CN106444680B - A kind of building electricity-saving control system and its working method based on ZigBee communication technology - Google Patents
A kind of building electricity-saving control system and its working method based on ZigBee communication technology Download PDFInfo
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Abstract
The invention discloses a kind of building electricity-saving control systems and its working method based on ZigBee communication technology, are made of central processing unit, temperature sense module, luminosity induction unit, electromagnetic induction chip, ZigBee communication module, remote monitoring module；The temperature sense module is set on indoor wall；The luminosity induction unit is fixedly mounted in indoor ceiling；The electromagnetic induction chip is fixedly mounted on each desk upper right comer region；The ZigBee communication module is interconnected with central processing unit；The remote monitoring module is connect with ZigBee communication module remote control.A kind of building electricity-saving control system based on ZigBee communication technology of the present invention, the system automation degree is high, indoor temperature, illumination brightness can be automatically adjusted, intelligent management electric light opens quantity, and remote monitoring and administration is realized using ZigBee communication technology.
Description
Technical field
The invention belongs to build energy-saving application field, and in particular to a kind of building economize on electricity control based on ZigBee communication technology
System and its working method processed.
Background technology
" energy saving, intelligence science and technology and aesthetics, the theme of 21 century construction industry." in recent years, it is sent out with the high speed of domestic city
It opens up, continuous improvement of the economic quick flourishing and people to living standard and environmental quality requirement, office building, religion in city
Room, factory lamp place electricity consumption are increasing, and power saving is urgently to be resolved hurrily.According to statistics, China year electric consumption on lighting amount accounts for total power generation
10% or so of amount, and based on inefficient illumination, energy-saving potential is very big.In specific works, electric energy saving design can neither
To sacrifice building function, damage use demand as cost, it can not blindly increase investment, be energy saving and energy saving.Therefore, it is solution
The big problem of traditional energy-saving technique energy waste, New Generation of Building Electric technology are attempt to use various advanced control modes
Traditional architecture lighting apparatus is effectively controlled.
In daily life, people mostly use manual mode to close the electric appliances such as electric light, air-conditioning, thus exist and forget to close
The case where closing causes the waste of electric power, therefore, real in order to improve the utilization ratio of electric energy, sophistication and technological means
Intelligent control now is carried out to each lamp (single lamp) or each group of lamp (grouping), including according to staff's presence or absence, is realized
The automatic switch of lighting apparatus opens and closes, and adjustment, control by time segment to voltage, to the working condition of each lamp
It realizes automatic monitoring etc., achievees the purpose that the comprehensive cost that saves lighting with intelligentized control mode.
Invention content
In order to solve the above technical problem, the present invention provides a kind of, and the building economize on electricity control based on ZigBee communication technology is
System, including：Central processing unit 100, temperature sense module 101, luminosity induction unit 102, electromagnetic induction chip 103,
ZigBee communication module 104, remote monitoring module 105；The temperature sense module 101 is set on indoor wall, interior every 4
There are one temperature sense modules 101, temperature sense module 101 to be led with central processing unit 100 for setting in~6 square metres of region
Line traffic control connects；The luminosity induction unit 102 is fixedly mounted in indoor ceiling, between two luminosity induction units 102
Between 4m~5m, luminosity induction unit 102 is connected distance by conducting wire and the control of central processing unit 100；The electromagnetism sense
It is rectangular configuration to answer chip 103, and for thickness between 2mm~5mm, electromagnetic induction chip 103 is fixedly mounted on each desk
Upper right comer region, electromagnetic induction chip 103 are connect with 100 polygon control survey of central processing unit；The ZigBee communication module 104
It is interconnected with central processing unit 100；The remote monitoring module 105 is connect with 104 remote control of ZigBee communication module.
Further, the central processing unit 100 uses CC2530 chip processors.
Further, the temperature sense module 101 includes：Infrared temperature probe 101-1, amplifying circuit 101-2, A/
D conversion module 101-3, address latch module 101-4, key control module 101-5, LED display module 101-6, warning device
101-7；The temperature information that the wherein described amplifying circuit 101-2 acquires infrared temperature probe 101-1 after enhanced processing,
A/D conversion module 101-3 are sent to, final transformed data are stored in address latch module 101-4；The A/D conversions
Module 101-3 is connected with the control of central processing unit 100；The key control module 101-5 is fixedly mounted on wall, high
Degree is apart from ground between 1.2m~1.5m；The LED display module 101-6, warning device 101-7 pass through conducting wire and center
The control connection of processing unit 100.
Further, the luminosity induction unit 102 is provided with S curve intensity control circuit, in luminosity induction unit 102
Luminous intensity measurement element use photosensitive sensor, the S curve intensity control circuit, photosensitive sensor pass through conducting wire with center
The control connection of processing unit 100.
