CN106513652B - Erosion-resistant stopper - Google Patents

Erosion-resistant stopper Download PDF

Info

Publication number
CN106513652B
CN106513652B CN201611007489.0A CN201611007489A CN106513652B CN 106513652 B CN106513652 B CN 106513652B CN 201611007489 A CN201611007489 A CN 201611007489A CN 106513652 B CN106513652 B CN 106513652B
Authority
CN
China
Prior art keywords
stick body
ring
parts
ventilative
annulus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201611007489.0A
Other languages
Chinese (zh)
Other versions
CN106513652A (en
Inventor
李龙
陈永
彭和平
曾建华
李扬洲
陈刚
冯松
李平凡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Advanced Metal Materials Industry Technology Research Institute Co Ltd
Original Assignee
Chengdu Advanced Metal Materials Industry Technology Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Advanced Metal Materials Industry Technology Research Institute Co Ltd filed Critical Chengdu Advanced Metal Materials Industry Technology Research Institute Co Ltd
Priority to CN201611007489.0A priority Critical patent/CN106513652B/en
Publication of CN106513652A publication Critical patent/CN106513652A/en
Application granted granted Critical
Publication of CN106513652B publication Critical patent/CN106513652B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/14Closures
    • B22D41/16Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
    • B22D41/18Stopper-rods therefor
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B30/00Compositions for artificial stone, not containing binders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0087Uses not provided for elsewhere in C04B2111/00 for metallurgical applications
    • C04B2111/00887Ferrous metallurgy
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)

Abstract

The invention discloses one kind capable of improving stopper corrosion resistance, extends the erosion-resistant stopper of stopper service life.The erosion-resistant stopper includes stick body, and the stick body is provided with ventilative ring, and gas-permeable channels are provided in the ventilative ring;The gas-permeable channels include vertical air inlet pipe, annulus snorkel;Described vertical air inlet pipe one end is extended in ventilative ring by ventilative ring upper bottom surface and is connected to annulus snorkel;The stick body is located in the annulus of annulus snorkel, and the annulus snorkel and stick body are coaxial, and circumferentially equally distributed branch pipe is provided on the circular ring shape tracheae, and the branch pipe radially extends, and the branch pipe is located in ventilative ring;Ventilative ring be made of the component of following parts by weight:Al2O364~88 parts, TiO22~4 parts, 10~12 parts of graphite, Ti3SiC22~4 parts, 1~3 part of Al powder, 4~8 parts of resin.Using the erosion-resistant stopper, service life is long, and simple in structure, and manufacturing cost is low.

