CN106540817A - The method for floating of limonite is removed in a kind of concentrate from potassium feldspar - Google Patents
The method for floating of limonite is removed in a kind of concentrate from potassium feldspar Download PDFInfo
- Publication number
- CN106540817A CN106540817A CN201611116610.3A CN201611116610A CN106540817A CN 106540817 A CN106540817 A CN 106540817A CN 201611116610 A CN201611116610 A CN 201611116610A CN 106540817 A CN106540817 A CN 106540817A
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- CN
- China
- Prior art keywords
- limonite
- potassium feldspar
- concentrate
- iron content
- plus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/08—Subsequent treatment of concentrated product
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/002—Inorganic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/005—Dispersants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/06—Depressants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/10—Potassium ores
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The method for floating of limonite is removed in a kind of concentrate from potassium feldspar, is comprised the steps:Using sodium hexameta phosphate as dispersant, make the inhibitor of potassium feldspar with mercaptopropionic acid sodium and acid black, hydroxamic acid is made the activator of limonite, combined with lauryl amine with enuatrol and make limonite collecting agent;In floatation process, first plus after ore pulp is disperseed by sodium hexameta phosphate, then plus mercaptopropionic acid sodium makees the inhibitor of potassium feldspar with acid black, add the activator that hydroximic acid makees limonite, finally plus enuatrol combines collecting limonite with lauryl amine, mine tailing is then potassium feldspar concentrate product that iron content is relatively low.The limonite in potassium feldspar concentrate can be effectively removed using the present invention, the iron content of potassium feldspar concentrate in mine tailing is reduced.Under the conditions of being 1.84~2.71%, potassium feldspar 88.10~89.36% to ore deposit iron content, triple cleaning is scanned three times through one roughing, iron content 0.15~0.18% is obtained, K-feldspar 91.30~92.54%, the response rate are 85.10~86.35% potassium feldspar concentrate.
Description
First, technical field
The present invention relates to the method for floating of limonite is removed in a kind of concentrate from potassium feldspar, it is adaptable to need to reduce potassium feldspar
The method for floating of iron content in concentrate.
2nd, background technology
China's potassium feldspar rich in mineral resources, widely distributed and distribution Relatively centralized, becomes China's advantage nonmetallic minerals
Resource.With the development of science and technology, potassium feldspar is widely used in commercial production.China is using potassium feldspar production glass, pottery
The industries such as the side such as porcelain, chemical fertilizer, have strictly to the iron content in potassium feldspar raw material when being especially applicable to the industries such as glass, ceramics
Requirement, the height of one side iron content not only affects the whiteness of product, while have an effect on the performance of product, if by potassium feldspar
Iron content in raw material is reduced to a certain extent, can not only improve product quality, while can also improve product economy value, be enterprise
Industry increases economic benefit.
3rd, the content of the invention
It is an object of the invention to provide the method for floating of limonite is removed in a kind of concentrate from potassium feldspar, it can reduce
Iron content in potassium feldspar concentrate, improves potassium feldspar concentrate quality.
The present invention is employed the following technical solutions and reaches above-mentioned purpose:The flotation of limonite is removed in a kind of concentrate from potassium feldspar
Method, raw materials used for potassium feldspar concentrate, in concentrate, iron content is 1.84~2.71%, potassium feldspar 88.10~89.36%, thing
Facies analyses show, in addition to potassium feldspar, impure mineral is mainly limonite and a small amount of goethitum, aluminum silicon mineral and calcareous mineral,
Comprise the following steps and regime of agent:
(1) using sodium hexameta phosphate as dispersant,
(2) mercaptopropionic acid sodium and acid black make the inhibitor of wollastonite,
(3) hydroxamic acid makees the activator of limonite,
(4) combined with lauryl amine with enuatrol and make limonite collecting agent,
(5) in floatation process, first plus after ore pulp is disperseed by sodium hexameta phosphate, then plus mercaptopropionic acid sodium makees potassium with acid black
The inhibitor of Anhydrite, adds the activator that hydroximic acid makees limonite, finally plus enuatrol combines collecting limonite with lauryl amine,
Mine tailing is then the potassium feldspar concentrate product that iron content is relatively low,
(6) dosing is:
During use, the medicament is first configured to into following concentration expressed in percentage by weight:
Unless otherwise indicated, percentage ratio of the present invention is mass percent, and each component content percent sum is
100%.
The present invention's has the prominent advantages that:
1st, the limonite in potassium feldspar concentrate, the iron content in reduction mine tailing in potassium feldspar concentrate can effectively be removed.
2nd, flowage structure is simple, and dosing is few, less energy consumption.
4th, specific embodiment
By the following examples technical scheme is described in further detail.
Embodiment 1
In the long concentrate from potassium of the present invention remove limonite method for floating an example, comprise the following steps and
Regime of agent:
1. raw mineral materials:
It is raw materials used that in concentrate, iron content is 1.84%, potassium feldspar 88.10%, and material phase analysis show for potassium feldspar concentrate,
In addition to potassium feldspar, impure mineral is mainly limonite and a small amount of goethitum, aluminum silicon mineral and calcareous mineral.