Further, the electromagnetic induction chip 103 is molded by high molecular material pressing mold, the group of electromagnetic induction chip 103
It is as follows at ingredient and manufacturing process：
One, 103 constituent of electromagnetic induction chip：
It counts in parts by weight, 40~95 parts of phenylacetic acid -2- methoxies -4- (2- acrylic) benzene (phenol) ester, (1R, S) is suitable, instead
72~157 parts of the m- phenoxy group ester of formula -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropane-carboxylic acids -, 4- [3- (3,4- bis-
Methoxyphenyl) -3- (4- fluorophenyls) acryloyl] 43~102 parts of morpholine, (S) alpha-cyano-phenoxy benzyl (1R, 3R) -3-
130~194 parts of (2,2- dibromo vinyl) -2,2- dimethyl cyclopropane carboxylic acids ester, (S)-alpha- cyano -3- phenoxy group benzyls
Base-(S) -2- (4- chlorphenyls) -112~205 parts of 3 Methylbutanoic acid ester, (1R)-trans- -2,2- dimethyl -3- (2- methyl-1s -
Acrylic) -50~121 parts of cyclopropane-carboxylic acid -3- phenoxy benzyls ester, cyano-(the 3- phenoxy groups of a concentration of 32ppm~68ppm
Phenyl) methyl -3- (2,2- dichloroethylene) -78~139 parts of 2,2- dimethyl cyclopropane carboxylic acids ester, (S) -3- allyls -2-
Methyl -4- oxos-ring amyl- 2- alkenyls (1R, 3R) -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropanecarboxylcompound 86~
165 parts, the trans- -3- of 1R- (2,2- dichloroethylene) -2,2- dimethyl cyclopropane carboxylic acids-(2,3,5,6,-tetrafluoro phenyl) methyl
92~176 parts of ester, 33~80 parts of crosslinking agent, 5- (2- cyano -4- nitrophenylazos) -6- (2- hydroxyethylaminos) -4- methyl -
2- [[3- (2- phenoxy groups) propyl] amino] 86~121 parts of -3- pyridine carbonitriles, N- [5- [bis- (2- methoxy ethyls) ammonia
Base] -2- [(2- cyano -4,6- dinitrophenyl) azo] phenyl] 52~143 parts of-acetamide, N- [5- [two [2- (acetyl oxygen
Base) ethyl] amino] -2- [(4- nitrobenzophenones) azo] phenyl] 119~214 parts of benzamide, 2- [[4- [[2- (acetyl oxygen
Base) ethyl] butylamino] -2- aminomethyl phenyls] azo] 105~188 parts of -5- nitro -1,3- benzene dicarbonitriles；
The crosslinking agent is N, bis- (2- ethoxys) methylamines of N-, N- (aoxidize diethylidene) -2-[4-morpholinodithio sulfenamide,
Any one in the chloro- monoacetylanilines of 2-；
Two, the manufacturing process of electromagnetic induction chip 103, comprises the steps of：
1st step：3150~3680 parts of the ultra-pure water that conductivity is 4.22 μ of μ S/cm~7.28 S/cm is added in a kettle,
Start reaction kettle in blender, rotating speed be 58rpm~114rpm, start heat pump, make reactor temperature rise to 68 DEG C~
108℃；It is suitable to sequentially add phenylacetic acid -2- methoxies -4- (2- acrylic) benzene (phenol) ester, (1R, S), trans- -2,2- dimethyl -3-
The m- phenoxy group ester of (2- methyl-1-propylenes base) cyclopropane-carboxylic acid -, 4- [3- (3,4- Dimethoxyphenyls) -3- (4- fluorophenyls)
Acryloyl] morpholine, to being completely dissolved, it is 5.5~8.4 to adjust pH value, and agitator speed is adjusted to 118rpm~164rpm for stirring,
Temperature is 78 DEG C~155 DEG C, esterification 13~21 hours；
2nd step：Take (S) alpha-cyano-phenoxy benzyl (1R, 3R) -3- (2,2- dibromo vinyls) -2,2- diformazans basic ring third
Alkane carboxylate, (S)-alpha- cyano -3- phenoxy benzyls-(S) -2- (4- chlorphenyls) -3 Methylbutanoic acid ester crush, powder
Last grain size is 1300~1900 mesh；(1R)-trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid-is added
3- phenoxy benzyl esters be uniformly mixed, be laid in pallet, tiling thickness be 25mm~36mm, use dosage for 4.4kGy~
8.3kGy, the alpha ray that energy is 16MeV~23MeV irradiate 105~166 minutes and the same dose of β x ray irradiation xs 73~
146 minutes；
3rd step：The mixed-powder handled through the 2nd step is dissolved in cyano-(3- Phenoxyphenyls) methyl -3- (bis- chloroethenes of 2,2-
Alkenyl) in -2,2- dimethyl cyclopropane carboxylic acid's esters, reaction kettle is added, agitator speed is 82rpm~173rpm, temperature 101
DEG C~152 DEG C, starting vacuum pump makes the vacuum degree of reaction kettle reach -0.53MPa~1.49MPa, keeps this state response 7~17
Hour；Pressure release is simultaneously passed through radon gas, and it is 0.42MPa~1.77MPa to make reacting kettle inner pressure, and heat preservation stands 12~25 hours；Stirring
Device rotating speed is promoted to 162rpm~215rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add (S) -3- allyl -2- methyl -
4- oxos-ring amyl- 2- alkenyls (1R, 3R) -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropanecarboxylcompound, 1R- be trans- -
After 3- (2,2- dichloroethylene) -2,2- dimethyl cyclopropane carboxylic acids-(2,3,5,6,-tetrafluoro phenyl) methyl ester is completely dissolved,
Crosslinking agent is added to be stirred so that the hydrophilic lipophilic balance of reaction kettle solution is 4.5~7.6, and it is small that heat preservation stands 15~28
When；
4th step：When agitator speed is 218rpm~266rpm, 5- (2- cyano -4- nitrophenylazos are sequentially added
Base) -6- (2- hydroxyethylaminos) -4- methyl -2- [[3- (2- phenoxy groups) propyl] amino] -3- pyridine carbonitriles, N- [5-
[bis- (2- methoxy ethyls) amino] -2- [(2- cyano -4,6- dinitrophenyls) azo] phenyl]-acetamide, N- [5- [two
[2- (acetoxyl group) ethyl] amino] -2- [(4- nitrobenzophenones) azo] phenyl] benzamide and 2- [[4- [[2- (acetyl oxygen
Base) ethyl] butylamino] -2- aminomethyl phenyls] azo] -5- nitro -1,3- benzene dicarbonitriles, reactor pressure is promoted, it is made to reach
To 1.6MPa~3.2MPa, temperature is 133 DEG C~175 DEG C, polymerisation 9~18 hours；By reaction kettle internal pressure after the completion of reaction
Power is down to 0MPa, is cooled to 34 DEG C~43 DEG C, and discharging enters molding press and can be prepared by electromagnetic induction chip 103.