Description

Erosion-resistant stopper
Technical field
The present invention designs a kind of stopper, especially a kind of erosion-resistant stopper.
Background technology
It is well-known:Sequence casting is carried out during continuous casting of ultralow carbon steel, tundish usually selects Al2O3- C matter stoppers Flow control is carried out, existing stopper is stick body and caput, and is provided with venting channels in stick body.Using existing stopper, With the extension of casting time, there is apparent melting loss in slag lining and caput, directly affect the service life of stopper, more unfavorable It is stopper to molten steel carburetting, to influence Molten Steel Cleanliness.
For the defect of existing stopper, this field scientific research personnel improves existing stopper, such as:
1, application No. is the Chinese invention patents of 201310129083.X to disclose a kind of porous stopper of continuous casting, by the mouth of a river It is cleaned out with the impurity product of stopper head contact portion, reduces molten steel bias current in the mouth of a river.
2, application No. is the Chinese invention patents of 201010513576.X to disclose a kind of wave-shaped stopper rod for continuous casting, stopper Head is at least disposed with two round platforms of the first round platform and the second round platform along its axis, and the diameter of the first round platform is more than described second The diameter of round platform.It can prevent vortex from generating, improve the stability of steel stream, and then continuous casting steel machine billet quality can be improved.
3, application No. is 201010513579.3 Chinese invention patents to disclose a kind of Multilayer stopper rod used in continuous casting, including plug Barred body and stopper head, the stopper head, which includes at least, one layer of backing layer, the backing layer outer surface and the Stopper Body appearance Face seamlessly transits.The backing layer of different materials, reduction can be selected to wash away stopper head at different positions as needed, With better corrosion resistance the pollution to molten steel is reduced to extend the service life of stopper.
4, application No. is 201110048979.6 Chinese invention patents to disclose a kind of spindle-shaped integrated stopper rod, and slag line is Spindle.By optimization design body shape, increase the thickness of slag lining, to extend product service life, reduces The production and design problem that compound slag line design is brought.
Foregoing invention patent cannot reduce molten steel and flow into the vortex that knot device is formed by stopper surrounding, to not be avoided that whirlpool Stream is involved in slag, it cannot be guaranteed that flowing into the cleanliness factor of molten steel in mold;Also the slag line of stopper is easy by slag corrosion simultaneously, Service life is shorter.
5, application No. is 201010513576.X, patent name is《Continuous casting wave stopper》Chinese invention patent, A kind of wave-shaped stopper rod for continuous casting is disclosed, stopper head is at least disposed with the first round platform and two, the second round platform along its axis Round platform, the diameter of the first round platform are more than the diameter of second round platform.It can prevent vortex from generating, improve the stability of steel stream, And then continuous casting steel machine billet quality can be improved.
Since the first round platform and the second round platform are arranged at caput, above caput, it is possible to create minimum vortex, Slag in molten steel is brought into crystallizer, although above structure can prevent to form turbine substitution slag at caput, It is that effect is poor, it cannot be guaranteed that the cleanliness factor of molten steel in mold.
6, application No. is 201110419505.8 Chinese patent, to disclose a kind of continuous casting oxide-non-oxidized substance compound Integral column of sagger, for the stick of integral column of sagger as alumina-carbon material, stopper head is refractory composites, caput and stick Using mixed transition material between the two between body.Make full use of non-oxidized substance fusing point height, low thermal expansion, thermal shock resistance Well, the advantages of being not easy to be infiltrated by molten steel, anti-molten steel when improving caput materials'use washes away and aggressivity.
7, application No. is the Chinese patents of 201110134527.X to disclose a kind of ceramic combined integral stopper rod and its system Make technique, it is ensured that stopper can be withstood to be washed away, corrodes for a long time, phenomena such as turning around, peeling off is less prone to, when can meet long Between direct casting requirement.
8, application No. is the Chinese invention patents of CN201110415487.6 to disclose a kind of continuous casting high corrosion-resistant entirety Stopper reduces the porosity of stopper stick body, improves slag-resistant permeability, it is molten to reduce alkalinity by optimizing the material of stopper stick body Erosion of the slag to integral column of sagger stick body, improves the service life of stopper.
9, application No. is 201110215202.4, and application No. is 201110217390.4 patents of invention to disclose hair With aluminium titanates, mullite, the carbon-free integral column of sagger based on alundum (Al2O3) contributes to clean steel continuous casting.
