CN106475398A - A kind of industrial waste salt carbonization treatment method - Google Patents

A kind of industrial waste salt carbonization treatment method Download PDF

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Publication number
CN106475398A
CN106475398A CN201610891340.7A CN201610891340A CN106475398A CN 106475398 A CN106475398 A CN 106475398A CN 201610891340 A CN201610891340 A CN 201610891340A CN 106475398 A CN106475398 A CN 106475398A
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Prior art keywords
salt
carbonization
predecomposition
pneumatic tube
carbonization treatment
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CN201610891340.7A
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CN106475398B (en
Inventor
王鸣彦
邓庆跃
陶万生
李书江
张继宇
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LIAONING DONGDA POWDER ENGINEERING TECHNOLOGY Co Ltd
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LIAONING DONGDA POWDER ENGINEERING TECHNOLOGY Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00Halides of sodium, potassium or alkali metals in general
    • C01D3/14Purification
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B2101/00Type of solid waste
    • B09B2101/02Gases or liquids enclosed in discarded articles, e.g. aerosol cans or cooling systems of refrigerators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/0075Disposal of medical waste
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A kind of industrial waste salt carbonization treatment method, abraum salt moisture is removed by flash dryer, pneumatic tube preheater and spouted bed carbide furnace are thermally decomposed and carbonization treatment to dried abraum salt, in abraum salt Organic substance by being dried, decomposing, after carbonization treatment as carbonization salt output.High temperature incineration carried out to the tail gas producing in technical process, burning the hot-air producing provides heat mostly as system heat sources, remaining hot gas through residual heat boiler for exchanging heat and through eluting column chilling but after harmless discharge.The method material carries out heat exchange with hot-air directly contact and in spouted fluidised form in spouted bed carbide furnace, makes material depth carbonization, and carbonization purity salt improves;The surface softening of carburizing temperature and salt is easy to control, can avoid materials from bonding and stammerer phenomenon, be conducive to continuous prodution;There is provided thermal source, energy saving using the high-temperature gas that the tail gas during burning process produces for system.