Further, the work for building electricity-saving control system based on ZigBee communication technology that the invention also discloses a kind of
Method, this method include following steps：
1st step：Staff presses total power switch, and indoor each electric appliance and electronic component are powered on；Wherein temperature sense
It answers the infrared temperature probe 101-1 in module 101 to monitor indoor temperature in real time, and the temperature signal detected is sent
Amplifying circuit 101-2 is given, the temperature signal after enhanced processing sends central processing to after the 101-3 effects of A/D conversion modules
Unit 100；In cooling mode, the temperature value received is compared by central processing unit 100 with default value A, when
When the temperature value received is less than A, central processing unit 100 controls room conditioning and reduces air quantity output, until temperature value reaches
Setting value A；When the temperature value received is higher than A, central processing unit 100 controls room conditioning enhancing air quantity output, until
Temperature value is reduced to setting value A；In a heating mode, central processing unit 100 is by the temperature value received and default value B
It is compared, when the temperature value received is less than B, central processing unit 100 controls room conditioning enhancing air quantity output, until
Temperature value reaches setting value B；When the temperature value received is higher than B, central processing unit 100 controls room conditioning and reduces air quantity
Output, until temperature value is reduced to setting value B；The temperature value real-time display that central processing unit 100 receives shows mould in LED
On block 101-6；
2nd step：Photosensitive sensor in luminosity induction unit 102 monitors indoor illumination intensity in real time；Work as light sensor
Device detects that indoor illumination intensity is more than 106cd/m2When, central processing unit 100, which controls S curve intensity control circuit, reduces room
Interior intensity of illumination is to 88cd/m2~98cd/m2；When photosensitive sensor detects that indoor illumination intensity is less than 66cd/m2When, center
Processing unit 100, which controls S curve intensity control circuit, enhances indoor illumination intensity to 88cd/m2~98cd/m2；
3rd step：When staff is in place at a desk, the electromagnetic induction chip in the lower desk upper right corner is touched with finger
103, inductive signal is sent to central processing unit 100 by electromagnetic induction chip 103, data processing in central processing unit 100
Module arranges to inductive signal according to the distribution of 103 regional location of electromagnetic induction chip, the calculating in central processing unit 100
Unit calculates the quantity of inductive signal in the regions every 2 ㎡, is controlled in 2 ㎡ according to inductive signal quantity central processing unit 100
The unlatching number of lamp；
4th step：Remote monitoring module 105 is by ZigBee communication module 104 to indoor electric appliance remote monitoring and operation；When
When indoor nobody and electric appliance are not turned off, administrative staff can be turned off by the remote monitoring module 105 of electronic device terminal.
A kind of building electricity-saving control system based on ZigBee communication technology disclosed by the invention, the advantage is that：
(1) system can automatically adjust indoor temperature, intensity of illumination, high degree of automation, energy conservation and environmental protection；
(2) system can utilize ZigBee communication technology, can remote monitoring and operation indoor electric appliance use, artificial
When forgetting to close indoor electric appliance, it can close in time, avoid the unnecessary waste of electric power；
(3) system can realize the optimal of electric energy according to the densely distributed degree of personnel, the intelligentized number for opening lamp
Change application.
A kind of building electricity-saving control system based on ZigBee communication technology of the present invention, the system automation degree
Height can automatically adjust indoor temperature, illumination brightness, and intelligent management electric light opens quantity, real using ZigBee communication technology
Existing remote monitoring and administration.
Description of the drawings
Fig. 1 is a kind of heretofore described building electricity-saving control system schematic diagram based on ZigBee communication technology.
Fig. 2 is heretofore described temperature sense modular system block diagram.
Fig. 3 is heretofore described temperature sense module work flow diagram.
Fig. 4 is heretofore described electromagnetic induction wafer material corrosion resistant erosion degree with usage time variation diagram.
In figure 1 above~Fig. 2, central processing unit 100, temperature sense module 101, infrared temperature probe 101-1 puts
Big circuit 101-2, A/D conversion module 101-3, address latch module 101-4, key control module 101-5, LED display module
101-6, warning device 101-7, luminosity induction unit 102, electromagnetic induction chip 103, ZigBee communication module 104 are long-range to supervise
Control module 105.
Specific implementation mode
With reference to the accompanying drawings and examples to a kind of building economize on electricity control based on ZigBee communication technology provided by the invention
System processed is further described.
As shown in Figure 1, Fig. 1 is a kind of heretofore described building electricity-saving control system based on ZigBee communication technology
Schematic diagram.It is seen in fig. 1, that including：Central processing unit 100, temperature sense module 101, luminosity induction unit 102, electromagnetism
Incude chip 103, ZigBee communication module 104, remote monitoring module 105；The temperature sense module 101 is set to indoor wall
On wall, there are one temperature sense module 101, temperature sense module 101 and centers for setting in indoor every 4~6 square metres of region
100 polygon control survey of processing unit connects；The luminosity induction unit 102 is fixedly mounted in indoor ceiling, two luminosity inductions
Between 4m~5m, luminosity induction unit 102 is connected the distance between unit 102 by conducting wire and the control of central processing unit 100
It connects；The electromagnetic induction chip 103 is rectangular configuration, and between 2mm~5mm, electromagnetic induction chip 103 is fixedly mounted thickness
In each desk upper right comer region, electromagnetic induction chip 103 is connect with 100 polygon control survey of central processing unit；It is described
ZigBee communication module 104 is interconnected with central processing unit 100；The remote monitoring module 105 and ZigBee communication mould
104 remote control of block connects.
Central processing unit 100 uses CC2530 chip processors.
Luminosity induction unit 102 is provided with S curve intensity control circuit, the luminous intensity measurement member in luminosity induction unit 102
Part uses photosensitive sensor, and the S curve intensity control circuit, photosensitive sensor pass through conducting wire and central processing unit 100
Control connection.