10, application No. is 201210553827.6 Chinese invention patents to disclose a kind of composite monolithic stopper rod and its making Method, the composite monolithic stopper rod include caput, changeover portion and stick body, and caput uses magnesium carbon materials matter, stick body to use aluminium carbon materials matter, stick Changeover portion between head and stick body uses spinelle carbon materials matter, this composite monolithic stopper rod to avoid conventional transition material using process In due to react generate spinelle and generate volume expansion, eventually lead to caput fracture the phenomenon that.
11, application No. is 201610040164.6 Chinese invention patent, to disclose a kind of corundum, mullite integrated poured Stopper, meet continuous casting requirement.
Above-mentioned Chinese invention patent 6-11 is by changing the manufacture material of stopper, to avoid the fracture of stopper, improve Anti- molten steel wash away with aggressivity, improve stopper service life or improve Cleanliness of Molten Steel, but material used by said program The complex process of material processing stopper, cost are higher.
Invention content
The technical problem to be solved by the present invention is to:Stopper corrosion resistance can be improved by providing one kind, and extending stopper makes With the erosion-resistant stopper in service life.
The technical solution adopted by the present invention to solve the technical problems is:Erosion-resistant stopper, including stick body, the stick body One end is free end, and the other end is provided with caput;There is slag line with the stick;It is provided with ventilative ring with the stick, it is described Ventilative ring is round platform, and the smaller one end of ventilative ring bottom surface radius is located at the lower section of the larger one end of bottom surface radius;Ventilative ring bottom surface The smaller one end of radius is concordant with the initial position of slag line;
It is provided with gas-permeable channels in the ventilative ring;The gas-permeable channels include vertical air inlet pipe, annulus snorkel;It is described Vertical air inlet pipe one end is extended in ventilative ring by ventilative ring upper bottom surface and is connected to annulus snorkel;The stick body is logical positioned at annulus In the annulus of tracheae, the annulus snorkel and stick body are coaxial, and are provided on the circular ring shape tracheae and are circumferentially uniformly distributed Branch pipe, the branch pipe radially extends, and the branch pipe is located in ventilative ring;
Ventilative ring be made of the component of following parts by weight:
Al2O364~88 parts,
TiO22~4 parts,
10~12 parts of graphite,
Ti3SiC22~4 parts, 1~3 part of Al powder,
4~8 parts of resin.
Preferably, the Al2O3Group become:
Grain size is less than or equal to 3mm, and the Al more than 1mm2O34~8 parts,
Grain size is less than or equal to 1mm, and the Al more than or equal to 0.074mm2O335~45 parts,
Grain size is less than the Al of 0.074mm2O325~35 parts.
Preferably, the TiO2Grain size is 10~20nm.
Further, the angle between two neighboring branch pipe axis is 10~20 °.
Preferably, the radius of stick body free end is less than the radius of the stick body other end, stick body free end and stick body The junction of two one end forms boss, and the ventilative ring set is located on the free end of stick body on boss;The ventilative ring Sealing ring is provided on the bottom surface being located above, the ventilative gap between ring and stick body outer surface of the sealing ring sealing is described It is identical that the annular radii that annulus snorkel axis surrounds and stick are relatively large in diameter the diameter of one end with it.
Preferably, the radius of stick body free end is 0.6R, and the radius of the other end is R, the ventilative ring have two The larger bottom surface of radius is upper bottom surface in a bottom surface, and the smaller bottom surface of radius is bottom surface;The bottom radius surface of the ventilative ring Upper bottom surface radius for 1.5R, the ventilative ring is 2R.
Preferably, the length of the branch pipe is 0.2~0.3R.
Preferably, the sealing ring is formed using aluminium oxide pouring.
Preferably, the height of the ventilative ring is 200~300mm.
The beneficial effects of the invention are as follows:Erosion-resistant stopper of the present invention, due to the start bit of the slag line in stick body It installs and is equipped with ventilative ring, and the ventilative ring is round platform, while gas-permeable channels are provided in ventilative ring;The gas-permeable channels packet Include vertical air inlet pipe, annulus snorkel;Described vertical air inlet pipe one end is extended in ventilative ring by ventilative ring upper bottom surface and annulus Snorkel is connected to;The annulus snorkel and stick body are coaxial, and are provided on the circular ring shape tracheae circumferentially equally distributed Branch pipe, the branch pipe radially extend, and the branch pipe is located in ventilative ring.Therefore in use, by leading to ventilative Road is passed through inert gas, and inert gas forms air film on the outer surface of ventilative ring, to avoid slag from being in direct contact with slag line, It avoids slag from causing to corrode to the slag line with stick, therefore the service life of stopper can be extended.Simultaneously because the ventilative ring of institute by The component of following parts by weight is made:Al2O364~88 parts, TiO22~4 parts, 10~12 parts of graphite, Ti3SiC22~4 parts, Al 1~3 part of powder, 4~8 parts of resin;Therefore the corrosion resistance of ventilative ring can be improved, while reduces manufacturing cost.
