CN106520003A - Thermal conductive graphite tape used for laptops - Google Patents

Thermal conductive graphite tape used for laptops Download PDF

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Publication number
CN106520003A
CN106520003A CN201610787557.3A CN201610787557A CN106520003A CN 106520003 A CN106520003 A CN 106520003A CN 201610787557 A CN201610787557 A CN 201610787557A CN 106520003 A CN106520003 A CN 106520003A
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CN
China
Prior art keywords
graphite
film
kapton
pet film
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610787557.3A
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Chinese (zh)
Inventor
金闯
梁豪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sidike New Materials Jiangsu Co Ltd
Original Assignee
Sidike New Materials Jiangsu Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sidike New Materials Jiangsu Co Ltd filed Critical Sidike New Materials Jiangsu Co Ltd
Priority to CN201610787557.3A priority Critical patent/CN106520003A/en
Publication of CN106520003A publication Critical patent/CN106520003A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K7/00Constructional details common to different types of electric apparatus
    • H05K7/20Modifications to facilitate cooling, ventilating, or heating
    • H05K7/2039Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K7/00Constructional details common to different types of electric apparatus
    • H05K7/20Modifications to facilitate cooling, ventilating, or heating
    • H05K7/2039Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
    • H05K7/205Heat-dissipating body thermally connected to heat generating element via thermal paths through printed circuit board [PCB]
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
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    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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    • B32B37/153Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
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    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/522Graphite
    • CCHEMISTRY; METALLURGY
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    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/524Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from polymer precursors, e.g. glass-like carbon material
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62218Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic films, e.g. by using temporary supports
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    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J2203/326Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J2400/10Presence of inorganic materials
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Abstract

The present invention discloses a thermal conductive graphite tape used for laptops. The tape contains a first thermal conductive adhesive layer, a graphite layer and a second thermal conductive adhesive layer. The graphite layer is prepared by the following technological method, and the method comprises the following steps: coating upper and lower surfaces of a polyimide film processed in step one with a layer of a graphite modifier to prepare a processed polyimide film; heating the processed polyimide film to 800 DEG C and keeping the temperature, and then raising the temperature to 1200 DEG C to prepare a prefired carbonized film; calendaring the prefired carbonized film obtained in step four by using a calender; raising the temperature to 2400 DEG C and keeping the temperature, and then raising the temperature to 2900 DEG C, so as to prepare a mainly fired graphite film; and calendaring the mainly fired graphite film obtained in step five to prepare the graphite layer. According to the invention, the tape is protected against local overheating, the uniformity of the thermal conductivity of the tape is achieved and the stability and reliability of heat dissipation performance of the product are improved in the meanwhile.