As shown in Fig. 2, Fig. 2 is heretofore described temperature sense modular system block diagram.Find out from Fig. 2 or Fig. 1, temperature
Spending induction module 101 includes：Infrared temperature probe 101-1, amplifying circuit 101-2, A/D conversion module 101-3, address latch
Module 101-4, key control module 101-5, LED display module 101-6, warning device 101-7；The wherein described amplifying circuit
The temperature information that 101-2 acquires infrared temperature probe 101-1 is sent to A/D conversion modules 101- after enhanced processing
3, final transformed data are stored in address latch module 101-4；The A/D conversion modules 101-3 and central processing list
100 control connection of member；The key control module 101-5 is fixedly mounted on wall, height distance ground 1.2m~
Between 1.5m；The LED display module 101-6, warning device 101-7 are connected by conducting wire and the control of central processing unit 100
It connects.
A kind of course of work of building electricity-saving control system based on ZigBee communication technology of the present invention is：
1st step：Staff presses total power switch, and indoor each electric appliance and electronic component are powered on；Wherein temperature sense
It answers the infrared temperature probe 101-1 in module 101 to monitor indoor temperature in real time, and the temperature signal detected is sent
Amplifying circuit 101-2 is given, the temperature signal after enhanced processing sends central processing to after the 101-3 effects of A/D conversion modules
Unit 100；In cooling mode, the temperature value received is compared by central processing unit 100 with default value A, when
When the temperature value received is less than A, central processing unit 100 controls room conditioning and reduces air quantity output, until temperature value reaches
Setting value A；When the temperature value received is higher than A, central processing unit 100 controls room conditioning enhancing air quantity output, until
Temperature value is reduced to setting value A；In a heating mode, central processing unit 100 is by the temperature value received and default value B
It is compared, when the temperature value received is less than B, central processing unit 100 controls room conditioning enhancing air quantity output, until
Temperature value reaches setting value B；When the temperature value received is higher than B, central processing unit 100 controls room conditioning and reduces air quantity
Output, until temperature value is reduced to setting value B；The temperature value real-time display that central processing unit 100 receives shows mould in LED
On block 101-6；
2nd step：Photosensitive sensor in luminosity induction unit 102 monitors indoor illumination intensity in real time；Work as light sensor
Device detects that indoor illumination intensity is more than 106cd/m2When, central processing unit 100, which controls S curve intensity control circuit, reduces room
Interior intensity of illumination is to 88cd/m2~98cd/m2；When photosensitive sensor detects that indoor illumination intensity is less than 66cd/m2When, center
Processing unit 100, which controls S curve intensity control circuit, enhances indoor illumination intensity to 88cd/m2~98cd/m2；
3rd step：When staff is in place at a desk, the electromagnetic induction chip in the lower desk upper right corner is touched with finger
103, inductive signal is sent to central processing unit 100 by electromagnetic induction chip 103, data processing in central processing unit 100
Module arranges to inductive signal according to the distribution of 103 regional location of electromagnetic induction chip, the calculating in central processing unit 100
Unit calculates the quantity of inductive signal in the regions every 2 ㎡, is controlled in 2 ㎡ according to inductive signal quantity central processing unit 100
The unlatching number of lamp；
4th step：Remote monitoring module 105 is by ZigBee communication module 104 to indoor electric appliance remote monitoring and operation；When
When indoor nobody and electric appliance are not turned off, administrative staff can be turned off by the remote monitoring module 105 of electronic device terminal.
A kind of building electricity-saving control system based on ZigBee communication technology of the present invention, the system automation degree
Height can automatically adjust indoor temperature, illumination brightness, and intelligent management electric light opens quantity, real using ZigBee communication technology
Existing remote monitoring and administration.
It is the embodiment of the manufacturing process of electromagnetic induction chip 103 of the present invention below, embodiment is in order to further
Illustrate present disclosure, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention,
To changing and replacing made by the method for the present invention, step or condition, all belong to the scope of the present invention.
Unless otherwise specified, the conventional means that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
Electromagnetic induction chip 103 of the present invention is manufactured according to the following steps, and is counted in parts by weight：
1st step：3150 parts of the ultra-pure water that conductivity is 4.22 μ S/cm is added in a kettle, starts stirring in reaction kettle
Device, rotating speed 58rpm start heat pump, reactor temperature are made to rise to 68 DEG C；Sequentially add phenylacetic acid -2- methoxies -4-
40 parts of (2- acrylic) benzene (phenol) ester, (1R, S) is suitable, trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropane carboxylic acid
Acid-m- 72 parts of phenoxy group ester, 4- [3- (3,4- Dimethoxyphenyl) -3- (4- fluorophenyls) acryloyl] 43 parts of morpholine, stirring is extremely
It is completely dissolved, it is 5.5 to adjust pH value, agitator speed is adjusted to 118rpm, temperature is 78 DEG C, esterification 13 hours；
2nd step：Take (S) alpha-cyano-phenoxy benzyl (1R, 3R) -3- (2,2- dibromo vinyls) -2,2- diformazans basic ring third
130 parts of alkane carboxylate, (S)-alpha- cyano -3- phenoxy benzyls-(S) -2- (4- chlorphenyls) -112 parts of 3 Methylbutanoic acid ester
