CN106436323A - Natural antibacterial and deodorizing finishing agent for non-woven fabrics and preparation method of finishing agent - Google Patents
Natural antibacterial and deodorizing finishing agent for non-woven fabrics and preparation method of finishing agent Download PDFInfo
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- CN106436323A CN106436323A CN201610884350.8A CN201610884350A CN106436323A CN 106436323 A CN106436323 A CN 106436323A CN 201610884350 A CN201610884350 A CN 201610884350A CN 106436323 A CN106436323 A CN 106436323A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/006—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with wool-protecting agents; with anti-moth agents
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
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- General Chemical & Material Sciences (AREA)
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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Abstract
The invention relates to a natural antibacterial and deodorizing finishing agent for non-woven fabrics. The formula of the natural antibacterial and deodorizing finishing agent comprises the following components in percentage by weight: 5%-20% of polyoxyethylene sorbitan tristearate, 1%-10% of ester-base quaternary ammonium salt, 5%-20% of a natural antibacterial composition, 5%-9% of polyethylene glycol glyceryl ether, 3%-8% of a fragrant slow-released system and the balance of deionized water, wherein the natural antibacterial composition comprises chitosan, aloe oil, chitin, catechinic acid, tea polyphenol, tea-seed oil, tea saponin, a grape seed extract, citric acid, amino acid chelate, an amino acid derivative and an emulsifying agent. The natural antibacterial and deodorizing finishing agent has no stimulation to the skin of the human body, is capable of inhibiting the invasion and breeding of bacteria and high in ammonia absorptivity and further has outstanding antibacterial and deodorization effects. The natural antibacterial and deodorizing finishing agent has the characteristics that fragrance is uniformly released, the fragrance preservation time is long, and the added value of the product is high.
Description
Technical field
The present invention relates to fabric finishing field, more particularly to a kind of non-weaving cloth natural antibacterial deodorization finishing agent and its system
Preparation Method.
Background technology
With the improvement of people's living standards, people are additional except packaging, abnormal smells from the patient, color, shape etc. except being concerned about commodity
The health of oneself and household beyond value, is become more concerned with, also increasingly worries fiber weaving product or nonwovens in daily life
In easy breed bacteria potential danger, it is therefore necessary to provide a kind of carrying natural antibacterial fiber and its products so that fiber
Product has anti-microbial property, suppresses fibre surface bacterial growth, keeps fibre surface itself clean.
In recent years, the domestic Research on antibacterial to fibre or non-weaving cloth gradually increased, and which is mainly in general fibre
Or add the method for a small amount of antibacterial in the dressing liquid of non-weaving cloth and obtain, antibacterial be a class can kill or suppress antibacterial,
The harmful microbe functional material such as virus, through searching document, the antibacterial that applies in general fibre or non-weaving cloth at present
Inorganic antiseptic, organic antibacterial agent and the big series of natural antibacterial agent three are broadly divided into by structure.Wherein：
1）Organic antibacterial agent includes quaternary ammonium salt, imidazoles, pyridines, organic metal class etc., although sterilization speed is fast, and antibacterial is imitated
Fruit is notable, but exists and be also easy to produce drug resistance, and heat stability is poor, and Durability of antimicrobial effect is short, toxicity is big wait not enough, so as to give fiber and its
Product brings new healthy hidden danger.
2）Compared with organic antibacterial agent, inorganic antibacterial collection have have a safety feature, heat decomposition temperature height, good stability, resist
Bacterium ability is strong and the features such as antibacterial is lasting, research at present at most most extensive.
Inorganic antiseptic is typically to be made up of antibacterial components and carrier, the metal ion with antibacterial activity have silver, chromium,
Cobalt, nickel, copper, zinc and ferrum plasma, consider, silver ion is best jointly from safety and antibiotic property.But silver ion antimicrobial agent is direct
Using silver ion as antibacterial, there is following defect：First, silver ion is easily reduced in simple substance and is changed into black, impact silver
Application of the ion antibacterial agent in light color article, anti-tarnishing ability is poor.Secondly, easily silver oxide precipitates are generated in alkaline environment,
Sustained release performance is poor, affects Durability of antimicrobial effect.Again, when silver ion meets article or the environment of chloride ion, easily generate silver chloride and sink
Form sediment and lose activity, salt resistant character is poor.Finally, silver carrying amount is relatively low, complex process, and required auxiliary agent species is various.
