CN106517885A - Tableware with high breaking strength and preparation method of tableware - Google Patents

Tableware with high breaking strength and preparation method of tableware Download PDF

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Publication number
CN106517885A
CN106517885A CN201610929788.3A CN201610929788A CN106517885A CN 106517885 A CN106517885 A CN 106517885A CN 201610929788 A CN201610929788 A CN 201610929788A CN 106517885 A CN106517885 A CN 106517885A
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China
Prior art keywords
tableware
breaking strength
high breaking
compound
magazine
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CN201610929788.3A
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Chinese (zh)
Inventor
张万龙
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Hezhou Baoxing New Materials Co Ltd
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Hezhou Baoxing New Materials Co Ltd
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Priority to CN201610929788.3A priority Critical patent/CN106517885A/en
Publication of CN106517885A publication Critical patent/CN106517885A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/125Melamine-formaldehyde condensation polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N5/00Manufacture of non-flat articles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Table Devices Or Equipment (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to the field of ceramic imitating materials and particularly relates to tableware with high breaking strength and a preparation method of the tableware. The tableware with the high breaking strength is prepared from components in parts by weight as follows; 75-85 parts of calcium carbonate, 15-25 parts of melamine-formaldehyde plastic and 0.1-0.2 parts of a fluorescent whitening agent. The preparation method of the tableware with the high breaking strength comprises steps as follows: stirring, weighing, preheating, press forming, secondary forming, addition of the fluorescent whitening agent and polishing. The ceramic imitating material is mainly prepared from calcium carbonate and melamine-formaldehyde plastic, has good corrosion resistance and high breaking strength, has the production cost lower than that of a traditional material, has low formaldehyde migration volume and extremely low harmful ingredients for human bodies and is healthy, environment-friendly, easy to clean, stable in chemical property and durable.