Description of the drawings
Fig. 1 is the perspective view of erosion-resistant stopper in the embodiment of the present invention;
Fig. 2 is the front view of erosion-resistant stopper in the embodiment of the present invention;
Fig. 3 is the A-A sectional views in Fig. 2;
Fig. 4 is the B-B sectional views in Fig. 2;
It is indicated in figure:1- stick bodies, the free ends 11-, 2- caputs, 3- venting channels, 4- breathe freely ring, 5- annulus snorkels, 6- Branch pipe, the vertical air inlet pipe of 7-, 8- sealing rings.
Specific implementation mode
The specific implementation mode of the present invention is described further with reference to the accompanying drawings and examples.
Embodiment one
First with white fused alumina (Al2O3More than 97%), graphite (C be more than 97%), nanometer (TiO297%) and resin purity is more than For raw material, consisting of:3~1mm Al2O34~8 parts, 1~0.074mm Al2O335~45 parts,<0.074mm Al2O3 25 ~35 parts, 10~20nm TiO22~5 parts, 8~12 parts of graphite, 1~3 part of antioxidant Al powder, 4~8 parts of resin.Isostatic pressed Conventional stopper size is made in molding, 800~1200MPa of pressure so that the radius of the free end 11 of the stick body 1 of stopper is stick body 1 Then 0.6 times of the radius of the other end is processed into the cylinder that radius is stick body radius 0.6 to stick tail direction in stopper slag line, And away from the annular groove for processing depth 3mm wide 5mm at 200~300mm of slag line starting position.By the stopper processed 500~600 It is toasted at DEG C spare.
The annulus snorkel 5 of stick body radius is made of the steel pipe of 3~5mm of internal diameter, 5 radial direction of annulus snorkel every 10~20 ° are provided with connection annulus snorkel 5, and with the matched branch pipe 6 of 5 internal diameter of annulus snorkel, 6 length of branch pipe is 0.2~ The radius of stick body lower end described in 0.3R, 5 vertical direction of annulus snorkel setting connection annulus snorkel 5, and with annulus snorkel 5 The matched vertical air inlet pipe 7 of internal diameter, connect with external Ar.The end of branch pipe 6 is shut using plastic sheet.
With 3~1mm of grain size Al2O34 parts, 1~0mm of grain size Al2O335 parts, grain size<0.074mm Al2O325 parts, 10 ~20nm TiO22 parts, 10 parts of graphite, Ti3SiC22 parts, 1 part of Al powder, 4 parts of resin is raw material hydrostatic profile, pressure 600~ The ventilative ring 4 of truncated cone-shaped is made in 800MPa, and so that the bottom radius surface of ventilative ring 4 is the diameter that stick body 1 is relatively large in diameter one end 1.5 times, the upper bottom surface radius of the ventilative ring 4 is 2 times of the diameter that stick body 1 is relatively large in diameter one end.
Then it is toasted at 500~600 DEG C spare;Plastic sheet during baking at 6 port of branch pipe is burned off, and is made It obtains branch pipe and 4 surface of ventilative ring after molding is ventilative.By the stick body 1 of the installation of ventilative ring 4 after baking after baking, in annular groove Place is filled to form 8,120 DEG C of dryings of sealing ring for 24 hours with aluminium oxide pouring material, is with tundish baking after brush antioxidant coating It can be used, adjust Ar throughputs according to actual conditions in casting process, making slag, there are air films to be advisable with ventilative interannular.
Embodiment two
First with white fused alumina (Al2O3More than 97%), graphite (C be more than 97%), nanometer (TiO297%) and resin purity is more than For raw material, consisting of:3~1mm Al2O34~8 parts, 1~0mm Al2O335~45 parts,<0.074mm Al2O325~35 Part, 10~20nm TiO22~5 parts, 8~12 parts of graphite, 1~3 part of antioxidant Al powder, 4~8 parts of resin.Isostatic pressing, Conventional stopper size is made in 800~1200MPa of pressure so that the radius of the free end 11 of the stick body 1 of stopper is 1 other end of stick body 0.6 times of radius, be then processed into the cylinder that radius is stick body radius 0.6 to stick tail direction in stopper slag line, and away from The annular groove of depth 3mm wide 5mm is processed at 200~300mm of slag line starting position.The stopper processed is dried at 500~600 DEG C It is roasting spare.
The annulus snorkel 5 of stick body radius is made of the steel pipe of 3~5mm of internal diameter, 5 radial direction of annulus snorkel every 10~20 ° are provided with connection annulus snorkel 5, and with the matched branch pipe 6 of 5 internal diameter of annulus snorkel, 6 length of branch pipe is 0.2~ The radius of stick body lower end described in 0.3R, 5 vertical direction of annulus snorkel setting connection annulus snorkel 5, and with annulus snorkel 5 The matched vertical air inlet pipe 7 of internal diameter, connect with external Ar.The end of branch pipe 6 is shut using plastic sheet.
