CN106543747A - A kind of metallized membrane capacitance embedding material - Google Patents

A kind of metallized membrane capacitance embedding material Download PDF

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Publication number
CN106543747A
CN106543747A CN201610946375.6A CN201610946375A CN106543747A CN 106543747 A CN106543747 A CN 106543747A CN 201610946375 A CN201610946375 A CN 201610946375A CN 106543747 A CN106543747 A CN 106543747A
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CN
China
Prior art keywords
embedding material
membrane capacitance
modified
stirring
oil
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Pending
Application number
CN201610946375.6A
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Chinese (zh)
Inventor
胡忠胜
华玲萍
吴良军
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Anhui Feida Electrical Technology Co Ltd
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Anhui Feida Electrical Technology Co Ltd
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Priority to CN201610946375.6A priority Critical patent/CN106543747A/en
Publication of CN106543747A publication Critical patent/CN106543747A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/224Housing; Encapsulation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of metallized membrane capacitance embedding material of disclosure of the invention, is made up of following component:Modified salad oil, mica powder, glutamic acid, polyvinyl alcohol resin, polyisobutylene, soybean lecithin, latent curing agent, plasticizer.Embedding Material of the present invention has an excellent electrical properties, and moisture resistance, flowing domestic animal, thermostability and tolerance to cold are good, with good performance, ensure that stablizing for metallization film capacitor electrical property, can abundant added metal membrane capacitance gap.

