CN106522965A - Slurry for stabilizing shield excavated surface in marine stratum and construction method - Google Patents

Slurry for stabilizing shield excavated surface in marine stratum and construction method Download PDF

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Publication number
CN106522965A
CN106522965A CN201610953599.XA CN201610953599A CN106522965A CN 106522965 A CN106522965 A CN 106522965A CN 201610953599 A CN201610953599 A CN 201610953599A CN 106522965 A CN106522965 A CN 106522965A
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CN
China
Prior art keywords
mud
sodium
based bentonite
face
composite sodium
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Pending
Application number
CN201610953599.XA
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Chinese (zh)
Inventor
朱雁飞
范杰
曹金文
吕锦
黄德中
刘宽
何人
李刚
黄凯
王旋东
李磊
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Zhuhai Hengqin Ltd By Share Ltd
Shanghai Tunnel Engineering Co Ltd
Original Assignee
Zhuhai Hengqin Ltd By Share Ltd
Shanghai Tunnel Engineering Co Ltd
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Publication date
Application filed by Zhuhai Hengqin Ltd By Share Ltd, Shanghai Tunnel Engineering Co Ltd filed Critical Zhuhai Hengqin Ltd By Share Ltd
Priority to CN201610953599.XA priority Critical patent/CN106522965A/en
Publication of CN106522965A publication Critical patent/CN106522965A/en
Pending legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21DSHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
    • E21D9/00Tunnels or galleries, with or without linings; Methods or apparatus for making thereof; Layout of tunnels or galleries
    • E21D9/06Making by using a driving shield, i.e. advanced by pushing means bearing against the already placed lining
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/10Mortars, concrete or artificial stone characterised by specific physical values for the viscosity

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Excavating Of Shafts Or Tunnels (AREA)

Abstract

The invention discloses slurry for stabilizing a shield excavated surface in a marine stratum and a construction method. The slurry is composite sodium-based bentonite slurry and is prepared by composite sodium-based bentonite. The composite sodium-based bentonite is formed by mixing sodium-based bentonite, polymers and an additive. According to the slurry for stabilizing the shield excavated surface in the marine stratum and the construction method, a shield excavated surface muddy water material is prepared by the composite sodium-based bentonite slurry adaptive to seawater and has the capability to resist seawater draining, and a research gap of stabilizing of the muddy water shield excavated surface in the marine stratum in the tunnel construction process is filled up; the idea of adopting muddy water high in seawater adaptability is put forward; the viscosity of the muddy water of the excavated surface is improved; and a high-quality mud film is formed to stabilize the excavated surface.