It crushes, powder diameter is 1300 mesh；(1R)-trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane is added
50 parts of carboxylic acid -3- phenoxy benzyls ester is uniformly mixed, and is laid in pallet, and tiling thickness is 25mm, use dosage for 4.4kGy,
The alpha ray that energy is 16MeV irradiates 105 minutes and the same dose of β x ray irradiation xs 73 minutes；
3rd step：The mixed-powder handled through the 2nd step is dissolved in cyano-(3- Phenoxyphenyls) methyl-of a concentration of 32ppm
In 3- (2,2- dichloroethylene) -78 parts of 2,2- dimethyl cyclopropane carboxylic acids ester, addition reaction kettle, agitator speed 82rpm,
Temperature is 101 DEG C, and starting vacuum pump makes the vacuum degree of reaction kettle reach -0.53MPa, keeps this state response 7 hours；Pressure release is simultaneously
It is passed through radon gas, it is 0.42MPa to make reacting kettle inner pressure, and heat preservation stands 12 hours；Agitator speed is promoted to 162rpm, while anti-
Answer kettle pressure release to 0MPa；Sequentially add (S) -3- allyl -2- methyl -4- oxos-amyl- 2- alkenyls (1R, 3R) -2,2- diformazans of ring
Base -3- (2- methyl-1-propylenes base) 86 parts of cyclopropanecarboxylcompound, the trans- -3- of 1R- (2,2- dichloroethylene) -2,2- dimethyl
After cyclopropane-carboxylic acid-(2,3,5,6 ,-tetrafluoro phenyl) 92 parts of methyl ester is completely dissolved, 33 parts of crosslinking agent is added and is stirred, makes
The hydrophilic lipophilic balance for obtaining reaction kettle solution is 4.5, and heat preservation stands 15 hours；
4th step：When agitator speed is 218rpm, 5- (2- cyano -4- nitrophenylazos) -6- (2- are sequentially added
Hydroxyethylamino) -4- methyl -2- [[3- (2- phenoxy groups) propyl] amino] 86 parts of -3- pyridine carbonitriles, [5- is [double by N-
(2- methoxy ethyls) amino] -2- [(2- cyano -4,6- dinitrophenyl) azo] phenyl] 52 parts of-acetamide, N- [5- [two
[2- (acetoxyl group) ethyl] amino] -2- [(4- nitrobenzophenones) azo] phenyl] 119 parts of benzamide, 2- [[4- [[2- (second
Acyloxy) ethyl] butylamino] -2- aminomethyl phenyls] azo] 105 parts of -5- nitros -1,3- benzene dicarbonitrile, promote reaction kettle pressure
Power reaches 1.6MPa, and temperature is 133 DEG C, polymerisation 9 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction,
34 DEG C are cooled to, discharging enters molding press and can be prepared by electromagnetic induction chip 103；
The crosslinking agent is N, bis- (2- ethoxys) methylamines of N-.
Embodiment 2
Electromagnetic induction chip 103 of the present invention is manufactured according to the following steps, and is counted in parts by weight：
1st step：3680 parts of the ultra-pure water that conductivity is 7.28 μ S/cm is added in a kettle, starts stirring in reaction kettle
Device, rotating speed 114rpm start heat pump, reactor temperature are made to rise to 108 DEG C；Sequentially add phenylacetic acid -2- methoxies -4-
95 parts of (2- acrylic) benzene (phenol) ester, (1R, S) is suitable, trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropane carboxylic acid
Acid-m- 157 parts of phenoxy group ester, 4- [3- (3,4- Dimethoxyphenyl) -3- (4- fluorophenyls) acryloyl] 102 parts of morpholine, stirring
To being completely dissolved, it is 8.4 to adjust pH value, agitator speed is adjusted to 164rpm, temperature is 155 DEG C, esterification 21 hours；
2nd step：Take (S) alpha-cyano-phenoxy benzyl (1R, 3R) -3- (2,2- dibromo vinyls) -2,2- diformazans basic ring third
194 parts of alkane carboxylate, (S)-alpha- cyano -3- phenoxy benzyls-(S) -2- (4- chlorphenyls) -205 parts of 3 Methylbutanoic acid ester
It crushes, powder diameter is 1900 mesh；(1R)-trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane is added
121 parts of carboxylic acid -3- phenoxy benzyls ester is uniformly mixed, and is laid in pallet, and tiling thickness is 36mm, use dosage for
8.3kGy, the alpha ray that energy is 23MeV irradiate 166 minutes and the same dose of β x ray irradiation xs 146 minutes；
3rd step：The mixed-powder handled through the 2nd step is dissolved in cyano-(3- Phenoxyphenyls) methyl-of a concentration of 68ppm
In 3- (2,2- dichloroethylene) -139 parts of 2,2- dimethyl cyclopropane carboxylic acids ester, reaction kettle is added, agitator speed is
173rpm, temperature are 152 DEG C, and starting vacuum pump makes the vacuum degree of reaction kettle reach 1.49MPa, keeps this state response 17 small
When；Pressure release is simultaneously passed through radon gas, and it is 1.77MPa to make reacting kettle inner pressure, and heat preservation stands 25 hours；Agitator speed is promoted to
215rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add (S) -3- allyl -2- methyl -4- oxos-amyl- 2- alkenyls of ring
(1R, 3R) -2,2- dimethyl -3- (2- methyl-1-propylenes base) 165 parts of cyclopropanecarboxylcompound, the trans- -3- of 1R- (2,2- bis- chloroethenes
Alkenyl) after -2,2- dimethyl cyclopropane carboxylic acids-(2,3,5,6,-tetrafluoro phenyl) 176 parts of methyl ester is completely dissolved, crosslinking is added
80 parts of agent is stirred so that the hydrophilic lipophilic balance of reaction kettle solution is 7.6, and heat preservation stands 28 hours；
4th step：When agitator speed is 266rpm, 5- (2- cyano -4- nitrophenylazos) -6- (2- are sequentially added
Hydroxyethylamino) -4- methyl -2- [[3- (2- phenoxy groups) propyl] amino] 121 parts of -3- pyridine carbonitriles, [5- is [double by N-
(2- methoxy ethyls) amino] -2- [(2- cyano -4,6- dinitrophenyl) azo] phenyl] 143 parts of-acetamide, N- [5- [two
[2- (acetoxyl group) ethyl] amino] -2- [(4- nitrobenzophenones) azo] phenyl] 214 parts of benzamide, 2- [[4- [[2- (second
Acyloxy) ethyl] butylamino] -2- aminomethyl phenyls] azo] 188 parts of -5- nitros -1,3- benzene dicarbonitrile, promote reaction kettle pressure
Power reaches 3.2MPa, and temperature is 175 DEG C, polymerisation 18 hours；Reacting kettle inner pressure is down to after the completion of reaction
0MPa, is cooled to 43 DEG C, and discharging enters molding press and can be prepared by electromagnetic induction chip 103；
The crosslinking agent is N- (oxidation diethylidene) -2-[4-morpholinodithio sulfenamide.