Description

For the conductive graphite adhesive tape of notebook computer
Technical field
The present invention relates to a kind of conductive graphite adhesive tape for notebook computer, belongs to double faced adhesive chip technology field.
Background technology
As modern microelectronic technology high-speed develops, electronic equipment(Such as notebook computer, mobile phone, panel computer etc.)Increasingly Become ultra-thin, light, this structure causes electronic equipment internal power density to significantly improve, the heat produced by operation is difficult Discharge, be easy to rapid accumulation and form high temperature.On the other hand, high temperature can reduce the performance of electronic equipment, reliability and use the longevity Life.Therefore, Current electronic industry proposes higher and higher requirement for the heat sink material as heat control system core component, urgently Need a kind of high-efficiency heat conduction, light material to transfer heat away from rapidly, ensure that electronic equipment normally runs.
In prior art, Kapton is mostly used for flexible PCB, although has and is obtained using polyimide film sintered Graphite heat radiation fin, so as to be covered on thermal source, but be constrained to Kapton product quality and performances the good and the bad not Together, the performance of the two-sided pad pasting heat dispersion of radiating has been had influence on, has there is following technical problem:Radiating is uneven, adhesive tape easily occurs Hot-spot, the heat dispersion that improve product is unstable, reliability performance is poor, is unfavorable for product quality management control, affects product Competitiveness.
The content of the invention
It is an object of the present invention to provide a kind of conductive graphite adhesive tape for notebook computer, this is used for leading for notebook computer Hot graphite glue band is both vertically and horizontally improve heat conductivility, it is to avoid adhesive tape hot-spot, realizes adhesive tape and leads Heat dispersion stability, the reliability of product while the uniformity of hot property, is improve, the cost of product is greatly reduced.
For reaching above-mentioned purpose, the technical solution used in the present invention is:A kind of conductive graphite glue for notebook computer Band, the two-sided pad pasting of the radiating are fitted between radiating piece and heat generating components, and the two-sided pad pasting of the radiating includes light strippable PET Film and re-release type PET film, be disposed between this light strippable PET film and re-release type PET film the first heat conduction adhesive layer, Graphite linings and the second heat conduction adhesive layer;The graphite linings are obtained by following process, and this process is comprised the following steps:
Step one, Kapton is risen to into 250 DEG C from room temperature, after rising to 400 DEG C after insulation, be down to room temperature;
Step 2, one layer graphite modified dose is coated with the upper and lower surface of the Kapton through step one and is processed Kapton afterwards, described graphite modified dose of viscosity is 30000 ~ 48000CP;
The graphite modified dose of component by following weight portion is constituted:20 parts of benzophenone tetracarboxylic dianhydride, pyromellitic acid anhydride 13 parts, 28 parts of MDA, 31 parts of dimethylformamide, 2 parts of ethylene glycol, 3 parts of dimethyl silicone polymer;
Step 3, the Kapton after process is warming up to into 800 DEG C, 1200 DEG C are being warming up to after insulation, are being cooled down after insulation, So as to obtain the carbonized film of pre-burned;
Step 4, rolled using calender the step 4 pre-burned carbonized film;
Step 5,2400 DEG C are warming up to, after insulation, are warming up to 2900 DEG C again, cooled down after insulation, so as to obtain the graphite of main firing Film;
The graphite film of the main firing obtained by step 6 and then step 5 is rolled so as to obtain the graphite linings.
In above-mentioned technical proposal, further improved scheme is as follows:
1st, in such scheme, step 4 acquisition graphite film is carried out into calendering process.
2nd, in such scheme, the grammes per square metre of the light strippable PET film peeling force is 5 ~ 10g/m2, re-release type PET The grammes per square metre of film peeling force is 50 ~ 100g/m2
As above-mentioned technical proposal is used, the present invention has following advantages and effect compared with prior art:
Conductive graphite adhesive tape of the present invention for notebook computer, in its structure, graphite linings are coated with one layer of stone by upper and lower surface The Kapton of black modifying agent is prepared from, and improves in heat conductivility both vertically and horizontally, it is to avoid adhesive tape Hot-spot, realizes the uniformity of adhesive tape heat conductivility;Secondly, its be located at graphite modified dose of Kapton surface by Benzophenone tetracarboxylic dianhydride, pyromellitic acid anhydride, MDA, dimethylformamide, ethylene glycol, poly dimethyl silicon Oxygen alkane constitute, be coated on Kapton, the pin hole being filled with heating process, improve degree of crystallinity while, also overcome It is uneven caused by thermal contraction is excessive, improve graphite linings biaxial tension performance;Again, Kapton surface has stone Black modifying agent, improves graphite linings and heat conduction adhesive layer heat conductivility in two-sided pad pasting, and rolls the pre-burning using calender The carbonized film of system, it is to avoid the volume contraction in fold and graphitization sintering process, improves compactness and degree of crystallinity, further Improve in heat conductivility both vertically and horizontally.
Specific embodiment
With reference to embodiment, the invention will be further described:
Embodiment:A kind of conductive graphite adhesive tape for notebook computer, the two-sided pad pasting of the radiating fit in radiating piece 1 and send out Between thermal part 2, the two-sided pad pasting that radiates includes light strippable PET film 3 and re-release type PET film 4, this light strippable PET The first heat conduction adhesive layer 5, graphite linings 6 and the second heat conduction adhesive layer 7 is disposed between film 3 and re-release type PET film 4;Institute State graphite linings 6 to obtain by following process, this process is comprised the following steps:
Step one, Kapton is risen to into 250 DEG C with 4 ~ 6 degree/min speed from room temperature, kept for 0.9 ~ 1.1 hour, then With 2.5 ~ 3.5 degree/min, 400 DEG C are risen to, after being kept for 1 hour, be down to room temperature;
Step 2, one layer graphite modified dose is coated with the upper and lower surface of the Kapton through step one and is processed Kapton afterwards, the graphite modified dose of component by following weight portion are constituted, as shown in table 1:Benzophenone tetracid It is 20 parts of dianhydride, 13 parts of pyromellitic acid anhydride, 28 parts of MDA, 31 parts of dimethylformamide, 2 parts of ethylene glycol, poly- 3 parts of dimethyl siloxane;Graphite modified dose of viscosity is 45000CP.
Step 3,800 DEG C are risen to the speed of 4 ~ 6 degree/min, kept for 0.9 ~ 1.1 hour;Again with the speed of 9 ~ 11 degree/min Degree rises to 1200 DEG C, cools down, so as to obtain the carbonized film of pre-burned after preserving 0.9 ~ 1.1 hour;
Step 4, rolled using calender the step 4 pre-burned carbonized film;
Step 5,2400 DEG C are risen to the speed of 19 ~ 21 degree/min, kept for 0.9 ~ 1.1 hour, then with the speed of 19 ~ 21 degree/min Degree rises to 2900 DEG C, cools down, so as to obtain the graphite film of main firing after being kept for 1.8 ~ 2.2 hours;
The graphite film of the main firing obtained by step 6 and then step 5 is rolled so as to obtain the graphite linings 6.
Step 6 acquisition graphite linings are carried out into calendering process.
The grammes per square metre of above-mentioned light 1 peeling force of strippable PET film is 5 ~ 10g/m2, 2 peeling force of re-release type PET film gram Weight is 50 ~ 100g/m2
During using above-mentioned conductive graphite adhesive tape for notebook computer, in its structure, graphite linings are applied by upper and lower surface The Kapton for covering one layer graphite modified dose is prepared from, and improves in heat conductivility both vertically and horizontally, Adhesive tape hot-spot is avoided, the uniformity of adhesive tape heat conductivility is realized;Secondly, which is located at the graphite on Kapton surface Modifying agent is by benzophenone tetracarboxylic dianhydride, pyromellitic acid anhydride, MDA, dimethylformamide, ethylene glycol, poly- Dimethyl siloxane is constituted, and is coated on Kapton, and the pin hole being filled with heating process improves degree of crystallinity same When, also overcome thermal contraction it is excessive caused by it is uneven, improve graphite linings biaxial tension performance;Again, Kapton Surface has graphite modified dose, improves graphite linings and heat conduction adhesive layer heat conductivility in two-sided pad pasting, and adopts calender pressure Prolong the carbonized film of the pre-burned, it is to avoid the volume contraction in fold and graphitization sintering process, improve compactness and knot Brilliant degree, further increases in heat conductivility both vertically and horizontally.
Above-described embodiment technology design only to illustrate the invention and feature, its object is to allow person skilled in the art Scholar will appreciate that present disclosure and implement according to this, can not be limited the scope of the invention with this.It is all according to the present invention Equivalence changes or modification that Spirit Essence is made, should all be included within the scope of the present invention.

