CN106539056A - A kind of reductive water maltosemalt sugar and its Mashing process for having high moisturizing activity - Google Patents
A kind of reductive water maltosemalt sugar and its Mashing process for having high moisturizing activity Download PDFInfo
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- CN106539056A CN106539056A CN201610925525.5A CN201610925525A CN106539056A CN 106539056 A CN106539056 A CN 106539056A CN 201610925525 A CN201610925525 A CN 201610925525A CN 106539056 A CN106539056 A CN 106539056A
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- sugar
- alcohol
- reductive water
- amylase
- maltosemalt sugar
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 230000002829 reductive effect Effects 0.000 title claims abstract description 27
- 230000003020 moisturizing effect Effects 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000005360 mashing Methods 0.000 title claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- DBTMGCOVALSLOR-UHFFFAOYSA-N 32-alpha-galactosyl-3-alpha-galactosyl-galactose Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(OC2C(C(CO)OC(O)C2O)O)OC(CO)C1O DBTMGCOVALSLOR-UHFFFAOYSA-N 0.000 claims abstract description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 6
- RXVWSYJTUUKTEA-UHFFFAOYSA-N D-maltotriose Natural products OC1C(O)C(OC(C(O)CO)C(O)C(O)C=O)OC(CO)C1OC1C(O)C(O)C(O)C(CO)O1 RXVWSYJTUUKTEA-UHFFFAOYSA-N 0.000 claims abstract description 6
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims abstract description 6
- LUEWUZLMQUOBSB-UHFFFAOYSA-N UNPD55895 Natural products OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(OC2C(OC(OC3C(OC(O)C(O)C3O)CO)C(O)C2O)CO)C(O)C1O LUEWUZLMQUOBSB-UHFFFAOYSA-N 0.000 claims abstract description 6
- UYQJCPNSAVWAFU-UHFFFAOYSA-N malto-tetraose Natural products OC1C(O)C(OC(C(O)CO)C(O)C(O)C=O)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(O)C(CO)O2)O)C(CO)O1 UYQJCPNSAVWAFU-UHFFFAOYSA-N 0.000 claims abstract description 6
- LUEWUZLMQUOBSB-OUBHKODOSA-N maltotetraose Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O[C@@H]3[C@@H](O[C@@H](O)[C@H](O)[C@H]3O)CO)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-OUBHKODOSA-N 0.000 claims abstract description 6
- FYGDTMLNYKFZSV-UHFFFAOYSA-N mannotriose Natural products OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(OC2C(OC(O)C(O)C2O)CO)C(O)C1O FYGDTMLNYKFZSV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 238000000746 purification Methods 0.000 claims abstract description 6
- 239000000600 sorbitol Substances 0.000 claims abstract description 6
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 claims abstract description 6
- 229920001542 oligosaccharide Polymers 0.000 claims abstract description 5
- 150000002482 oligosaccharides Chemical class 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims description 31
- 150000005846 sugar alcohols Chemical class 0.000 claims description 24
- 239000004382 Amylase Substances 0.000 claims description 19
- 102000004190 Enzymes Human genes 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 238000005349 anion exchange Methods 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- 238000005984 hydrogenation reaction Methods 0.000 claims description 10
- 235000013336 milk Nutrition 0.000 claims description 10
- 239000008267 milk Substances 0.000 claims description 10
- 210000004080 milk Anatomy 0.000 claims description 10
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 238000005341 cation exchange Methods 0.000 claims description 8
- 108010065511 Amylases Proteins 0.000 claims description 7
- 102000013142 Amylases Human genes 0.000 claims description 7
- 108010073178 Glucan 1,4-alpha-Glucosidase Proteins 0.000 claims description 7
- 102100022624 Glucoamylase Human genes 0.000 claims description 7
- 235000019418 amylase Nutrition 0.000 claims description 7
- 108010019077 beta-Amylase Proteins 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 239000002028 Biomass Substances 0.000 claims description 5
- 229920002261 Corn starch Polymers 0.000 claims description 5
- 239000007868 Raney catalyst Substances 0.000 claims description 5
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 claims description 5
- 229910000564 Raney nickel Inorganic materials 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- 239000008120 corn starch Substances 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 229910052705 radium Inorganic materials 0.000 claims description 5
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 230000002000 scavenging effect Effects 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 235000013305 food Nutrition 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- 230000000675 anti-caries Effects 0.000 abstract description 2
- 206010012601 diabetes mellitus Diseases 0.000 abstract description 2
- 235000005911 diet Nutrition 0.000 abstract description 2
- 230000037213 diet Effects 0.000 abstract description 2
- 239000003906 humectant Substances 0.000 abstract description 2
- 238000010186 staining Methods 0.000 abstract description 2
- 238000002425 crystallisation Methods 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 3
- 229920001908 Hydrogenated starch hydrolysate Polymers 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 208000002925 dental caries Diseases 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P19/00—Preparation of compounds containing saccharide radicals