Embodiment 3
Electromagnetic induction chip 103 of the present invention is manufactured according to the following steps, and is counted in parts by weight：
1st step：3420 parts of the ultra-pure water that conductivity is 5.58 μ S/cm is added in a kettle, starts stirring in reaction kettle
Device, rotating speed 88rpm start heat pump, reactor temperature are made to rise to 83 DEG C；Sequentially add phenylacetic acid -2- methoxies -4-
62 parts of (2- acrylic) benzene (phenol) ester, (1R, S) is suitable, trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropane carboxylic acid
Acid-m- 112 parts of phenoxy group ester, 4- [3- (3,4- Dimethoxyphenyl) -3- (4- fluorophenyls) acryloyl] 73 parts of morpholine, stirring
To being completely dissolved, it is 7.3 to adjust pH value, agitator speed is adjusted to 142rpm, temperature is 116 DEG C, esterification 17 hours；
2nd step：Take (S) alpha-cyano-phenoxy benzyl (1R, 3R) -3- (2,2- dibromo vinyls) -2,2- diformazans basic ring third
160 parts of alkane carboxylate, (S)-alpha- cyano -3- phenoxy benzyls-(S) -2- (4- chlorphenyls) -158 parts of 3 Methylbutanoic acid ester
It crushes, powder diameter is 1600 mesh；(1R)-trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane is added
85 parts of carboxylic acid -3- phenoxy benzyls ester is uniformly mixed, and is laid in pallet, and tiling thickness is 30mm, use dosage for 6.4kGy,
The alpha ray that energy is 19MeV irradiates 135 minutes and the same dose of β x ray irradiation xs 104 minutes；
3rd step：The mixed-powder handled through the 2nd step is dissolved in cyano-(3- Phenoxyphenyls) methyl-of a concentration of 47ppm
In 3- (2,2- dichloroethylene) -108 parts of 2,2- dimethyl cyclopropane carboxylic acids ester, reaction kettle is added, agitator speed is
127rpm, temperature are 126 DEG C, and starting vacuum pump makes the vacuum degree of reaction kettle reach 0.85MPa, keeps this state response 12 small
When；Pressure release is simultaneously passed through radon gas, and it is 1.05MPa to make reacting kettle inner pressure, and heat preservation stands 18 hours；Agitator speed is promoted to
185rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add (S) -3- allyl -2- methyl -4- oxos-amyl- 2- alkenyls of ring
(1R, 3R) -2,2- dimethyl -3- (2- methyl-1-propylenes base) 126 parts of cyclopropanecarboxylcompound, the trans- -3- of 1R- (2,2- bis- chloroethenes
Alkenyl) after -2,2- dimethyl cyclopropane carboxylic acids-(2,3,5,6,-tetrafluoro phenyl) 132 parts of methyl ester is completely dissolved, crosslinking is added
58 parts of agent is stirred so that the hydrophilic lipophilic balance of reaction kettle solution is 6.1, and heat preservation stands 22 hours；
4th step：When agitator speed is 235rpm, 5- (2- cyano -4- nitrophenylazos) -6- (2- are sequentially added
Hydroxyethylamino) -4- methyl -2- [[3- (2- phenoxy groups) propyl] amino] 106 parts of -3- pyridine carbonitriles, [5- is [double by N-
(2- methoxy ethyls) amino] -2- [(2- cyano -4,6- dinitrophenyl) azo] phenyl] 93 parts of-acetamide, N- [5- [two
[2- (acetoxyl group) ethyl] amino] -2- [(4- nitrobenzophenones) azo] phenyl] 169 parts of benzamide, 2- [[4- [[2- (second
Acyloxy) ethyl] butylamino] -2- aminomethyl phenyls] azo] 145 parts of -5- nitros -1,3- benzene dicarbonitrile, promote reaction kettle pressure
Power reaches 2.4MPa, and temperature is 153 DEG C, polymerisation 13 hours；Reacting kettle inner pressure is down to after the completion of reaction
0MPa, is cooled to 38 DEG C, and discharging enters molding press and can be prepared by electromagnetic induction chip 103；
The crosslinking agent is the chloro- monoacetylanilines of 2-.
Reference examples
Reference examples are the electromagnetic induction chip of certain commercially available brand.
Embodiment 4
The electromagnetic induction chip described in electromagnetic induction chip 103 and reference examples that Examples 1 to 3 is prepared is into enforcement
Use Contrast on effect.The two Unit Weight, reaction time, transmission rate, wear-resistant rate are counted, the results are shown in Table 1.
As seen from Table 1, electromagnetic induction chip 103 of the present invention, it is Unit Weight, the reaction time, transmission rate, resistance to
The indexs such as wear rate are superior to the product of prior art production.
In addition, as shown in figure 4, being that 103 material corrosion resistant erosion degree of electromagnetic induction chip of the present invention becomes with usage time
The statistics of change.Find out in figure, electromagnetic induction chip 103 used in Examples 1 to 3, material corrosion resistant erosion degree changes with usage time
Degree is substantially better than existing product.