As can be seen here, silver ion antimicrobial agent is mainly by physical absorption or the method for ion exchange, will be with antibacterial energy
The metal of power or metal ion be fixed on the surface of certain carrier for example zeolite, activated carbon, phosphate, silicate, dissolubility glass,
The material that makes on the carriers such as porous metals.Patent of invention as Publication No. CN102599164B provides a kind of nano lamellar
The preparation method of silver-amino acid complex antibacterial is carried, first silver salt, aminoacid, hydromassage that is compared 1:1:2.7 are mixed
Close, 30min is stirred at room temperature, 50 DEG C of stirring in water bath 15min, mixing speed is 8000r/min, obtained solution, secondly in 50 DEG C of water
In bath under mixing speed 8000r/min add Diosmectite, agitation and filtration, obtain feed liquid, after carry out solid-liquid separation, be placed in room
The lower drying of temperature, obtains fluffy ivory shape anti-bacterial powders, and which has preferable discoloration-resisting, improves the slow release of antibacterial
Performance and salt tolerance.
However, the inorganic antiseptic based on the metal ions such as silver, zinc, though with antimicrobial efficiency height, strong excellent of thermostability
Point, but which is expensive, and environmental protection is short of, meanwhile, life-time service and product of the touch containing metal ions such as silver, zinc can be to human bodies
Liver adversely affect；The silver ion antimicrobial agent application in the product of these drawbacks limit.Based on previous reasons, natural
Antibacterial comes into existence as the situation requires, and compared with aforementioned antibacterial, natural antibacterial agent is extracted from plant, animal or biology, and its source is wide
General, low cost, with safety non-toxic, antimicrobial efficiency height, heat-resist, drug resistance is not likely to produce, excellent with environment friendly etc.
Point, therefore its application and research are increasingly subject to people's attention.As patent of invention of the notification number for CN103800928B is disclosed
Antibacterial deodorant, it is main effective with the alkaloid in plant Radix Cryptolepis sinensis source and new 5-methyl-5H-indolo[3,2-b analog which is mainly a kind of
The antibacterial deodorising product of composition, including weak acid regulator, dipotassium hydrogen phosphate, solubilizing agent, metal-chelating salt, cyclodextrin, activity
Composition, essence, can eliminate abnormal flavour in cloth products, while effective antibacterial for removing in cloth products or being attached in cloth products and disease
Poison, and safely and effectively, fundamentally remove due to bacterial stink.
In sum, the present invention is in the sandwich layer of skin-core structure fiber, by natural antibacterial is combined in spinning process
Thing and core layer polymer such as polypropylene, polyester blend melt spinning, can be directly prepared into polypropylene with aromatic function, polyester long
Silk or chopped fiber, which is compared with the woven textile of traditional afterfinish method, and the fibre armaticity of the method production are more
Persistently, at the same product have the characteristics that soft, fine and smooth and comfortable, while with natural antibacterial active component, cloth products can be eliminated
Middle abnormal flavour, while effective antibacterial for removing in cloth products or being attached in cloth products and virus, and safely and effectively, fundamentally go
Remove due to bacterial stink.
Content of the invention
The purpose of the present invention be exactly for providing a kind of non-weaving cloth natural antibacterial deodorization finishing agent, in order to realize above-mentioned mesh
Mark, the technical scheme that a kind of non-weaving cloth natural antibacterial deodorization finishing agent is taken：A kind of non-weaving cloth natural antibacterial
Deodorization finishing agent, by weight percentage, its formula is as follows：Polyoxyethylene sorbitan tristearate 5%-20%；Ester group season
Ammonium salt 1%-10%；Natural antibacterial composition 5-20%；Balance of deionized water.Wherein, the natural antibacterial composition is by weight
Number meter, its component and its deal are as follows：Shitosan 2-8 part；Aloe 10-15 part；Chitin 3-8 part；Catechin 5-10 part；
Tea polyphenols 10-40 part；Oleum Camelliae 5-25 part；Tea saponin 0.1-2 part；Semen Vitis viniferae extract 5-15 part；Citric acid 5-25 part；Amino
Sour chelate 5-25 part；Amino acid derivativges 0-8 part；Emulsifying agent 1-8 part.
Used as further preferred version, the non-weaving cloth natural antibacterial deodorization finishing agent also includes that Polyethylene Glycol is sweet
Oily ether, its component and formula are as follows：Polyethylene glycol glycerol ether 5%-9%；Polyoxyethylene sorbitan tristearate 8%-15%；
Ester based quaternary ammonium salt 5%-8%；Natural antibacterial composition 10-16%；Balance of deionized water.
