CN106498152A - A kind of limonite super thick bed of material sintering method using pre-sintering - Google Patents

A kind of limonite super thick bed of material sintering method using pre-sintering Download PDF

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Publication number
CN106498152A
CN106498152A CN201610815344.7A CN201610815344A CN106498152A CN 106498152 A CN106498152 A CN 106498152A CN 201610815344 A CN201610815344 A CN 201610815344A CN 106498152 A CN106498152 A CN 106498152A
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sintering
cloth
limonite
bed
sintered
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CN106498152B (en
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刘杰
周明顺
唐复平
翟立委
姚林
王义栋
韩淑峰
任子平
张辉
徐礼兵
宫作岩
吴远飞
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Angang Steel Co Ltd
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Angang Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating
    • C22B1/22Sintering; Agglomerating in other sintering apparatus

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The present invention discloses a kind of using pre-sintered limonite super thick bed of material sintering method.Full limonite sintering is adopted in ground floor cloth, basicity is 2.25 2.35 high alkalinity, on the one hand the content of high intensity calcium ferrite is improve, on the other hand in sintering, amount of liquid phase increases, the a large amount of holes produced during limonite sintering are filled up, make limonite densified, after repaving the second layered material simultaneously, insulation and binder effect are served to underlying material to a certain extent, the sintering deposit of bottom is made to have sufficient time and temperature-curable crystallization, also reduce the extremely cold impact to sinter strength during full limonite sintering, the full limonite sintering of the ground floor that makes from the impact of above pre-sintering process feature is possibly realized.And the compound of second layer iron ore concentrate and limonite, two kinds of iron ore raw materials of the different physical and chemical performances for making achieve characteristic complementation, so as to improve sintering technology index.