Claims (3)

1. a kind of conductive graphite adhesive tape for notebook computer, the two-sided pad pasting of the radiating fit in radiating piece and heat generating components Between, the two-sided pad pasting of the radiating includes light strippable PET film and re-release type PET film, this light strippable PET film and re-release The first heat conduction adhesive layer, graphite linings and the second heat conduction adhesive layer is disposed between type PET film;It is characterized in that:The stone Layer of ink is obtained by following process, and this process is comprised the following steps:
Step one, Kapton is risen to into 250 DEG C from room temperature, after rising to 400 DEG C after insulation, be down to room temperature;
Step 2, one layer graphite modified dose is coated with the upper and lower surface of the Kapton through step one and is processed Kapton afterwards, described graphite modified dose of viscosity is 30000 ~ 48000CP;
The graphite modified dose of component by following weight portion is constituted:20 parts of benzophenone tetracarboxylic dianhydride, pyromellitic acid anhydride 13 parts, 28 parts of MDA, 30 ~ 35 parts of dimethylformamide, 1.5 ~ 2.5 parts of ethylene glycol, dimethyl silicone polymer 2 ~ 3 Part;
Step 3, the Kapton after process is warming up to into 800 DEG C, 1200 DEG C are being warming up to after insulation, are being cooled down after insulation, So as to obtain the carbonized film of pre-burned;
Step 4, rolled using calender the step 4 pre-burned carbonized film;
Step 5,2400 DEG C are warming up to, after insulation, are warming up to 2900 DEG C again, cooled down after insulation, so as to obtain the graphite of main firing Film;
The graphite film of the main firing obtained by step 6 and then step 5 is rolled so as to obtain the graphite linings.
2. the conductive graphite adhesive tape for notebook computer according to claim 1, it is characterised in that:By the step 4 Obtaining graphite linings carries out calendering process.
3. the conductive graphite adhesive tape for notebook computer according to claim 1, it is characterised in that:It is described light exfoliated The grammes per square metre of PET film peeling force is 5 ~ 10g/m2, the grammes per square metre of the re-release type PET film peeling force is 50 ~ 100g/m2
CN201610787557.3A 2014-01-26 2014-01-26 Thermal conductive graphite tape used for laptops Pending CN106520003A (en)