Used as further preferred version, finishing agent described in the non-weaving cloth natural antibacterial deodorization finishing agent is also wrapped
Fragrant slow release body is included, fragrant slow release body is the aromatic micro-capsule in cladding core-shell structure, comprising capsule-core, cyst wall, its component and join
Side is as follows：Polyethylene glycol glycerol ether 5%-9%；Polyoxyethylene sorbitan tristearate 8%-15%；Ester based quaternary ammonium salt 5%-
8%；Natural antibacterial composition 10-16%；Fragrant slow release body 3%-8%；Balance of deionized water.
Nano titanium oxide, molecular formula is TiO2, have the characteristics that safety non-toxic, possess certain hydrophilic and moisture absorption
Property, TiO2Middle Ti-O bond polarity is larger, and the water of surface adsorption is dissociated because of polarization, easily forms hydroxyl, and which not only has
Automatic cleaning action, also has certain bactericidal property, is applied in the present invention to promote the bactericidal properties from fragrant antimicrobial fiber, protects
Hold the cleaning of fiber.Accordingly, as further preferred version, the non-weaving cloth is with described in natural antibacterial deodorization finishing agent
Finishing agent also includes nano titanium oxide, and its component and formula are as follows：Polyethylene glycol glycerol ether 5%-9%；Polyoxyethylene sorbitan mountain
Pears tristearate 8%-15%；Ester based quaternary ammonium salt 5%-8%；Natural antibacterial composition 10-16%；Fragrant slow release body 3%-8%；Receive
Rice titanium dioxide 0.5%-5%；Balance of deionized water.
As further preferred version, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid two, described ester based quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt,
Ethanol diester quaternary ammonium, double ethyl stearte base hydroxyethyl methyl sulfate methyl ammoniums, stearic acid triethanolamine ester quaternary, 2,3-
One or more in dihydroxypropyl dibasic acid esters ammonium halide, double hydroxyethyl fatty acid ester dimethy lammonium chloride.
As further preferred version, described emulsifying agent is dodecylbenzene sodium sulfonate, fatty acid mono glycidol, Laurel
One kind in sour monoglyceride, methyl glycol fatty acid ester, polyoxyethylene sorbitan fatty acid ester, Span-80, sodium stearate
Or it is several.
Used as further preferred version, the amino-acid chelate is zinc and amino-acids chelate, including zinc glycinate, Soviet Union
One or more in propylhomoserin zinc, zinc lysine and zinc methionine.
Used as further preferred version, the amino acid derivativges are that amino-acid ester, the amino-acid ester includes to rely ammonia
One or more in sour Lauryl Ester, L-Glutamic Acid cellulose esters, aspartic acid cellulose esters.
Used as further preferred version, the odor type of the fragrant slow release body includes hay-scented type, rose scent, Forest Bath perfume
Type, jasmine fragrance, lavender flavor type, fruit flavouring, lemon flavor and osmanthus flower fragrant.
As it was previously stated, a kind of preparation method of non-weaving cloth natural antibacterial deodorization finishing agent of the present invention includes following step
Suddenly：
1）The preparation of natural antibacterial deodorant compositions：First citric acid is dissolved in deionized water and stirs acquisition solution A；Again by youngster
Theine, tea polyphenols, Semen Vitis viniferae extract are dissolved in solution A respectively and are mixing uniformly to form solution B；Solution B is heated to 50-
After 60 DEG C, add in emulsifying agent in solution B and stir, be subsequently adding tea saponin, shitosan, the aloe of part, carapace
Element, Oleum Camelliae, amino-acid chelate, amino acid derivativges are simultaneously uniformly mixed；Finally it is dried using spray dryer,
Size-reduced grinding forms natural antibacterial deodorant compositions powder.
2）Deionized water is heated to 40-60 DEG C, is subsequently adding polyoxyethylene sorbitan tristearate, ester group quaternary ammonium
Salt, polyethylene glycol glycerol ether, are uniformly mixed, and form solution C.
3）Under conditions of stirring, toward step（Two）Solution C in add natural antibacterial composition, fragrant slow release body, continue
Continuous stirring causes bactericidal composition, the dissolving of fragrant slow release body or mix homogeneously, forms solution D.
4）Solution D is cooled to room temperature, discharging, prepared natural antibacterial deodorization finishing agent.
The beneficial effect that the present invention is realized：The present invention has following effect：
1）Natural antibacterial deodorization finishing agent is non-stimulated to human body skin, with excellent antibiotic property, can suppress the invasion of antibacterial
With grow, to ammonia absorbance height, antibacterial and mouldproof and deodorizing effect are projected.
2）Be conducive to protecting volatile oil not decomposed, lasting fragrance by high temperature using from fragrant slow release body using microcapsule
Property long, good stability, can weave after meeting arrange processing different demands.
3）Ensure that the chronicity of wash resistant and bacteriostasis, and deodorization effect and fragrant fragrance, added value of product height, application city
Field has a extensive future.
