CN106495594A - A kind of Reinforced Concrete Materials suitable for ocean coral island and preparation method thereof - Google Patents

A kind of Reinforced Concrete Materials suitable for ocean coral island and preparation method thereof Download PDF

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Publication number
CN106495594A
CN106495594A CN201610977029.4A CN201610977029A CN106495594A CN 106495594 A CN106495594 A CN 106495594A CN 201610977029 A CN201610977029 A CN 201610977029A CN 106495594 A CN106495594 A CN 106495594A
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China
Prior art keywords
reinforced concrete
coral
concrete materials
ocean
corallium japonicum
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Pending
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CN201610977029.4A
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Chinese (zh)
Inventor
冯兴国
徐逸文
石锐龙
陈达
江朝华
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Hohai University HHU
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Hohai University HHU
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Priority to CN201610977029.4A priority Critical patent/CN106495594A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/245Curing concrete articles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/02Selection of the hardening environment
    • C04B40/0277Hardening promoted by using additional water, e.g. by spraying water on the green concrete element
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/24Sea water resistance

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

The invention discloses a kind of Reinforced Concrete Materials suitable for ocean coral island, including reinforcing bar and concrete, concrete includes the following raw material for mixing in mass ratio:Corrosion inhibitor for cement quality 0.1% 0.5%;Cement is 1 with the mass ratio of coral sand aggregate:3‑1:4;The ratio of mud is 2:5‑3:5.The Reinforced Concrete Materials of the present invention, in conjunction with ocean coral island feature, draw materials nearby, with the direct mix maintenance of sea water, using coral sand as coarse aggregate and fine aggregate, the demand to the building material from transcontinental shipments is reduced, reduced cost of transportation, saved islands and reefs construction cost and accelerate islands and reefs construction speed;2205 two phase stainless steels are adopted for arrangement of reinforcement, 2205 stainless steel rebar excellent corrosion-proof performances, in conjunction with the corrosion inhibitor that aluminium triphosphate is host, further increase the corrosion resisting property of stainless steel rebar, extend Reinforced Concrete Materials service life, and convenient later maintenance, maintenance cost is cheap.