- C12P19/44—Preparation of O-glycosides, e.g. glucosides
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P19/00—Preparation of compounds containing saccharide radicals
- C12P19/14—Preparation of compounds containing saccharide radicals produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase, e.g. by cellulase, hemicellulase
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P19/00—Preparation of compounds containing saccharide radicals
- C12P19/22—Preparation of compounds containing saccharide radicals produced by the action of a beta-amylase, e.g. maltose
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
The invention discloses a kind of reductive water maltosemalt sugar and its Mashing process for having high moisturizing activity, in the concentrated solution of the reductive water maltosemalt sugar, the mass percent concentration of the chemical composition not comprising water is as follows：Oligosaccharide alcohol 10 15%；Maltotetraose alcohol 1 5%；Maltotriose alcohol 2 5%；Maltose alcohol 32 35%；Sorbitol 42 48%.The procedure of processing of the reductive water maltosemalt sugar is as follows：Liquefying-saccharifying of sizing mixing decolourizes to be hydrogenated with purification concentration.A kind of reductive water maltosemalt sugar of the high moisturizing activity of tool of the present invention is compared to the prior art, with superperformances such as non-staining, anti-crystallization, humectants, in food production field, particularly have a good application prospect in terms of diet food, anti-caries food and diabetic special food；The Mashing process is simple, easy to operate, easily realizes industrialization production.
Description
Technical field
The present invention relates to technical field of food preparation, specifically a kind of reductive water maltosemalt sugar and its sugar for having high moisturizing activity
Chemical industry skill.
Background technology
Reductive water maltosemalt sugar as feature hydrogenated starch hydrolysate, with the food additive additivity energy such as good moisturizing, crystallization-preventive
With low energy, the health care characteristic of non-dental caries.These properties cause it to be widely used in chemical industry, light industry, food etc.
Industry.Especially in the food industry, it is a kind of functional sweetener for having much prospect, goes through in the application of Japan's existing more than ten years
History, also goes through to use in other many countries.And China is for the research not system and deeply in this field, in hydrogenated starch
It is after the various excellent materializations of hydrolysate and physiology characteristic are extensively accepted in the world, domestic to be badly in need of carrying out the depth in this field
Enter research, and form systematic research data and product line.
The content of the invention
The technical assignment of the present invention is to provide a kind of reductive water maltosemalt sugar and its Mashing process of the high moisturizing activity of tool.
The technical assignment of the present invention is realized in the following manner, in the concentrated solution of the reductive water maltosemalt sugar, the change not comprising water
The mass percent concentration for studying point is as follows：
Oligosaccharide alcohol 10-15%；Maltotetraose alcohol 1-5%；Maltotriose alcohol 2-5%；Maltose alcohol 32-35%；Sorbitol
42-48%.
Described oligosaccharide alcohol is the mixture of the polymolecular sugar alcohol more than or equal to five sugar alcohols.
The Mashing process step of the reductive water maltosemalt sugar of the high moisturizing activity of the tool is as follows：
1）Size mixing：Liquid corn starch milk is stirred in material-compound tank, plus pure water is diluted to 16～20 ° of B é of Baume degrees；
2）Liquefaction：10 are added in the emulsion sized mixing-5～10-3а-the amylase of times emulsion volume, at 90～110 DEG C
At a temperature of laminar flow tank in react 2～6 h after, using high-temperature steam improve temperature to 130 DEG C or so, maintain 10 min, go out
Enzyme；
3）Saccharifying：Liquefaction liquid temp is down to into 50～60 DEG C, 10 are separately added into-5～10-3а-the amylase of times liquefier volume and
Beta amylase, and add 10-6～10-4The glucoamylase of times liquefier volume, 50～80 DEG C of continuous stirring saccharification reacts
30～70 h；
4）Decolourize：The Powdered Activated Carbon for accounting for starch milk dry biomass 1%～3%, 60～90 DEG C of decolourings will be added in saccharified liquid
10～40 min, plate-and-frame filtration obtain sugar liquid of the printing opacity more than 90%；
5）Hydrogenation：According to the concentration and quality of destaining solution, radium Buddhist nun's Raney nickel is added, be hydrogenated with High Temperature High Pressure；
6）Purification：By hydrogenation liquid Filtration of catalyst, filtrate pass sequentially through cation exchange column, anion-exchange column, sun from
Sub- exchange column, anion-exchange column, remove the foreign ion in sugar liquid so as to which conductance is less than 30us/cm；Room temperature feeds, charging
Speed is about 0.5～3.0 times of resin volume/hour；
7）Concentration：It is 60～80% that scavenging solution is concentrated into the total mass percentage concentration of sugar alcohol, obtains reductive water maltosemalt sugar product.