Specific embodiment
Term " volatile oil "：Volatile oil is a kind of plants essential oil that can distribute aromatic odor, its be by multiple chemistry
The mixture of material composition, can be divided into aliphatic, aromatic series and 3 big class compound of terpenoid by chemical constitution and theirs is oxygen-containing
Derivant such as alcohol, aldehyde, ketone, acid, ester, lactone, ether and terpenes etc..Quintessence oil is readily flowed transparency liquid or body of paste mostly,
In colourless, faint yellow, and for the physical property of quintessence oil, most of quintessence oils are water insoluble or are slightly soluble in water, and plant from fragrance
The obtained quintessence oil containing fragrant part of thing typically all has certain volatility at room temperature.
Plants essential oil has certain inhibitory action to antibacterial or mycete, and such as single iodoacetate ester of terpenoid has very strong
Antifungal activity, Herba Rosmarini Officinalis has stronger broad-spectrum antibacterial performance, and clove oil has excellent sterilization and fungistatic effect.
Additionally, Oleum Camelliae can suppress the Repiration of antibacterial, increase the permeability of somatic cells matter so as to which self-dissolving occurs
Effect and dead.
Term " microcapsule "：Microcapsule technology is one of high-tech emerging technology of 21 century industrial circle focus development,
Microcapsule technology can effectively overcome the problem that quintessence oil volatility is high, action time is short, extend the storage time of volatile material, carry
High material stability, particularly, microcapsule technology refer to by a certain purpose thing with various natural, semi-synthetic or synthesis high score
Sub- thin film（Cyst wall）Cladding gets up to form microcapsule completely, and capsule-core material tunica wall is coated and isolated with external environment, reduces outer
The impact of boundary's condition change, but under suitable condition, but when cyst wall is destroyed, capsule-core material is discharged, that is, rely on capsule
The shielding action protection core of wall.The method of micro encapsulation is divided into chemical method, physical-chemical process and Physical, and such as chemical method includes
Interfacial polymerization, emulsion process, situ aggregation method, supercritical fluid technology etc., physical method includes spray drying method, electrostatic precipitation
Method etc., the spray drying method in the preferred Physical of the present invention.
With regard to Semen Vitis viniferae extract, Semen Vitis viniferae extract is a kind of polyphenols of new and effective natural anti-oxidation,
Containing abundant bioflavonoids and procyanidin, antiinflammatory, antiallergic and antioxidant effect are notable.
By weight percentage, its formula is as follows for the non-weaving cloth of present invention natural antibacterial deodorization finishing agent：Polyoxy second
Alkene Sorbitan tristearate 5%-20%；Ester based quaternary ammonium salt 1%-10%；Natural antibacterial composition 5-20%；Balance of go from
Sub- water.Wherein, the natural antibacterial composition is counted by weight, and its component and its deal are as follows：Shitosan 2-8 part；Aloe
Oily 10-15 part；Chitin 3-8 part；Catechin 5-10 part；Tea polyphenols 10-40 part；Oleum Camelliae 5-25 part；Tea saponin 0.1-2 part；
Semen Vitis viniferae extract 5-15 part；Citric acid 5-25 part；Amino-acid chelate 5-25 part；Amino acid derivativges 0-8 part；Emulsifying agent
1-8 part.In a specific embodiment, preferably, the non-weaving cloth natural antibacterial deodorization finishing agent is also wrapped
Polyethylene glycol glycerol ether or fragrant slow release body is included, or includes polyethylene glycol glycerol ether, fragrant slow release body, and nano-silica simultaneously
Change titanium.Wherein, the addition of polyethylene glycol glycerol ether is 5%-9%, and the addition of fragrant slow release body is 3%-8%, nanometer titanium dioxide
Titanium 0.5%-5%, its component and formula are as follows：Polyethylene glycol glycerol ether 5%-9%；Fragrant sustained release 3%-8%；Polyoxyethylene sorbitan mountain
Pears tristearate 8%-15%；Ester based quaternary ammonium salt 5%-8%；Natural antibacterial composition 10-16%；Nano titanium oxide 0.5%-
5%；Balance of deionized water.
In a specific embodiment, the preferred Petiolus Trachycarpi cationoid ester based quaternary ammonium salt of the ester based quaternary ammonium salt or stearic acid diethyl
Alcohol diester quaternary ammonium.The emulsifying agent preferred fatty acid list glyceride, methyl glycol fatty acid ester, polyoxyethylene sorbitol acid anhydride fat
Fat acid esters or Span-80.