With 3~1mm of grain size Al2O36 parts, 1~0mm of grain size Al2O340 parts, grain size<0.074mm Al2O330 parts, grain 10~20nm of diameter TiO23 parts, 11 parts of graphite, Ti3SiC23 parts, 2 parts of Al powder, 6 parts of resin is raw material hydrostatic profile, pressure 600 The ventilative ring 4 of truncated cone-shaped is made in~800MPa, and so that the bottom radius surface of ventilative ring 4 is that stick body 1 is relatively large in diameter the straight of one end 1.5 times of diameter, the upper bottom surface radius of the ventilative ring 4 are 2 times of the diameter that stick body 1 is relatively large in diameter one end.
Then it is toasted at 500~600 DEG C spare;Plastic sheet during baking in branch pipe 6 is burned off so that branch Pipe 6 and 4 surface of ventilative ring after molding are ventilative.By the stick body 1 of the installation of ventilative ring 4 after baking after baking, at annular groove It is filled to form 8,120 DEG C of dryings of sealing ring for 24 hours with aluminium oxide pouring material, be toasted with tundish after brush antioxidant coating It uses, adjusts Ar throughputs according to actual conditions in casting process, making slag, there are air films to be advisable with ventilative interannular.
Embodiment three
First with white fused alumina (Al2O3More than 97%), graphite (C be more than 97%), nano-TiO2(purity is more than 97%) and resin For raw material, consisting of:3~1mm Al2O34~8 parts, 1~0.074mm Al2O335~45 parts,<0.074mm Al2O3 25 ~35 parts, 10~20nm TiO22~5 parts, 8~12 parts of graphite, 1~3 part of antioxidant Al powder, 4~8 parts of resin.Isostatic pressed Conventional stopper size is made in molding, 800~1200MPa of pressure so that the radius of the free end 11 of the stick body 1 of stopper is stick body 1 Then 0.6 times of the radius of the other end is processed into the cylinder that radius is stick body radius 0.6 to stick tail direction in stopper slag line, And away from the annular groove for processing depth 3mm wide 5mm at 200~300mm of slag line starting position.By the stopper processed 500~600 It is toasted at DEG C spare.
The annulus snorkel 5 of stick body radius is made of the steel pipe of 3~5mm of internal diameter, 5 radial direction of annulus snorkel every 10~20 ° are provided with connection annulus snorkel 5, and with the matched branch pipe 6 of 5 internal diameter of annulus snorkel, 6 length of branch pipe is 0.2~ The radius of stick body lower end described in 0.3R, 5 vertical direction of annulus snorkel setting connection annulus snorkel 5, and with annulus snorkel 5 The matched vertical air inlet pipe 7 of internal diameter, connect with external Ar.The end of branch pipe 6 is shut using plastic sheet.
With 3~1mm of grain size Al2O38 parts, 1~0.074mm of grain size Al2O345 parts, grain size<0.074mm Al2O3 35 Part, 10~20nm of grain size TiO24 parts, 12 parts of graphite, Ti3SiC24 parts, 3 parts of Al powder, 8 parts of resin is raw material hydrostatic profile, pressure The ventilative ring 4 of truncated cone-shaped is made in 600~800MPa of power, and so that the bottom radius surface of ventilative ring 4 is that stick body 1 is relatively large in diameter one end 1.5 times of diameter, the upper bottom surface radius of the ventilative ring 4 is 2 times of the diameter that stick body 1 is relatively large in diameter one end.
Then it is toasted at 500~600 DEG C spare;Plastic sheet during baking at 6 mouthfuls of branch pipe is burned off so that Branch pipe and 4 surface of ventilative ring after molding are ventilative.By the stick body 1 of the installation of ventilative ring 4 after baking after baking, at annular groove It is filled to form 8,120 DEG C of dryings of sealing ring for 24 hours with aluminium oxide pouring material, be toasted with tundish after brush antioxidant coating It uses, adjusts Ar throughputs according to actual conditions in casting process, making slag, there are air films to be advisable with ventilative interannular.
Ventilative ring 4 is made of the component of following parts by weight known to above-described embodiment:Al2O364~88 parts, TiO22~4 Part, 10~12 parts of graphite, Ti3SiC22~4 parts, 1~3 part of Al powder, 4~8 parts of resin;Continuous casting requirement can be met, while resisting and invading Corrosion is preferable, and manufacturing cost is relatively low.
As shown in Figures 1 to 4, erosion-resistant stopper of the present invention, including stick body 1, described 1 one end of stick body are freely End, the other end are provided with caput 2;There is slag line on the stick body 1;Ventilative ring 4, the ventilative ring 4 are provided on the stick body 1 For round platform, the smaller one end of 4 bottom surface radius of ventilative ring is located at the lower section of the larger one end of bottom surface radius;4 bottom surface radius of ventilative ring Smaller one end is concordant with the initial position of slag line;
It is provided with gas-permeable channels in the ventilative ring 4;The gas-permeable channels include vertical air inlet pipe 7, annulus snorkel 5; Described 7 one end of vertical air inlet pipe is extended in ventilative ring 4 by ventilative 4 upper bottom surface of ring and is connected to annulus snorkel 5;The stick body 1 In the annulus of annulus snorkel 5, the annulus snorkel 5 is coaxial with stick body 1, and is provided on the circular ring shape tracheae 5 Circumferentially equally distributed branch pipe 6, the branch pipe 6 radially extend, and the branch pipe 6 is located in ventilative ring 4.
