CN106552605A - A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent - Google Patents
A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent Download PDFInfo
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- CN106552605A CN106552605A CN201611079123.4A CN201611079123A CN106552605A CN 106552605 A CN106552605 A CN 106552605A CN 201611079123 A CN201611079123 A CN 201611079123A CN 106552605 A CN106552605 A CN 106552605A
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- quick lime
- drying agent
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- composite drying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/261—Drying gases or vapours by adsorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/46—Materials comprising a mixture of inorganic and organic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
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- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
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- Processes Of Treating Macromolecular Substances (AREA)
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Disclosed by the invention is a kind of preparation method with polyacrylic acid and organic quick lime composite drying agent, add quick lime and acrylic acid in the vacuum ball grinder of planetary ball mill, take out the air in vacuum ball grinder, it is filled with nitrogen to be ground, after grinding terminates, products obtained therefrom is taken out and is dried, that is, be obtained with acrylic acid and organic quick lime composite drying agent.Organic quick lime composite drying agent moisture sorption effect prepared by the present invention is good, and reaction after water suction relaxes, and safety is good, and process is simple, low cost, and no coupling product production, environmental protection and energy saving are adapted to large-scale production.
Description
Technical field
The present invention relates to it is a kind of with polyacrylic acid and the preparation method of organic quick lime composite drying agent, belong to desiccant system
Standby field.
Background technology
Quick lime is the conventional desiccant that vapor is removed using chemical absorption method, is also used for iron and steel, pesticide, medicine, dry
Dehydration of drying prescription, process hides and alcohol etc..Be particularly well-suited to the local and special products such as puffed food, Lentinus Edodess, Auricularia, and instrument, medicine,
The product of the industries such as dress ornament, electronics telecommunication, leather, weaving.Generally 500-600 DEG C is heated to by material calciferous so as to
It is decomposed into calcium oxide and carbon dioxide.Profile is white, unformed, is widely used in desiccant, typically contains in quick lime
Overdo Calx and the Calx that has not been cooked or heated long enough, and the Calx structure that overdoes is closely knit, and surface often coats one layer of fused mass, dissolves very slowly, has not been cooked or heated long enough in Calx
Calcium Carbonate do not decompose completely, lack cohesive force during use.Quick lime can occur chemical reaction with water, will be heated at once surpass
More 300 DEG C of high temperature.As quick lime and water can occur the chemical reaction (hydration reaction) of fierceness, calcium hydroxide is generated, is had
Extremely strong water absorption, can be used as a kind of fabulous desiccant raw material.But calcium oxide react when can drastically heat release, its reaction swash
It is strong, uncontrollability is shown, blast can be caused often and fire is occurred when storing.
Polyacrylic acid series product it is nontoxic, nonirritant, mildly bitter flavor, with good water solublity, and with many Organic substances
Component has good intermiscibility.As in the recirculating cooling water systems such as power plant, chemical plant, chemical fertilizer factory, oil plant and air conditioning system
Dirt dispersion agent, have extremely wide application in many industries.
The content of the invention
The present invention provide with prepare it is simple, using safety, drying effect is good, be adapted to the technical characterstics such as large-scale production
A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent.
A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent that the present invention is provided, it is using as follows
Step：
1) by mass fraction, 100 parts of lump limes, 5-13 parts acrylic acid and isopropyl alcohol mixture are taken, by 100 parts of blocks
Shape quick lime is crushed, ground 100-240 mesh sieves, is placed in vacuum planetary ball mill tank, vacuum planetary ball mill tank is taken out very
Sky, is filled with nitrogen, adds 5-13 parts acrylic acid and isopropyl alcohol mixture, the vacuum planetary ball mill tank under the conditions of 40-50 DEG C
In, with 1000-2000r/min grinding rates, griding reaction 1-1.5h, grinding rate is then at the uniform velocity reduced, until stopping completely
Grinding, keeps the quiet reaction 0.5-1h of vacuum, obtains product A；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 105-110 DEG C, 1-2h is dried, obtain 3-6mm
The organic quick lime composite drying agent of graininess.
