Erosion-resistant stopper
Technical field
The present invention designs a kind of stopper, especially a kind of erosion-resistant stopper.
Background technology
It is well-known:Sequence casting is carried out during continuous casting of ultralow carbon steel, tundish usually selects Al2O3- C matter stoppers
Flow control is carried out, existing stopper is stick body and caput, and is provided with venting channels in stick body.Using existing stopper,
With the extension of casting time, there is apparent melting loss in slag lining and caput, directly affect the service life of stopper, more unfavorable
It is stopper to molten steel carburetting, to influence Molten Steel Cleanliness.
For the defect of existing stopper, this field scientific research personnel improves existing stopper, such as:
1, application No. is the Chinese invention patents of 201310129083.X to disclose a kind of porous stopper of continuous casting, by the mouth of a river
It is cleaned out with the impurity product of stopper head contact portion, reduces molten steel bias current in the mouth of a river.
2, application No. is the Chinese invention patents of 201010513576.X to disclose a kind of wave-shaped stopper rod for continuous casting, stopper
Head is at least disposed with two round platforms of the first round platform and the second round platform along its axis, and the diameter of the first round platform is more than described second
The diameter of round platform.It can prevent vortex from generating, improve the stability of steel stream, and then continuous casting steel machine billet quality can be improved.
3, application No. is 201010513579.3 Chinese invention patents to disclose a kind of Multilayer stopper rod used in continuous casting, including plug
Barred body and stopper head, the stopper head, which includes at least, one layer of backing layer, the backing layer outer surface and the Stopper Body appearance
Face seamlessly transits.The backing layer of different materials, reduction can be selected to wash away stopper head at different positions as needed,
With better corrosion resistance the pollution to molten steel is reduced to extend the service life of stopper.
4, application No. is 201110048979.6 Chinese invention patents to disclose a kind of spindle-shaped integrated stopper rod, and slag line is
Spindle.By optimization design body shape, increase the thickness of slag lining, to extend product service life, reduces
The production and design problem that compound slag line design is brought.
Foregoing invention patent cannot reduce molten steel and flow into the vortex that knot device is formed by stopper surrounding, to not be avoided that whirlpool
Stream is involved in slag, it cannot be guaranteed that flowing into the cleanliness factor of molten steel in mold;Also the slag line of stopper is easy by slag corrosion simultaneously,
Service life is shorter.
5, application No. is 201010513576.X, patent name is《Continuous casting wave stopper》Chinese invention patent,
A kind of wave-shaped stopper rod for continuous casting is disclosed, stopper head is at least disposed with the first round platform and two, the second round platform along its axis
Round platform, the diameter of the first round platform are more than the diameter of second round platform.It can prevent vortex from generating, improve the stability of steel stream,
And then continuous casting steel machine billet quality can be improved.
Since the first round platform and the second round platform are arranged at caput, above caput, it is possible to create minimum vortex,
Slag in molten steel is brought into crystallizer, although above structure can prevent to form turbine substitution slag at caput,
It is that effect is poor, it cannot be guaranteed that the cleanliness factor of molten steel in mold.
6, application No. is 201110419505.8 Chinese patent, to disclose a kind of continuous casting oxide-non-oxidized substance compound
Integral column of sagger, for the stick of integral column of sagger as alumina-carbon material, stopper head is refractory composites, caput and stick
Using mixed transition material between the two between body.Make full use of non-oxidized substance fusing point height, low thermal expansion, thermal shock resistance
Well, the advantages of being not easy to be infiltrated by molten steel, anti-molten steel when improving caput materials'use washes away and aggressivity.
7, application No. is the Chinese patents of 201110134527.X to disclose a kind of ceramic combined integral stopper rod and its system
Make technique, it is ensured that stopper can be withstood to be washed away, corrodes for a long time, phenomena such as turning around, peeling off is less prone to, when can meet long
Between direct casting requirement.
8, application No. is the Chinese invention patents of CN201110415487.6 to disclose a kind of continuous casting high corrosion-resistant entirety
Stopper reduces the porosity of stopper stick body, improves slag-resistant permeability, it is molten to reduce alkalinity by optimizing the material of stopper stick body
Erosion of the slag to integral column of sagger stick body, improves the service life of stopper.