Description

It is applied to the stable mud in shield tunneling face and construction method in marine bed
Technical field
The present invention relates to shield-tunneling construction field, more particularly to a kind of it is applied to the stable mud in shield tunneling face in marine bed Slurry and construction method.
Background technology
In recent years, track traffic development in domestic city is extremely rapid, and to before and after 2015, China builds up and building track friendship Logical circuit is up to 158, and total kilometrage will be more than 4189 kilometers.Shield Method has mechanized construction degree height, opens Dig efficiency high, the features such as effect on environment is little, obtained quite being widely applied in urban rail transit in China construction.
Modern tunnel construction engineering just gradually increases with cross section diameter, the trend of section complex formation.Existing shield Construction is adapted to be constructed in more single soft soil layer, soft rock strata and layer of sand, and soft or hard it is uneven, on it is soft under It is a greater impact when constructing in the hard and compound stratum containing high intensity hard rock, technical experience is deficient.
In existing shield construction, the stable method of slurry shield excavation face is in face shape using high-performance muddy water Into high-quality mud film.In marine bed, seawater can make general muddy water material produce dripization, make muddy water performance decline to a great extent, from And mud film quality is affected, certain difficulty is brought to stablizing for excavation face.Water quality used by existing muddy water preparation technique is running water, Bad adaptability of the muddy water material to seawater.In slurry shield construction at present, the muddy water that seawater is adapted to used in marine bed is steady Determine research or the blank of face.
The content of the invention
The technical problem to be solved is to provide and a kind of is applied to the stable mud in shield tunneling face in marine bed Slurry and construction method, are the construction technology of the stable excavation face of muddy water that seawater is adapted in marine bed, solve marine bed shield The stable problem of structure excavation face.
To realize above-mentioned technique effect, the invention discloses a kind of composite sodium-based bentonite mud, is applied to marine bed Middle shield tunneling face is stable, and the composite sodium-based bentonite mud is formulated by composite sodium-based bentonite, described composite sodium-based Bentonite is mixed by sodium bentonite, polymer and additive.
The composite sodium-based bentonite mud is further improved by, and includes sodium in the composition of the sodium bentonite Base montmorillonite, includes montmorillonite, beidellite and nontronite.
The composite sodium-based bentonite mud is further improved by, and the polymer and the additive are gathered by amine Compound is constituted with cellulose family additive.
The composite sodium-based bentonite mud is further improved by, the sodium bentonite, the polymer and institute The content ratio for stating additive is 6:3:1.
The composite sodium-based bentonite mud is further improved by, the water content of the composite sodium-based bentonite mud For 7%~10%, sand factor is less than 1%.
The composite sodium-based bentonite mud is further improved by, the colloidity of the composite sodium-based bentonite mud More than 96%, filter loss is less than 20ml.
The composite sodium-based bentonite mud is further improved by, and the PF values of composite sodium-based bentonite mud are 7~ 9。
The invention also discloses a kind of be applied to the stable construction method in shield tunneling face in marine bed, shield is in marine facies Tunnel in stratum, composite sodium-based bentonite mud is sent into into excavation face, mud film, stable excavation face are formed in excavation face.
It is described be applied to marine bed in the stable construction method in shield tunneling face be further improved by, it is described compound When the mud film is formed, produce mud pressure, and part mud pressure is changed into the soil body has effect to sodium bentonite mud Power is acted in excavation face.
It is described be applied to marine bed in the stable construction method in shield tunneling face be further improved by, the soil body Effective stress gradually increases from the top of the excavation face to bottom.
The present invention is as a result of above technical scheme so as to have the advantages that:Adapt to having to seawater Property composite sodium-based bentonite mud configuration shield tunneling face muddy water material, the muddy water material has the ability of resistant to sea water dripization, uses Amount is identical with general muddy water material;When shield is tunneled in marine bed, by the muddy water material for adding high viscosity and high concentration Material, make the mud balance of feeding excavation face in 1.15g/cm3~1.25g/cm3, viscosity in more than 20s, so as to before face It is square into high-quality mud film, keep excavation face stable.
Description of the drawings
Fig. 1 is that the excavation face stability principle for being applied to the stable construction method in shield tunneling face in marine bed of the invention shows It is intended to.
Specific embodiment
Below in conjunction with the accompanying drawings and specific embodiment the present invention is further detailed explanation.
The present invention is applied to the main purpose of the stable mud in shield tunneling face and construction method in marine bed:Carry For a kind of construction technology of the stable face of muddy water that seawater is adapted in marine bed, marine bed shield tunneling face is solved steady Fixed problem.
Face is a term in tunnel construction, that is, excavate tunnel (mine, mining or Tunnel Engineering in) constantly to The working face of front propulsion.Face is to excavate the working face constantly pushed ahead of tunnel, and it is not a fixed face, excavation face There are face, abutment wall face and vault face, exactly face is that working face for constantly moving forward for facing shield. Stable problem of the primary study just to the excavation face of shield in the present invention, therefore, face is exactly excavation face in the present invention, That is, the working face that shield is constantly pushed ahead.
In existing shield construction, the stable method of slurry shield excavation face is in face shape using high-performance muddy water Into high-quality mud film.In marine bed, seawater can make general muddy water material produce dripization, make muddy water performance decline to a great extent, from And mud film quality is affected, certain difficulty is brought to stablizing for excavation face.Water quality used by existing muddy water configuring technical is running water, Bad adaptability of the muddy water material to seawater.In slurry shield construction at present, the muddy water that seawater is adapted to used in marine bed is steady Determine research or the blank of face.
Prior art:Hohai University professor Zhu Wei has done to the muddy water performance in slurry shield construction and has deeply ground for a long time Study carefully.He thinks that part mud pressure is converted into effective stress and is acted in excavation face by the formation of mud film, supporting excavation face soil Body, it is ensured that excavation face is stablized.Slip affects larger to mud film quality, and when level is matched somebody with somebody and density is identical, mud viscosity is high, Physical stability is good, then mud film is easily formed, and formation mud film is thin, fine and close, and drainage amount is little.