Preferably, the fragrant slow release body be in cladding core-shell structure aromatic micro-capsule, comprising capsule-core,
Cyst wall, the cyst wall is the compositionss that polymer, the capsule-core is volatile oil or volatile oil and aluminium hydrosilicate, by weight
Number meter, its component and its deal are as follows：Capsule-core 20-70%；Cyst wall 30-80%.Wherein, the cyst wall polymer is polyurethane tree
One or more in fat, gelatin, cyclodextrin, low melting point polyamide, epoxy resin, Lauxite, arabic gum；The fragrance
The essence type of quintessence oil includes hay-scented type, rose scent, Forest Bath odor type, jasmine fragrance, lavender flavor type, fruit flavouring, lemon
Lemon odor type and osmanthus flower fragrant, the volatile oil belongs to the volatile oil of high temperature resistant type, is resistant to processing temperature 100-160 DEG C.
Used as further preferred version, the amino-acid chelate is zinc and amino-acids chelate, the zinc and amino-acids chela
Compound is formed with Covalent bonding together through chelating technique with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union with zinc ion by described aminoacid, and described aminoacid is aspartic acid, Soviet Union
Propylhomoserin, serine, L-Glutamic Acid, Glycine, propylhomoserin, phenylalanine, lysine, arginine, histidine, one kind of methionine or several
Kind.As further preferred embodiment, the preferred zinc glycinate of the zinc and amino-acids chelate, threonine zinc, lysine
One or more of zinc, zinc methionine.The amino acid derivativges are amino-acid ester, and the amino-acid ester includes lysine Laurel
Base ester, L-Glutamic Acid cellulose esters, aspartic acid cellulose esters.
Used as further preferred version, the capsule-core is the compositionss of volatile oil and aluminium hydrosilicate, i.e., with water
Aluminium silicate is closed as the carrier of volatile oil so that volatile oil is stored inside which after being absorbed by aluminium hydrosilicate microsphere, is reached
To the effect for persistently holding perfume, the volatile oil is 30-45% with the quality accounting of aluminium hydrosilicate:55-70%, its preparation technology
Including first volatile oil being carried in aluminium hydrosilicate microsphere, enter after coupling processing is made to aluminium hydrosilicate microsphere surface again
Row micro encapsulation is processed, prepared volatile oil microcapsule.
In order to make further understanding to the present invention, now by embodiment, which is explained.
Embodiment 1
In the present embodiment, non-weaving cloth is as follows with the process for preparation of natural antibacterial deodorization finishing agent and step：
（One）Preparation：
The dispensing of natural antibacterial deodorant compositions：Shitosan 2kg；6 kg of aloe；2.5 kg of chitin；3 kg of catechin；Tea
9 kg of polyphenol；5 kg of Oleum Camelliae；0.4 kg of tea saponin；4.5 kg of Semen Vitis viniferae extract；6 kg of citric acid；Amino-acid chelate 6
kg；2.5 kg of amino acid derivativges；2 kg of emulsifying agent, deionized water 100kg.
The dispensing of natural antibacterial deodorization finishing agent：10 kg of polyoxyethylene sorbitan tristearate；Polyethylene Glycol is sweet
6 kg of oily ether；5 kg of ester based quaternary ammonium salt；10 kg of natural antibacterial composition；6 kg of fragrant slow release body；63 kg of deionized water.
（Two）Process for preparation：
Step one：The preparation of natural antibacterial deodorant compositions：First citric acid is dissolved in deionized water and stirs acquisition solution A；
Again catechin, tea polyphenols, Semen Vitis viniferae extract are dissolved in solution A respectively and are mixing uniformly to form solution B；By solution B plus
Heat is added in emulsifying agent in solution B and stirs, be subsequently adding tea saponin, shitosan, aloe, first to after 50-60 DEG C
Shell element, Oleum Camelliae, amino-acid chelate, amino acid derivativges are simultaneously uniformly mixed；Finally done using spray dryer
Dry, size-reduced grinding forms natural antibacterial deodorant compositions powder.
Step 2：Deionized water is heated to 40-60 DEG C, is subsequently adding polyoxyethylene sorbitan tristearate, ester
Based quaternary ammonium salt, polyethylene glycol glycerol ether, are uniformly mixed, and form solution C.
Step 3：Under conditions of stirring, toward step（Two）Solution C in add natural antibacterial composition, fragrant slow release
Body, continues stirring and causes natural antibacterial composition, the dissolving of fragrant slow release body or mix homogeneously, form solution D.
Step 4：Solution D is cooled to room temperature, discharging, prepared natural antibacterial deodorization finishing agent.
