CN106495561A - A kind of ceramic base 3D printing material and preparation method thereof - Google Patents
A kind of ceramic base 3D printing material and preparation method thereof Download PDFInfo
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- CN106495561A CN106495561A CN201610978038.5A CN201610978038A CN106495561A CN 106495561 A CN106495561 A CN 106495561A CN 201610978038 A CN201610978038 A CN 201610978038A CN 106495561 A CN106495561 A CN 106495561A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
Abstract
The invention discloses a kind of ceramic base 3D printing material and preparation method thereof, the ceramic base 3D printing material, according to the primary raw material of weight portion are：5 11 parts of modified Nano ceramic powders, 46 parts of organic silicone oil, 9 15 parts of polyacrylamide, 24 parts of shitosan, 5 12 parts of Graphene, 0.4 1.2 parts of nano aluminium oxide, 0.02 0.05 parts of salicylate ultraviolet absorbent, 11 18 parts of phenolic resin, 0.8 2.0 parts of calcium carbonate.The present invention solves nano ceramic material shaping long, the complex process that there is molding cycle, and low precision, the defect of shaped article simple structure have prepared the nano ceramic material product with high intensity and high tenacity, and empirical tests, wear resistance improve more than 60%；Toughness improves 30 40%；Tensile strength improves 15% or so.
Description
Technical field
The present invention relates to a kind of 3D printing Material Field, specifically a kind of ceramic base 3D printing material and preparation method thereof.
Background technology
3D printing technique, also known as increases material manufacturing technology, is a kind of emerging technology in rapid shaping field, it be one kind with number
Based on word model file, with powdery metal or plastics etc. can jointing material, come structure by way of successively printing
The technology of body.With the development and application of 3D printing technique, material becomes the key factor for limiting 3D printing technique future trend
One of, to a certain extent, the development of material decides that can 3D printing have widely application.At present, 3D printing material master
Engineering plastics to be included, photosensitive resin, rubber type of material, metal material and ceramic material etc., in addition, coloured plaster material
The food material such as material, artificial bone meal, cell biological raw material, wood materials and granulated sugar is also applied in 3D printing field.
Nano ceramics refers to that in the microstructure of ceramic material crystal grain, crystal boundary and the combination between them are at receiving
Meter Shui Ping (1～100nm) so that the intensity of material, toughness and superplasticity are increased substantially, overcomes many of engineering ceramics not
Foot, and material impact is produced to performances such as the mechanics of material, electricity, calorifics, magnetics, optics, it is the application of Replacing engineering pottery
Frontier is opened up.Nano ceramics as new ceramic material, with its excellent performance, with wide market application before
Scape, but nano ceramic material difficult forming, complex forming technology, it is difficult to meet application of the nano ceramics in productive life.Pass
The nano ceramics forming method of system is all by nano powder is made lumpy nanometer ceramic material, both passes through certain technical process,
Hole is removed, to form the bulk of densification, and during densified, nanocrystalline characteristic is maintained again, but be there is shaping
Cycle is long, complex process, low precision, shaped article simple structure, the narrow defect of application surface.
Content of the invention
It is an object of the invention to provide a kind of ceramic base 3D printing material and preparation method thereof, to solve above-mentioned background skill
The problem proposed in art.
For achieving the above object, the present invention provides following technical scheme：
A kind of ceramic base 3D printing material, according to the primary raw material of weight portion be：Modified Nano ceramic powders 5-11 parts, have
Machine silicone oil 4-6 parts, polyacrylamide 9-15 parts, shitosan 2-4 parts, Graphene 5-12 parts, nano aluminium oxide 0.4-1.2 parts, water
Poplar esters of gallic acid ultra-violet absorber 0.02-0.05 parts, phenolic resin 11-18 parts, calcium carbonate 0.8-2.0 parts；The modified Nano
The preparation method of ceramic powders is that nano ceramic powder is immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, after draining
Sepiolite powder and barium carbonate powder is added, and frit reaction is carried out after mixing, and is mixed with amylopectin after the reaction, i.e.,
?.