9, application No. is 201110215202.4, and application No. is 201110217390.4 patents of invention to disclose hair
With aluminium titanates, mullite, the carbon-free integral column of sagger based on alundum (Al2O3) contributes to clean steel continuous casting.
10, application No. is 201210553827.6 Chinese invention patents to disclose a kind of composite monolithic stopper rod and its making
Method, the composite monolithic stopper rod include caput, changeover portion and stick body, and caput uses magnesium carbon materials matter, stick body to use aluminium carbon materials matter, stick
Changeover portion between head and stick body uses spinelle carbon materials matter, this composite monolithic stopper rod to avoid conventional transition material using process
In due to react generate spinelle and generate volume expansion, eventually lead to caput fracture the phenomenon that.
11, application No. is 201610040164.6 Chinese invention patent, to disclose a kind of corundum, mullite integrated poured
Stopper, meet continuous casting requirement.
Above-mentioned Chinese invention patent 6-11 is by changing the manufacture material of stopper, to avoid the fracture of stopper, improve
Anti- molten steel wash away with aggressivity, improve stopper service life or improve Cleanliness of Molten Steel, but material used by said program
The complex process of material processing stopper, cost are higher.
Invention content
The technical problem to be solved by the present invention is to:Stopper corrosion resistance can be improved by providing one kind, and extending stopper makes
With the erosion-resistant stopper in service life.
The technical solution adopted by the present invention to solve the technical problems is:Erosion-resistant stopper, including stick body, the stick body
One end is free end, and the other end is provided with caput;There is slag line with the stick;It is provided with ventilative ring with the stick, it is described
Ventilative ring is round platform, and the smaller one end of ventilative ring bottom surface radius is located at the lower section of the larger one end of bottom surface radius;Ventilative ring bottom surface
The smaller one end of radius is concordant with the initial position of slag line;
It is provided with gas-permeable channels in the ventilative ring;The gas-permeable channels include vertical air inlet pipe, annulus snorkel;It is described
Vertical air inlet pipe one end is extended in ventilative ring by ventilative ring upper bottom surface and is connected to annulus snorkel;The stick body is logical positioned at annulus
In the annulus of tracheae, the annulus snorkel and stick body are coaxial, and are provided on the circular ring shape tracheae and are circumferentially uniformly distributed
Branch pipe, the branch pipe radially extends, and the branch pipe is located in ventilative ring;
Ventilative ring be made of the component of following parts by weight:
Al2O364~88 parts,
TiO22~4 parts,
10~12 parts of graphite,
Ti3SiC22~4 parts, 1~3 part of Al powder,
4~8 parts of resin.
Preferably, the Al2O3Group become:
Grain size is less than or equal to 3mm, and the Al more than 1mm2O34~8 parts,
Grain size is less than or equal to 1mm, and the Al more than or equal to 0.074mm2O335~45 parts,
Grain size is less than the Al of 0.074mm2O325~35 parts.
Preferably, the TiO2Grain size is 10~20nm.
Further, the angle between two neighboring branch pipe axis is 10~20 °.
Preferably, the radius of stick body free end is less than the radius of the stick body other end, stick body free end and stick body
The junction of two one end forms boss, and the ventilative ring set is located on the free end of stick body on boss;The ventilative ring
Sealing ring is provided on the bottom surface being located above, the ventilative gap between ring and stick body outer surface of the sealing ring sealing is described
It is identical that the annular radii that annulus snorkel axis surrounds and stick are relatively large in diameter the diameter of one end with it.
Preferably, the radius of stick body free end is 0.6R, and the radius of the other end is R, the ventilative ring have two
The larger bottom surface of radius is upper bottom surface in a bottom surface, and the smaller bottom surface of radius is bottom surface;The bottom radius surface of the ventilative ring
Upper bottom surface radius for 1.5R, the ventilative ring is 2R.
Preferably, the length of the branch pipe is 0.2~0.3R.
Preferably, the sealing ring is formed using aluminium oxide pouring.
Preferably, the height of the ventilative ring is 200~300mm.