Description

A kind of Reinforced Concrete Materials suitable for ocean coral island and preparation method thereof
Technical field
The present invention relates to a kind of Reinforced Concrete Materials, and in particular to a kind of long-life steel suitable for ocean coral island Reinforced concrete material.
Background technology
In the islands and reefs engineering of ocean, if construction material will bring the freight of great number and longer to build from transcontinental shipments If the duration.
Rustless steel steel reinforcing bar has after good corrosion resistance, and stainless steel rebar corrosion without obvious Volumetric expansion, because This stainless steel reinforced concrete has good durability in marine environment.But it is under the conditions of high concentration corrosive medium, stainless Steel reinforcing bar still can occur pitting corrosion, cause steel area to reduce so that the bearing capacity drop of stainless steel reinforced concrete structure Low.
Corrosion inhibitor have antiseptic effect substantially, easy construction, the feature such as with low cost.Tradition is with nitrite as host Corrosion inhibitor not only has toxicity, and there is the not enough corrosion for accelerating reinforcing bar on the contrary of consumption.
Therefore, reduce stainless steel rebar pitting corrosion probability in the Corallium Japonicum Kishinouye sand concrete of high porosity, develop long-life Stainless steel rebar coral concrete structural material has important practical significance.
Content of the invention
For solving the deficiencies in the prior art, it is an object of the invention to provide a kind of combine coral island feature, take nearby Material prepares the long-life Reinforced Concrete Materials for being applied to ocean coral island.
A kind of Reinforced Concrete Materials suitable for ocean coral island, including reinforcing bar and concrete, the concrete by Following raw materials according is mixed together in mass ratio:
0.1%-0.5% of the corrosion inhibitor for cement quality;
Cement is 1 with the mass ratio of coral sand aggregate:3-1:4;
The ratio of mud is 2:5-3:5.
Above-mentioned reinforcing bar is 2205 two phase stainless steel reinforcing bars.
Above-mentioned water is sea water.
Above-mentioned coral sand bone includes Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand.
Further, the mass ratio of above-mentioned Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand is 3:1-4:1.
Above-mentioned corrosion inhibitor is with aluminium triphosphate as host.
The preparation method of the above-mentioned Reinforced Concrete Materials suitable for ocean coral island, comprises the following steps:
S1, the tied silk that 2205 two phase stainless steel reinforcing bars are passed through same material or nylon tied silk colligation are into steel bar framework;
S2, by mass ratio with cement, the corrosion inhibitor with aluminium triphosphate as host is added in cement, mix is uniform;
S3, prepare coral sand aggregate:Corallite is carried out Mechanical Crushing, will broken after Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand according to 3: 1-4:1 quality cooperation stirs and prepares coral sand aggregate;
S4, prepare dry material:The cement of mix corrosion inhibitor is stirred in mass ratio with coral sand aggregate, dry material is made;
S5, prepare Corallium Japonicum Kishinouye mortar:Certain ratio of mud is pressed, in above-mentioned dry material, adds sea water, mixed and make coral sand Slurry;
S6, above-mentioned Corallium Japonicum Kishinouye mortar is poured in steel bar framework, vibrate and make Reinforced Concrete Materials;
S7, maintenance:The fixed-type rear form removal of above-mentioned Reinforced Concrete Materials, was mixed with sea water maintenance Corallium Japonicum Kishinouye within a period of time Solidifying soil.
The invention has benefit that:A kind of armored concrete material suitable for ocean coral island that the present invention is provided Material, in conjunction with ocean coral island feature, is drawn materials nearby, with the direct mix maintenance of sea water, using coral sand as coarse aggregate and thin bone Material, reduces the demand to the building material from transcontinental shipments, reduces cost of transportation, saves islands and reefs construction cost and accelerate island Reef construction speed, is particularly suited for emergency first-aid repair islands and reefs engineering structure;2205 two phase stainless steels are adopted for arrangement of reinforcement, 2205 rustless steels Reinforcing bar excellent corrosion-proof performance, is the corrosion inhibitor of host in conjunction with aluminium triphosphate, further increases the corrosion resisting property of stainless steel rebar, Extend Reinforced Concrete Materials service life, solve in the islands and reefs engineering of ocean durability of the building structure in marine environment not The problem of foot;Convenient later maintenance, maintenance cost are cheap, and stainless steel rebar does not have obvious corrosion product volumetric expansion effect Should.