General muddy water material is all to configure muddy water material, not only high cost, and the adaptability to seawater with running water , arbitrarily there is dripization phenomenon in difference, and the mud film quality of formation is poor, stablizes unfavorable to shield tunneling face.
Therefore, the invention provides a kind of muddy water that seawater is adapted in marine bed stablizes the composite sodium-based swollen of face The native mud of profit, in being applied to marine bed, shield tunneling face is stable.The composite sodium-based bentonite mud is by composite sodium-based bentonite Directly it is formulated, and the composite sodium-based bentonite is mixed by two parts, a part is high-quality sodium bentonite, another portion It has been the polymer and additive for proposing the effect of viscous, filtrate reducing to divide.Wherein, the content ratio of sodium bentonite, polymer and additive Generally 6:3:1 (weight).
The main component of sodium bentonite is na-montmorillonite (ENa+/Σ EC >=50%).
Key component is:Montmorillonite Na+ 0.33(Al1.67Mg0.33)Si4O10(OH)2·nH2
Beidellite Na+ 0.33Al2(Si3.67Al0.33)O10(OH)2·nH2O。
Nontronite Na+ 0.33Fe3+ 2(Si3.67Al0.33)O10(OH)2·nH2O。
Wherein, montmorillonite is a kind of natural nano-material, and to be similar to sandwich, levels are silicon-oxy tetrahedrons to structure, in Between be alumina octahedral, interlamellar spacing is 0.8 nanometer~1.0 nanometers, and interlayer is negatively charged, with very strong ion exchangeable, main If cation such as Na+、Ca2+、K+、Mg2+、Li+、H+、Al3+Deng exchange is reversible.Hand in the medium cationic that pH is 7 Capacity is changed for 70me/100g~140me/100g.Colloidality with very strong adsorption capacity and height, plasticity and bonding Power, therefore water imbibition is very strong, add water expansion, and volume can increase several times to more than ten times.Natural smectite is with the commutative sun of its interlayer The species of ion, content divide genotype, when the content of a certain cation exceedes cation exchange capacity (Σ EC) 50%, i.e., with The cation is named, such as na-montmorillonite (ENa+/Σ EC >=50%), ca-montmorillonite (ECa2+/Σ EC >=50%), aluminium Base montmorillonite (EAl3+/Σ EC >=50%).When interlayer neither one cations are more than 50% exchange capacity, then containing Two most cation names of amount, such as Ca-Na-montmorillonite, calcium and magnesium base montmorillonite etc..
Ca in seawater2+Ion concentration is too high, can affect bentonitic pulping performance, makes bentonite cohesion sedimentation separation; Work as Cl-Ion concentration is too high, can affect the cohesive force between clay particle, reduces the viscosity and shear force of muddy water, and fluid loss increases Greatly, stability declines.
And the present invention using na-montmorillonite (ENa+/Σ EC >=50%) as the main component of sodium bentonite, can be with Ca in seawater is solved well2+The too high problem of ion concentration, reduces the harmful effect to ringing the cohesive force between clay particle; Cl in seawater can also be reduced simultaneously-The content of ion, improves the viscosity of muddy water, and physical stability is good, and mud film is easily formed, and shape Thin, fine and close into mud film, drainage amount is little.
Polymer, additive in composite sodium-based bentonite mud of the present invention is mainly added by amine polymer and cellulose family Plus agent composition, contribute to controlling the leakage of mud, and lift the performance of mud, form the colloidal solution of cross-linked network.
The polymer of mud viscosity is lifted, with swelling soil interaction, good mud skeleton is formed.Bentonite mud is provided The higher gel strength of slurry and gel strength.
Mud leakage control additive, with swelling soil interaction, forms thin and compact mud skin in hole wall, reduces mud Filter loss.
The main performance index of composite sodium-based bentonite mud of the present invention is as shown in following table table 1:
The main performance index of 1 composite sodium-based bentonite mud of table
Water content 7~10%
Granularity 99~100% can pass through 200 eye mesh screens
Sand content <1%
Colloidity >96%
Filter loss <20ml
PH value 7~9
It is below that shield tunneling face is steady during one kind of application composite sodium-based bentonite mud of the present invention is applied to marine bed Fixed construction method, predominantly:When shield is tunneled in marine bed, by adding the composite sodium-based swollen of high viscosity and high concentration The muddy water material of the native mud configuration of profit, makes the mud balance of feeding excavation face in g/cm3~1.25g/cm3, viscosity in more than 20s, So as to form high-quality mud film in front of tunnel heading, keep excavation face stable.
Coordinate shown in Fig. 1, shield tunneling face stable mechanism is:Mud pressure be equal to slurry penetration pressure and ground water pressure it With.Composite sodium-based bentonite mud produces mud pressure, and part mud pressure is converted when front of tunnel heading forms mud film Act in excavation face into soil body effective stress, with soil pressure P in original soil layerSoilWith ground water pressure PWaterContend with, balance excavation face Stressing conditions, so as to stablize excavation face.It can be seen that the soil body effective stress obtained by mud pressure Partial Conversion Gradually increase from the top of excavation face to bottom, with soil pressure P in original soil layerSoilWith ground water pressure PWaterDistribution is consistent.
The present invention is applied to the stable mud in shield tunneling face and construction method in marine bed and provides a kind of adapt to sea The high-quality composite sodium-based bentonite mud of water, in marine bed, the high-quality muddy water of adaptation seawater advantageously forms high-quality Mud film, stably favourable to excavation face, the present invention with having adaptive composite sodium-based bentonite mud configuration shield to seawater Excavation face muddy water material, the muddy water material have the ability of resistant to sea water dripization, and consumption is identical with general muddy water material;Shield is in marine facies When tunneling in stratum, by the muddy water material for adding high viscosity and high concentration, the mud balance of feeding excavation face is made to exist 1.15g/cm3~1.25g/cm3, viscosity so as to form high-quality mud film in front of tunnel heading, keeps excavation face in more than 20s It is stable.During compensate for tunnel construction, the research stable to slurry shield excavation face in marine bed is blank;Propose employing The adaptable muddy water of seawater, improves the viscosity of the muddy water of excavation face, forms high-quality mud film to stablize excavation face.
The present invention is described in detail above in association with drawings and Examples, those skilled in the art can basis Described above makes many variations example to the present invention.Thus, some of embodiment details should not constitute limitation of the invention, The present invention is by the scope defined using appended claims as protection scope of the present invention.