In the present embodiment, the natural antibacterial composition can make cladding according to the preparation technology of aromatic micro-capsule in the present invention
The natural antibacterial microcapsule of core-shell structure, the particle diameter of the natural antibacterial microcapsule is below 3 μm, and its capsule-core is natural antibacterial group
Compound, cyst material by aromatic micro-capsule of the present invention cyst material constitute, with improve natural antibacterial composition slow-releasing and
Long-lasting.
Embodiment 2
In the present embodiment, non-weaving cloth is as follows with the process for preparation of natural antibacterial deodorization finishing agent and step：
（One）Preparation：
The dispensing of natural antibacterial deodorant compositions：Shitosan 2kg；6 kg of aloe；2.5 kg of chitin；3 kg of catechin；Tea
9 kg of polyphenol；5 kg of Oleum Camelliae；0.4 kg of tea saponin；4.5 kg of Semen Vitis viniferae extract；6 kg of citric acid；Amino-acid chelate 6
kg；2.5 kg of amino acid derivativges；2 kg of emulsifying agent, deionized water 100kg.
The dispensing of natural antibacterial deodorization finishing agent：Polyoxyethylene sorbitan tristearate 15kg；Polyethylene glycol glycerol
8 kg of ether；7 kg of ester based quaternary ammonium salt；Natural antibacterial deodorant compositions 15kg；4 kg of fragrant slow release body, 51 kg of deionized water.
（Two）Process for preparation：The step of according to embodiment 1, prepared natural antibacterial deodorization finishing agent.
Embodiment 3
The present embodiment is arranged to PP spunbonded nonwovens using the finishing agent of embodiment 1, polypropylene spunbond nonwoven
Cloth square grammes per square metre is 18g/m2, it is as follows which arranges step：
Step one：Natural antibacterial deodorization obtained in embodiment 1 is arranged dilution agent the solution that concentration is 20% is formulated as, be obtained whole
Reason liquid.
Step 2：Non-weaving cloth is positioned in dressing liquid and impregnates 20-30min at room temperature.
Step 3：By adjusting the spacing of control roll, by step（Two）The non-weaving cloth of gained carries out drying process.
Step 4：Drying temperature is set as 110 DEG C, by step（Three）The non-weaving cloth of gained carries out baking and curing process.
A kind of PP spunbonded nonwovens comprising natural antibacterial deodorization finishing agent, and day have been obtained by above step
So antibacterial and deodouring finishing agent is 0.4% with the weight ratio of PP spunbonded nonwovens, i.e., polypropylene spun-bonded non-at per square metre
In woven cloths, the adhesion amount of natural antibacterial and deodouring finishing agent is 0.08g.
The non-weaving cloth physical property comprising natural antibacterial deodorization finishing agent of the present embodiment is：Square grammes per square metre is
18.08g/m2, the fracture strength of 50mm width is 24N.
Embodiment 4
The present embodiment is arranged to polypropylene Through-Air Thermal Bonded Nonwovens using the finishing agent of embodiment 2, and polypropylene hot blast is non-woven
Cloth square grammes per square metre is 16g/m2, its arrange step be obtained by the process of embodiment 3 and step a kind of comprising natural antibacterial deodorization
The non-weaving cloth of finishing agent, and natural antibacterial deodorization finishing agent is 0.6% with the weight ratio of polypropylene Through-Air Thermal Bonded Nonwovens.
The physical property of the non-weaving cloth comprising natural antibacterial deodorization finishing agent of the present embodiment of the present embodiment is：Square
Grammes per square metre is 16.10g/m2, the fracture strength of 50mm width is 13N.
Embodiment 5
The present embodiment to embodiment 3, the antibacterial of the obtained non-weaving cloth comprising natural antibacterial deodorization finishing agent of embodiment 4, remove
Smelly and fragrant performance is tested.
（One）Anti-microbial property test
Detection sample：Embodiment 3, the obtained non-weaving cloth comprising natural antibacterial deodorization finishing agent of embodiment 4, control sample.Its
Middle control sample is the non-weaving cloth for arranging without natural antibacterial deodorization finishing agent in embodiment 3 or embodiment 4.
Anti-microbial property detects foundation：JIS Z 2801:2000《The detection of antibacterial product anti-microbial property and par》.
Bacterium is used in detection：Escherichia coli（Escherichia coli）ATCC 25822.
Staphylococcus aureuses（Staphylcococcus aureus）ATCC 6538.
Testing result is as shown in table 1：
（Two）Fragranced stability test
Detection sample：Embodiment 3, the obtained non-weaving cloth comprising natural antibacterial deodorization finishing agent of embodiment 4.
Fragrance Detection of Stability method：The sample is placed 365 days under field conditions (factors) through washing 100 times.