Described step 2）Middle а-amylase is high temperature resistant а-amylase, and operative temperature is 90-110 DEG C.
Described step 3）Middle а-amylase, beta amylase and glucoamylase are while in addition liquefier.
Described step 3）Middle а-diastatic operative temperature is 50-70 DEG C.
A kind of reductive water maltosemalt sugar of the high moisturizing activity of tool of the present invention is compared to the prior art, brilliant with non-staining, resistive connection
The superperformances such as property, humectant, in food production field, particularly in diet food, anti-caries food and diabetic
Have a good application prospect in terms of special food；The Mashing process is simple, easy to operate, easily realizes industrialization production.
Specific embodiment
Embodiment 1：
The preparation technology of this kind of reductive water maltosemalt sugar is as follows：
1）Size mixing：A certain amount of liquid corn starch milk is taken, is stirred in material-compound tank, plus pure water is diluted to Baume degrees extremely
16°Bé。
2）Liquefaction：2 × 10 are added in the emulsion sized mixing-4High temperature а-the amylase of times emulsion volume（а-the shallow lake
Powder enzyme is high temperature resistant а-amylase, and operative temperature is 90-110 DEG C, is purchased from Shandong Longke Enzyme Co., Ltd.）, at 90 DEG C
At a temperature of laminar flow tank in react 4 h after, using high-temperature steam improve temperature to 130 DEG C or so, maintain 10 min, enzyme denaturing.
3）Saccharifying：Liquefaction liquid temp is down to into 50 DEG C, while adding 10-4The middle temperature а-amylase of times liquefier volume（Should
Place's а-diastatic operative temperature is 50-70 DEG C, is purchased from Shandong Longke Enzyme Co., Ltd.）And beta amylase, and while
Add 5 × 10-6The glucoamylase of times liquefier volume, 55 DEG C of 45 h of continuous stirring saccharification react.
4）Decolourize：The Powdered Activated Carbon for accounting for starch milk dry biomass 1%, 70 DEG C of decolourings 25 will be added in saccharified liquid
Min, filters, obtains sugar liquid of the printing opacity more than 90%.
5）Hydrogenation：According to the concentration and quality of destaining solution, a certain amount of radium Buddhist nun Raney nickel is added（It is purchased from the village and believes ten thousand richization
Work company limited）, it is hydrogenated with High Temperature High Pressure.
6）Purification：By hydrogenation liquid Filtration of catalyst, filtrate pass sequentially through cation exchange column, anion-exchange column,
Cation exchange column, anion-exchange column, remove the foreign ion in sugar liquid so as to which conductance is less than 30us/cm.Room temperature feeds,
Charging rate is about 1.0 times of resin volume/hours；
7）Concentration：It is 70% by the mass percent concentration that scavenging solution is concentrated into sugar alcohol, obtains this kind of reductive water maltosemalt sugar product.Which is dense
Sugar alcohol component in contracting liquid（In water content is not counted in）And mass percentage concentration（%）It is as follows：Five sugar alcohols, six sugar alcohols, seven sugar alcohols and eight
The mixture 15 of sugar alcohol；Maltotetraose alcohol 4；Maltotriose alcohol 4；Maltose alcohol 35；Sorbitol 42.