Claims (2)
1. a kind of building electricity-saving control system based on ZigBee communication technology, including：Central processing unit（100）, temperature sense
Answer module（101）, luminosity induction unit（102）, electromagnetic induction chip（103）, ZigBee communication module（104）, remote monitoring
Module（105）；It is characterized in that, the temperature sense module（101）It is set on indoor wall, indoor every 4~6 square metres
There are one temperature sense modules for setting in region（101）, temperature sense module（101）With central processing unit（100）Conducting wire control
System connection；The luminosity induction unit（102）It is fixedly mounted in indoor ceiling, two luminosity induction units（102）Between
Distance is between 4m~5m, luminosity induction unit（102）Pass through conducting wire and central processing unit（100）Control connection；The electricity
Magnetic induction chip（103）For rectangular configuration, thickness is between 2mm~5mm, electromagnetic induction chip（103）It is fixedly mounted on every
A desk upper right comer region, electromagnetic induction chip（103）With central processing unit（100）Polygon control survey connects；It is described
ZigBee communication module（104）With central processing unit（100）Interactive connection；The remote monitoring module（105）With ZigBee
Communication module（104）Remote control connects；
The central processing unit（100）Using CC2530 chip processors；
The temperature sense module（101）Including：Infrared temperature probe（101-1）, amplifying circuit（101-2）, A/D moduluss of conversion
Block（101-3）, address latch module（101-4）, key control module（101-5）, LED display module（101-6）, warning device
（101-7）；The wherein described amplifying circuit（101-2）By infrared temperature probe（101-1）The temperature information of acquisition is by amplification
After processing, it is sent to A/D conversion modules（101-3）, final transformed data are stored in address latch module（101-4）In；
The A/D conversion modules（101-3）With central processing unit（100）Control connection；The key control module（101-5）It is fixed
On wall, height distance ground is between 1.2m~1.5m；The LED display module（101-6）, warning device
（101-7）Pass through conducting wire and central processing unit（100）Control connection；
The luminosity induction unit（102）It is provided with S curve intensity control circuit, luminosity induction unit（102）In light intensity survey
It measures element and uses photosensitive sensor, the S curve intensity control circuit, photosensitive sensor pass through conducting wire and central processing unit
（100）Control connection；
The electromagnetic induction chip（103）It is molded by high molecular material pressing mold, electromagnetic induction chip（103）Constituent and system
It is as follows to make process：
One, electromagnetic induction chip（103）Constituent：
It counts in parts by weight, 40~95 parts of phenylacetic acid -2- methoxies -4- (2- acrylic) benzene (phenol) ester, (1R, S) is suitable, and trans- -2,
72~157 parts of the m- phenoxy group ester of 2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropane-carboxylic acids -, 4- [3- (3,4- dimethoxies
Base phenyl) -3- (4- fluorophenyls) acryloyl] 43~102 parts of morpholine, (S) alpha-cyano-phenoxy benzyl (1R, 3R) -3- (2,2-
Dibromo vinyl) -130~194 parts of 2,2- dimethyl cyclopropane carboxylic acids ester, (S)-alpha- cyano -3- phenoxy benzyl-(S) -
2- (4- chlorphenyls) -112~205 parts of 3 Methylbutanoic acid ester, (1R)-trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base) -
50~121 parts of cyclopropane-carboxylic acid -3- phenoxy benzyls ester, the cyano-(3- Phenoxyphenyls) of a concentration of ppm of 32 ppm~68
Methyl -3- (2,2- dichloroethylene) -78~139 parts of 2,2- dimethyl cyclopropane carboxylic acids ester, (S) -3- allyl -2- methyl -
4- oxos-ring amyl- 2- alkenyls (1R, 3R) -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropanecarboxylcompound 86~165
Part, the trans- -3- of 1R- (2,2- dichloroethylene) -2,2- dimethyl cyclopropane carboxylic acids-(2,3,5,6,-tetrafluoro phenyl) methyl ester
92~176 parts, 33~80 parts of crosslinking agent, 5- (2- cyano -4- nitrophenylazos) -6- (2- hydroxyethylaminos) -4- methyl -2-
[[3- (2- phenoxy groups) propyl] amino] 86~121 parts of -3- pyridine carbonitriles, N- [5- [bis- (2- methoxy ethyls) ammonia
Base] -2- [(2- cyano -4,6- dinitrophenyl) azo] phenyl] 52~143 parts of-acetamide, N- [5- [two [2- (acetyl oxygen
Base) ethyl] amino] -2- [(4- nitrobenzophenones) azo] phenyl] 119~214 parts of benzamide, 2- [[4- [[2- (acetyl oxygen
Base) ethyl] butylamino] -2- aminomethyl phenyls] azo] 105~188 parts of -5- nitro -1,3- benzene dicarbonitriles；
The crosslinking agent is N, bis- (2- ethoxys) methylamines of N-, N- (oxidation diethylidene) -2-[4-morpholinodithio sulfenamide, 2-
Any one in chloro- monoacetylaniline；
Two, electromagnetic induction chip（103）Manufacturing process, comprise the steps of：
1st step：3150~3680 parts of the ultra-pure water that conductivity is 4.22 μ of μ S/cm~7.28 S/cm is added in a kettle, opens
Blender in dynamic reaction kettle, rotating speed are the rpm of 58 rpm~114, start heat pump, make reactor temperature rise to 68 DEG C~
108 ℃；It is suitable to sequentially add phenylacetic acid -2- methoxies -4- (2- acrylic) benzene (phenol) ester, (1R, S), trans- -2,2- dimethyl -3-
The m- phenoxy group ester of (2- methyl-1-propylenes base) cyclopropane-carboxylic acid -, 4- [3- (3,4- Dimethoxyphenyls) -3- (4- fluorophenyls)
Acryloyl] morpholine, to being completely dissolved, it is 5.5~8.4 to adjust pH value, and agitator speed is adjusted to 118 rpm~164 for stirring
Rpm, temperature are 78 DEG C~155 DEG C, esterification 13~21 hours；
2nd step：Take (S) alpha-cyano-phenoxy benzyl (1R, 3R) -3- (2,2- dibromo vinyls) -2,2- dimethylcyclopropane carboxylics
Acid esters, (S)-alpha- cyano -3- phenoxy benzyls-(S) -2- (4- chlorphenyls) -3 Methylbutanoic acid ester crush, powder grain