Evaluation methodology：Via the evaluation group of spice expert composition, fragrance is qualitatively judged by olfactory sensation.
Evaluation result：Each sample is respectively provided with fragrance, and fragrance purity, illustrates that the invention is obtained comprising natural antibacterial deodorization
The fragrance stability height of the non-weaving cloth of finishing agent, aroma-keeping time is long, wash resistant.
（Three）Deodoriging properties are tested
Detection sample：Embodiment 3, the obtained non-weaving cloth comprising natural antibacterial deodorization finishing agent of embodiment 4.
Detection method：Non-weaving cloth comprising natural antibacterial deodorization finishing agent is positioned over known odor concentration C0Closed
In container, foul smell composition is the mixed gas being made up of ammonia, hydrogen sulfide gas, closed placement 30-60min, then with detection
Odor concentration C in the closed instrument of instrument test1, and clearance of the sample to foul smell is calculated as follows, test result such as 2 institute of table
Show.
Computing formula：Foul smell clearance（%）=（C0- C1）/ C0× 100%, C in formula0For foul smell initial concentration, C1It is to be wrapped
Residual odor concentration after the non-weaving cloth absorption of the finishing agent of deodorization containing natural antibacterial.
Embodiment 6
The present embodiment testing example 3, the obtained non-weaving cloth comprising natural antibacterial deodorization finishing agent of embodiment 4 are to physiology salt
The permeance property of water.Test result is as follows：
Wherein, method of testing refers to method of testing of the sanitary goods industry to non-weaving cloth to normal saline permeance property, specifically
As follows：
Step 1：Take standard filter paper 3-5 to open, non-weaving cloth is cut to and standard filter paper sample of the same size, is placed in standard
On filter paper, smooth after insert in LISTER permeameter, the filling opening of its Instrumental faces the center position of non-weaving cloth.
Step 2：Take in 5ml normal saline injection LISTER liquid storage cylinder, open liquid feeding switching fluid and non-weaving cloth is penetrated into, and
Synchronously start by manual time-keeping, when normal saline completely penetrates through non-weaving cloth, i.e., when non-woven cloth cover upper liquid body disappears, timing is tied
Bundle, records first time time of penetration T1.
Step 3：Repeat step after 60s（2）, record second time of penetration T2.
Step 4：Repeat step after 60s（2）, third time time of penetration T3 is recorded, other times of penetration test class according to this
Push away.
Although the present invention describes specific case study on implementation, the scope of the present invention is not limited to above-mentioned concrete reality
Example is applied, without departing from the case in the spirit of the invention, the various modifications to the present invention, variations and alternatives each fall within the guarantor of the present invention
Shield scope.
Claims (9)
1. a kind of non-weaving cloth natural antibacterial deodorization finishing agent, by weight percentage, its formula is as follows：
Polyoxyethylene sorbitan tristearate 5%-20%；
Ester based quaternary ammonium salt 1%-10%；
Natural antibacterial composition 5-20%；
Balance of deionized water；
The natural antibacterial composition is counted by weight, and its component and its deal are as follows：Shitosan 2-8 part；Aloe 10-15
Part；Chitin 3-8 part；Catechin 5-10 part；Tea polyphenols 10-40 part；Oleum Camelliae 5-25 part；Tea saponin 0.1-2 part；Semen Vitis viniferae is carried
Take thing 5-15 part；Citric acid 5-25 part；Amino-acid chelate 5-25 part；Amino acid derivativges 0-8 part；Emulsifying agent 1-8 part.
2. a kind of non-weaving cloth according to claim 1 natural antibacterial deodorization finishing agent, it is characterised in that：Also include to gather
Glycol glycerin ether, its component and formula are as follows：
Polyethylene glycol glycerol ether 5%-9%；
Polyoxyethylene sorbitan tristearate 8%-15%；
Ester based quaternary ammonium salt 5%-8%；
Natural antibacterial composition 10-16%；
Balance of deionized water.
3. a kind of non-weaving cloth according to claim 1 natural antibacterial deodorization finishing agent, it is characterised in that：The arrangement
Agent also includes fragrant slow release body, and fragrant slow release body is the aromatic micro-capsule in cladding core-shell structure, comprising capsule-core, cyst wall, its group
Divide and formula is as follows：
Polyethylene glycol glycerol ether 5%-9%；
Polyoxyethylene sorbitan tristearate 8%-15%；
Ester based quaternary ammonium salt 5%-8%；
Natural antibacterial composition 10-16%；
Fragrant slow release body 3%-8%；
Balance of deionized water.