2. floating agent and operating condition:
In floatation process, first plus after ore pulp is disperseed by sodium hexameta phosphate, then plus mercaptopropionic acid sodium to make potassium with acid black long
The inhibitor of stone, adds the activator that hydroximic acid makees limonite, finally plus enuatrol combines collecting limonite, tail with lauryl amine
Ore deposit is then the relatively low potassium feldspar concentrate product of iron content.Test is shown, effectively can be removed using process above and agentia condition brown
Iron mine, is being 1.84% to ore deposit iron content, under the conditions of potassium feldspar 88.10%, is scanning triple cleaning three times through one roughing, obtain
Iron content 0.15% is obtained, K-feldspar 91.30%, the response rate are 85.10% potassium feldspar concentrate.
Embodiment 2
Another example of the method for floating of limonite, including following step are removed in the concentrate from potassium feldspar of the present invention
Rapid and regime of agent:
1. raw mineral materials:
It is raw materials used that in concentrate, iron content is 2.12%, potassium feldspar 88.67%, and material phase analysis show for wollastonite concentrate,
In addition to wollastonite, impure mineral is mainly limonite and a small amount of goethitum, aluminum silicon mineral and calcareous mineral.
2. floating agent and operating condition:
In floatation process, first plus after ore pulp is disperseed by sodium hexameta phosphate, then plus mercaptopropionic acid sodium to make potassium with acid black long
The inhibitor of stone, adds the activator that hydroximic acid makees limonite, finally plus enuatrol combines collecting limonite, tail with lauryl amine
Ore deposit is then the relatively low potassium feldspar concentrate product of iron content.Test is shown, effectively can be removed using process above and agentia condition brown
Iron mine, is being 2.12% to ore deposit iron content, under the conditions of potassium feldspar 88.67%, is scanning triple cleaning three times through one roughing, obtain
Iron content 0.16% is obtained, K-feldspar 91.77%, the response rate are 85.90% potassium feldspar concentrate.
Embodiment 3
Another example of the method for floating of limonite, including following step are removed in the concentrate from potassium feldspar of the present invention
Rapid and regime of agent:
1. raw mineral materials:
It is raw materials used that in concentrate, iron content is 2.71%, potassium feldspar 89.36%, and material phase analysis show for wollastonite concentrate,
In addition to wollastonite, impure mineral is mainly limonite and a small amount of goethitum, aluminum silicon mineral and calcareous mineral.
2. floating agent and operating condition:
In floatation process, first plus after ore pulp is disperseed by sodium hexameta phosphate, then plus mercaptopropionic acid sodium to make potassium with acid black long
The inhibitor of stone, adds the activator that hydroximic acid makees limonite, finally plus enuatrol combines collecting limonite, tail with lauryl amine
Ore deposit is then the relatively low potassium feldspar concentrate product of iron content.Test is shown, effectively can be removed using process above and agentia condition brown
Iron mine, is being 2.71% to ore deposit iron content, under the conditions of potassium feldspar 89.36%, is scanning triple cleaning three times through one roughing, obtain
Iron content 0.18% is obtained, K-feldspar 92.54%, the response rate are 86.35% potassium feldspar concentrate.
Claims (2)
1. the method for floating of limonite is removed in a kind of concentrate from potassium feldspar, it is characterised in that raw materials used for potassium feldspar concentrate,
In concentrate, iron content is 1.84~2.71%, potassium feldspar 88.10~89.36%, and material phase analysis show, in addition to potassium feldspar, impurity
Mineral are mainly limonite and a small amount of goethitum, aluminum silicon mineral and calcareous mineral,
Comprise the following steps and regime of agent:
(1) using sodium hexameta phosphate as dispersant,
(2) mercaptopropionic acid sodium and acid black make the inhibitor of wollastonite,
(3) hydroxamic acid makees the activator of limonite,
(4) combined with lauryl amine with enuatrol and make limonite collecting agent,
(5) in floatation process, first plus after ore pulp is disperseed by sodium hexameta phosphate, then plus mercaptopropionic acid sodium makees potassium feldspar with acid black
Inhibitor, add the activator that hydroximic acid makees limonite, finally plus enuatrol combines collecting limonite, mine tailing with lauryl amine
It is then the potassium feldspar concentrate product that iron content is relatively low,
(6) dosing is:
2. the method for floating of limonite is removed in the concentrate from potassium feldspar according to claim 1, it is characterised in that
During use, the medicament is first configured to into following concentration expressed in percentage by weight:
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109052422A (en) * | 2018-08-30 | 2018-12-21 | 贺州市骏鑫矿产品有限责任公司 | The purifying technique of potassium feldspar emery dust |
CN109052423A (en) * | 2018-08-31 | 2018-12-21 | 贺州市骏鑫矿产品有限责任公司 | A kind of method of purification of potassium albite ore |
CN109179434A (en) * | 2018-08-31 | 2019-01-11 | 贺州市骏鑫矿产品有限责任公司 | A kind of deferrization process of low-quality potassium feldspar |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109052422A (en) * | 2018-08-30 | 2018-12-21 | 贺州市骏鑫矿产品有限责任公司 | The purifying technique of potassium feldspar emery dust |
CN109052423A (en) * | 2018-08-31 | 2018-12-21 | 贺州市骏鑫矿产品有限责任公司 | A kind of method of purification of potassium albite ore |
CN109179434A (en) * | 2018-08-31 | 2019-01-11 | 贺州市骏鑫矿产品有限责任公司 | A kind of deferrization process of low-quality potassium feldspar |
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