Description

A kind of industrial waste salt carbonization treatment method
Technical field
The present invention relates to industrial waste recycling, particularly a kind of industrial waste salt carbonization treatment method.
Background technology
In the production process of organic or inorganic chemical products, all there is abraum salt to produce, especially in pesticide, medicine, become more meticulous Work field abraum salt yield is huge.During pesticide producing, the annual by-product abraum salt in the whole nation just reaches more than 5,000,000 tons.Many enterprises Industry adopts stock to stack abraum salt at present, because taking a large amount of places so as to become the key factor of restriction enterprise development.Most of The main component of industrial waste salt is sodium chloride, carries a large amount of organic or inorganic impurity secretly because of it and can not continue to make as raw material of industry salt With.Because abraum salt belongs to poisonous and harmful substance, long-term stacking, not only waste land resource, and to environment structure grave danger. Therefore, using suitable technique and equipment, abraum salt is carried out harmless treatment, inorganic salt resource therein is recycled, Manufacturing enterprise and society are significant.
At present, domestic industry abraum salt is processed mainly following four method:
1st, desalinization of soil by flooding or leaching method
Industrial waste salt is washed off harmful soluble substance in abraum salt by washing or with detergent, this method is applied to process impurity The few abraum salt of single and impurity content.
2nd, high temperature melting facture
Organic impuritiess in abraum salt salt slag are made to resolve into gas at high temperature, thus reaching the purpose removing organic impuritiess.? In pyrolytic, directly brine waste can be thermally decomposed and be decomposed it is also possible to make solid crystal abraum salt form fused salt.? Exist in decomposition nozzle easily block, wear and tear, the technical problem such as high temperature bond, stammerer, equipment corrosion.
3rd, high temperature cabonization oxidizing process
Its principle is Organic substance in abraum salt to be carried out decomposing carbonization and oxidation at high operating temperatures, makes Organic substance one in abraum salt Partial thermal decomposition is escaping gas, and another part is changed into Solid organic carbon and aoxidizes formation ash.Technique used by the method at present Using rake multilamellar carbonization furnace apparatus.The method is there is problems that the surface softening of carburizing temperature and salt is wayward, easily Cause the bonding to carbonizing apparatus, affect continuous prodution.
4th, Method of Soda processed
Abraum salt salt slag is made saturated brine solution, is passed through ammonia and carbon dioxide under certain condition, form carbon Sour hydrogen sodium, makes soda (sodium carbonate) through pyrolytic.The method can only produce soda.
Content of the invention
The problem existing for prior art, it is an object of the invention to provide a kind of industrial waste salt carbonization treatment method.
The process equipment implementing the method is by feeder, flash dryer, pneumatic tube predecomposition device, spouted bed carbide furnace (in stove no gas distribution orifice), air heating incinerator, one-level catcher, two grades of catchers, circulating fan, aerator, remaining Heat boiler, eluting column, pipe-line system and control system composition;
Abraum salt is sent into flash dryer by feeder and is dried, and removes the moisture in abraum salt;Dried abraum salt is through one Level catcher trapping, and send into pneumatic tube predecomposition device and carry out heat resolve;Abraum salt after predecomposition is caught through two grades of catchers Collection, send into spouted bed carbide furnace carry out carbonization treatment, the carbonization salt after carbonization as product overflow discharge out of the furnace (through cooling laggard Enter postorder refining system to be refined);
Meanwhile, the tail gas after flash dryer dry materials is through one-level catcher, and sends into air by circulating fan Heating incinerator carries out high temperature incineration;Air heats the hot-air that incinerator produces, and its major part sends into spouted bed through aerator In carbide furnace, provide institute calorific requirement for material carbonization treatment, remainder through residual heat boiler for exchanging heat, then through eluting column drip washing heel row Empty;Tail gas after spouted bed carbide furnace material carbonization enters pneumatic tube preheater, is that pneumatic tube predecomposition device is pre- to material Resolution process provides institute's calorific requirement;Tail gas after pneumatic tube predecomposition implements material predecomposition, through two grades of catchers, enters flash distillation Drying machine, provides heat for abraum salt dried.
In said method, described flash dryer is dried at a temperature of 250~350 DEG C;Described pneumatic tube divides in advance Solution device predecomposition abraum salt is carried out at a temperature of 400~500 DEG C;In described spouted bed carbide furnace, material carbonization is in 500~750 DEG C of temperature Carry out under degree, material carbonization time and carbonation rate are adjusted according to industrial waste salt constituent;Described air heating is burned Stove carries out gas burning at 1000~1100 DEG C;After the described dedusting through eluting column, the exhaust temperature of emptying is below 150 DEG C.
Described pneumatic tube predecomposition device and spray-moving type carbide furnace can not limit according to impurity content combination in any in abraum salt Compound mode, is beneficial to adjustment and decomposes and carbonization time and carburizing temperature.
Industrial waste salt carbonization treatment method of the present invention, removes abraum salt free moisture, in pneumatic tube in flash dryer In preheater and spouted bed carbide furnace, abraum salt after drying is thermally decomposed and carbonization treatment.Organic substance in abraum salt passes through dry Dry, decompose, after carbonization as carbonization salt output.High temperature incineration is carried out to the tail gas producing in technical process, burns the heat producing Air provides heat mostly as system heat sources, and remainder changes its heat through waste heat boiler, more but arranges through eluting column chilling Put, in case harmful gass produce, realize harmless discharge.
The invention has the beneficial effects as follows:
1st, the inorganic salt in industrial waste salt can be reclaimed by the present invention well, and the product after gained carbonization can be processed Essence
Make the industrial salt (can be used as the raw material of industry needed for chlorine industry) that purity meets National Industrial salt standard, realize Recycling, and reach national requirements for environmental protection.
2nd, the present invention adopts spouted bed carbide furnace, no gas distribution orifice in stove, material and hot-air can directly contact simultaneously In spouted fluidised form, to realize the heat exchange of material and hot gas, material can be made to obtain depth carbonization, be conducive to improving gained carbonization The purity of salt;Materials from bonding and the stammerer phenomenon producing because being distributed plate can be avoided, the surface of carburizing temperature and salt is soft simultaneously Change easy to control, be conducive to continuous prodution.
3rd, the high-temperature gas that the tail gas during utilizing air to heat incinerator burning process produces provides thermal source for system, Can energy saving.
4th, the high-temperature tail gas that air heating incinerator produces empty after residual heat boiler for exchanging heat and eluting column dedusting, can achieve The echelon of heat energy utilizes and tail gas hazard-free discharge.
5th, present invention process is ripe, and its device adopts existing modular system, simple system, and suitable industrialization continuously produces, Have
Good economic and social benefit.
Brief description
Fig. 1 is the process flow diagram of industrial waste salt carbonization treatment method of the present invention.
Specific embodiment
By the following examples the technique effect of the present invention is verified.
The present embodiment industrial waste salt derives from the waste salt dregs that pharmaceutical and chemical enterprises Wastewater Pretreatment produces, and its main component is Sodium chloride and height boiling Organic substance (containing C, H, O and S, N etc.), aqueous 8%.Carbon is carried out to it using the inventive method as shown in Figure 1 Change is processed.
Device therefor is the pilot-plant of 2 tons of (100kg/h) carbonization salt of daily output, works continuously, and baking temperature is 320 DEG C, Predecomposition temperature is 480 DEG C, and carburizing temperature is 700 DEG C, and incinerator incineration temperature is 1050 DEG C, and exhaust emissions temperature is 180 DEG C.
Carbonization salt after gained carbonization treatment, the purified salt being refining to obtain through refining system, sodium chloride content > 97g/ 100g, water-insoluble≤0.1g/100g, remaining index all meets Nacl standard;Exhaust emissions meet the requirement of environmental protection.