As a kind of improvement, step 1) described in acrylic acid and the mass ratio of isopropanol be 1:1.
Used as a kind of improvement, organic quick lime surface aggregate has polyacrylic acid, the polyacrylic average molecular
Amount is between 100000-2000000.
A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent that the present invention is provided, it is using as follows
Step：
1) by mass fraction, 100 parts of lump limes, 9 parts of acrylic acid and isopropyl alcohol mixture are taken, it is block by 100 parts
Quick lime is crushed, ground 170 mesh sieve, is placed in vacuum planetary ball mill tank, and vacuum planetary ball mill tank evacuation is filled with
Nitrogen, adds 9 parts of acrylic acid and isopropyl alcohol mixture, in the vacuum planetary ball mill tank under the conditions of 45 DEG C, with 1500r/min
Then grinding rate, griding reaction 1.3h at the uniform velocity reduce grinding rate, until stopping grinding completely, keep the quiet reaction of vacuum
0.8h, obtains product A；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 107 DEG C, dry 1.5h, obtain 4.5mm
Granular organic quick lime composite drying agent.
As a kind of improvement, step 1) described in acrylic acid and the mass ratio of isopropanol be 1:1, step 2) institute that obtains
Stating organic quick lime surface aggregate has polyacrylic acid, and the polyacrylic relative molecular weight is 1050000.
The profitable effect of the present invention：Preparation process is filled with sufficient nitrogen, and the desiccant purity prepared is high, granule is equal
It is even；Moisture sorption effect is good, and reaction after water suction relaxes, and safety is good, and process is simple, low cost, no coupling product production, environmental protection and energy saving,
Suitable large-scale production；Polyacrylic acid itself has good wash water so that the moisture in air can not directly by quick lime
Absorb, polyacrylic acid absorbs moisture first, be then passed to quick lime, it is to avoid quick lime directly quickly absorbs moisture, occurs
Vigorous reaction, produces substantial amounts of heat, causes potential safety hazard；Polyacrylic acid non-toxic and safe reliability itself, tensile strength are big, to calculogenesis
There is blast in ash, with protective action.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail：
A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent of the present invention, using following step
Suddenly：
1) by mass fraction, 100 parts of lump limes, 5-13 parts acrylic acid and isopropyl alcohol mixture are taken, by 100 parts of blocks
Shape quick lime is crushed, ground 100-240 mesh sieves, is placed in vacuum planetary ball mill tank, vacuum planetary ball mill tank is taken out very
Sky, is filled with nitrogen, adds 5-13 parts acrylic acid and isopropyl alcohol mixture, the vacuum planetary ball mill tank under the conditions of 40-50 DEG C
In, with 1000-2000r/min grinding rates, griding reaction 1-1.5h, grinding rate is then at the uniform velocity reduced, until stopping completely
Grinding, keeps the quiet reaction 0.5-1h of vacuum, obtains product A；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 105-110 DEG C, 1-2h is dried, obtain 3-6mm
The organic quick lime composite drying agent of graininess.
As a kind of improved embodiment, step 1) described in the mass ratio of acrylic acid and isopropanol be 1:1.
Used as a kind of improved embodiment, organic quick lime surface aggregate has polyacrylic acid, described polyacrylic
Relative molecular weight is between 100000-2000000.
Embodiment 1：A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent, the preparation method are adopted
Following steps：
1) by mass fraction, 100 parts of lump limes, 5 parts of acrylic acid and isopropyl alcohol mixture, described acrylic acid are taken
Mass ratio with isopropanol is 1:1,100 parts of lump limes are crushed, ground 100 mesh sieve is placed in vacuum planet ball
In grinding jar, by vacuum planetary ball mill tank evacuation, nitrogen is filled with, adds 5 parts of acrylic acid and isopropyl alcohol mixture, in 40 DEG C of bars
In vacuum planetary ball mill tank under part, with 1000r/min grinding rates, griding reaction 1h, grinding rate is then at the uniform velocity reduced, directly
To grinding is stopped completely, the quiet reaction 0.5h of vacuum is kept, product A is obtained；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 105 DEG C, 1h is dried, obtain the graininess of 3mm
Organic quick lime composite drying agent, organic quick lime surface aggregate have polyacrylic acid, the polyacrylic average molecular
Measure as 100000.