Embodiment 2：
The preparation technology of this kind of reductive water maltosemalt sugar is as follows：
1）Size mixing：A certain amount of liquid corn starch milk is taken, is stirred in material-compound tank, plus pure water is diluted to Baume degrees extremely
17°Bé。
2）Liquefaction：3 × 10 are added in the emulsion sized mixing-4High temperature а-the amylase of times emulsion volume（а-the shallow lake
Powder enzyme is high temperature resistant а-amylase, and operative temperature is 90-110 DEG C, is purchased from Shandong Longke Enzyme Co., Ltd.）, at 95 DEG C
At a temperature of laminar flow tank in react 3 h after, using high-temperature steam improve temperature to 130 DEG C or so, maintain 10 min, enzyme denaturing.
3）Saccharifying：Liquefaction liquid temp is down to into 60 DEG C, 2 × 10 are separately added into-4The middle temperature а-amylase of times liquefier volume
And beta amylase（At this, а-diastatic operative temperature is 50-70 DEG C, is purchased from Shandong Longke Enzyme Co., Ltd.）, while
Add 10-5The glucoamylase of times liquefier volume, 60 DEG C of 40 h of continuous stirring saccharification react.
4）Decolourize：The Powdered Activated Carbon for accounting for starch milk dry biomass 2%, 75 DEG C of decolourings 20 will be added in saccharified liquid
Min, filters, obtains sugar liquid of the printing opacity more than 90%.
5）Hydrogenation：According to the concentration and quality of destaining solution, radium Buddhist nun's Raney nickel is added（It is purchased from the village and believes the limited public affairs of ten thousand Feng Huagong
Department）, it is hydrogenated with High Temperature High Pressure.
6）Purification：By hydrogenation liquid Filtration of catalyst, filtrate pass sequentially through cation exchange column, anion-exchange column,
Cation exchange column, anion-exchange column, remove the foreign ion in sugar liquid so as to which conductance is less than 30us/cm.Room temperature feeds,
Charging rate is about 1.0 times of resin volume/hours.
7）Concentration：It is 70% by the mass percent concentration that scavenging solution is concentrated into sugar alcohol, obtains this kind of reductive water maltosemalt sugar product,
Sugar alcohol component in its concentrated solution（In water content is not counted in）And mass percentage concentration（%）It is as follows：Five sugar alcohols, nine sugar alcohols, ten sugar alcohols
And 11 sugar alcohol mixture 14；Maltotetraose alcohol 1；Maltotriose alcohol 2；Maltose alcohol 35；Sorbitol 48.
Embodiment 3：
The preparation technology of this kind of reductive water maltosemalt sugar is as follows：
1）Size mixing：A certain amount of liquid corn starch milk is taken, is stirred in material-compound tank, plus pure water is diluted to Baume degrees extremely
17°Bé。
2）Liquefaction：3 × 10 are added in the emulsion sized mixing-4High temperature а-the amylase of times emulsion volume（а-the shallow lake
Powder enzyme is high temperature resistant а-amylase, and operative temperature is 90-110 DEG C, is purchased from Shandong Longke Enzyme Co., Ltd.）, 100
After 2 h are reacted in laminar flow tank at a temperature of DEG C, temperature is improved to 130 DEG C or so using high-temperature steam, maintain 10 min, enzyme denaturing.
3）Saccharifying：Liquefaction liquid temp is down to into 60 DEG C, 5 × 10 are separately added into-4The middle temperature а-amylase of times liquefier volume
And beta amylase（At this, а-diastatic operative temperature is 50-70 DEG C, is purchased from Shandong Longke Enzyme Co., Ltd.）, while
Add 5 × 10-5The glucoamylase of times liquefier volume, 60 DEG C of 35 h of continuous stirring saccharification react.
4）Decolourize：The Powdered Activated Carbon for accounting for starch milk dry biomass 3%, 80 DEG C of decolourings 30 will be added in saccharified liquid
Min, filters, obtains sugar liquid of the printing opacity more than 90%.
5）Hydrogenation：According to the concentration and quality of destaining solution, radium Buddhist nun's Raney nickel is added（It is purchased from the village and believes the limited public affairs of ten thousand Feng Huagong
Department）, it is hydrogenated with High Temperature High Pressure.
6）Purification：By hydrogenation liquid Filtration of catalyst, filtrate pass sequentially through cation exchange column, anion-exchange column,
Cation exchange column, anion-exchange column, remove the foreign ion in sugar liquid so as to which conductance is less than 30us/cm.Room temperature feeds,
Charging rate is about 2.0 times of resin volume/hours.
