CN106498769A - Nylon fibre/cotton fiber union wet method transfer printing method - Google Patents

Nylon fibre/cotton fiber union wet method transfer printing method Download PDF

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Publication number
CN106498769A
CN106498769A CN201610830515.3A CN201610830515A CN106498769A CN 106498769 A CN106498769 A CN 106498769A CN 201610830515 A CN201610830515 A CN 201610830515A CN 106498769 A CN106498769 A CN 106498769A
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China
Prior art keywords
cotton fiber
nylon fibre
union
fiber union
transfer printing
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Application number
CN201610830515.3A
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Chinese (zh)
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CN106498769B (en
Inventor
黄庄芳容
左凯杰
颜怀成
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Changzhou New Wide Knitting & Dyeing Co Ltd
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Changzhou New Wide Knitting & Dyeing Co Ltd
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Priority to CN201610830515.3A priority Critical patent/CN106498769B/en
Priority to PCT/CN2016/106390 priority patent/WO2018049726A1/en
Publication of CN106498769A publication Critical patent/CN106498769A/en
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8219Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003Transfer printing

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of nylon fibre/cotton fiber union wet method transfer printing method, has steps of:1. printing thin film is made;2. nylon fibre/cotton fiber the union of moistening is obtained;3. the nylon fibre of moistening/cotton fiber union is fit together with printing thin film, enters transfer device roll compacting, make the clear patterns on printing thin film is transferred to nylon fibre/cotton fiber union surface;4. introducing continuous way rapid steamer carries out evaporating color development, carries out conventional washing, drying after going out rapid steamer.The present invention is by selecting suitable mill base and pretreatment fluid, in mill base, especially add suitable acid stain and reactive dye and pH regulators are added in pretreatment fluid, using Graft versus host disease, and optimize and evaporate technique, so as to realize the wet transfer printing of nylon fibre/cotton fiber union, not only color saturation is plentiful, decalcomania remarkable fluency, and soft, and fastness is good.