Claims (3)

1. a kind of industrial waste salt carbonization treatment method it is characterised in that:
The process equipment implementing the method is by feeder, flash dryer, pneumatic tube predecomposition device, spouted bed carbide furnace, sky Gas heating incinerator, one-level catcher, two grades of catchers, circulating fan, aerator, waste heat boiler, eluting column, pipe-line system and Control system forms;
Abraum salt is sent into flash dryer by feeder and is dried, and removes the moisture in abraum salt;Dried abraum salt is caught through one-level Storage traps, and sends into pneumatic tube predecomposition device and carry out heat resolve;Abraum salt after predecomposition traps through two grades of catchers, send Enter spouted bed carbide furnace and carry out carbonization treatment, the carbonization salt after carbonization overflows as product and discharges out of the furnace;
Meanwhile, the tail gas after flash dryer dry materials is through one-level catcher, and sends into air heating by circulating fan Incinerator carries out high temperature incineration;Air heats the hot-air that incinerator produces, and its major part sends into spouted bed carbonization through aerator In stove, provide institute's calorific requirement for material carbonization treatment, remainder empties through residual heat boiler for exchanging heat, then after eluting column drip washing; Tail gas after spouted bed carbide furnace material carbonization enters pneumatic tube preheater, is pneumatic tube predecomposition device to material predecomposition Process and institute's calorific requirement is provided;Tail gas after pneumatic tube predecomposition implements material predecomposition, through two grades of catchers, enters expansion drying Machine, provides heat for abraum salt dried.
2. according to claim 1 industrial waste salt carbonization treatment method it is characterised in that:Described flash dryer 250~ It is dried at a temperature of 350 DEG C;Described pneumatic tube predecomposition device predecomposition abraum salt is carried out at a temperature of 400~500 DEG C;Described In spouted bed carbide furnace, material carbonization is carried out at a temperature of 500~750 DEG C, and material carbonization time and carbonation rate are according to Industry Waste Salt constituent is adjusted;Described air heating incinerator carries out gas burning at 1000~1100 DEG C;Described through drip washing After tower dedusting, the exhaust temperature of emptying is below 150 DEG C.
3. according to claim 1 industrial waste salt carbonization treatment method it is characterised in that:Described pneumatic tube predecomposition device and Spray-moving type carbide furnace can not limit compound mode according to impurity content combination in any in abraum salt.
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106914474A (en) * 2017-04-17 2017-07-04 辽宁东大粉体工程技术有限公司 A kind of Processes and apparatus of industrial waste salt decomposition carbonization harmless treatment
CN107185948A (en) * 2017-06-13 2017-09-22 北京纬纶华业环保科技股份有限公司 A kind of industrial waste salt system and method
CN107803395A (en) * 2017-12-11 2018-03-16 广州叶林环保科技有限公司 A kind of organic abraum salt low-temperature carbonization handling process
CN108278613A (en) * 2018-04-04 2018-07-13 江苏科行环保股份有限公司 The apparatus and method that industrial dangerous waste salt disposition and resource utilization utilize
CN108408744A (en) * 2018-02-08 2018-08-17 聊城鲁西聚碳酸酯有限公司 A kind of system and method that hot fluid is classified organic matter in stripping process industrial waste salt
CN108479088A (en) * 2018-03-02 2018-09-04 东南大学 Salty organic waste liquid desalination pyrolysis treating method and system
CN109579025A (en) * 2018-11-27 2019-04-05 东北大学 A kind of industrial waste salt efficient fusion incinerator
CN109681885A (en) * 2019-01-30 2019-04-26 重庆世银科技有限公司 A kind of self- propagating pyrolysis system applied to fixed-end forces
CN109865734A (en) * 2019-03-13 2019-06-11 兰州有色冶金设计研究院有限公司 A method of vitreum is produced using chemical industry abraum salt
CN109970078A (en) * 2019-04-02 2019-07-05 江苏杰林环保科技有限公司 A method of decomposing organic matter in chemical industry abraum salt
CN109970079A (en) * 2019-04-02 2019-07-05 江苏杰林环保科技有限公司 A kind of chemical industry abraum salt refining methd
CN110372013A (en) * 2019-07-30 2019-10-25 天津理工大学 A method of refining industrial salt is prepared using industrial waste salt
CN113385517A (en) * 2021-05-08 2021-09-14 江苏杰林环保科技有限公司 Harmless treatment method for chemical waste salt
CN115846356A (en) * 2022-11-21 2023-03-28 江南大学 Method for removing organic pollutants in industrial waste salt