Description of the drawings
Fig. 1 is a kind of Reinforced Concrete Materials suitable for ocean coral island and the carbon steel concrete of the present invention in sea water The middle immersion AC impedance comparison diagram of 33 days.
Specific embodiment
Make specific introduction to the present invention below in conjunction with the drawings and specific embodiments.
Embodiment 1:
A kind of Reinforced Concrete Materials suitable for ocean coral island,
S1, cement and coral sand aggregate are pressed 1:3 mass ratio stirs, and makes dry material, Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand Mass ratio be 3:1;
S2 and cement are added into the corrosion inhibitor with aluminium triphosphate as host in above-mentioned dry material, are mixed by 0.2% mass ratio Close uniform;
S3, the ratio of mud by 0.45, add sea water, mix and are prepared into Corallium Japonicum Kishinouye mortar;
S4, above-mentioned Corallium Japonicum Kishinouye mortar is inserted in 2205 two phase stainless steel frameworks of steel reinforcement and makes Reinforced Concrete Materials;
S5, form removal after 1 day, were watered per 4 hours 5 minutes with sea water in 5 days for starting and conserve coral concrete.
Embodiment 2:
A kind of Reinforced Concrete Materials suitable for ocean coral island,
S1, cement and coral sand aggregate are pressed 2:7 mass ratio stirs, and makes dry material, Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand Mass ratio be 3:1;
S2 and cement are added into the corrosion inhibitor with aluminium triphosphate as host in above-mentioned dry material, are mixed by 0.3% mass ratio Close uniform;
S3, the ratio of mud by 0.4, add sea water, mix and are prepared into Corallium Japonicum Kishinouye mortar;
S4, above-mentioned Corallium Japonicum Kishinouye mortar is inserted in 2205 two phase stainless steel frameworks of steel reinforcement and makes Reinforced Concrete Materials;
S5, form removal after 1 day, were watered per 6 hours 10 minutes with sea water in 10 days for starting and conserve coral concrete.
Embodiment 3:
A kind of Reinforced Concrete Materials suitable for ocean coral island,
S1, cement and coral sand aggregate are pressed 1:4 mass ratio stirs, and makes dry material, Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand Mass ratio be 3:1;
S2 and cement are added into the corrosion inhibitor with aluminium triphosphate as host in above-mentioned dry material, are mixed by 0.2% mass ratio Close uniform;
S3, the ratio of mud by 0.6, add sea water, mix and are prepared into Corallium Japonicum Kishinouye mortar;
S4, above-mentioned Corallium Japonicum Kishinouye mortar is inserted in 2205 two phase stainless steel frameworks of steel reinforcement and makes Reinforced Concrete Materials;
S5, form removal after 1 day, were watered per 5 hours 8 minutes with sea water in 7 days for starting and conserve coral concrete.
Sample experiment is made with the Corallium Japonicum Kishinouye mortar that embodiment 3 makes:
The 2205 stainless reinforcing bars of a diameter of Ф 10mm are processed into the reinforcing bar sample of length 50mm, in the welding of reinforcing bar sample one end Copper cash, and with epoxy-coated reinforcement sample two ends, sample is put into exsiccator after epoxy resin is fully cured stand-by.
Corallium Japonicum Kishinouye mortar is loaded in Ф 40mm moulds of the height for 80mm, ready reinforcing bar sample heeling-in is entered mortar examination Mortar specimen is taken out and is soaked in sea water by sample center, form removal after 1 day, by Study on AC impedance resistance rust effect.
From accompanying drawing 1 as can be seen that in the Reinforced Concrete Materials, the impedance arc radius of reinforcing bar are significantly greater than carbon in sea water Impedance arc radius of the steel in normal concrete, show that the rusting rate of reinforcing bar in the material is significantly reduced.
The basic principles, principal features and advantages of the present invention have been shown and described above.The technical staff of the industry should Understand, the invention is not limited in any way for above-described embodiment, all obtained by the way of equivalent or equivalent transformation Technical scheme, all falls within protection scope of the present invention.