The beneficial effects of the invention are as follows:Erosion-resistant stopper of the present invention, due to the start bit of the slag line in stick body
It installs and is equipped with ventilative ring, and the ventilative ring is round platform, while gas-permeable channels are provided in ventilative ring;The gas-permeable channels packet
Include vertical air inlet pipe, annulus snorkel;Described vertical air inlet pipe one end is extended in ventilative ring by ventilative ring upper bottom surface and annulus
Snorkel is connected to;The annulus snorkel and stick body are coaxial, and are provided on the circular ring shape tracheae circumferentially equally distributed
Branch pipe, the branch pipe radially extend, and the branch pipe is located in ventilative ring.Therefore in use, by leading to ventilative
Road is passed through inert gas, and inert gas forms air film on the outer surface of ventilative ring, to avoid slag from being in direct contact with slag line,
It avoids slag from causing to corrode to the slag line with stick, therefore the service life of stopper can be extended.Simultaneously because the ventilative ring of institute by
The component of following parts by weight is made:Al2O364~88 parts, TiO22~4 parts, 10~12 parts of graphite, Ti3SiC22~4 parts, Al
1~3 part of powder, 4~8 parts of resin;Therefore the corrosion resistance of ventilative ring can be improved, while reduces manufacturing cost.
Description of the drawings
Fig. 1 is the perspective view of erosion-resistant stopper in the embodiment of the present invention;
Fig. 2 is the front view of erosion-resistant stopper in the embodiment of the present invention;
Fig. 3 is the A-A sectional views in Fig. 2;
Fig. 4 is the B-B sectional views in Fig. 2;
It is indicated in figure:1- stick bodies, the free ends 11-, 2- caputs, 3- venting channels, 4- breathe freely ring, 5- annulus snorkels, 6-
Branch pipe, the vertical air inlet pipe of 7-, 8- sealing rings.
Specific implementation mode
The specific implementation mode of the present invention is described further with reference to the accompanying drawings and examples.
Embodiment one
First with white fused alumina (Al2O3More than 97%), graphite (C be more than 97%), nanometer (TiO297%) and resin purity is more than
For raw material, consisting of:3~1mm Al2O34~8 parts, 1~0.074mm Al2O335~45 parts,<0.074mm Al2O3 25
~35 parts, 10~20nm TiO22~5 parts, 8~12 parts of graphite, 1~3 part of antioxidant Al powder, 4~8 parts of resin.Isostatic pressed
Conventional stopper size is made in molding, 800~1200MPa of pressure so that the radius of the free end 11 of the stick body 1 of stopper is stick body 1
Then 0.6 times of the radius of the other end is processed into the cylinder that radius is stick body radius 0.6 to stick tail direction in stopper slag line,
And away from the annular groove for processing depth 3mm wide 5mm at 200~300mm of slag line starting position.By the stopper processed 500~600
It is toasted at DEG C spare.
The annulus snorkel 5 of stick body radius is made of the steel pipe of 3~5mm of internal diameter, 5 radial direction of annulus snorkel every
10~20 ° are provided with connection annulus snorkel 5, and with the matched branch pipe 6 of 5 internal diameter of annulus snorkel, 6 length of branch pipe is 0.2~
The radius of stick body lower end described in 0.3R, 5 vertical direction of annulus snorkel setting connection annulus snorkel 5, and with annulus snorkel 5
The matched vertical air inlet pipe 7 of internal diameter, connect with external Ar.The end of branch pipe 6 is shut using plastic sheet.
With 3~1mm of grain size Al2O34 parts, 1~0mm of grain size Al2O335 parts, grain size<0.074mm Al2O325 parts, 10
~20nm TiO22 parts, 10 parts of graphite, Ti3SiC22 parts, 1 part of Al powder, 4 parts of resin is raw material hydrostatic profile, pressure 600~
The ventilative ring 4 of truncated cone-shaped is made in 800MPa, and so that the bottom radius surface of ventilative ring 4 is the diameter that stick body 1 is relatively large in diameter one end
1.5 times, the upper bottom surface radius of the ventilative ring 4 is 2 times of the diameter that stick body 1 is relatively large in diameter one end.