7）Concentration：It is 80% by the mass percent concentration that scavenging solution is concentrated into sugar alcohol, obtains this kind of reductive water maltosemalt sugar product,
Sugar alcohol component in its concentrated solution（In water content is not counted in）And mass percentage concentration（%）It is as follows：Five sugar alcohols, eight sugar alcohols, ten sugar alcohols
And 16 sugar alcohol mixture 10；Maltotetraose alcohol 5；Maltotriose alcohol 5；Maltose alcohol 32；Sorbitol 48.
By specific embodiment above, the those skilled in the art can readily realize the present invention.But should
Work as understanding, the present invention is not limited to above-mentioned several specific embodiments.On the basis of disclosed embodiment, the technology
The technical staff in field can the different technical characteristic of combination in any, so as to realize different technical schemes.
Claims (6)
1. it is a kind of to have the active reductive water maltosemalt sugar of high moisturizing, it is characterised in that in the concentrated solution of the reductive water maltosemalt sugar, the change not comprising water
The mass percent concentration for studying point is as follows：
Oligosaccharide alcohol 10-15%；Maltotetraose alcohol 1-5%；Maltotriose alcohol 2-5%；Maltose alcohol 32-35%；Sorbitol
42-48%.
2. the reductive water maltosemalt sugar of a kind of tool according to claim 1 high moisturizing activity, it is characterised in that described oligosaccharide alcohol is
More than or equal to the mixture of the polymolecular sugar alcohol of five sugar alcohols.
3. the Mashing process of the reductive water maltosemalt sugar of a kind of tool high moisturizing activity, it is characterised in that the processing step is as follows：
1）Size mixing：Liquid corn starch milk is stirred in material-compound tank, plus pure water is diluted to 16～20 ° of B é of Baume degrees；
2）Liquefaction：10 are added in the emulsion sized mixing-5～10-3а-the amylase of times emulsion volume, at 90～110 DEG C
At a temperature of laminar flow tank in react 2～6 h after, using high-temperature steam improve temperature to 130 DEG C or so, maintain 10 min, go out
Enzyme；
3）Saccharifying：Liquefaction liquid temp is down to into 50～60 DEG C, 10 are separately added into-5～10-3а-the amylase of times liquefier volume and
Beta amylase, and add 10-6～10-4The glucoamylase of times liquefier volume, 50～80 DEG C of continuous stirring saccharification reacts
30～70 h；
4）Decolourize：The Powdered Activated Carbon for accounting for starch milk dry biomass 1%～3%, 60～90 DEG C of decolourings will be added in saccharified liquid
10～40 min, plate-and-frame filtration obtain sugar liquid of the printing opacity more than 90%；
5）Hydrogenation：According to the concentration and quality of destaining solution, radium Buddhist nun's Raney nickel is added, be hydrogenated with High Temperature High Pressure；
6）Purification：By hydrogenation liquid Filtration of catalyst, filtrate pass sequentially through cation exchange column, anion-exchange column, sun from
Sub- exchange column, anion-exchange column, remove the foreign ion in sugar liquid so as to which conductance is less than 30us/cm；Room temperature feeds, charging
Speed is about 0.5～3.0 times of resin volume/hour；
7）Concentration：It is 60～80% that scavenging solution is concentrated into the total mass percentage concentration of sugar alcohol, obtains reductive water maltosemalt sugar product.
4. the Mashing process of the reductive water maltosemalt sugar of a kind of tool according to claim 3 high moisturizing activity, it is characterised in that described
The step of 2）Middle а-amylase is high temperature resistant а-amylase, and operative temperature is 90-110 DEG C.
5. the Mashing process of the reductive water maltosemalt sugar of a kind of tool according to claim 3 high moisturizing activity, it is characterised in that described
The step of 3）Middle а-amylase, beta amylase and glucoamylase are while in addition liquefier.
6. a kind of Mashing process of the reductive water maltosemalt sugar of the high moisturizing activity of tool according to claim 3 or 5, it is characterised in that
Described step 3）Middle а-diastatic operative temperature is 50-70 DEG C.
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| CN112674196A (en) * | 2021-01-29 | 2021-04-20 | 山东健奕宏生物制药有限公司 | Polyhydric sugar alcohol with high viscosity and low sweetness and production process thereof |
| CN113502037A (en) * | 2021-08-16 | 2021-10-15 | 苏州科宁多元醇有限公司 | Novel polyhydric sugar alcohol plasticizer, preparation method thereof and application thereof in preparation of starch-based degradable material |
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