Description

A kind of tableware with high breaking strength and preparation method thereof
Technical field
The invention belongs to the technical field of porcelain imitation material and its deep processing, more particularly to a kind of meal with high breaking strength Tool and preparation method thereof.
Background technology
With the progress and the development of science and technology of society, the daily necessities of many different materials is occurred in that, including plastic material, Resin material, ceramic material.Melamine dishware is more and more universal to be used by family, school, restaurant, fast-food restaurant, snack bar, special Be not due to its it is not easily broken the characteristics of so that many families are used as Child tableware, due to the popularity applied and convenient and practical Property, melamine dishware is more and more approved by people.Traditional melamine product due to a variety of causes, exist resistance to elevated temperatures it is poor, Weatherability is poor, low intensity the shortcomings of, can produce the harmful substances such as formaldehyde under high temperature or microwave, affect health.It is several Also various Ceramic-imitated tablewares are occurred in that over year, but major part be cited as because discharging the noxious materials such as melamine, formaldehyde it is unqualified Or the product of inferior quality, be gradually eliminated out market.Although the tableware of plastic material solves the problems, such as drop resistant, and its adhesiveness By force, price is low, can put microwave-oven-heating into, but and occur in that the defect such as non-refractory, poisonous.The tableware tool of resin material Have it is easy to clean, solid it is resistance to fall, acid resistance it is good, but in the market with Lauxite replace melamine resin as base material The tableware inferior of making is more, there is potential safety hazard.Crockery has good corrosion resistance, it is easy to clean, stable chemical nature, It is durable in use, but ceramics are in Long-Time Service, reel unavoidably, so needing have higher wanting to the wearability of crockery Ask, while intensity hardness is not enough, such as rupture strength, it is impossible to enough to meet requirement.
The content of the invention
It is an object of the invention to provide a kind of tableware with high breaking strength and preparation method thereof, which can reach wear-resisting Property it is high, hardness is stronger, health environment-friendly and the effect with high breaking strength.
It is achieved especially by below scheme:
A kind of tableware with high breaking strength, by weight including following component:Calcium carbonate 75~85, melamine Formaldehyde plastics 15~25,100 parts of total amount.
Further, component also includes following component by weight:Fluorescent whitening agent 0.1~0.2,100 parts of total amount.
A kind of preparation method of the tableware with high breaking strength, comprises the steps of:
A:Stirring:It is put in mixer by above-mentioned formula rate, stirs and evenly mixs into compound, it is standby;
B:Weigh:The amount of compound according to needed for the tableware of different size is weighed, and is inserted in magazine;
C:Preheating:The magazine for filling compound is preheated into 50~70s at a temperature of 80~100 DEG C, is formed compound Bulk powder;
D:It is compressing:Bulk powder will be filled and be placed in compressing in the mould of forming machine, the technique bar of pressing process Part is:In 160~200kgf/cm2Pressure under keep 8~12s, be vented 1.0~1.5s;
E:Post forming:The product being molded in D is carried out into secondary compacting again, the process conditions of pressing process are:It is placed in 160~200kgf/cm2Pressure under keep 7~9s, be vented 0.8~1.2s;
F:Product surface is carried out into deburring polishing, bruting process includes corase grind, fine grinding, is then polished.
A kind of preparation method of the tableware with high breaking strength, comprises the steps of:
A:Stirring:It is put in mixer by above-mentioned formula rate, stirs and evenly mixs into compound, it is standby;
B:Weigh:The amount of compound according to needed for the tableware of different size is weighed, and is inserted in magazine;
C:Preheating:The magazine for filling compound is preheated into 50~70s at a temperature of 80~100 DEG C, is formed compound Bulk powder;
D:It is compressing:Bulk powder will be filled and be placed in compressing in the mould of forming machine, the technique bar of pressing process Part is:In 160~200kgf/cm2Pressure under keep 8~12s, be vented 1.0~1.5s;
E:Post forming:The product being molded in D is carried out into secondary compacting again, the process conditions of pressing process are:It is placed in 160~200kgf/cm2Pressure under keep 7~9s, be vented 0.8~1.2s;
F:Addition fluorescent whitening agent:According to the above ratio in the product surface even application fluorescent whitening agent of step E processing, plus Press and keep 20~25s;
G:Product surface is carried out into deburring polishing, bruting process includes corase grind, fine grinding, is then polished.
Further, the calcium carbonate can be substituted with the bamboo powder of 50~60 weight portions.
Granularity >=95% of bamboo powder described further, ash≤2%, moisture content≤6%.
Further, in above-mentioned technical proposal, in step C, magazine is placed in preheating in cycle machine.
Beneficial effects of the present invention:
The porcelain imitation material of the present invention is mainly made up of calcium carbonate and melamine plastic, with good corrosion resistance, together When which has a high breaking strength, and lower compared to tableware its production cost of traditional material, formaldehyde migration amount is low, to human body Harmful components it is extremely low, health environment-friendly, it is easy to clean, stable chemical nature are durable in use.
Specific embodiment
Technical scheme is further limited with reference to specific embodiment, but claimed Scope is not only limited to description.