During use, it is passed through argon gas by the venting channels being arranged in stick body 1, molten steel is by 1 surrounding caput 2 of stick body Flowing, is then flowed into crystallizer.Inert gas, such as argon gas are passed through into vertical air inlet pipe 7 simultaneously.Due to described ventilative It is provided with gas-permeable channels in ring 4;The gas-permeable channels include vertical air inlet pipe 7, annulus snorkel 5;The vertical air inlet pipe 7 one End is extended in ventilative ring 4 by ventilative 4 upper bottom surface of ring and is connected to annulus snorkel 5;The annulus snorkel 5 is coaxial with stick body 1, And it is provided with circumferentially equally distributed branch pipe 6 on the circular ring shape tracheae 5, the branch pipe 6 radially extends, and the branch pipe 6 are located in ventilative ring 4;Therefore inert gas can uniformly be transported to the outer surface of ventilative ring 4 by gas-permeable channels.Simultaneously because The smaller one end of 4 bottom surface radius of ventilative ring is located at the lower section of the larger one end of bottom surface radius;Therefore inert gas is flowing up During contacted always with the outer surface of ventilative ring 4 so that inert gas is between the outer surface and molten steel of ventilative ring 4 Form one layer of air film.
The smaller one end of 4 bottom surface radius of ventilative ring is concordant with the initial position of slag line simultaneously;Therefore can avoid slag with Slag line on stick body 1 is in direct contact, and so as to reduce erosion of the slag to stick body 1, improves the service life of stopper.
In conclusion erosion-resistant stopper of the present invention, since the initial position of the slag line in stick body 1 is provided with Compression ring 4, and ventilative 4 rings are round platform, while being provided with gas-permeable channels in ventilative ring 4;The gas-permeable channels include vertical Air inlet pipe 7, annulus snorkel 5;Described 7 one end of vertical air inlet pipe is extended to by ventilative 4 upper bottom surface of ring in ventilative ring to be led to annulus Tracheae 5 is connected to;The annulus snorkel 5 is coaxial with stick body 1, and is provided on the circular ring shape tracheae 5 and is circumferentially uniformly distributed Branch pipe 6, the branch pipe 6 radially extends, and the branch pipe is located in ventilative ring 4.Therefore in use, by saturating Gas channel is passed through inert gas, and inert gas forms air film on the outer surface of ventilative ring, to avoid slag direct with slag line Contact, avoids slag from causing to corrode to the slag line with stick, therefore can extend the service life of stopper.
Specifically as shown in Fig. 2, models and application of the wherein starting altitude H of slag line according to different manufacturers using stopper Requirement sets itself of the production environment to slag line height.
In order to enable inert gas reaches when breathing freely 4 outer surface of ring, fine and close air film can be formed, it is further, adjacent Angle between two 6 axis of branch pipe is 10~20 °.Since inert gas is transported to 4 outer surface of ventilative ring by branch pipe 6, because The angle of this 6 axis of two neighboring branch pipe be 10~20 ° can ensure two neighboring branch pipe 6 convey gases can be full of it is adjacent Region of two branch pipes 6 between ventilative 4 outer surface of ring, so as to ensure that ventilative 4 outer surface of ring is formed continuously, completely , fine and close air film.
The ventilative ring 4 may be used various ways and be provided on stick body 1, for example pass through interference fit, or welding.For Ensure the stability of structure, while convenient for the replacement to ring 4 of breathing freely, it is preferred that the radius of 1 free end of stick body is less than stick The junction of the radius of 1 other end of body, 1 free end of stick body and 1 liang of one end of stick body forms boss, and the ventilative ring 4 is set with On the free end of stick body 1, and on boss;Sealing ring 8 is provided on the bottom surface that the ventilative ring 4 is located above, it is described Gap between ventilative 1 outer surface of ring 4 and stick body of the sealing of sealing ring 8;Annular radii that 5 axis of annulus snorkel surrounds with The diameter that one end is relatively large in diameter on stick body 1 is identical.
Following manner setting may be used in specific sealing ring 8, at the height for ring 4 of breathing freely away from slag line starting position distance The annular groove for processing depth 3mm wide 5mm, fills to form sealing ring 8 at annular groove with aluminium oxide pouring material.
In order to ensure that slag can not be in direct contact with stick body 1, while the manufacture material for ring 4 of breathing freely is saved, in another reality Apply in example, specifically, the radius of 1 free end of stick body is 0.6R, the radius of the other end is R, the ventilative ring 4 have two The larger bottom surface of radius is upper bottom surface in a bottom surface, and the smaller bottom surface of radius is bottom surface;The bottom radius surface of the ventilative ring 4 Upper bottom surface radius for 1.5R, the ventilative ring 4 is 2R.Specifically, the length of the branch pipe 6 is 0.2~0.3R.
While can ensure that slag section can not be in direct contact with stick body 1, the manufacture material for ring of breathing freely is saved, another In embodiment, specifically, the height of the ventilative ring 4 is 200~300mm.