Claims (7)

1. a kind of Reinforced Concrete Materials suitable for ocean coral island, it is characterised in that including reinforcing bar and concrete, described Concrete includes the following raw material for mixing in mass ratio:
0.1%-0.5% of the corrosion inhibitor for cement quality;
Cement is 1 with the mass ratio of coral sand aggregate:3-1:4;
The ratio of mud is 2:5-3:5.
2. a kind of Reinforced Concrete Materials suitable for ocean coral island according to claim 1, it is characterised in that institute Reinforcing bar is stated for 2205 two phase stainless steel reinforcing bars.
3. a kind of Reinforced Concrete Materials suitable for ocean coral island according to claim 1, it is characterised in that institute Water is stated for sea water.
4. a kind of Reinforced Concrete Materials suitable for ocean coral island according to claim 1, it is characterised in that institute Stating coral sand aggregate includes Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand.
5. a kind of Reinforced Concrete Materials suitable for ocean coral island according to claim 4, it is characterised in that institute The mass ratio for stating Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand is 3:1-4:1.
6. a kind of Reinforced Concrete Materials suitable for ocean coral island according to claim 1, it is characterised in that institute Corrosion inhibitor is stated with aluminium triphosphate as host.
7. the preparation side of the Reinforced Concrete Materials suitable for ocean coral island according to claim 1-6 described in any one Method, it is characterised in that comprise the following steps:
S1, the tied silk that 2205 two phase stainless steel reinforcing bars are passed through same material or nylon tied silk colligation are into steel bar framework;
S2, by mass ratio with cement, the corrosion inhibitor with aluminium triphosphate as host is added in cement, mix is uniform;
S3, prepare coral sand aggregate:Corallite is carried out Mechanical Crushing, will broken after Corallium Japonicum Kishinouye coarse sand and Corallium Japonicum Kishinouye fine sand according to 3: 1-4:1 quality cooperation stirs and prepares coral sand aggregate;
S4, prepare dry material:The cement of mix corrosion inhibitor is stirred in mass ratio with coral sand aggregate, dry material is made;
S5, prepare Corallium Japonicum Kishinouye mortar:Certain ratio of mud is pressed, in above-mentioned dry material, adds sea water, mixed and make coral sand Slurry;
S6, above-mentioned Corallium Japonicum Kishinouye mortar is poured in steel bar framework, vibrate and make Reinforced Concrete Materials;
S7, maintenance:The fixed-type rear form removal of above-mentioned Reinforced Concrete Materials, was mixed with sea water maintenance Corallium Japonicum Kishinouye within a period of time Solidifying soil.
CN201610977029.4A 2016-11-08 2016-11-08 A kind of Reinforced Concrete Materials suitable for ocean coral island and preparation method thereof Pending CN106495594A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107125181A (en) * 2017-04-01 2017-09-05 浙江大学宁波理工学院 Utilize the method for house frame manufacture artificial marine habitat to be torn open
CN109354431A (en) * 2018-11-09 2019-02-19 南京航空航天大学 A kind of corrosion inhibitor incorporation method promoting coral concrete structure durability
CN109358108A (en) * 2018-11-09 2019-02-19 南京航空航天大学 A method of promoting coral concrete structural anticorrosion
CN112832190A (en) * 2020-12-10 2021-05-25 武汉理工大学 Coral island wave wall structure and construction method thereof
CN115792196A (en) * 2022-12-01 2023-03-14 武汉理工大学 Method for establishing coral concrete elastic model and age calculation model based on nondestructive testing

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CN106007441A (en) * 2016-05-25 2016-10-12 河海大学 Low-dosage environment-friendly rebar corrosion inhibitor

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107125181A (en) * 2017-04-01 2017-09-05 浙江大学宁波理工学院 Utilize the method for house frame manufacture artificial marine habitat to be torn open
CN107125181B (en) * 2017-04-01 2019-06-28 浙江大学宁波理工学院 Utilize the method for house frame manufacture artificial marine habitat to be torn open
CN109354431A (en) * 2018-11-09 2019-02-19 南京航空航天大学 A kind of corrosion inhibitor incorporation method promoting coral concrete structure durability
CN109358108A (en) * 2018-11-09 2019-02-19 南京航空航天大学 A method of promoting coral concrete structural anticorrosion
CN109354431B (en) * 2018-11-09 2021-09-07 南京航空航天大学 Method for doping rust inhibitor for improving durability of coral concrete structure
CN109358108B (en) * 2018-11-09 2021-11-30 南京航空航天大学 Method for improving corrosion resistance of coral concrete structure
CN112832190A (en) * 2020-12-10 2021-05-25 武汉理工大学 Coral island wave wall structure and construction method thereof
CN112832190B (en) * 2020-12-10 2022-06-14 武汉理工大学 Coral island wave wall structure and construction method thereof
CN115792196A (en) * 2022-12-01 2023-03-14 武汉理工大学 Method for establishing coral concrete elastic model and age calculation model based on nondestructive testing

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