Description

Nylon fibre/cotton fiber union wet method transfer printing method
Technical field
The invention belongs to printing in textiles technical field, and in particular to a kind of nylon fibre/cotton fiber union wet method Method for transfer printing.
Background technology
Nylon fabric typically adopts acid stain stamp in acid condition, and bafta is typically using reactive dye in alkalescence Under the conditions of stamp, its respective production technology is very ripe, in China's printing in textiles occupies significant proportion.Fine for chinlon The stamp of dimension/cotton fiber union, larger in chinlon content(Generally more than 90%)When, then can ignore cotton fiber and adopt With the independent stamp of acid stain;In the same manner, larger in cotton content(Generally also more than 90%)When, then can ignore nylon fibre and Using the independent stamp of reactive dye.But when nylon fibre content is closer to cotton fiber content, it is impossible to using single Acid stain or reactive dye carry out stamp, can only otherwise go up dye one of which fiber, and another kind of fiber shows money or valuables one carries unintentionally, and causes cloth Face becomes Flos Cannabiss color, and has a strong impact on the presentation quality of printed articles.
For the problems referred to above, existing document report prints nylon fibre/cotton fiber that content is closer to using pigment printing Union, the method although can solve the problem that nylon fibre and cotton fiber and meanwhile colouring problem, but there is Boardy Feeling, fastness The problems such as difference, and common flower pattern is also suitable only in terms of flower pattern representability, it is impossible to show the complex effects such as gradual change, moire.
Content of the invention
It is an object of the invention to solving the above problems, there is provided a kind of not only color saturation is plentiful, decalcomania is smooth certainly So, and the good nylon fibre of soft, fastness/cotton fiber union wet method transfer printing method.
The technical scheme for realizing above-mentioned purpose of the present invention is:A kind of nylon fibre/cotton fiber union wet method transfer print Flower method, has steps of:
1. using the mill base for preparing, flower pattern is printed on the thin film of coating by the roller on intaglio press, is made Into printing thin film;
2. nylon fibre/cotton fiber union is introduced into and fills the padding in groove of pretreatment fluid, 10~30 DEG C of one leaching one of room temperature Roll, by controlling to pad the speed of service of pressure and padding machine controlling the moisture content of nylon fibre/cotton fiber union be 70%~100%, obtain the nylon fibre/cotton fiber union of moistening;
The printing thin film that 1. nylon fibre of the moistening for 3. 2. obtaining step/cotton fiber union is obtained with step is fitted in Together, transfer device roll compacting is entered, by controlling the speed of service and transfer pressure of nylon fibre/cotton fiber union, is made Clear patterns on printing thin film are transferred to nylon fibre/cotton fiber union surface;After going out transfer device, chinlon is fine Dimension/cotton fiber union is separated with printing thin film, by transfer after the independent clot of thin film, nylon fibre/cotton fiber knits Thing is then dried through tensionless dryer;
4. the nylon fibre for 3. obtaining step/cotton fiber union introduces continuous way rapid steamer and carries out evaporating color development, and root According to technological requirement, strictly temperature and time is evaporated in control, to guarantee that acid stain is filled with nylon fibre, reactive dye and cotton fiber Divide and react, after going out rapid steamer, carry out conventional washing, drying.
Above-mentioned steps 1. described in mill base be formulated by the component of following weight percentage ratio:Acid stain 3%~15%, Reactive dye 3%~15%, dispersant 5%~10%, thickener 20%~40%, non-silicon defoaming agent 0.5%~1%, wetting agent 0.5%~1%, Remaining is water.
The species of above-mentioned acid stain and reactive dye is particularly significant for the present invention.
For acid stain, application claims are the good weak acid dyes of dissolubility.
For reactive dye, application claims are middle warm types(Dyeing fixed temperature is 50~70 DEG C)Or high temperature Type(Dyeing fixed temperature is 80~100 DEG C)Reactive dye.
The main component of above-mentioned dispersant is the moon/nonionic surfactant, and thickener is modified guar gum or modification Starch thickener or sodium alginate thickener, the main component of wetting agent is Siloxane-Oxyalkylene Copolymers polymer.
Above-mentioned steps 1. described in roller be electric carving chromium plating roller, carving depth be 4~7.
Above-mentioned steps 2. described in pretreatment fluid be formulated by the component of following weight percentage ratio:Thickener 0.5%~ 3%th, pH regulators 2%~5%, reduction preventing agent 1%~3%, chelated dispersants 1%~3%, non-silicon defoaming agent 0.5%~1%, remaining is Water.
Above-mentioned pH regulators use the Jintesalt ET of Suzhou Fu Binxin Chemical Co., Ltd.s production, and which is main Composition is nonionic surfactant, its role is to:Acidic materials are discharged gradually during evaporating, so that cloth cover pH The alkalescence that is fixed by suitable reactive dye gradually becomes the acidity of suitable acid stain fixation.