Then it is toasted at 500~600 DEG C spare;Plastic sheet during baking at 6 port of branch pipe is burned off, and is made
It obtains branch pipe and 4 surface of ventilative ring after molding is ventilative.By the stick body 1 of the installation of ventilative ring 4 after baking after baking, in annular groove
Place is filled to form 8,120 DEG C of dryings of sealing ring for 24 hours with aluminium oxide pouring material, is with tundish baking after brush antioxidant coating
It can be used, adjust Ar throughputs according to actual conditions in casting process, making slag, there are air films to be advisable with ventilative interannular.
Embodiment two
First with white fused alumina (Al2O3More than 97%), graphite (C be more than 97%), nanometer (TiO297%) and resin purity is more than
For raw material, consisting of:3~1mm Al2O34~8 parts, 1~0mm Al2O335~45 parts,<0.074mm Al2O325~35
Part, 10~20nm TiO22~5 parts, 8~12 parts of graphite, 1~3 part of antioxidant Al powder, 4~8 parts of resin.Isostatic pressing,
Conventional stopper size is made in 800~1200MPa of pressure so that the radius of the free end 11 of the stick body 1 of stopper is 1 other end of stick body
0.6 times of radius, be then processed into the cylinder that radius is stick body radius 0.6 to stick tail direction in stopper slag line, and away from
The annular groove of depth 3mm wide 5mm is processed at 200~300mm of slag line starting position.The stopper processed is dried at 500~600 DEG C
It is roasting spare.
The annulus snorkel 5 of stick body radius is made of the steel pipe of 3~5mm of internal diameter, 5 radial direction of annulus snorkel every
10~20 ° are provided with connection annulus snorkel 5, and with the matched branch pipe 6 of 5 internal diameter of annulus snorkel, 6 length of branch pipe is 0.2~
The radius of stick body lower end described in 0.3R, 5 vertical direction of annulus snorkel setting connection annulus snorkel 5, and with annulus snorkel 5
The matched vertical air inlet pipe 7 of internal diameter, connect with external Ar.The end of branch pipe 6 is shut using plastic sheet.
With 3~1mm of grain size Al2O36 parts, 1~0mm of grain size Al2O340 parts, grain size<0.074mm Al2O330 parts, grain
10~20nm of diameter TiO23 parts, 11 parts of graphite, Ti3SiC23 parts, 2 parts of Al powder, 6 parts of resin is raw material hydrostatic profile, pressure 600
The ventilative ring 4 of truncated cone-shaped is made in~800MPa, and so that the bottom radius surface of ventilative ring 4 is that stick body 1 is relatively large in diameter the straight of one end
1.5 times of diameter, the upper bottom surface radius of the ventilative ring 4 are 2 times of the diameter that stick body 1 is relatively large in diameter one end.
Then it is toasted at 500~600 DEG C spare;Plastic sheet during baking in branch pipe 6 is burned off so that branch
Pipe 6 and 4 surface of ventilative ring after molding are ventilative.By the stick body 1 of the installation of ventilative ring 4 after baking after baking, at annular groove
It is filled to form 8,120 DEG C of dryings of sealing ring for 24 hours with aluminium oxide pouring material, be toasted with tundish after brush antioxidant coating
It uses, adjusts Ar throughputs according to actual conditions in casting process, making slag, there are air films to be advisable with ventilative interannular.
Embodiment three
First with white fused alumina (Al2O3More than 97%), graphite (C be more than 97%), nano-TiO2(purity is more than 97%) and resin
For raw material, consisting of:3~1mm Al2O34~8 parts, 1~0.074mm Al2O335~45 parts,<0.074mm Al2O3 25
~35 parts, 10~20nm TiO22~5 parts, 8~12 parts of graphite, 1~3 part of antioxidant Al powder, 4~8 parts of resin.Isostatic pressed
Conventional stopper size is made in molding, 800~1200MPa of pressure so that the radius of the free end 11 of the stick body 1 of stopper is stick body 1
Then 0.6 times of the radius of the other end is processed into the cylinder that radius is stick body radius 0.6 to stick tail direction in stopper slag line,
And away from the annular groove for processing depth 3mm wide 5mm at 200~300mm of slag line starting position.By the stopper processed 500~600
It is toasted at DEG C spare.
