CN106497245A - 一种添加高导热填料的复合氯磺化聚乙烯防腐涂料 - Google Patents

一种添加高导热填料的复合氯磺化聚乙烯防腐涂料 Download PDF

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CN106497245A
CN106497245A CN201611010898.6A CN201611010898A CN106497245A CN 106497245 A CN106497245 A CN 106497245A CN 201611010898 A CN201611010898 A CN 201611010898A CN 106497245 A CN106497245 A CN 106497245A
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Abstract

本发明公开了一种添加高导热填料的复合氯磺化聚乙烯防腐涂料，由下列重量份的原料制成：氯磺化聚乙烯胶乳60‑65、氯丁胶乳35‑40、聚氧乙烯脂肪醇醚7‑8、去离子水适量、硅烷偶联剂KH5602.5‑3、氧化镧2‑3、三氧化二铈1.5‑2、浓度为65wt%的硝酸溶液适量、浓度为50wt%的碳酸氢铵溶液、金红石型钛白粉10‑12、分散剂NNO0.9‑1.1、六方氮化硼6‑7、多壁碳纳米管3‑4、异丙醇适量、钛酸酯偶联剂TC‑20.16‑0.18。本发明制成的涂料具有优良的防腐蚀作用和散热降温作用，可以避免金属结构材质因热胀冷缩长久下来会导致金属产生疲劳，导致粉化、腐蚀生锈现象。