Embodiment 2：A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent, the preparation method are adopted
Following steps：
1) by mass fraction, 100 parts of lump limes, 9 parts of acrylic acid and isopropyl alcohol mixture, described acrylic acid are taken
Mass ratio with isopropanol is 1:1,100 parts of lump limes are crushed, ground 170 mesh sieve is placed in vacuum planet ball
In grinding jar, by vacuum planetary ball mill tank evacuation, nitrogen is filled with, adds 9 parts of acrylic acid and isopropyl alcohol mixture, in 45 DEG C of bars
In vacuum planetary ball mill tank under part, with 1500r/min grinding rates, griding reaction 1.3h, grinding rate is then at the uniform velocity reduced,
Until stopping grinding completely, the quiet reaction 0.8h of vacuum is kept, product A is obtained；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 107 DEG C, dry 1.5h, obtain 4.5mm
Granular organic quick lime composite drying agent, organic quick lime surface aggregate have polyacrylic acid, described polyacrylic relative
Molecular weight is 1050000.
Embodiment 3：A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent, the preparation method are adopted
Following steps：
1) by mass fraction, 100 parts of lump limes, 13 parts of acrylic acid and isopropyl alcohol mixture, described propylene are taken
Acid is 1 with the mass ratio of isopropanol:1,100 parts of lump limes are crushed, ground 240 mesh sieve is placed in vacuum planet
In ball grinder, by vacuum planetary ball mill tank evacuation, nitrogen is filled with, adds 13 parts of acrylic acid and isopropyl alcohol mixture, 50
In vacuum planetary ball mill tank under the conditions of DEG C, with 2000r/min grinding rates, griding reaction 1.5h, grinding is then at the uniform velocity reduced
Speed, until stopping grinding completely, keeps the quiet reaction 1h of vacuum, obtains product A；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 110 DEG C, 2h is dried, obtain the granule of 3-6mm
The organic quick lime composite drying agent of shape, organic quick lime surface aggregate have a polyacrylic acid, described polyacrylic relative point
Son amount is 2000000.
Embodiment of the present invention is not limited to the above 3 embodiment, by aforementioned disclosed numerical range,
With regard to arbitrarily being replaced in specific embodiment, such that it is able to obtain countless embodiments, this is not enumerated.
Claims (5)
1. a kind of preparation method with polyacrylic acid and organic quick lime composite drying agent, it is characterised in that the preparation method is adopted
Following steps：
1) by mass fraction, 100 parts of lump limes, 5-13 parts acrylic acid and isopropyl alcohol mixture are taken, it is block raw by 100 parts
Calx is crushed, ground 100-240 mesh sieves, is placed in vacuum planetary ball mill tank, and vacuum planetary ball mill tank evacuation fills
Enter nitrogen, add 5-13 parts acrylic acid and isopropyl alcohol mixture, in the vacuum planetary ball mill tank under the conditions of 40-50 DEG C, with
Then 1000-2000r/min grinding rates, griding reaction 1-1.5h at the uniform velocity reduce grinding rate, until stop grinding completely,
The quiet reaction 0.5-1h of vacuum is kept, product A is obtained；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 105-110 DEG C, dry 1-2h, obtain 3-6mm
Granular organic quick lime composite drying agent.
2. a kind of preparation method with polyacrylic acid and organic quick lime composite drying agent according to claim 1, which is special
Levy and be：Step 1) described in the mass ratio of acrylic acid and isopropanol be 1:1.