As further scheme of the invention：The ceramic base 3D printing material, according to the primary raw material of weight portion be：Change
Property nano ceramic powder 6-10 parts, organic silicone oil 4-6 parts, polyacrylamide 10-14 parts, shitosan 2-4 parts, Graphene 7-11
Part, nano aluminium oxide 0.7-1.1 parts, salicylate ultraviolet absorbent 0.02-0.05 parts, phenolic resin 13-17 parts, carbonic acid
Calcium 0.9-1.3 parts；The preparation method of the modified Nano ceramic powders is that nano ceramic powder is immersed in ethyl acetate, leaching
Bubble temperature control adds sepiolite powder and barium carbonate powder at 37 DEG C after draining, and carries out frit reaction after mixing, and in reaction
Mixed with amylopectin afterwards, obtained final product.
As further scheme of the invention：The ceramic base 3D printing material, according to the primary raw material of weight portion be：Change
8 parts of nano ceramic powder of property, 5 parts of organic silicone oil, 12 parts of polyacrylamide, 3 parts of shitosan, 10 parts of Graphene, nano aluminium oxide
0.9 part, 0.04 part of salicylate ultraviolet absorbent, 15 parts of phenolic resin, 1.0 parts of calcium carbonate；The modified Nano pottery
The preparation method of powder is that nano ceramic powder is immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, adds after draining
Sepiolite powder and barium carbonate powder, are carried out frit reaction, and are mixed with amylopectin after the reaction, obtained final product after mixing.
A kind of preparation method of ceramic base 3D printing material, concretely comprises the following steps：
First, by modified Nano ceramic powders, organic silicone oil, polyacrylamide, shitosan, Graphene, nano aluminium oxide,
Salicylate ultraviolet absorbent, phenolic resin, calcium carbonate are mixed, and in placing response kettle, are heat-treated followed by using ultrasound
Oscillation treatment, the power of sonic oscillation process is 730W, and the time is 30 minutes, and at a temperature of being placed in 4 DEG C, low temperature drying granulation, obtains
Ceramic base 3D printing material.
Compared with prior art, the invention has the beneficial effects as follows：
The present invention solves nano ceramic material shaping long, the complex process that there is molding cycle, and low precision, shaped article are tied
The simple defect of structure, has prepared the nano ceramic material product with high intensity and high tenacity, empirical tests, wear resistance
Improve more than 60%；Toughness improves 30-40%；Tensile strength improves 15% or so.
Specific embodiment
Below in conjunction with the embodiment of the present invention, to the embodiment of the present invention in technical scheme be clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiment.In based on the present invention
Embodiment, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of ceramic base 3D printing material, according to the primary raw material of weight portion be：5 parts of modified Nano ceramic powders, organic
4 parts of silicone oil, 9 parts of polyacrylamide, 2 parts of shitosan, 5 parts of Graphene, 0.4 part of nano aluminium oxide, salicylate ultraviolet are inhaled
Receive 0.02 part of agent, 11 parts of phenolic resin, 0.8 part of calcium carbonate；The preparation method of the modified Nano ceramic powders is that nanometer is made pottery
Porcelain powder is immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, adds sepiolite powder and barium carbonate powder after draining, and is mixed
Frit reaction is carried out after even, and is mixed with amylopectin after the reaction, obtain final product.
A kind of preparation method of ceramic base 3D printing material, concretely comprises the following steps：
First, by modified Nano ceramic powders, organic silicone oil, polyacrylamide, shitosan, Graphene, nano aluminium oxide,
Salicylate ultraviolet absorbent, phenolic resin, calcium carbonate are mixed, and in placing response kettle, are heat-treated followed by using ultrasound
Oscillation treatment, the power of sonic oscillation process is 730W, and the time is 30 minutes, and at a temperature of being placed in 4 DEG C, low temperature drying granulation, obtains
Ceramic base 3D printing material.