Claims (9)

1. erosion-resistant stopper, including stick body (1), described stick body (1) one end is free end, and the other end is provided with caput (2);Institute Stating has slag line on stick body (1);It is characterized in that:Ventilative ring (4) is provided on the stick body (1), the ventilative ring (4) is circle Platform, the smaller one end of ventilative ring (4) bottom surface radius are located at the lower section of the larger one end of bottom surface radius;Ventilative ring (4) bottom surface radius Smaller one end is concordant with the initial position of slag line;
It is provided with gas-permeable channels in the ventilative ring (4);The gas-permeable channels include vertical air inlet pipe (7), annulus snorkel (5);Described vertical air inlet pipe (7) one end is extended to by ventilative ring (4) upper bottom surface in ventilative ring (4) to be connected with annulus snorkel (5) It is logical;The stick body (1) is located in the annulus of annulus snorkel (5), and the annulus snorkel (5) and stick body (1) are coaxially, and described Circumferentially equally distributed branch pipe (6) is provided on annulus snorkel (5), the branch pipe (6) radially extends, and the branch pipe (6) it is located in ventilative ring (4);
Ventilative ring (4) be made of the component of following parts by weight:
Al2O364~88 parts,
TiO22~4 parts,
10~12 parts of graphite,
Ti3SiC22~4 parts, 1~3 part of Al powder,
4~8 parts of resin.
2. erosion-resistant stopper according to claim 1, it is characterised in that:The Al2O3Group become:
Grain size is less than or equal to 3mm, and the Al more than 1mm2O34~8 parts,
Grain size is less than or equal to 1mm, and the Al more than or equal to 0.074mm2O335~45 parts,
Grain size is less than the Al of 0.074mm2O325~35 parts.
3. erosion-resistant stopper according to claim 2, it is characterised in that:The TiO2Grain size is 10~20nm.
4. erosion-resistant stopper as claimed in claim 1,2 or 3, it is characterised in that:Between two neighboring branch pipe (6) axis Angle is 10~20 °.
5. erosion-resistant stopper as claimed in claim 1,2 or 3, it is characterised in that:The radius of stick body (1) free end is small In the radius of stick body (1) other end, the junction of stick body (1) free end and (1) two one end of stick body forms boss, described Compression ring (4) is sleeved on the free end of stick body (1), and on boss;It is arranged on the bottom surface that the ventilative ring (4) is located above There are sealing ring (8), the ventilative gap between ring (4) and stick body (1) outer surface of sealing ring (8) sealing;The annulus ventilation The annular radii that pipe (5) axis surrounds is identical as the diameter of one end is relatively large in diameter on stick body (1).
6. erosion-resistant stopper as claimed in claim 5, it is characterised in that:The radius of stick body (1) free end is 0.6R, The radius of the other end is R, and the larger bottom surface of radius is upper bottom surface in two bottom surfaces that the ventilative ring (4) has, and radius is smaller Bottom surface be bottom surface;The bottom radius surface of the ventilative ring (4) is 1.5R, and the upper bottom surface radius of the ventilative ring (4) is 2R.
7. erosion-resistant stopper as claimed in claim 6, it is characterised in that:The length of the branch pipe (6) is 0.2~0.3R.
8. erosion-resistant stopper as claimed in claim 6, it is characterised in that:The sealing ring (8) uses aluminium oxide pouring shape At.
9. erosion-resistant stopper as claimed in claim 8, it is characterised in that:The height of the ventilative ring (4) be 200~ 300mm。
CN201611007489.0A 2016-11-16 2016-11-16 Erosion-resistant stopper Active CN106513652B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611007489.0A CN106513652B (en) 2016-11-16 2016-11-16 Erosion-resistant stopper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611007489.0A CN106513652B (en) 2016-11-16 2016-11-16 Erosion-resistant stopper