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CN201610696475.8A Pending CN106318251A (en) 2014-01-26 2014-01-26 Manufacture method of thermal transfer film
CN201610700227.6A Pending CN106413340A (en) 2014-01-26 2014-01-26 Heat conducting adhesive film for electronic product
CN201610787557.3A Pending CN106520003A (en) 2014-01-26 2014-01-26 Thermal conductive graphite tape used for laptops
CN201610777340.4A Pending CN106398566A (en) 2014-01-26 2014-01-26 Double-face pad pasting with heat radiation
CN201610696479.6A Pending CN106332521A (en) 2014-01-26 2014-01-26 Manufacturing method for double-sided adhesive graphite flake
CN201610777536.3A Pending CN106349965A (en) 2014-01-26 2014-01-26 preparing method of heat-conducting adhesive tape for consumer electronic product
CN201610704135.5A Pending CN106281087A (en) 2014-01-26 2014-01-26 Heat-conducting double-sided adhesive tape
CN201610696474.3A Pending CN106318250A (en) 2014-01-26 2014-01-26 Preparation process of thermal double-sided adhesive tape
CN201610705884.XA Pending CN106332522A (en) 2014-01-26 2014-01-26 High-heat-conductivity graphite film
CN201610794749.7A Pending CN106398570A (en) 2014-01-26 2014-01-26 High-compactness graphite soaking adhesive tape
CN201610777537.8A Pending CN106398567A (en) 2014-01-26 2014-01-26 Pressure sensitive adhesive tape for notebook computer
CN201610777925.6A Active CN106427180B (en) 2014-01-26 2014-01-26 Preparation method for the two-sided pad pasting of soaking
CN201610787521.5A Pending CN106535560A (en) 2014-01-26 2014-01-26 Manufacturing process for heat-conducting graphite paste films for flat computers
CN201610799197.9A Pending CN106381083A (en) 2014-01-26 2014-01-26 Isothermal pressure-sensitive adhesive tape used for intelligent mobile phones
CN201610705947.1A Active CN106304783B (en) 2014-01-26 2014-01-26 Thermal conductivity both-sided adhesive graphite flake
CN201610778259.8A Pending CN106634658A (en) 2014-01-26 2014-01-26 Manufacturing process for heat-conducting adhesive tape used for laptop
CN201610777909.7A Pending CN106366971A (en) 2014-01-26 2014-01-26 High-heat-conductivity double-sided adhesive tape
CN201610787504.1A Pending CN106520002A (en) 2014-01-26 2014-01-26 Heat-conducting pressure-sensitive double-sided tape
CN201410037378.9A Active CN103763892B (en) 2014-01-26 2014-01-26 Heat conduction graphite patch for microelectronic device
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CN201610777536.3A Pending CN106349965A (en) 2014-01-26 2014-01-26 preparing method of heat-conducting adhesive tape for consumer electronic product
CN201610704135.5A Pending CN106281087A (en) 2014-01-26 2014-01-26 Heat-conducting double-sided adhesive tape
CN201610696474.3A Pending CN106318250A (en) 2014-01-26 2014-01-26 Preparation process of thermal double-sided adhesive tape
CN201610705884.XA Pending CN106332522A (en) 2014-01-26 2014-01-26 High-heat-conductivity graphite film
CN201610794749.7A Pending CN106398570A (en) 2014-01-26 2014-01-26 High-compactness graphite soaking adhesive tape
CN201610777537.8A Pending CN106398567A (en) 2014-01-26 2014-01-26 Pressure sensitive adhesive tape for notebook computer
CN201610777925.6A Active CN106427180B (en) 2014-01-26 2014-01-26 Preparation method for the two-sided pad pasting of soaking
CN201610787521.5A Pending CN106535560A (en) 2014-01-26 2014-01-26 Manufacturing process for heat-conducting graphite paste films for flat computers
CN201610799197.9A Pending CN106381083A (en) 2014-01-26 2014-01-26 Isothermal pressure-sensitive adhesive tape used for intelligent mobile phones
CN201610705947.1A Active CN106304783B (en) 2014-01-26 2014-01-26 Thermal conductivity both-sided adhesive graphite flake
CN201610778259.8A Pending CN106634658A (en) 2014-01-26 2014-01-26 Manufacturing process for heat-conducting adhesive tape used for laptop
CN201610777909.7A Pending CN106366971A (en) 2014-01-26 2014-01-26 High-heat-conductivity double-sided adhesive tape
CN201610787504.1A Pending CN106520002A (en) 2014-01-26 2014-01-26 Heat-conducting pressure-sensitive double-sided tape
CN201410037378.9A Active CN103763892B (en) 2014-01-26 2014-01-26 Heat conduction graphite patch for microelectronic device
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