Embodiment 1
A kind of tableware with high breaking strength, by weight (kg) include following component:Calcium carbonate 75, melamine first Aldehyde plastics 25.(kg) also includes following component by weight:Fluorescent whitening agent 0.1.The calcium carbonate can be replaced with the bamboo powder of 50kg Granularity >=95% in generation, wherein bamboo powder, ash≤2%, moisture content≤6%.
A kind of preparation method of the tableware with high breaking strength, comprises the steps of:
A:Stirring:The component formula of the above-mentioned tableware with high breaking strength is put in mixer according to the above ratio, is stirred Mix and be mixed into compound, it is standby;
B:Weigh:The amount of compound according to needed for the tableware of different size is weighed, and is inserted in magazine;
C:Preheating:The magazine for filling compound is placed in cycle machine and 50s is preheated at a temperature of 80 DEG C, make compound Form bulk powder;
D:It is compressing:Bulk powder will be filled and be placed in compressing in the mould of forming machine, pressing process is: 160kgf/cm2Pressure under keep 8s, be vented 1.0s;
E:Post forming:The product being molded in D is carried out into secondary compacting again, pressing process is:It is placed in 160kgf/cm2 Pressure under keep 7s, be vented 0.8s;
F:Addition fluorescent whitening agent:By above-mentioned part by weight in product surface even application fluorescent whitening agent, pressurize and protect Hold 20s;
G:Product surface is carried out into deburring polishing, bruting process includes corase grind, fine grinding, is then polished.
Main performance is as shown in the table at normal temperatures for the tableware produced by above-described embodiment:
Project Inspection result Unit
Rupture strength 659 Kg/m2
Breakdown strength 1731 N
The modulus of rupture 29 MPa
Normal temperature wear extent 3.0 cm3
Embodiment 2
A kind of tableware with high breaking strength, by weight (kg) include following component:Calcium carbonate 85, melamine first Aldehyde plastics 15.(kg) also includes following component by weight:Fluorescent whitening agent 0.2.The calcium carbonate can be replaced with the bamboo powder of 60kg Granularity >=95% in generation, wherein bamboo powder, ash≤2%, moisture content≤6%.
A kind of preparation method of the tableware with high breaking strength, comprises the steps of:
A:Stirring:The component formula of the above-mentioned tableware with high breaking strength is put in mixer according to the above ratio, is stirred Mix and be mixed into compound, it is standby;
B:Weigh:The amount of compound according to needed for the tableware of different size is weighed, and is inserted in magazine;
C:Preheating:The magazine for filling compound is placed in cycle machine and 70s is preheated at a temperature of 100 DEG C, make mixing Material forms bulk powder;
D:It is compressing:Bulk powder will be filled and be placed in compressing in the mould of forming machine, pressing process is:200 kgf/cm2Pressure under keep 12s, be vented 1.5s;
E:Post forming:The product being molded in D is carried out into secondary compacting again, pressing process is:It is placed in 200kgf/cm2 Pressure under keep 9s, be vented 1.2s;
F:Addition fluorescent whitening agent:By above-mentioned part by weight in product surface even application fluorescent whitening agent, pressurize and protect Hold 25s;
G:Product surface is carried out into deburring polishing, bruting process includes corase grind, fine grinding, is then polished.
Main performance is as shown in the table at normal temperatures for the tableware produced by above-described embodiment:
Project Inspection result Unit
Rupture strength 678 Kg/m2
Breakdown strength 1778 N
The modulus of rupture 28 MPa
Normal temperature wear extent 3.2 cm3
Embodiment 3
A kind of tableware with high breaking strength, by weight (kg) include following component:Calcium carbonate 80, melamine first Aldehyde plastics 20.(kg) also includes following component by weight:Fluorescent whitening agent 0.15.The calcium carbonate can be replaced with the bamboo powder of 55kg Granularity >=95% in generation, wherein bamboo powder, ash≤2%, moisture content≤6%.
A kind of preparation method of the tableware with high breaking strength, comprises the steps of:
A:Stirring:The component formula of the above-mentioned tableware with high breaking strength is put in mixer according to the above ratio, is stirred Mix and be mixed into compound, it is standby;
B:Weigh:The amount of compound according to needed for the tableware of different size is weighed, and is inserted in magazine;
C:Preheating:The magazine for filling compound is placed in cycle machine and 60s is preheated at a temperature of 90 DEG C, make compound Form bulk powder;
D:It is compressing:Bulk powder will be filled and be placed in compressing in the mould of forming machine, pressing process is:180 kgf/cm2Pressure under keep 10s, be vented 1.25s;
E:Post forming:The product being molded in D is carried out into secondary compacting again, pressing process is:It is placed in 180kgf/cm2 Pressure under keep 8s, be vented 1.0s;
F:Addition fluorescent whitening agent:By above-mentioned part by weight in product surface even application fluorescent whitening agent, pressurize and protect Hold 22s;
G:Product surface is carried out into deburring polishing, bruting process includes corase grind, fine grinding, is then polished.
Main performance is as shown in the table at normal temperatures for the tableware produced by above-described embodiment:
Project Inspection result Unit
Rupture strength 718 Kg/m2
Breakdown strength 1803 N
The modulus of rupture 28 MPa
Normal temperature wear extent 2.9 cm3
Above-described is only the preferred embodiment of the present invention, it should be pointed out that for a person skilled in the art, On the premise of without departing from present configuration, some deformations and improvement can also be made, these are implemented all without the impact present invention Effect and practical applicability.