Description

一种添加高导热填料的复合氯磺化聚乙烯防腐涂料
技术领域
本发明涉及技术领域，尤其涉及一种添加高导热填料的复合氯磺化聚乙烯防腐涂料。
背景技术
腐蚀与防腐是化工、轻工、冶金、电力、纺织、印染、制船、建筑等行业突出的问题。每年因为腐蚀而造成损失巨大，所以防腐工作显得尤为重要，氯磺化聚乙烯防腐涂料，以优良的耐腐性，特别是极佳的柔韧性，得到广泛使用， 再加上价格不高，曾经一度深受业内人士的青睐。随着现代工业水平的飞速发展，对防腐涂料提出了更高、 更严格的承受环境腐蚀的能力。传统配方生产的氯磺化聚乙烯涂料的防腐性能一般很难达到要求。以往的氯磺化聚乙烯防腐涂料大都是溶剂型的，不但造成大量溶剂的浪费，而且所用溶剂有毒、易挥发，对环境造成污染，不符合环保要求，而水性涂料具有工艺清洁、技术先进、低排放、低能耗、安全无害的优点，因此，研究水性氯磺化聚乙烯防腐蚀涂料具有极大的社会效益和经济效益。
《水性氯磺化聚乙烯防腐蚀漆的研制》一文中以氯磺化聚乙烯胶乳与水性环氧树脂复配，通过蒸发釜减压脱除溶剂制成水性防腐涂料，制成的涂料性能优良、适应性强，涂刷过程中无毒无味、不易燃，生产过程简单，施工方便。由于水性环氧树脂的添加，提高了涂料的附着力的同时降低了防腐蚀性能，不能有效地提高了氯磺化聚乙烯的综合性能，固需要对水性氯磺化聚乙烯涂料进行进一步的改性，以满足行业发展的需求。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种添加高导热填料的复合氯磺化聚乙烯防腐涂料。
本发明是通过以下技术方案实现的：
一种添加高导热填料的复合氯磺化聚乙烯防腐涂料，由下列重量份的原料制成：氯磺化聚乙烯胶乳60-65、氯丁胶乳35-40、聚氧乙烯脂肪醇醚7-8、去离子水适量、硅烷偶联剂KH5602.5-3、氧化镧2-3、三氧化二铈1.5-2、浓度为65wt%的硝酸溶液适量、浓度为50wt%的碳酸氢铵溶液、金红石型钛白粉10-12、分散剂NNO0.9-1.1、六方氮化硼6-7、多壁碳纳米管3-4、异丙醇适量、钛酸酯偶联剂TC-20.16-0.18。
根据权利要求书1所述一种添加高导热填料的复合氯磺化聚乙烯防腐涂料，由下列具体方法制备而成：
（1）将氯磺化聚乙烯胶乳与氯丁胶乳混合，投入乳化器中，然后加入、聚氧乙烯脂肪醇醚以及总量等量的去离子水，以200-300转/份的速度搅拌形成初级乳液，再将其送入旋转蒸发器中，在真空度为0.01-0.03MPa、温度65-70℃下以70-80转/分的速度旋转蒸发出有机溶剂，得到混合胶乳；
（2）将氧化镧、三氧化二铈混合，加入2-2.5倍量的浓度为65wt%的硝酸溶液中，搅拌至完全溶解，然后加入与硝酸等量的浓度为50wt%的碳酸氢铵溶液进行沉淀反应，将得到的沉淀物过滤，用去离子水清洗后放入真空干燥箱中以60-70℃烘干，取出后灼烧60-90分钟，得到改性稀土；
（3）将六方氮化硼、多壁碳纳米管混合放入反应釜中，加入总量2-3倍量的异丙醇，室温下超声分散90-120分钟形成悬浮液，将钛酸酯偶联剂TC-2加入上述悬浮液中，加热至70-75℃搅拌2-3小时，反应结束后，抽滤，用去离子水洗涤2-3次，放入干燥箱中以80-90℃干燥90-120分钟；
（4）将硅烷偶联剂KH560溶于4-5倍量的去离子水中，然后加入步骤（2）得到的产物，超声分散30-40分钟后加入步骤（1）、（3）得到的产物，分散10-15分钟后加入其余剩余成分，用机械搅拌2-3小时，最后放入研磨机上研磨，过400目筛即得。
本发明的优点是：本发明采用水性配方，安全无毒，对环境友好，首先利用氯磺化聚乙烯胶乳与氯丁胶乳进行复配改性，提高了涂料的阻燃、耐老化性能；通过硅烷偶联剂KH560与改性稀土复配添加到涂料中，与涂料体系相容性能优异，而且稀土离子的众多空轨道可以捕捉不稳定的游离基，致其失去活性，有利于稳定作用，提高耐腐蚀性和耐老化性，同时稀土离子还可与涂料分子中的羟基、羟甲基等极性基团形成配位键，使涂料产生配位聚合干燥，从而提高漆膜的快干性。
本发明通过表面改性将多壁碳纳米管与六方氮化硼复配，能够与涂料很好的相容，不仅增强了涂料的耐磨性，同时提高了涂料的导热散热性；本发明制成的涂料具有优良的防腐蚀作用和散热降温作用，可以避免金属结构材质因热胀冷缩长久下来会导致金属产生疲劳，进而发生其材质表面漆膜爆裂剥落，水分子及氢、盐酸等接触金属表面，导致粉化、腐蚀生锈现象。
具体实施方式
一种添加高导热填料的复合氯磺化聚乙烯防腐涂料，由下列重量份（公斤）的原料制成：氯磺化聚乙烯胶乳60、氯丁胶乳35、聚氧乙烯脂肪醇醚7、去离子水适量、硅烷偶联剂KH5602.5、氧化镧2、三氧化二铈1.5、浓度为65wt%的硝酸溶液适量、浓度为50wt%的碳酸氢铵溶液、金红石型钛白粉10、分散剂NNO0.9、六方氮化硼6、多壁碳纳米管3、异丙醇适量、钛酸酯偶联剂TC-2 0.16。
根据权利要求书1所述一种添加高导热填料的复合氯磺化聚乙烯防腐涂料，由下列具体方法制备而成：
（1）将氯磺化聚乙烯胶乳与氯丁胶乳混合，投入乳化器中，然后加入、聚氧乙烯脂肪醇醚以及总量等量的去离子水，以200转/份的速度搅拌形成初级乳液，再将其送入旋转蒸发器中，在真空度为0.01MPa、温度65℃下以70转/分的速度旋转蒸发出有机溶剂，得到混合胶乳；
（2）将氧化镧、三氧化二铈混合，加入2倍量的浓度为65wt%的硝酸溶液中，搅拌至完全溶解，然后加入与硝酸等量的浓度为50wt%的碳酸氢铵溶液进行沉淀反应，将得到的沉淀物过滤，用去离子水清洗后放入真空干燥箱中以60℃烘干，取出后灼烧60分钟，得到改性稀土；
（3）将六方氮化硼、多壁碳纳米管混合放入反应釜中，加入总量2倍量的异丙醇，室温下超声分散90分钟形成悬浮液，将钛酸酯偶联剂TC-2加入上述悬浮液中，加热至70℃搅拌2小时，反应结束后，抽滤，用去离子水洗涤2次，放入干燥箱中以80℃干燥90分钟；
（4）将硅烷偶联剂KH560溶于4倍量的去离子水中，然后加入步骤（2）得到的产物，超声分散30分钟后加入步骤（1）、（3）得到的产物，分散10分钟后加入其余剩余成分，用机械搅拌2小时，最后放入研磨机上研磨，过400目筛即得。
对本实施例的涂料性能进行测试，细度小于50μm，附着力达到1 级，耐酸性(10%硫酸) 耐碱性( 10% 氢氧化钠) 耐盐水7 天不起泡，不脱落，不生锈。