Description

A kind of metallized membrane capacitance embedding material
Technical field
The present invention relates to capacitor technology field, more particularly to a kind of metallized membrane capacitance embedding material.
Background technology
Capacitor is quite varied in electric field application, in metallization film capacitor production, main medium and pole plate with Hole between main medium typically carries out embedding with a kind of material, to improve capacitance and insulating properties, and improves local and puts Electricity and heat resistance., there is under toughness plasticity difference low temperature easily embrittlement and have larger contraction in simple commodity in use paraffin or microwax Etc. defect, and there are many deficiencies in many places with epoxy fill-sealing materials performance, such as:It is elastic not enough, viscosity is big, solidification when There is certain internal stress, easily ftracture, the problems such as heatproof rushes ability.
The content of the invention
It is an object of the invention to provide a kind of metallized membrane capacitance embedding material, is achieved through the following technical solutions:
A kind of metallized membrane capacitance embedding material, is made up of following component by weight:Modified salad oil 80-120, Muscovitum Powder 15-18, glutamic acid 4-6, polyvinyl alcohol resin 6-10, polyisobutylene 5-8, soybean lecithin 2-5, latent curing agent 4-6, Plasticizer 2-4;The modified salad oil is 20 with latent curing agent mass ratio:1.
Further, the modified salad oil is made up of following component by weight:Fructus Zanthoxyli oil 2, canola oil 1, Fructus Vitis viniferae Seed oil 3, Oleum Ricini 12, butyrolactone 0.2,2- propyl group-thiophene 0.1, Methyl cellulose 0.3, its preparation method is:By Fructus Zanthoxyli oil, mustard Caul-fat, Oleum Vitis viniferae, Oleum Ricini are admixed together by respective weight portion, are heated to 68-72 DEG C, are stirred with 180r/min rotating speeds After 20min, add butyrolactone and methylcellulose, after continuing stirring 25min, add 2- propyl group-thiophene, continue to stir 35min Afterwards, it is incubated, stands 20min, then through deacidification, removing impurities, dephosphorization treatment, modified salad oil needed for obtaining final product.
Further, the plasticizer is tributyl citrate.
Further, the latent curing agent is made up of following component by weight:Melmac 4, phenyl Glycidyl ether 0.1, isooctyl acid 1.8, calcium sulfate 1.4, benzoin ethyl ether 0.1.
Further, the preparation method of the metallized membrane capacitance embedding material, comprises the following steps:
(1)The modified salad oil of corresponding weight, glutamic acid, polyvinyl alcohol resin are added in 55-58 DEG C of a mixing bowl, with 250r/min rotating speeds are stirred;
(2)Mica powder, the polyisobutylene of corresponding weight are weighed, is added slowly in a mixing bowl for stirring, adjust stirring speed Spend for 200r/min, continuation stirring;
(3)Weigh the soybean lecithin of corresponding weight, plasticizer to be added in a mixing bowl for stirring, continue with 200r/min Rotating speed is stirred 1 hour;
(4)The latent curing agent for weighing corresponding weight is added in a mixing bowl for stirring, and adjusts mixing speed to 800- 1000r/min, persistently stirs 2-3 hours, naturally cools to room temperature, you can, sealing is kept in dark place, and storage temperature is less than 30 ℃。
Metallized membrane capacitance embedding materials'use post cure condition of the present invention is preferably 43 DEG C at 40-45 DEG C, and is matched somebody with somebody Conjunction ultraviolet light UVA irradiation 30-25s, preferred 32s, the present invention coordinate ultraviolet light UVA irradiation 32s at 43 DEG C, and solidification is most smooth, Solidfied material is best in quality.
Beneficial effect of the present invention:Embedding Material of the present invention has an excellent electrical properties, moisture resistance, flowing domestic animal, thermostability and resistance to It is cold good, with good performance, stablizing for metallization film capacitor electrical property is ensure that, can abundant added metal Change membrane capacitance gap, harmful effect will not be produced to metallization film capacitor service behaviour;The present invention is by using modified color Draw oil to coordinate the coordinated effect of polyvinyl alcohol resin and soybean lecithin, enable to Embedding Material toughness plasticity height, low temperature Under be difficult embrittlement, water-tolerant, cure shrinkage are little, internal stress free when anti-seismic performance and heatproof rush good ability, solidification, it is to avoid The generation of cracking phenomena, can improve the capacitance and electrical strength of capacitor, and can improve partial discharge performance and thermostability.
Specific embodiment
Embodiment 1
A kind of metallized membrane capacitance embedding material, is made up of following component by weight:Modified salad oil 80, mica powder 15th, glutamic acid 4, polyvinyl alcohol resin 6, polyisobutylene 5, soybean lecithin 2, latent curing agent 4, plasticizer 2;It is described modified Salad oil is 20 with latent curing agent mass ratio:1.
Embodiment 2
A kind of metallized membrane capacitance embedding material, is made up of following component by weight:Modified salad oil 120, mica powder 18th, glutamic acid 6, polyvinyl alcohol resin 10, polyisobutylene 8, soybean lecithin 5, latent curing agent 6, plasticizer 4;It is described to change Property salad oil and latent curing agent mass ratio be 20:1.
Embodiment 3
A kind of metallized membrane capacitance embedding material, is made up of following component by weight:Modified salad oil 100, mica powder 16th, glutamic acid 5, polyvinyl alcohol resin 8, polyisobutylene 6, soybean lecithin 3, latent curing agent 5, plasticizer 3;It is described modified Salad oil is 20 with latent curing agent mass ratio:1.
In above-described embodiment:
Further, the modified salad oil is made up of following component by weight:Fructus Zanthoxyli oil 2, canola oil 1, Oleum Vitis viniferae 3rd, Oleum Ricini 12, butyrolactone 0.2,2- propyl group-thiophene 0.1, Methyl cellulose 0.3, its preparation method is:By Fructus Zanthoxyli oil, canola oil, Oleum Vitis viniferae, Oleum Ricini are admixed together by respective weight portion, are heated to 68-72 DEG C, stir 20min with 180r/min rotating speeds Afterwards, add butyrolactone and methylcellulose, after continuing stirring 25min, add 2- propyl group-thiophene, after continuing stirring 35min, protect Temperature, stands 20min, then through deacidification, removing impurities, dephosphorization treatment, modified salad oil needed for obtaining final product.
Further, the plasticizer is tributyl citrate.
Further, latent curing agent is made up of following component by weight:Melmac 4, phenyl glycidyl Glycerin ether 0.1, isooctyl acid 1.8, calcium sulfate 1.4, benzoin ethyl ether 0.1.
Further, the preparation method of the metallized membrane capacitance embedding material, comprises the following steps:
(1)The modified salad oil of corresponding weight, glutamic acid, polyvinyl alcohol resin are added in 55-58 DEG C of a mixing bowl, with 250r/min rotating speeds are stirred;
(2)Mica powder, the polyisobutylene of corresponding weight are weighed, is added slowly in a mixing bowl for stirring, adjust stirring speed Spend for 200r/min, continuation stirring;
(3)Weigh the soybean lecithin of corresponding weight, plasticizer to be added in a mixing bowl for stirring, continue with 200r/min Rotating speed is stirred 1 hour;
(4)The latent curing agent for weighing corresponding weight is added in a mixing bowl for stirring, and adjusts mixing speed to 800- 1000r/min, persistently stirs 2-3 hours, naturally cools to room temperature, you can, sealing is kept in dark place, and storage temperature is less than 30 ℃。
Metallized membrane capacitance embedding materials'use post cure condition of the present invention is preferably 43 DEG C at 40-45 DEG C, and is matched somebody with somebody Conjunction ultraviolet light UVA irradiation 20-25s, preferred 22s, the present invention coordinate ultraviolet light UVA irradiation 22s at 43 DEG C, and solidification is most smooth, Solidfied material is best in quality.
Embedding Material excellent flame retardancy of the present invention, can reach UL-94, V-0 levels.Additionally, its solidfied material temperature for- At 48-148 DEG C, can vary with temperature and dilation, be brought into close contact with capacitor body all the time, keep good insulating properties Can, also, in the temperature range, capacitor normally can be used.In addition, using embedding obtained in above-described embodiment 1 The capacitor life-span performance of material perfusion can about improve 20%, using the electric capacity of Embedding Material perfusion obtained in above-described embodiment 2 The device life-span can about improve 21%, can about be improved using the capacitor life-span of Embedding Material perfusion obtained in above-described embodiment 3 22%, effect is significant, when the salad oil that is modified in embodiment 3 is substituted for common salad oil, the capacitor life-span of perfusion can about be carried It is high by 10%, when latent curing agent in embodiment 3 is changed to 18 with modified salad oil mass ratio:1, be modified salad oil addition Constant, the capacitor life-span of perfusion can about improve 18%.
Through detection, in the present embodiment, the main performance of gained electric capacity impregnating agent is as follows:
Table 1
Wherein, comparative example 1 and the difference of the embodiment of the present invention 3 are only that modified salad oil is replaced with Oleum Ricini;
As can be seen from Table 1, the Embedding Material superior performance that prepared by the present invention.