Above-mentioned thickener is sodium alginate thickener, and the main component for reducing preventing agent is m-nitrobenzene sodium sulfonate, chelates dispersion The main component of agent is anion surfactant.
Above-mentioned steps 2. described in pad pressure for 0.2~0.6MPa, the speed of service of padding machine is 5~15m/min.
Above-mentioned steps 3. described in nylon fibre/cotton fiber union the speed of service be 5~15m/min, transfer Pressure is 0.5~1MPa.
Above-mentioned steps 4. described in rapid steamer be continuous way rapid steamer, evaporate temperature for 101~105 DEG C, evaporate the time For 30~40min.
In above-mentioned nylon fibre/cotton fiber union, nylon fibre content is 1: 4~4: 1 with the ratio of cotton fiber content; Preferably 1: 2~2: 1;More preferably 1: 1.
The good effect that the present invention has:The present invention passes through to select suitable mill base and pretreatment fluid, especially in color Suitable acid stain and reactive dye are added in slurry and in pretreatment fluid add pH regulators, using Graft versus host disease, and Optimize and evaporate technique such that it is able to realize the wet transfer printing of nylon fibre/cotton fiber union, not only color saturation is rich Full, decalcomania remarkable fluency, flower pattern fineness are high, and product quality is controllable, soft, and fastness is good, up to 3-4 levels More than.
Specific embodiment
(Embodiment 1)
The nylon fibre of the present embodiment/cotton fiber union wet method transfer printing method has steps of:
1. according to flower pattern needs, flower pattern is carved on version cylinder according to depth difference, using the mill base for preparing, by intaglio process Brush machine is printed on flower pattern on the thin film of coating, makes printing thin film.
The mill base that the present embodiment is adopted is formulated by the component of following weight percentage ratio:Acid stain 12.8%, activity dye Material 10%, dispersant 5%, thickener 30%, non-silicon defoaming agent 0.5%, wetting agent 0.5% and water 41.2%.
Wherein, acid stain uses Hensel and steps weaving dyeization(China)The weak acid dye of company limited;Activity dye Material uses the middle Resist Reactive Dyes of Shanghai Fang Ke Chemical Co., Ltd.s(Dyeing fixed temperature is 60 DEG C);Dispersant is adopted Be dispersant T, from Changzhou Hui Lan commerce and trade company limited, its main component is the moon/nonionic surfactant;Thickener is adopted It is Gum-14, from sun,moon and star commerce and trade company limited, its main component is modified guar gum;Non-silicon defoaming agent is adopted Be DM-7401, from dolantin chemical company, its main component be nonionic surfactant;Wetting agent uses HR- 8060, from Hong Rui Chemical Co., Ltd.s, its main component is Siloxane-Oxyalkylene Copolymers polymer.
2. nylon fibre/cotton fiber union be introduced into padding in groove for the pretreatment fluid that fills that temperature is 18 DEG C, one Immersing and rolling, controls to pad pressure for 0.5MPa, and the speed of service of padding machine is 12m/min, through roll compacting after nylon fibre/cotton fiber The moisture content of union is 85%, obtains the nylon fibre/cotton fiber union of moistening.
The pretreatment fluid that the present embodiment is adopted is formulated by the component of following weight percentage ratio:Thickener 3.5%, pH is adjusted Agent 5%, reduction preventing agent 4%, chelated dispersants 1%, non-silicon defoaming agent 0.5% and water 86%.
Wherein, thickener uses sodium alginate;PH regulators use the life of Suzhou Fu Binxin Chemical Co., Ltd.s The Jintesalt ET of product, its main component are nonionic surfactant;The HT-305 that reduction preventing agent is adopted, from Shanxi He Tai Chemical Co., Ltd.s of state city, its main component are m-nitrobenzene sodium sulfonate;Chelated dispersants use SQ-113, source In Shanghai Fu Bin Fine Chemical Co., Ltd, its main component is anion surfactant;Non-silicon defoaming agent uses DM- 7401, from dolantin chemical company, its main component is nonionic surfactant.
The printing thin film patch that 1. nylon fibre of the moistening for 3. 2. obtaining step/cotton fiber union is obtained with step It is combined, enters transfer device roll compacting, the speed of service for controlling nylon fibre/cotton fiber union is 12m/min, transfers Pressure is 1.0MPa, and make the clear patterns on printing thin film is transferred to nylon fibre/cotton fiber union surface;Go out transfer After device, nylon fibre/cotton fiber union is separated with printing thin film, by transfer after the independent clot of thin film, nylon fibre/ Cotton fiber union is then dried through tensionless dryer.
4. the nylon fibre for 3. obtaining step/cotton fiber union introduces continuous way rapid steamer and carries out evaporating color development, Technique is evaporated for 102 DEG C × 35min, during evaporating, start cloth cover pH for alkalescence, be suitable for the fixation of reactive dye, with steaming The prolongation of change time, pH regulators gradually discharge acidic materials, make cloth cover pH be changed into acid, so as to be suitable for consolidating for acid stain Color, finally guarantees that acid stain is fully reacted with cotton fiber with nylon fibre and reactive dye, carries out after going out rapid steamer The washing of routine, drying.
After testing, the nylon fibre of the present embodiment/cotton fiber union fastness up to 3-4 levels more than, and feel is soft Soft, color saturation is plentiful, decalcomania remarkable fluency.