Diameter is 1300~1900 mesh；(1R)-trans- -2,2- dimethyl -3- (2- methyl-1-propylenes base)-cyclopropane-carboxylic acid -3- benzene is added
Oxy-benzyl ester is uniformly mixed, and is laid in pallet, and tiling thickness is the mm of 25 mm~36, uses dosage for 4.4 kGy~8.3
KGy, the alpha ray that energy is the MeV of 16 MeV~23 irradiate 105~166 minutes and the same dose of β x ray irradiation xs 73~
146 minutes；
3rd step：The mixed-powder handled through the 2nd step is dissolved in cyano-(3- Phenoxyphenyls) methyl -3- (2,2- dichloroethylene
Base) in -2,2- dimethyl cyclopropane carboxylic acid's esters, reaction kettle is added, agitator speed is the rpm of 82 rpm~173, temperature 101
DEG C~152 DEG C, start vacuum pump so that the vacuum degree of reaction kettle is reached the MPa of -0.53 MPa~1.49, keep this state response 7~
17 hours；Pressure release is simultaneously passed through radon gas, and it is the MPa of 0.42 MPa~1.77 to make reacting kettle inner pressure, and heat preservation stands 12~25 hours；
Agitator speed is promoted to the rpm of 162 rpm~215, simultaneous reactions kettle pressure release to 0MPa；Sequentially add (S) -3- allyls -2-
Methyl -4- oxos-ring amyl- 2- alkenyls (1R, 3R) -2,2- dimethyl -3- (2- methyl-1-propylenes base) cyclopropanecarboxylcompound, 1R-
Trans- -3- (2,2- dichloroethylenes) -2,2- dimethyl cyclopropane carboxylic acids-(2,3,5,6,-tetrafluoro phenyl) methyl ester is completely molten
Xie Hou is added crosslinking agent and is stirred so that and the hydrophilic lipophilic balance of reaction kettle solution is 4.5~7.6, heat preservation standing 15~
28 hours；
4th step：When agitator speed is 218 rpm~266 rpm, 5- (2- cyano -4- nitrophenylazos)-is sequentially added
6- (2- hydroxyethylaminos) -4- methyl -2- [[3- (2- phenoxy groups) propyl] amino] -3- pyridine carbonitriles, [5- is [double by N-
(2- methoxy ethyls) amino] -2- [(2- cyano -4,6- dinitrophenyls) azo] phenyl]-acetamide, N- [5- [two [2-
(acetoxyl group) ethyl] amino] -2- [(4- nitrobenzophenones) azo] phenyl] benzamide and 2- [[4- [[2- (acetoxyl group)
Ethyl] butylamino] -2- aminomethyl phenyls] azo] -5- nitro -1,3- benzene dicarbonitriles, reactor pressure is promoted, is reached
The MPa of 1.6 MPa~3.2, temperature are 133 DEG C~175 DEG C, polymerisation 9~18 hours；By reaction kettle internal pressure after the completion of reaction
Power is down to 0 MPa, is cooled to 34 DEG C~43 DEG C, and discharging enters molding press and can be prepared by electromagnetic induction chip（103）.
2. a kind of building electricity-saving control system based on ZigBee communication technology according to claim 1, which is characterized in that
A kind of working method of the building electricity-saving control system based on ZigBee communication technology, this method includes following steps：
1st step：Staff presses total power switch, and indoor each electric appliance and electronic component are powered on；Wherein temperature sense mould
Block（101）In infrared temperature probe（101-1）Indoor temperature is monitored in real time, and the temperature signal detected is sent
To amplifying circuit（101-2）, the temperature signal after enhanced processing is through A/D conversion modules（101-3）After effect, center is sent to
Processing unit（100）；In cooling mode, central processing unit（100）The temperature value received and default value A are carried out
Compare, when the temperature value received is less than A, central processing unit（100）It controls room conditioning and reduces air quantity output, until temperature
Angle value reaches setting value A；When the temperature value received is higher than A, central processing unit（100）Controlling room conditioning enhances air quantity
Output, until temperature value is reduced to setting value A；In a heating mode, central processing unit（100）By the temperature value received with
Default value B is compared, when the temperature value received is less than B, central processing unit（100）Control room conditioning enhancing
Air quantity exports, until temperature value reaches setting value B；When the temperature value received is higher than B, central processing unit（100）Control
Room conditioning reduces air quantity output, until temperature value is reduced to setting value B；Central processing unit（100）The temperature value received
Real-time display is in LED display module（101-6）On；
2nd step：Luminosity induction unit（102）In photosensitive sensor indoor illumination intensity is monitored in real time；Work as photosensitive sensor
When detecting that indoor illumination intensity is more than 106 cd/m2, central processing unit（100）Controlling S curve intensity control circuit reduces
Indoor illumination intensity is to the cd/m2 of 88 cd/m2~98；It is more than 66 cd/m2 when photosensitive sensor detects that indoor illumination is less than
When, central processing unit（100）Controlling S curve intensity control circuit enhances indoor illumination intensity to the cd/m of 88 cd/m2~98
²；
3rd step：When staff is in place at a desk, the electromagnetic induction chip in the lower desk upper right corner is touched with finger
（103）, electromagnetic induction chip（103）Inductive signal is sent to central processing unit（100）, central processing unit（100）In
Data processing module is according to electromagnetic induction chip（103）Regional location distribution arranges to inductive signal, central processing unit
（100）In computing unit calculate the quantity of inductive signal in the regions every 2 ㎡, according to inductive signal quantity central processing unit
（100）Control the unlatching number of lamp in 2 ㎡；
4th step：Remote monitoring module（105）Pass through ZigBee communication module（104）To indoor electric appliance remote monitoring and operation；When
When indoor nobody and electric appliance are not turned off, administrative staff can pass through the remote monitoring module of electronic device terminal（105）It is closed
It closes.
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