Claims (5)

1. a kind of metallized membrane capacitance embedding material, it is characterised in that be made up of following component by weight:Modified salad It is oily 80-120, mica powder 15-18, glutamic acid 4-6, polyvinyl alcohol resin 6-10, polyisobutylene 5-8, soybean lecithin 2-5, latent Volt property firming agent 4-6, plasticizer 2-4;The modified salad oil is 20 with latent curing agent mass ratio:1.
2. a kind of metallized membrane capacitance embedding material according to claim 1, it is characterised in that the modified salad oil It is made up of following component by weight:Fructus Zanthoxyli oil 2, canola oil 1, Oleum Vitis viniferae 3, Oleum Ricini 12, butyrolactone 0.2,2- propyl group- Thiophene 0.1, Methyl cellulose 0.3, its preparation method is:Fructus Zanthoxyli oil, canola oil, Oleum Vitis viniferae, Oleum Ricini are pressed into respective weight portion It is admixed together, 68-72 DEG C is heated to, is stirred after 20min with 180r/min rotating speeds, is added butyrolactone and methylcellulose, after After continuous stirring 25min, add 2- propyl group-thiophene, after continuing stirring 35min, insulation stands 20min, then through deacidification, de- Miscellaneous, dephosphorization treatment, modified salad oil needed for obtaining final product.
3. a kind of metallized membrane capacitance embedding material according to claim 1, it is characterised in that the plasticizer is lemon Lemon acid tributyl.
4. a kind of metallized membrane capacitance embedding material according to claim 1, it is characterised in that the latent curing Agent is made up of following component by weight:Melmac 4, phenyl glycidyl ether 0.1, isooctyl acid 1.8, calcium sulfate 1.4th, benzoin ethyl ether 0.1.
5. a kind of metallized membrane capacitance embedding material according to any one of claim 1-4, it is characterised in that the gold The preparation method of categoryization membrane capacitance Embedding Material, comprises the following steps:
(1)The modified salad oil of corresponding weight, glutamic acid, polyvinyl alcohol resin are added in 55-58 DEG C of a mixing bowl, with 250r/min rotating speeds are stirred;
(2)Mica powder, the polyisobutylene of corresponding weight are weighed, is added slowly in a mixing bowl for stirring, adjust stirring speed Spend for 200r/min, continuation stirring;
(3)Weigh the soybean lecithin of corresponding weight, plasticizer to be added in a mixing bowl for stirring, continue with 200r/min Rotating speed is stirred 1 hour;
(4)The latent curing agent for weighing corresponding weight is added in a mixing bowl for stirring, and adjusts mixing speed to 800- 1000r/min, persistently stirs 2-3 hours, naturally cools to room temperature, you can, sealing is kept in dark place, and storage temperature is less than 30 ℃。
CN201610946375.6A 2016-10-26 2016-10-26 A kind of metallized membrane capacitance embedding material Pending CN106543747A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659135A (en) * 2018-11-29 2019-04-19 天津大学 The dc breakdown field strength method of condenser dielectric film is improved based on benzoin

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103540143A (en) * 2012-07-04 2014-01-29 江苏泰尔新材料股份有限公司 Wax for self-healing metalized capacitor
CN104292851A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 Filling and sealing agent composition for high pressure traction energy storage capacitor
CN104292750A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 IGBT absorption protection capacitor epoxy resin potting agent
CN104312427A (en) * 2014-10-11 2015-01-28 铜陵市新泰电容电器有限责任公司 Oily anti-oxidation film surface oil material for metalized capacitor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103540143A (en) * 2012-07-04 2014-01-29 江苏泰尔新材料股份有限公司 Wax for self-healing metalized capacitor
CN104292851A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 Filling and sealing agent composition for high pressure traction energy storage capacitor
CN104292750A (en) * 2014-09-24 2015-01-21 铜陵市新泰电容电器有限责任公司 IGBT absorption protection capacitor epoxy resin potting agent
CN104312427A (en) * 2014-10-11 2015-01-28 铜陵市新泰电容电器有限责任公司 Oily anti-oxidation film surface oil material for metalized capacitor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
胡玉明等: "《固化剂》", 30 April 2004, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659135A (en) * 2018-11-29 2019-04-19 天津大学 The dc breakdown field strength method of condenser dielectric film is improved based on benzoin
CN109659135B (en) * 2018-11-29 2021-01-05 天津大学 Method for improving direct-current breakdown field strength of capacitor dielectric film based on benzoin

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Application publication date: 20170329

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