Description

A kind of limonite super thick bed of material sintering method using pre-sintering
Technical field
The present invention relates to the sintering production method of iron ore, especially relates to a kind of using pre-sintered limonite super thick Bed of material sintering production method.
Background technology
Limonite is a kind of important iron ore material of ironmaking, but contains the higher crystallization water, coarse size, heap ratio due to which Weight is little, needs to consume substantial amounts of fuel when sintering is used.Simultaneously as which assimilates, temperature is low, and porosity is high, in production application When, easily cross at high temperature and melt, make the hot gas permeability of sinter bed be deteriorated, cause productivity of sinter to decline, under cold strength Drop, limit limonite in SINTERING PRODUCTION with addition of ratio.At present, in existing report, limonite really should in production 60% is not had more than with addition of ratio.
In current limonite sintering production, in order to improve the productivity ratio and sintering index of limonite, existing main Method is:1st, with addition of the bigger water yield;2nd, high alkalinity, high-carbon quantity are sintered;3rd, binder;4th, thickness of feed layer is improved.With addition of bigger The water yield, can improve yield rate to a certain extent, but continue to increase with rate of water added, burnup can be caused to increase, burning velocity Accelerate, quantity of return mines increases, productivity ratio declines;Due to the country, generally carry out is high-basicity sintering, excessively improves mixed carbon comtent not Productivity ratio yield rate can be effectively improved, the bed of material can be made on the contrary to superfuse, make gas permeability be deteriorated;Binder is to improve limonite consumption, carries Large-duty effective way, but binder limitation, if binder degree is too big, can make the gas permeability of the bed of material be deteriorated again, Reduce productivity ratio on the contrary;It is to improve the effective ways of limonite sintering productivity ratio to improve thickness of feed layer.
But under conditions of sintering area is constant, the thickness of feed layer of sintering machine is nor unrestrictedly can improve, which is received The many factors such as equipment scale, air exhauster ability, material condition, sinter quality are restricted.Once there are some researches show both at home and abroad, only leaned on The thickness of feed layer of simple raising sinter mixture, and corresponding technological measure is not taken, reach to a certain degree in thickness of feed layer Afterwards, the production capacity and quality of sintering machine all drastically can decline, and lose more than gain.So, current sintering material layer thickness is being adopted both at home and abroad Take under various technical measures, generally also only in 800mm or so, and global metallurgy is sintered into more than the 900mm super thick bed of materials A difficult problem.
Content of the invention
The technical problem to be solved is to provide a kind of limonite super thick bed of material sintering method using pre-sintering, The difficult point that limonite production is overcome well using brand-new pre-sintering process characteristic, breaches due to special cold and hot state property The bottleneck of vast scale application can be difficult to, with important economic worth and extensive generalization.
The present invention seeks to realized by techniques below scheme:
A kind of limonite super thick bed of material sintering method using pre-sintering, it is characterised in that on sintering belt type roasting machine It is configured with first and second mixing distributing device and No. first and second igniter;Whole SINTERING PRODUCTION adopts a set of exhausting system;Advanced Capable cloth first, after bed material distributing device grate-layer material, then by mixture distributor device cloth sinter mixture, igniting is sintered, After pre-sintering, second cloth sinter mixture is carried out in cloth layer surface first, sintering suction pressure keeps constant, to second Bed of cloth carries out igniting sintering, and when second bed of cloth completes to light a fire, the compound of bed of cloth is sintered first, is burning At knot machine tail, bed of cloth and second bed of cloth are complete sintering first;Compound for cloth first arranges dispensing, mixes Close and granulating system, be that the compound of second cloth arranges dispensing, mixing and granulating system, first during cloth, sintered compound In material, iron-bearing material is 100% limonite, and in 2.25-2.35, moisture weight percentage is 7.7%-8.5% to basicity, the bed of material The height chassis baffle plate high with 600-900mm is flushed, and firing temperature is controlled at 900 DEG C -1050 DEG C, after pre-sintered 4-20min, Using trapezoidal cloth method, more than chassis baffle plate, carry out second cloth again, in the sinter mixture of second cloth, iron content is former Expect in the magnetite concentrate or hematite concentrates of limonite and 60%-100% for 0-40% one or two, basicity is in 1.70- 1.95, moisture weight percentage is 7.2%-7.6%, and in 200mm-350mm, firing temperature control is 1100 for fabric thickness control ℃-1250℃;In total sinter mixture, it is 60%-90% that limonite accounts for the percentage by weight of total iron charge;Compound total alkali Degree is in 2.0-2.25.
Staflux is lime stone, quick lime, magnesite.
Bed of cloth thickness and second bed of cloth thickness sum >=900mm first;Sintering machine operation in whole sintering process Speed is 1.5m/min-2.5m/min, sinters suction pressure >=7000pa.
The present invention adopts full limonite sintering, basicity to be the high alkalinity of 2.25-2.35, on the one hand carry in ground floor cloth The high content of high intensity calcium ferrite, on the other hand in sintering, amount of liquid phase increases, and has filled up produce during limonite sintering big Metering-orifice hole, makes limonite densified, while after repaving the second layered material, serving insulation to underlying material to a certain extent and binder being made With, make the sintering deposit of bottom have sufficient time and temperature-curable crystallization, extremely cold to sintering when also reducing full limonite sintering The impact of ore deposit intensity, the full limonite sintering of the ground floor made from the impact of above pre-sintering process feature are possibly realized.And second Layer iron ore concentrate and the compound of limonite, two kinds of iron ore raw materials of the different physical and chemical performances for making achieve characteristic complementation, from And improve sintering technology index.When above technical measures effectively raise sintering limonite with addition of ratio, overcome A variety of difficulties during limonite sintering, change traditional limonite sintering pattern, with higher economic worth.
Figure of description
Fig. 1 is super thick bed of material sintering method process chart of the present invention using pre-sintering;
Wherein 1 mixture distributor device a, 2 is igniter a, and 3 are bed of cloth first, and 4 is mixture distributor device b, and 5 are igniting Device b, 6 is second bed of cloth.
Specific embodiment
Illustrate with reference to specific embodiment:
Embodiment 1:
Concrete technology flow process such as Fig. 1 of the present invention, in a 360m2, on the high 700mm sintering machines of trolley breast plate, carry out pre- When sintering process is produced, by the dispensing arranged for cloth first, mixing and granulating system, by 100% limonite and part Coke powder, lime stone, quick lime and magnesite carry out dispensing and mixed once, secondary granulation, before cloth, sintering deposit compound 2.25, moisture weight percentage composition is 7.7% for basicity control.Cloth first and igniting are carried out by distributing device 1 and igniter 2 When, bed depth is flushed with chassis baffle plate, and firing temperature is at 900 DEG C.
While lower floor's compound dispensing, mixing and granulation, 100% magnetite concentrate is carried out dispensing mixing and system Grain, before second cloth, 1.7, moisture weight percentage composition is 7.2% for the basicity of sinter mixture.Mixed in bottom sintering After closing 3 pre-sintering 5min of the bed of material, second cloth and igniting are carried out by distributing device 4 and igniter 5,6 is second bed of cloth, Fabric thickness is 200mm, and firing temperature is at 1100 DEG C.
2.10, limonite accounts for iron charge 72% with addition of ratio to the total alkalinity of sinter mixture.
Main sintering index such as table 1
Known by table 1, when limonite is 72% with addition of ratio, using the present invention, the yield rate of sintering deposit reaches 66.1%, drum strength has reached 78.2% and has all fully met production requirement of the blast furnace to sintering deposit, while low temperature reduction degradation Index has also reached 75.3%, and metallurgical performance index is excellent.The present invention is not being adopted, under same conditions of mixture ratios, there are no Industrial production is reported.
Embodiment 2:
Concrete technology flow process such as Fig. 1 of the present invention, in a 360m2, on the high 800mm sintering machines of trolley breast plate, carry out pre- When sintering process is produced, by the dispensing arranged for cloth first, mixing and granulating system, by 100% limonite and part Coke powder, lime stone, quick lime and magnesite carry out dispensing and mixed once, secondary granulation, before cloth, sintering deposit compound 2.3, moisture weight percentage composition is 8.0% for basicity control.Cloth first and igniting are carried out by distributing device 1 and igniter 2 When, bed depth is flushed with chassis baffle plate, and firing temperature is at 1000 DEG C.
While lower floor's compound dispensing, mixing and granulation, the hematite concentrates of 20% limonite and 80% are carried out Dispensing mixing and granulation, before second cloth, 1.8, moisture weight percentage composition exists the basicity of sinter mixture 7.3%.After 3 pre-sintering 10min of the bottom sintered compound bed of material, second cloth and point are carried out by distributing device 4 and igniter 5 Fire, 6 is second bed of cloth, and fabric thickness is 250mm, and firing temperature is at 1150 DEG C.
2.17, limonite accounts for iron charge 78% with addition of ratio to the total alkalinity of sinter mixture.
Main sintering index such as table 2
Known by table 2, when limonite is 78% with addition of ratio, using the present invention, the yield rate of sintering deposit reaches 65.8%, drum strength has reached 78.0% and has all fully met production requirement of the blast furnace to sintering deposit, while low temperature reduction degradation Index has also reached 75.0%, and metallurgical performance index is excellent.The present invention is not being adopted, under same conditions of mixture ratios, there are no Industrial production is reported.
Embodiment 3:
Concrete technology flow process such as Fig. 1 of the present invention, in a 360m2, on the high 700mm sintering machines of trolley breast plate, carry out pre- When sintering process is produced, by the dispensing arranged for cloth first, mixing and granulating system, by 100% limonite and part Coke powder, lime stone, quick lime and magnesite carry out dispensing and mixed once, secondary granulation, before cloth, sintering deposit compound 2.35, moisture weight percentage composition is 8.5% for basicity control.Cloth first and igniting are carried out by distributing device 1 and igniter 2 When, bed depth is flushed with chassis baffle plate, and firing temperature is at 1050 DEG C.
While lower floor's compound dispensing, mixing and granulation, the magnetite concentrate of 35% limonite and 65% is carried out Dispensing mixing and granulation, before second cloth, 1.9, moisture weight percentage composition exists the basicity of sinter mixture 7.4%.After 3 pre-sintering 15min of the bottom sintered compound bed of material, second cloth and point are carried out by distributing device 4 and igniter 5 Fire, 6 is second bed of cloth, and fabric thickness is 350mm, and firing temperature is at 1200 DEG C.
2.21, limonite accounts for iron charge 75% with addition of ratio to the total alkalinity of sinter mixture.
Main sintering index such as table 3
Known by table 3, when limonite is 75% with addition of ratio, using the present invention, the yield rate of sintering deposit reaches 66.3%, drum strength has reached 78.5% and has all fully met production requirement of the blast furnace to sintering deposit, while low temperature reduction degradation Index has also reached 75.7%, and metallurgical performance index is excellent.The present invention is not being adopted, under same conditions of mixture ratios, there are no Industrial production is reported.
Embodiment 4:
Concrete technology flow process such as Fig. 1 of the present invention, in a 360m2, on the high 750mm sintering machines of trolley breast plate, carry out pre- When sintering process is produced, by the dispensing arranged for cloth first, mixing and granulating system, by 100% limonite and part Coke powder, lime stone, quick lime and magnesite carry out dispensing and mixed once, secondary granulation, before cloth, sintering deposit compound 2.35, moisture weight percentage composition is 8.0% for basicity control.Cloth first and igniting are carried out by distributing device 1 and igniter 2 When, bed depth is flushed with chassis baffle plate, and firing temperature is at 1050 DEG C.
While lower floor's compound dispensing, mixing and granulation, the magnetite concentrate of 40% limonite and 60% is carried out Dispensing mixing and granulation, before second cloth, 1.95, moisture weight percentage composition exists the basicity of sinter mixture 7.6%.After 3 pre-sintering 20min of the bottom sintered compound bed of material, second cloth and point are carried out by distributing device 4 and igniter 5 Fire, 6 is second bed of cloth, and fabric thickness is 200mm, and firing temperature is at 1250 DEG C.
By the calculating to all raw materials of whole feed proportioning system, 2.25, limonite is matched somebody with somebody for the total alkalinity of sinter mixture Plus ratio accounts for iron charge 87%.
Main sintering index such as table 4
Known by table 4, when limonite is 87% with addition of ratio, using the present invention, the yield rate of sintering deposit reaches 66.1%, drum strength has reached 78.6% and has all fully met production requirement of the blast furnace to sintering deposit, while low temperature reduction degradation Index has also reached 75.2%, and metallurgical performance index is excellent.The present invention is not being adopted, under same conditions of mixture ratios, there are no Industrial production is reported.