Claims (9)

1. a kind of nylon fibre/cotton fiber union wet method transfer printing method, it is characterised in that comprise the following steps:
1. using the mill base for preparing, flower pattern is printed on the thin film of coating by the roller on intaglio press, is made Into printing thin film;
2. nylon fibre/cotton fiber union is introduced into and fills the padding in groove of pretreatment fluid, 10~30 DEG C of one leaching one of room temperature Roll, by controlling to pad the speed of service of pressure and padding machine controlling the moisture content of nylon fibre/cotton fiber union be 70%~100%, obtain the nylon fibre/cotton fiber union of moistening;
The printing thin film that 1. nylon fibre of the moistening for 3. 2. obtaining step/cotton fiber union is obtained with step is fitted in Together, transfer device roll compacting is entered, by controlling the speed of service and transfer pressure of nylon fibre/cotton fiber union, is made Clear patterns on printing thin film are transferred to nylon fibre/cotton fiber union surface;After going out transfer device, chinlon is fine Dimension/cotton fiber union is separated with printing thin film, by transfer after the independent clot of thin film, nylon fibre/cotton fiber knits Thing is then dried through tensionless dryer;
4. the nylon fibre for 3. obtaining step/cotton fiber union introduces continuous way rapid steamer and carries out evaporating color development, and root According to technological requirement, strictly temperature and time is evaporated in control, to guarantee that acid stain is filled with nylon fibre, reactive dye and cotton fiber Divide and react, after going out rapid steamer, carry out conventional washing, drying.
2. nylon fibre according to claim 1/cotton fiber union wet method transfer printing method, it is characterised in that: Above-mentioned steps 1. described in mill base be formulated by the component of following weight percentage ratio:Acid stain 3%~15%, reactive dye 3%~15%, dispersant 5%~10%, thickener 20%~40%, non-silicon defoaming agent 0.5%~1%, wetting agent 0.5%~1%, remaining is Water.
3. nylon fibre according to claim 1/cotton fiber union wet method transfer printing method, it is characterised in that: Described acid stain is the good weak acid dye of dissolubility, and described reactive dye are middle warm type or high temperature modification activity dye Material, the main component of described dispersant is the moon/nonionic surfactant, and described thickener for modified guar gum or changes Property starch thickener or sodium alginate thickener, the main component of described wetting agent is Siloxane-Oxyalkylene Copolymers polymer.
4. the nylon fibre according to one of claims 1 to 3/cotton fiber union wet method transfer printing method, its are special Levy and be:Above-mentioned steps 2. described in pretreatment fluid be formulated by the component of following weight percentage ratio:Thickener 0.5%~3%, PH regulators 2%~5%, reduction preventing agent 1%~3%, chelated dispersants 1%~3%, non-silicon defoaming agent 0.5%~1%, remaining is water.
5. nylon fibre according to claim 4/cotton fiber union wet method transfer printing method, it is characterised in that: Described thickener is sodium alginate thickener, and the main component of described pH regulators is nonionic surfactant, and described goes back The main component of former preventing agent is m-nitrobenzene sodium sulfonate, and the main component of described chelated dispersants is anion surface active Agent.
6. the nylon fibre according to one of claim 1 to 5/cotton fiber union wet method transfer printing method, its are special Levy and be:Above-mentioned steps 4. described in rapid steamer be continuous way rapid steamer, evaporate temperature for 101~105 DEG C, the time of evaporating is 30~40min.
7. the nylon fibre according to one of claim 1 to 6/cotton fiber union wet method transfer printing method, its are special Levy and be:In the nylon fibre/cotton fiber union, nylon fibre content is 1: 4~4: 1 with the ratio of cotton fiber content.
8. nylon fibre according to claim 7/cotton fiber union wet method transfer printing method, it is characterised in that: In the nylon fibre/cotton fiber union, nylon fibre content is 1: 2~2: 1 with the ratio of cotton fiber content.
9. nylon fibre according to claim 8/cotton fiber union wet method transfer printing method, it is characterised in that: In the nylon fibre/cotton fiber union, nylon fibre content is 1: 1 with the ratio of cotton fiber content.
CN201610830515.3A 2016-09-19 2016-09-19 Nylon fibre/cotton fiber union wet method transfer printing method Active CN106498769B (en)

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Application Number Priority Date Filing Date Title
CN201610830515.3A CN106498769B (en) 2016-09-19 2016-09-19 Nylon fibre/cotton fiber union wet method transfer printing method
PCT/CN2016/106390 WO2018049726A1 (en) 2016-09-19 2016-11-18 Wetting transfer printing method for chinlon fibre/cotton fibre interwoven fabric

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Cited By (3)

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CN107083698A (en) * 2017-04-07 2017-08-22 常州旭荣针织印染有限公司 Nylon fabric wet transfer printing padding liquid and its compound method
CN111172785A (en) * 2020-02-04 2020-05-19 军事科学院***工程研究院军需工程技术研究所 Alkaline printing method for nylon 56 and cellulose fiber blended fabric
CN111350088A (en) * 2020-04-20 2020-06-30 天津工业大学 Cotton/polyamide fabric ink-jet printing pretreating agent and pretreating process

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Publication number Priority date Publication date Assignee Title
CN107083698A (en) * 2017-04-07 2017-08-22 常州旭荣针织印染有限公司 Nylon fabric wet transfer printing padding liquid and its compound method
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CN111172785A (en) * 2020-02-04 2020-05-19 军事科学院***工程研究院军需工程技术研究所 Alkaline printing method for nylon 56 and cellulose fiber blended fabric
CN111350088A (en) * 2020-04-20 2020-06-30 天津工业大学 Cotton/polyamide fabric ink-jet printing pretreating agent and pretreating process

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