Embodiment 2
A kind of ceramic base 3D printing material, according to the primary raw material of weight portion be：6 parts of modified Nano ceramic powders, organic
4 parts of silicone oil, 10 parts of polyacrylamide, 2 parts of shitosan, 7 parts of Graphene, 0.7 part of nano aluminium oxide, salicylate ultraviolet are inhaled
Receive 0.02 part of agent, 13 parts of phenolic resin, 0.9 part of calcium carbonate；The preparation method of the modified Nano ceramic powders is that nanometer is made pottery
Porcelain powder is immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, adds sepiolite powder and barium carbonate powder after draining, and is mixed
Frit reaction is carried out after even, and is mixed with amylopectin after the reaction, obtain final product.
A kind of preparation method of ceramic base 3D printing material, concretely comprises the following steps：
First, by modified Nano ceramic powders, organic silicone oil, polyacrylamide, shitosan, Graphene, nano aluminium oxide,
Salicylate ultraviolet absorbent, phenolic resin, calcium carbonate are mixed, and in placing response kettle, are heat-treated followed by using ultrasound
Oscillation treatment, the power of sonic oscillation process is 730W, and the time is 30 minutes, and at a temperature of being placed in 4 DEG C, low temperature drying granulation, obtains
Ceramic base 3D printing material.
Embodiment 3
A kind of ceramic base 3D printing material, according to the primary raw material of weight portion be：8 parts of modified Nano ceramic powders, organic
5 parts of silicone oil, 12 parts of polyacrylamide, 3 parts of shitosan, 10 parts of Graphene, 0.9 part of nano aluminium oxide, salicylate ultraviolet
0.04 part of absorbent, 15 parts of phenolic resin, 1.0 parts of calcium carbonate；The preparation method of the modified Nano ceramic powders is by nanometer
Ceramic powders are immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, add sepiolite powder and barium carbonate powder after draining,
Frit reaction is carried out after mixing, and is mixed with amylopectin after the reaction, obtain final product.
A kind of preparation method of ceramic base 3D printing material, concretely comprises the following steps：
First, by modified Nano ceramic powders, organic silicone oil, polyacrylamide, shitosan, Graphene, nano aluminium oxide,
Salicylate ultraviolet absorbent, phenolic resin, calcium carbonate are mixed, and in placing response kettle, are heat-treated followed by using ultrasound
Oscillation treatment, the power of sonic oscillation process is 730W, and the time is 30 minutes, and at a temperature of being placed in 4 DEG C, low temperature drying granulation, obtains
Ceramic base 3D printing material.
Embodiment 4
A kind of ceramic base 3D printing material, according to the primary raw material of weight portion be：10 parts of modified Nano ceramic powders, organic
6 parts of silicone oil, 14 parts of polyacrylamide, 4 parts of shitosan, 11 parts of Graphene, 1.1 parts of nano aluminium oxide, salicylate ultraviolet
0.05 part of absorbent, 17 parts of phenolic resin, 1.3 parts of calcium carbonate；The preparation method of the modified Nano ceramic powders is by nanometer
Ceramic powders are immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, add sepiolite powder and barium carbonate powder after draining,
Frit reaction is carried out after mixing, and is mixed with amylopectin after the reaction, obtain final product.
A kind of preparation method of ceramic base 3D printing material, concretely comprises the following steps：
First, by modified Nano ceramic powders, organic silicone oil, polyacrylamide, shitosan, Graphene, nano aluminium oxide,
Salicylate ultraviolet absorbent, phenolic resin, calcium carbonate are mixed, and in placing response kettle, are heat-treated followed by using ultrasound
Oscillation treatment, the power of sonic oscillation process is 730W, and the time is 30 minutes, and at a temperature of being placed in 4 DEG C, low temperature drying granulation, obtains
Ceramic base 3D printing material.