The annulus snorkel 5 of stick body radius is made of the steel pipe of 3~5mm of internal diameter, 5 radial direction of annulus snorkel every
10~20 ° are provided with connection annulus snorkel 5, and with the matched branch pipe 6 of 5 internal diameter of annulus snorkel, 6 length of branch pipe is 0.2~
The radius of stick body lower end described in 0.3R, 5 vertical direction of annulus snorkel setting connection annulus snorkel 5, and with annulus snorkel 5
The matched vertical air inlet pipe 7 of internal diameter, connect with external Ar.The end of branch pipe 6 is shut using plastic sheet.
With 3~1mm of grain size Al2O38 parts, 1~0.074mm of grain size Al2O345 parts, grain size<0.074mm Al2O3 35
Part, 10~20nm of grain size TiO24 parts, 12 parts of graphite, Ti3SiC24 parts, 3 parts of Al powder, 8 parts of resin is raw material hydrostatic profile, pressure
The ventilative ring 4 of truncated cone-shaped is made in 600~800MPa of power, and so that the bottom radius surface of ventilative ring 4 is that stick body 1 is relatively large in diameter one end
1.5 times of diameter, the upper bottom surface radius of the ventilative ring 4 is 2 times of the diameter that stick body 1 is relatively large in diameter one end.
Then it is toasted at 500~600 DEG C spare;Plastic sheet during baking at 6 mouthfuls of branch pipe is burned off so that
Branch pipe and 4 surface of ventilative ring after molding are ventilative.By the stick body 1 of the installation of ventilative ring 4 after baking after baking, at annular groove
It is filled to form 8,120 DEG C of dryings of sealing ring for 24 hours with aluminium oxide pouring material, be toasted with tundish after brush antioxidant coating
It uses, adjusts Ar throughputs according to actual conditions in casting process, making slag, there are air films to be advisable with ventilative interannular.
Ventilative ring 4 is made of the component of following parts by weight known to above-described embodiment:Al2O364~88 parts, TiO22~4
Part, 10~12 parts of graphite, Ti3SiC22~4 parts, 1~3 part of Al powder, 4~8 parts of resin;Continuous casting requirement can be met, while resisting and invading
Corrosion is preferable, and manufacturing cost is relatively low.
As shown in Figures 1 to 4, erosion-resistant stopper of the present invention, including stick body 1, described 1 one end of stick body are freely
End, the other end are provided with caput 2;There is slag line on the stick body 1;Ventilative ring 4, the ventilative ring 4 are provided on the stick body 1
For round platform, the smaller one end of 4 bottom surface radius of ventilative ring is located at the lower section of the larger one end of bottom surface radius;4 bottom surface radius of ventilative ring
Smaller one end is concordant with the initial position of slag line;
It is provided with gas-permeable channels in the ventilative ring 4;The gas-permeable channels include vertical air inlet pipe 7, annulus snorkel 5;
Described 7 one end of vertical air inlet pipe is extended in ventilative ring 4 by ventilative 4 upper bottom surface of ring and is connected to annulus snorkel 5;The stick body 1
In the annulus of annulus snorkel 5, the annulus snorkel 5 is coaxial with stick body 1, and is provided on the circular ring shape tracheae 5
Circumferentially equally distributed branch pipe 6, the branch pipe 6 radially extend, and the branch pipe 6 is located in ventilative ring 4.
During use, it is passed through argon gas by the venting channels being arranged in stick body 1, molten steel is by 1 surrounding caput 2 of stick body
Flowing, is then flowed into crystallizer.Inert gas, such as argon gas are passed through into vertical air inlet pipe 7 simultaneously.Due to described ventilative
It is provided with gas-permeable channels in ring 4;The gas-permeable channels include vertical air inlet pipe 7, annulus snorkel 5;The vertical air inlet pipe 7 one
End is extended in ventilative ring 4 by ventilative 4 upper bottom surface of ring and is connected to annulus snorkel 5;The annulus snorkel 5 is coaxial with stick body 1,
And it is provided with circumferentially equally distributed branch pipe 6 on the circular ring shape tracheae 5, the branch pipe 6 radially extends, and the branch pipe
6 are located in ventilative ring 4;Therefore inert gas can uniformly be transported to the outer surface of ventilative ring 4 by gas-permeable channels.Simultaneously because
The smaller one end of 4 bottom surface radius of ventilative ring is located at the lower section of the larger one end of bottom surface radius;Therefore inert gas is flowing up
During contacted always with the outer surface of ventilative ring 4 so that inert gas is between the outer surface and molten steel of ventilative ring 4
Form one layer of air film.