Claims (2)

1.一种添加高导热填料的复合氯磺化聚乙烯防腐涂料，其特征在于，由下列重量份的原料制成：氯磺化聚乙烯胶乳60-65、氯丁胶乳35-40、聚氧乙烯脂肪醇醚7-8、去离子水适量、硅烷偶联剂KH5602.5-3、氧化镧2-3、三氧化二铈1.5-2、浓度为65wt%的硝酸溶液适量、浓度为50wt%的碳酸氢铵溶液、金红石型钛白粉10-12、分散剂NNO0.9-1.1、六方氮化硼6-7、多壁碳纳米管3-4、异丙醇适量、钛酸酯偶联剂TC-20.16-0.18。
2.根据权利要求书1所述一种添加高导热填料的复合氯磺化聚乙烯防腐涂料，其特征在于，由下列具体方法制备而成：
（1）将氯磺化聚乙烯胶乳与氯丁胶乳混合，投入乳化器中，然后加入、聚氧乙烯脂肪醇醚以及总量等量的去离子水，以200-300转/份的速度搅拌形成初级乳液，再将其送入旋转蒸发器中，在真空度为0.01-0.03MPa、温度65-70℃下以70-80转/分的速度旋转蒸发出有机溶剂，得到混合胶乳；
（2）将氧化镧、三氧化二铈混合，加入2-2.5倍量的浓度为65wt%的硝酸溶液中，搅拌至完全溶解，然后加入与硝酸等量的浓度为50wt%的碳酸氢铵溶液进行沉淀反应，将得到的沉淀物过滤，用去离子水清洗后放入真空干燥箱中以60-70℃烘干，取出后灼烧60-90分钟，得到改性稀土；
（3）将六方氮化硼、多壁碳纳米管混合放入反应釜中，加入总量2-3倍量的异丙醇，室温下超声分散90-120分钟形成悬浮液，将钛酸酯偶联剂TC-2加入上述悬浮液中，加热至70-75℃搅拌2-3小时，反应结束后，抽滤，用去离子水洗涤2-3次，放入干燥箱中以80-90℃干燥90-120分钟；
（4）将硅烷偶联剂KH560溶于4-5倍量的去离子水中，然后加入步骤（2）得到的产物，超声分散30-40分钟后加入步骤（1）、（3）得到的产物，分散10-15分钟后加入其余剩余成分，用机械搅拌2-3小时，最后放入研磨机上研磨，过400目筛即得。
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