Embodiment 5
A kind of ceramic base 3D printing material, according to the primary raw material of weight portion be：11 parts of modified Nano ceramic powders, organic
6 parts of silicone oil, 15 parts of polyacrylamide, 4 parts of shitosan, 12 parts of Graphene, 1.2 parts of nano aluminium oxide, salicylate ultraviolet
0.05 part of absorbent, 18 parts of phenolic resin, 2.0 parts of calcium carbonate；The preparation method of the modified Nano ceramic powders is by nanometer
Ceramic powders are immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, add sepiolite powder and barium carbonate powder after draining,
Frit reaction is carried out after mixing, and is mixed with amylopectin after the reaction, obtain final product.
A kind of preparation method of ceramic base 3D printing material, concretely comprises the following steps：
First, by modified Nano ceramic powders, organic silicone oil, polyacrylamide, shitosan, Graphene, nano aluminium oxide,
Salicylate ultraviolet absorbent, phenolic resin, calcium carbonate are mixed, and in placing response kettle, are heat-treated followed by using ultrasound
Oscillation treatment, the power of sonic oscillation process is 730W, and the time is 30 minutes, and at a temperature of being placed in 4 DEG C, low temperature drying granulation, obtains
Ceramic base 3D printing material.
Empirical tests, (public with Chinese patent " a kind of nano ceramic material and its 3D printing forming method for 3D printing "
Open/notification number：CN 105130402A) specific embodiment 1-5 compares, and the 3D printing material prepared by embodiment of the present invention 1-5 is resistance to
Wear resistance improves more than 60%；Toughness improves 30-40%；Tensile strength improves 15% or so.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Contain an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical scheme in each embodiment can also form those skilled in the art through appropriately combined
Understandable other embodiment.
Claims (4)
1. a kind of ceramic base 3D printing material, it is characterised in that the primary raw material according to weight portion is：Modified Nano ceramic powders
5-11 parts, organic silicone oil 4-6 parts, polyacrylamide 9-15 parts, shitosan 2-4 parts, Graphene 5-12 parts, nano aluminium oxide 0.4-
1.2 parts, salicylate ultraviolet absorbent 0.02-0.05 parts, phenolic resin 11-18 parts, calcium carbonate 0.8-2.0 parts；Described
The preparation method of modified Nano ceramic powders is that nano ceramic powder is immersed in ethyl acetate, and soaking temperature is controlled 37
DEG C, sepiolite powder and barium carbonate powder is added after draining, carry out frit reaction, and enter with amylopectin after mixing after the reaction
Row is mixed, and is obtained final product.
2. ceramic base 3D printing material according to claim 1, it is characterised in that the ceramic base 3D printing material, presses
Primary raw material according to weight portion is：Modified Nano ceramic powders 6-10 parts, organic silicone oil 4-6 parts, polyacrylamide 10-14 parts,
Shitosan 2-4 parts, Graphene 7-11 parts, nano aluminium oxide 0.7-1.1 parts, salicylate ultraviolet absorbent 0.02-0.05
Part, phenolic resin 13-17 parts, calcium carbonate 0.9-1.3 parts；The preparation method of the modified Nano ceramic powders is by nano ceramics
Powder is immersed in ethyl acetate, and soaking temperature is controlled at 37 DEG C, adds sepiolite powder and barium carbonate powder after draining, and is mixed
After carry out frit reaction, and mixed with amylopectin after the reaction, obtained final product.
3. ceramic base 3D printing material according to claim 1 and 2, it is characterised in that the ceramic base 3D printing material,
Primary raw material according to weight portion is：8 parts of modified Nano ceramic powders, 5 parts of organic silicone oil, 12 parts of polyacrylamide, shitosan 3
Part, 10 parts of Graphene, 0.9 part of nano aluminium oxide, 0.04 part of salicylate ultraviolet absorbent, 15 parts of phenolic resin, carbonic acid
1.0 parts of calcium；The preparation method of the modified Nano ceramic powders is that nano ceramic powder is immersed in ethyl acetate, immersion temperature
Degree control adds sepiolite powder and barium carbonate powder at 37 DEG C after draining, and carries out frit reaction after mixing, and after the reaction with
Amylopectin is mixed, and is obtained final product.