Publications (2)

Publication Number Publication Date
CN106513652A CN106513652A (en) 2017-03-22
CN106513652B true CN106513652B (en) 2018-10-09

Family

ID=58353335

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611007489.0A Active CN106513652B (en) 2016-11-16 2016-11-16 Erosion-resistant stopper

Country Status (1)

Country Link
CN (1) CN106513652B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0508246A1 (en) * 1991-04-09 1992-10-14 Vesuvius France S.A. Stopper rod having an erosion-resistant sleeve
CN1326390A (en) * 1998-11-20 2001-12-12 维苏维尤斯·克鲁斯布公司 Stopper rod
CN101607309A (en) * 2009-07-14 2009-12-23 华耐国际(宜兴)高级陶瓷有限公司 Controllable flow is gone into the integral type stopper of gas
CN204381357U (en) * 2014-11-27 2015-06-10 华耐国际(宜兴)高级陶瓷有限公司 A kind of stopper that can control argon flow amount
CN205519624U (en) * 2016-02-02 2016-08-31 苏州宝明高温陶瓷有限公司 Argon stopper stick is blown to integrative die -casting formula dispersivity

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0508246A1 (en) * 1991-04-09 1992-10-14 Vesuvius France S.A. Stopper rod having an erosion-resistant sleeve
CN1326390A (en) * 1998-11-20 2001-12-12 维苏维尤斯·克鲁斯布公司 Stopper rod
CN101607309A (en) * 2009-07-14 2009-12-23 华耐国际(宜兴)高级陶瓷有限公司 Controllable flow is gone into the integral type stopper of gas
CN204381357U (en) * 2014-11-27 2015-06-10 华耐国际(宜兴)高级陶瓷有限公司 A kind of stopper that can control argon flow amount
CN205519624U (en) * 2016-02-02 2016-08-31 苏州宝明高温陶瓷有限公司 Argon stopper stick is blown to integrative die -casting formula dispersivity

Also Published As

Publication number Publication date
CN106513652A (en) 2017-03-22

Similar Documents

Publication Publication Date Title
CN104497650B (en) A kind of release coating and the integral column of sagger using the release coating
EP0721388A1 (en) Casting part comprising an external layer appropriate to form a gas impervious layer, and implementation process
CN106216653A (en) A kind of long nozzle for continuous casting and manufacture method thereof
JP4933430B2 (en) Stopper rod for supplying gas to molten metal
CN105108132B (en) A kind of anti-nitrogen pick-up long nozzle of continuous casting production
CN106392051B (en) continuous casting stopper rod
CN109382506A (en) A kind of method of molten steel nitrogen increased amount in reduction continuous casting process
JP5069592B2 (en) Immersion nozzle
CN106513653B (en) Continuous casting stopper rod with ventilative ring
CN100467427C (en) Argon-blowing narrow brick
CN106513652B (en) Erosion-resistant stopper
CN108284217B (en) Stopper rod for purifying molten steel for continuous casting and preparation method thereof
CN106513654B (en) The stopper of the ventilative ring of band
CN105985122A (en) Refractory material for submersed nozzle inner hole body
CN109928770B (en) Preparation method of graphene refractory material for water gap
CN104439229A (en) Sandwich type long nozzle sealing piece and manufacturing method thereof
CN209424539U (en) The big packet long nozzle of molten steel nitrogen increased amount in a kind of reduction continuous casting process
WO2009072217A1 (en) Immersion nozzle and method of continuous casting
CN106735153B (en) Polycyclic stopper
CN207857846U (en) A kind of tundish upper nozzle
CN102489679A (en) Anti-blocking water feeding port with low air permeability
WO1995034395A1 (en) Casting part comprising an external layer appropriate to form a gas impervious layer, and implementation process
JP2007326111A (en) Immersion nozzle and continuous casting method
CN104744057B (en) The preparation method of ferro-silicon nitride porous ceramics slide plate
JP7157387B2 (en) Nozzle on tundish

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20180829

Address after: 610306 Chengdu City, Chengdu, Sichuan, China (Sichuan) free trade test zone, Chengdu City, Qingbaijiang District, xiangdao Boulevard, Chengxiang Town, No. 1509 (room 13, A District, railway port mansion), room 1319

Applicant after: Chengdu advanced metal material industry technology Research Institute Co., Ltd.

Address before: 617000 Taoyuan street, East District, Panzhihua, Sichuan Province, No. 90

Applicant before: Pangang Group Panzhihua Iron & Steel Research Institute Co., Ltd.

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder

Address after: 610306 Chengdu City, Chengdu, Sichuan, China (Sichuan) free trade test zone, Chengdu City, Qingbaijiang District, xiangdao Boulevard, Chengxiang Town, No. 1509 (room 13, A District, railway port mansion), room 1319

Patentee after: Chengdu advanced metal material industry technology Research Institute Co.,Ltd.

Address before: 610306 Chengdu City, Chengdu, Sichuan, China (Sichuan) free trade test zone, Chengdu City, Qingbaijiang District, xiangdao Boulevard, Chengxiang Town, No. 1509 (room 13, A District, railway port mansion), room 1319

Patentee before: CHENGDU ADVANCED METAL MATERIAL INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE Co.,Ltd.

CP01 Change in the name or title of a patent holder