Claims (3)

1. a kind of using pre-sintered limonite super thick bed of material sintering method, it is characterised in that to match somebody with somebody on sintering belt type roasting machine It is equipped with first and second mixing distributing device and No. first and second igniter;Whole SINTERING PRODUCTION adopts a set of exhausting system;First carry out Cloth, after bed material distributing device grate-layer material, then by mixture distributor device cloth sinter mixture, lights a fire and sinters, pre- first After sintering, second cloth sinter mixture is carried out in cloth layer surface first, sintering suction pressure keeps constant, to second cloth The bed of material carries out igniting sintering, and when second bed of cloth completes to light a fire, the compound of bed of cloth is sintered first, in sintering At machine tail, bed of cloth and second bed of cloth are complete sintering first;Compound for cloth first arranges dispensing, mixing And granulating system, it is that the compound of second cloth arranges dispensing, mixing and granulating system, first during cloth, sinter mixture Middle iron-bearing material is 100% limonite, and in 2.25-2.35, moisture weight percentage is 7.7%-8.5% to basicity, and the bed of material is high The degree chassis baffle plate high with 600-900mm is flushed, and firing temperature is controlled at 900 DEG C -1050 DEG C, after pre-sintered 4-20min, is adopted Trapezoidal cloth method is used, more than chassis baffle plate, carries out second cloth, in the sinter mixture of second cloth, iron-bearing material again For one or two in the magnetite concentrate or hematite concentrates of the limonite and 60%-100% of 0-40%, basicity is in 1.70- 1.95, moisture weight percentage is 7.2%-7.6%, and in 200mm-350mm, firing temperature control is 1100 for fabric thickness control ℃-1250℃;In total sinter mixture, it is 60%-90% that limonite accounts for the percentage by weight of total iron charge;Compound total alkali Degree is in 2.0-2.25.
2. according to claim 1 a kind of using pre-sintered limonite super thick bed of material sintering method, it is characterised in that to burn Knot flux is lime stone, quick lime, magnesite.
3. according to claim 1 a kind of using pre-sintered limonite super thick bed of material sintering method, it is characterised in that first Secondary bed of cloth thickness and second bed of cloth thickness sum >=900mm;In whole sintering process, the sintering machine speed of service is 1.5m/ Min-2.5m/min, sinters suction pressure >=7000pa.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109022659A (en) * 2018-09-30 2018-12-18 兰州有色冶金设计研究院有限公司 A kind of distribution device producing sponge iron and method
CN113249566A (en) * 2021-03-03 2021-08-13 广西北港新材料有限公司 Sintering system and method for limonite type laterite-nickel ore

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03193828A (en) * 1989-12-22 1991-08-23 Nippon Steel Corp Production of sintering raw material and sintered ore
JPH09209050A (en) * 1996-02-05 1997-08-12 Nippon Steel Corp Manufacture of sintered ore by high layer thickness
CN102242255A (en) * 2011-06-27 2011-11-16 攀钢集团有限公司 Method for sintering high-titanium vanadium titanium magnetite concentrate mixed with limonite
CN104278144A (en) * 2013-07-08 2015-01-14 鞍钢股份有限公司 Method for improving limonite sintering productivity
CN105316478A (en) * 2014-06-11 2016-02-10 鞍钢股份有限公司 Sintering production method increasing limonite proportion

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03193828A (en) * 1989-12-22 1991-08-23 Nippon Steel Corp Production of sintering raw material and sintered ore
JPH09209050A (en) * 1996-02-05 1997-08-12 Nippon Steel Corp Manufacture of sintered ore by high layer thickness
CN102242255A (en) * 2011-06-27 2011-11-16 攀钢集团有限公司 Method for sintering high-titanium vanadium titanium magnetite concentrate mixed with limonite
CN104278144A (en) * 2013-07-08 2015-01-14 鞍钢股份有限公司 Method for improving limonite sintering productivity
CN105316478A (en) * 2014-06-11 2016-02-10 鞍钢股份有限公司 Sintering production method increasing limonite proportion

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109022659A (en) * 2018-09-30 2018-12-18 兰州有色冶金设计研究院有限公司 A kind of distribution device producing sponge iron and method
CN113249566A (en) * 2021-03-03 2021-08-13 广西北港新材料有限公司 Sintering system and method for limonite type laterite-nickel ore
CN113249566B (en) * 2021-03-03 2023-02-07 广西北港新材料有限公司 Sintering system and method for limonite type laterite-nickel ore

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