The smaller one end of 4 bottom surface radius of ventilative ring is concordant with the initial position of slag line simultaneously;Therefore can avoid slag with
Slag line on stick body 1 is in direct contact, and so as to reduce erosion of the slag to stick body 1, improves the service life of stopper.
In conclusion erosion-resistant stopper of the present invention, since the initial position of the slag line in stick body 1 is provided with
Compression ring 4, and ventilative 4 rings are round platform, while being provided with gas-permeable channels in ventilative ring 4;The gas-permeable channels include vertical
Air inlet pipe 7, annulus snorkel 5;Described 7 one end of vertical air inlet pipe is extended to by ventilative 4 upper bottom surface of ring in ventilative ring to be led to annulus
Tracheae 5 is connected to;The annulus snorkel 5 is coaxial with stick body 1, and is provided on the circular ring shape tracheae 5 and is circumferentially uniformly distributed
Branch pipe 6, the branch pipe 6 radially extends, and the branch pipe is located in ventilative ring 4.Therefore in use, by saturating
Gas channel is passed through inert gas, and inert gas forms air film on the outer surface of ventilative ring, to avoid slag direct with slag line
Contact, avoids slag from causing to corrode to the slag line with stick, therefore can extend the service life of stopper.
Specifically as shown in Fig. 2, models and application of the wherein starting altitude H of slag line according to different manufacturers using stopper
Requirement sets itself of the production environment to slag line height.
In order to enable inert gas reaches when breathing freely 4 outer surface of ring, fine and close air film can be formed, it is further, adjacent
Angle between two 6 axis of branch pipe is 10~20 °.Since inert gas is transported to 4 outer surface of ventilative ring by branch pipe 6, because
The angle of this 6 axis of two neighboring branch pipe be 10~20 ° can ensure two neighboring branch pipe 6 convey gases can be full of it is adjacent
Region of two branch pipes 6 between ventilative 4 outer surface of ring, so as to ensure that ventilative 4 outer surface of ring is formed continuously, completely
, fine and close air film.
The ventilative ring 4 may be used various ways and be provided on stick body 1, for example pass through interference fit, or welding.For
Ensure the stability of structure, while convenient for the replacement to ring 4 of breathing freely, it is preferred that the radius of 1 free end of stick body is less than stick
The junction of the radius of 1 other end of body, 1 free end of stick body and 1 liang of one end of stick body forms boss, and the ventilative ring 4 is set with
On the free end of stick body 1, and on boss;Sealing ring 8 is provided on the bottom surface that the ventilative ring 4 is located above, it is described
Gap between ventilative 1 outer surface of ring 4 and stick body of the sealing of sealing ring 8;Annular radii that 5 axis of annulus snorkel surrounds with
The diameter that one end is relatively large in diameter on stick body 1 is identical.
Following manner setting may be used in specific sealing ring 8, at the height for ring 4 of breathing freely away from slag line starting position distance
The annular groove for processing depth 3mm wide 5mm, fills to form sealing ring 8 at annular groove with aluminium oxide pouring material.
In order to ensure that slag can not be in direct contact with stick body 1, while the manufacture material for ring 4 of breathing freely is saved, in another reality
Apply in example, specifically, the radius of 1 free end of stick body is 0.6R, the radius of the other end is R, the ventilative ring 4 have two
The larger bottom surface of radius is upper bottom surface in a bottom surface, and the smaller bottom surface of radius is bottom surface;The bottom radius surface of the ventilative ring 4
Upper bottom surface radius for 1.5R, the ventilative ring 4 is 2R.Specifically, the length of the branch pipe 6 is 0.2~0.3R.
While can ensure that slag section can not be in direct contact with stick body 1, the manufacture material for ring of breathing freely is saved, another
In embodiment, specifically, the height of the ventilative ring 4 is 200~300mm.