) | A kind of low smoke and zero halogen mesohigh direct current cables cable material of polyolefin and preparation method | |
| CN105295160B (en) | Halogen crosslinkable resin composition, cross linked insulation electric wire and cable | |
| CN113527891A (en) | High-temperature porcelain-forming silicon rubber composition, flame-retardant B1-grade flexible control cable and preparation method thereof | |
| CN103524853B (en) | A kind of formula of cable insulation material of excellent performance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190130 Address after: 215421 No. 90 New North East Road, Shaxi Town, Taicang City, Suzhou City, Jiangsu Province Applicant after: Cgnpc Delta (Jiangsu) Plastic Co., Ltd. Applicant after: China General Nuclear Power Corporation Address before: 215421 No. 90 New North East Road, Shaxi Town, Taicang City, Suzhou City, Jiangsu Province Applicant before: Cgnpc Delta (Jiangsu) Plastic Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170419 |
|
| RJ01 | Rejection of invention patent application after publication |