Claims (7)

1. a kind of tableware with high breaking strength, it is characterised in that by weight including following component:Calcium carbonate 75~ 85, melamine plastic 15~25,100 parts of total amount.
2. the tableware with high breaking strength according to claim 1, it is characterised in that component also includes following by weight Component:Fluorescent whitening agent 0.1~0.2,100 parts of total amount.
3. the preparation method of a kind of tableware with high breaking strength described in claims 1, it is characterised in that comprising following Step:
A:Stirring:Formula rate according to claim 1 is put in mixer, stirs and evenly mixs into compound, standby;
B:Weigh:The amount of compound according to needed for the tableware of different size is weighed, and is inserted in magazine;
C:Preheating:The magazine for filling compound is preheated into 50~70s at a temperature of 80~100 DEG C, makes compound form bulk Powder;
D:It is compressing:Bulk powder will be filled and be placed in compressing in the mould of forming machine, the process conditions of pressing process are: In 160~200kgf/cm2Pressure under keep 8~12s, be vented 1.0~1.5s;
E:Post forming:The product being molded in D is carried out into secondary compacting again, the process conditions of pressing process are:It is placed in 160~ 200kgf/cm2Pressure under keep 7~9s, be vented 0.8~1.2s;
F:Product surface is carried out into deburring polishing, bruting process includes corase grind, fine grinding, is then polished.
4. the preparation method of a kind of tableware with high breaking strength described in claim 2, it is characterised in that comprising following step Suddenly:
A:Stirring:Formula rate according to claim 2 is put in mixer, stirs and evenly mixs into compound, standby;
B:Weigh:The amount of compound according to needed for the tableware of different size is weighed, and is inserted in magazine;
C:Preheating:The magazine for filling compound is preheated into 50~70s at a temperature of 80~100 DEG C, makes compound form bulk Powder;
D:It is compressing:Bulk powder will be filled and be placed in compressing in the mould of forming machine, the process conditions of pressing process are: In 160~200kgf/cm2Pressure under keep 8~12s, be vented 1.0~1.5s;
E:Post forming:The product being molded in D is carried out into secondary compacting again, the process conditions of pressing process are:It is placed in 160~ 200kgf/cm2Pressure under keep 7~9s, be vented 0.8~1.2s;
F:Addition fluorescent whitening agent:In the product surface even application fluorescent brightening that the ratio in claim 2 is processed in step E Agent, pressurizes and keeps 20~25s;
G:Product surface is carried out into deburring polishing, bruting process includes corase grind, fine grinding, is then polished.
5. the tableware with low water absorption according to claim 3 or 4, it is characterised in that the calcium carbonate can be with 50 The bamboo powder of~60 weight portions is substituted.
6. the tableware with low water absorption according to claim 5, it is characterised in that granularity >=95% of the bamboo powder, Ash≤2%, moisture content≤6%.
7. the preparation method of the tableware with high breaking strength according to claim 3 or 4, it is characterised in that in step C Magazine is placed in preheating in cycle machine.
CN201610929788.3A 2016-10-31 2016-10-31 Tableware with high breaking strength and preparation method of tableware Pending CN106517885A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610929788.3A CN106517885A (en) 2016-10-31 2016-10-31 Tableware with high breaking strength and preparation method of tableware

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Publication Number Publication Date
CN106517885A true CN106517885A (en) 2017-03-22

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08283534A (en) * 1995-04-20 1996-10-29 Sumitomo Bakelite Co Ltd Melamine-phenol resin composition
CN101654542A (en) * 2009-09-16 2010-02-24 浙江万安塑料有限公司 High-temperature resistant porcelain imitation material and production method thereof
CN102794803A (en) * 2012-08-30 2012-11-28 大连绿之态科技有限公司 Manufacturing method for vegetable fiber compound tableware
CN103013040A (en) * 2012-12-31 2013-04-03 重庆美尔康塑胶有限公司 Ceramic-imitated tableware and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08283534A (en) * 1995-04-20 1996-10-29 Sumitomo Bakelite Co Ltd Melamine-phenol resin composition
CN101654542A (en) * 2009-09-16 2010-02-24 浙江万安塑料有限公司 High-temperature resistant porcelain imitation material and production method thereof
CN102794803A (en) * 2012-08-30 2012-11-28 大连绿之态科技有限公司 Manufacturing method for vegetable fiber compound tableware
CN103013040A (en) * 2012-12-31 2013-04-03 重庆美尔康塑胶有限公司 Ceramic-imitated tableware and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张佳欢等: "竹粉含量对密胺树脂复合材料性能的影响", 《中国化学会第28届学术年会第七分会场摘要集》 *

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Application publication date: 20170322