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CN102997247A (en) * 2012-12-25 2013-03-27 季栋梁 System and method for incineration treatment of saliferous waste residue, saliferous waste water and stink waste gas
CN103900089A (en) * 2012-12-29 2014-07-02 中国中化股份有限公司 Organic-pollutant-contained industrial waste salt processing method
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106914474A (en) * 2017-04-17 2017-07-04 辽宁东大粉体工程技术有限公司 A kind of Processes and apparatus of industrial waste salt decomposition carbonization harmless treatment
CN106914474B (en) * 2017-04-17 2019-06-21 辽宁东大粉体工程技术有限公司 A kind of Processes and apparatus of industrial waste salt decomposition carbonization harmless treatment
CN107185948A (en) * 2017-06-13 2017-09-22 北京纬纶华业环保科技股份有限公司 A kind of industrial waste salt system and method
CN107803395A (en) * 2017-12-11 2018-03-16 广州叶林环保科技有限公司 A kind of organic abraum salt low-temperature carbonization handling process
CN108408744B (en) * 2018-02-08 2020-11-03 聊城鲁西聚碳酸酯有限公司 System and method for treating organic matters in industrial waste salt through hot fluid fractionation and gas stripping
CN108408744A (en) * 2018-02-08 2018-08-17 聊城鲁西聚碳酸酯有限公司 A kind of system and method that hot fluid is classified organic matter in stripping process industrial waste salt
CN108479088A (en) * 2018-03-02 2018-09-04 东南大学 Salty organic waste liquid desalination pyrolysis treating method and system
CN108479088B (en) * 2018-03-02 2020-12-11 东南大学 Desalting and pyrolysis treatment method and system for salt-containing organic waste liquid
CN108278613A (en) * 2018-04-04 2018-07-13 江苏科行环保股份有限公司 The apparatus and method that industrial dangerous waste salt disposition and resource utilization utilize
CN109579025A (en) * 2018-11-27 2019-04-05 东北大学 A kind of industrial waste salt efficient fusion incinerator
CN109681885A (en) * 2019-01-30 2019-04-26 重庆世银科技有限公司 A kind of self- propagating pyrolysis system applied to fixed-end forces
CN109681885B (en) * 2019-01-30 2024-02-27 重庆世银科技有限公司 Self-propagating pyrolysis system applied to solid waste treatment
CN109865734A (en) * 2019-03-13 2019-06-11 兰州有色冶金设计研究院有限公司 A method of vitreum is produced using chemical industry abraum salt
CN109970079A (en) * 2019-04-02 2019-07-05 江苏杰林环保科技有限公司 A kind of chemical industry abraum salt refining methd
CN109970078A (en) * 2019-04-02 2019-07-05 江苏杰林环保科技有限公司 A method of decomposing organic matter in chemical industry abraum salt
CN110372013A (en) * 2019-07-30 2019-10-25 天津理工大学 A method of refining industrial salt is prepared using industrial waste salt
CN113385517A (en) * 2021-05-08 2021-09-14 江苏杰林环保科技有限公司 Harmless treatment method for chemical waste salt
CN115846356A (en) * 2022-11-21 2023-03-28 江南大学 Method for removing organic pollutants in industrial waste salt

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