Claims (10)

1. a kind of composite sodium-based bentonite mud, in being applied to marine bed, shield tunneling face is stable, it is characterised in that:It is described multiple Close sodium bentonite mud to be formulated by composite sodium-based bentonite, the composite sodium-based bentonite is by sodium bentonite, polymerization Thing and additive are mixed.
2. composite sodium-based bentonite mud as claimed in claim 1, it is characterised in that:Wrap in the composition of the sodium bentonite Containing na-montmorillonite, include montmorillonite, beidellite and nontronite.
3. composite sodium-based bentonite mud as claimed in claim 1, it is characterised in that:The polymer and the additive by Amine polymer is constituted with cellulose family additive.
4. composite sodium-based bentonite mud as claimed in claim 1, it is characterised in that:The sodium bentonite, the polymerization The content ratio of thing and the additive is 6:3:1.
5. composite sodium-based bentonite mud as claimed in claim 1, it is characterised in that:The composite sodium-based bentonite mud Water content is 7%~10%, and sand factor is less than 1%.
6. composite sodium-based bentonite mud as claimed in claim 1, it is characterised in that:The composite sodium-based bentonite mud Colloidity is more than 96%, and filter loss is less than 20ml.
7. composite sodium-based bentonite mud as claimed in claim 1, it is characterised in that:The PF values of composite sodium-based bentonite mud For 7~9.
It is 8. a kind of to be applied to the stable construction method in shield tunneling face in marine bed, it is characterised in that:Shield is in marine bed Composite sodium-based bentonite mud as described in any one in claim 1~7 is sent into excavation face, in excavation face by middle driving Form mud film, stable excavation face.
9. the stable construction method in shield tunneling face in marine bed is applied to as claimed in claim 8, it is characterised in that:Institute Composite sodium-based bentonite mud is stated when the mud film is formed, mud pressure is produced, and part mud pressure is changed into into the soil body Effective stress is acted in excavation face.
10. the stable construction method in shield tunneling face in marine bed is applied to as claimed in claim 8, it is characterised in that: The soil body effective stress gradually increases from the top of the excavation face to bottom.
CN201610953599.XA 2016-11-03 2016-11-03 Slurry for stabilizing shield excavated surface in marine stratum and construction method Pending CN106522965A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108358491A (en) * 2018-02-02 2018-08-03 中南大学 A kind of integrated conduct method and mixing feeding device of shield discarded slurry
CN109749748A (en) * 2018-12-20 2019-05-14 中铁开发投资集团有限公司 A kind of rich water round gravel stratum shield sediment improvement method and sediment improvement agent
CN110437812A (en) * 2019-08-28 2019-11-12 中铁隧道局集团有限公司 A kind of shield warehouse entry slurries with pressure and preparation method thereof
CN112110682A (en) * 2020-08-10 2020-12-22 中交武汉港湾工程设计研究院有限公司 High-efficiency plugging film-forming shield slurry material for emergency