3. a kind of preparation method with polyacrylic acid and organic quick lime composite drying agent according to claim 1, which is special
Levy and be：Organic quick lime surface aggregate has polyacrylic acid, and the polyacrylic relative molecular weight is in 100000-
Between 2000000.
4. a kind of preparation method with polyacrylic acid and organic quick lime composite drying agent, it is characterised in that the preparation method is adopted
Following steps：
1) by mass fraction, 100 parts of lump limes, 9 parts of acrylic acid and isopropyl alcohol mixture are taken, by 100 parts of block calculogenesis
Ash is crushed, ground 170 mesh sieve, is placed in vacuum planetary ball mill tank, by vacuum planetary ball mill tank evacuation, is filled with nitrogen
Gas, is added 9 parts of acrylic acid and isopropyl alcohol mixture, in the vacuum planetary ball mill tank under the conditions of 45 DEG C, is ground with 1500r/min
Then mill speed, griding reaction 1.3h at the uniform velocity reduce grinding rate, until stopping grinding completely, keep the quiet reaction 0.8h of vacuum,
Obtain product A；
2) take step 1) the product A that obtains, in the baking oven being placed under the conditions of 107 DEG C, 1.5h is dried, obtain the graininess of 4.5mm
Organic quick lime composite drying agent.
5. a kind of preparation method with polyacrylic acid and organic quick lime composite drying agent according to claim 4, which is special
Levy and be：Step 1) described in the mass ratio of acrylic acid and isopropanol be 1:1, step 2) described organic quick lime table for obtaining
Face polymerization has polyacrylic acid, and the polyacrylic relative molecular weight is 1050000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611079123.4A CN106552605B (en) | 2016-11-30 | 2016-11-30 | A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611079123.4A CN106552605B (en) | 2016-11-30 | 2016-11-30 | A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent |
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| Publication Number | Publication Date |
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| CN106552605A true CN106552605A (en) | 2017-04-05 |
| CN106552605B CN106552605B (en) | 2019-03-26 |
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| CN201611079123.4A Expired - Fee Related CN106552605B (en) | 2016-11-30 | 2016-11-30 | A kind of preparation method with polyacrylic acid and organic quick lime composite drying agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109126399A (en) * | 2018-08-22 | 2019-01-04 | 浙江理工大学 | A kind of preparation method of fibroin and organic quick lime composite drying agent of modified polyurethane rigid foam plastic wraps |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007121259A2 (en) * | 2006-04-11 | 2007-10-25 | Alcan Packaging Flexible France | Films having a desiccant material incorporated therein and methods of use and manufacture |
| WO2015038129A1 (en) * | 2013-09-12 | 2015-03-19 | Multisorb Technologies, Inc. | Coated sorbents and methods of making |
| CN104910366A (en) * | 2015-05-19 | 2015-09-16 | 浙江理工大学 | Organic quicklime composite desiccant and preparation method therefor |
| CN104923043A (en) * | 2015-05-19 | 2015-09-23 | 浙江理工大学 | Organic quicklime composite desiccant and preparation method thereof |
-
2016
- 2016-11-30 CN CN201611079123.4A patent/CN106552605B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007121259A2 (en) * | 2006-04-11 | 2007-10-25 | Alcan Packaging Flexible France | Films having a desiccant material incorporated therein and methods of use and manufacture |
| WO2015038129A1 (en) * | 2013-09-12 | 2015-03-19 | Multisorb Technologies, Inc. | Coated sorbents and methods of making |
| CN104910366A (en) * | 2015-05-19 | 2015-09-16 | 浙江理工大学 | Organic quicklime composite desiccant and preparation method therefor |
| CN104923043A (en) * | 2015-05-19 | 2015-09-23 | 浙江理工大学 | Organic quicklime composite desiccant and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109126399A (en) * | 2018-08-22 | 2019-01-04 | 浙江理工大学 | A kind of preparation method of fibroin and organic quick lime composite drying agent of modified polyurethane rigid foam plastic wraps |
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| CN106552605B (en) | 2019-03-26 |
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Granted publication date: 20190326 Termination date: 20211130 |