4. a kind of preparation method of the ceramic base 3D printing material as described in claim 1-3 is arbitrary, it is characterised in that concrete walk
Suddenly it is：First, by modified Nano ceramic powders, organic silicone oil, polyacrylamide, shitosan, Graphene, nano aluminium oxide, water
Poplar esters of gallic acid ultra-violet absorber, phenolic resin, calcium carbonate are mixed, and in placing response kettle, heat treatment is followed by shaken using ultrasound
Process is swung, the power of sonic oscillation process is 730W, and the time is 30 minutes, and low temperature drying granulation, is made pottery at a temperature of being placed in 4 DEG C
Porcelain base 3D printing material.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106966736A (en) * | 2017-04-27 | 2017-07-21 | 合肥蔚然花绿化工程有限公司 | A kind of 3D printing material based on ceramics |
| CN113103576A (en) * | 2021-04-07 | 2021-07-13 | 吉林大学 | 3D printing system and method for ordered gradient porous material |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105130402A (en) * | 2015-06-30 | 2015-12-09 | 成都新柯力化工科技有限公司 | Nanometer ceramic material used for 3D printing and 3D printing molding method thereof |
| CN105566860A (en) * | 2015-12-11 | 2016-05-11 | 上海联泰科技股份有限公司 | Ceramic material for 3D (three-dimensional) light curing forming printing and preparation method thereof |
| CN105562677A (en) * | 2015-12-22 | 2016-05-11 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | High-strength ceramic material combination for printer and preparing method for high-strength ceramic |
| CN105583401A (en) * | 2015-12-25 | 2016-05-18 | 华中科技大学 | Method for preparing composite powder for 3D printing, product and application |
| CN105645840A (en) * | 2015-12-30 | 2016-06-08 | 成都新柯力化工科技有限公司 | Ceramic material for 3D printing and manufacturing method thereof |
| CN106007671A (en) * | 2016-05-19 | 2016-10-12 | 深圳长朗三维科技有限公司 | Ceramic composite for 3D printing and preparation method thereof |
| CN106045548A (en) * | 2016-06-02 | 2016-10-26 | 苏州福德龙水产养殖有限公司 | High-strength 3D nano ceramic printing material and preparation method thereof |
-
2016
- 2016-11-08 CN CN201610978038.5A patent/CN106495561A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105130402A (en) * | 2015-06-30 | 2015-12-09 | 成都新柯力化工科技有限公司 | Nanometer ceramic material used for 3D printing and 3D printing molding method thereof |
| CN105566860A (en) * | 2015-12-11 | 2016-05-11 | 上海联泰科技股份有限公司 | Ceramic material for 3D (three-dimensional) light curing forming printing and preparation method thereof |
| CN105562677A (en) * | 2015-12-22 | 2016-05-11 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | High-strength ceramic material combination for printer and preparing method for high-strength ceramic |
| CN105583401A (en) * | 2015-12-25 | 2016-05-18 | 华中科技大学 | Method for preparing composite powder for 3D printing, product and application |
| CN105645840A (en) * | 2015-12-30 | 2016-06-08 | 成都新柯力化工科技有限公司 | Ceramic material for 3D printing and manufacturing method thereof |
| CN106007671A (en) * | 2016-05-19 | 2016-10-12 | 深圳长朗三维科技有限公司 | Ceramic composite for 3D printing and preparation method thereof |
| CN106045548A (en) * | 2016-06-02 | 2016-10-26 | 苏州福德龙水产养殖有限公司 | High-strength 3D nano ceramic printing material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 汪多仁: "《绿色纳米化学品》", 31 July 2007, 科学技术文献出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106966736A (en) * | 2017-04-27 | 2017-07-21 | 合肥蔚然花绿化工程有限公司 | A kind of 3D printing material based on ceramics |
| CN113103576A (en) * | 2021-04-07 | 2021-07-13 | 吉林大学 | 3D printing system and method for ordered gradient porous material |
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Application publication date: 20170315 |