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1614196A (en) * 2004-10-14 2005-05-11 上海隧道工程股份有限公司 Ground deformation control for going through soft earth layer by double circular shielding
CN101191417A (en) * 2007-12-21 2008-06-04 沈阳重型机械集团有限责任公司 Bentonite mud water pressurization equilibration shield machine
JP2009228391A (en) * 2008-03-25 2009-10-08 Ohbayashi Corp Tunnel construction method, inner mold, tunnel lining body, and tunnel structure
CN101565945A (en) * 2009-05-19 2009-10-28 上海隧道工程股份有限公司 Application method of composite sodium-based bentonite on construction of underground continuous wall
CN103967499A (en) * 2014-04-21 2014-08-06 河海大学 Excavation face supporting method for shield tunneling machine to open chamber under pressure
CN105464674A (en) * 2015-12-29 2016-04-06 上海市基础工程集团有限公司 Construction method of cutter replacing under pressure in shield-method tunnel construction

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1614196A (en) * 2004-10-14 2005-05-11 上海隧道工程股份有限公司 Ground deformation control for going through soft earth layer by double circular shielding
CN101191417A (en) * 2007-12-21 2008-06-04 沈阳重型机械集团有限责任公司 Bentonite mud water pressurization equilibration shield machine
JP2009228391A (en) * 2008-03-25 2009-10-08 Ohbayashi Corp Tunnel construction method, inner mold, tunnel lining body, and tunnel structure
CN101565945A (en) * 2009-05-19 2009-10-28 上海隧道工程股份有限公司 Application method of composite sodium-based bentonite on construction of underground continuous wall
CN103967499A (en) * 2014-04-21 2014-08-06 河海大学 Excavation face supporting method for shield tunneling machine to open chamber under pressure
CN105464674A (en) * 2015-12-29 2016-04-06 上海市基础工程集团有限公司 Construction method of cutter replacing under pressure in shield-method tunnel construction

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
张天启等: "《竖炉球团技能300问》", 30 June 2013 *
杨勇: "复合钠基膨润土泥浆护壁机理及其工程应用", 《地下空间与工程学报》 *
祝强: "新型复合钠基膨润土泥浆在地下连续墙施工中的应用", <地下工程与隧道> *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108358491A (en) * 2018-02-02 2018-08-03 中南大学 A kind of integrated conduct method and mixing feeding device of shield discarded slurry
CN109749748A (en) * 2018-12-20 2019-05-14 中铁开发投资集团有限公司 A kind of rich water round gravel stratum shield sediment improvement method and sediment improvement agent
CN110437812A (en) * 2019-08-28 2019-11-12 中铁隧道局集团有限公司 A kind of shield warehouse entry slurries with pressure and preparation method thereof
CN112110682A (en) * 2020-08-10 2020-12-22 中交武汉港湾工程设计研究院有限公司 High-efficiency plugging film-forming shield slurry material for emergency

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