4. a kind of non-weaving cloth according to claim 1 natural antibacterial deodorization finishing agent, it is characterised in that：The ester group
Quaternary ammonium salt is Petiolus Trachycarpi cationoid ester based quaternary ammonium salt, stearic acid diethanol diester quaternary ammonium, double ethyl stearte Ji Qiangyijijia
Base sulfate methyl ammonium, stearic acid triethanolamine ester quaternary, 2,3- dihydroxypropyl dibasic acid esters ammonium halide, double hydroxyethyl fatty acids
One or more in ester dimethy lammonium chloride.
5. a kind of non-weaving cloth according to claim 1 natural antibacterial deodorization finishing agent, it is characterised in that：The emulsifying
Agent is dodecylbenzene sodium sulfonate, fatty acid mono glycidol, glycerol monolaurate, methyl glycol fatty acid ester, polyoxyethylene mountain
One or more in pears sugar alcohol acid anhydride fatty acid ester, Span-80, sodium stearate.
6. a kind of non-weaving cloth according to claim 1 natural antibacterial deodorization finishing agent, it is characterised in that：The amino
Sour chelate is zinc and amino-acids chelate, including one kind in zinc glycinate, threonine zinc, zinc lysine and zinc methionine or several
Kind.
7. a kind of non-weaving cloth according to claim 1 natural antibacterial deodorization finishing agent, it is characterised in that：The amino
Acid derivative is amino-acid ester, and the amino-acid ester includes Lysine Lauryl Ester, L-Glutamic Acid cellulose esters, aspartic acid fiber
One or more in plain ester.
8. a kind of non-weaving cloth according to claim 3 natural antibacterial deodorization finishing agent, it is characterised in that：The fragrance
The odor type of sustained release includes hay-scented type, rose scent, Forest Bath odor type, jasmine fragrance, lavender flavor type, fruit flavouring, Fructus Citri Limoniae
Odor type and osmanthus flower fragrant.
9. a kind of non-weaving cloth as claimed in claim 1 preparation method of natural antibacterial deodorization finishing agent, walks including following
Suddenly：
1）The preparation of natural antibacterial deodorant compositions：First citric acid is dissolved in deionized water and stirs acquisition solution A；Again by youngster
Theine, tea polyphenols, Semen Vitis viniferae extract are dissolved in solution A respectively and are mixing uniformly to form solution B；Solution B is heated to 50-
After 60 DEG C, add in emulsifying agent in solution B and stir, be subsequently adding tea saponin, shitosan, the aloe of part, carapace
Element, Oleum Camelliae, amino-acid chelate, amino acid derivativges are simultaneously uniformly mixed；Finally it is dried using spray dryer,
Size-reduced grinding forms natural antibacterial deodorant compositions powder；
2）Deionized water is heated to 40-60 DEG C, be subsequently adding polyoxyethylene sorbitan tristearate, ester based quaternary ammonium salt,
Polyethylene glycol glycerol ether, is uniformly mixed, and forms solution C；
3）Under conditions of stirring, toward step（Two）Solution C in add natural antibacterial composition, fragrant slow release body, continue to stir
Mix so that bactericidal composition, the dissolving of fragrant slow release body or mix homogeneously, form solution D；
4）Solution D is cooled to room temperature, discharging, prepared natural antibacterial deodorization finishing agent.
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| CN109675427A (en) * | 2017-10-18 | 2019-04-26 | 广州康滤净化科技有限公司 | Air purifying composition and its preparation method and application |
| CN111954733A (en) * | 2018-03-19 | 2020-11-17 | 生活保卫股份公司 | Organic antibacterial textile |
| CN110409174A (en) * | 2019-08-07 | 2019-11-05 | 苏州经贸职业技术学院 | A kind of phenols environmental protection finishing agent and preparation method thereof |
| CN112391834A (en) * | 2020-09-28 | 2021-02-23 | 广州立白企业集团有限公司 | Composition for removing bacteria, removing peculiar smell and keeping fragrance for long time and preparation method thereof |
| CN112391834B (en) * | 2020-09-28 | 2022-11-01 | 广州立白企业集团有限公司 | Composition for removing bacteria, removing peculiar smell and keeping fragrance for long time and preparation method thereof |
| CN114712548A (en) * | 2021-01-06 | 2022-07-08 | 浙江卫星石化股份有限公司 | Preparation method of antibacterial fragrance slow-release type deodorizing super absorbent resin |
| CN114354593A (en) * | 2022-01-07 | 2022-04-15 | 西南石油大学 | Composite test paper for detecting hydrogen sulfide gas leakage |
| CN114481596A (en) * | 2022-01-07 | 2022-05-13 | 嵊州凯丽制衣有限公司 | Leisure clothing fabric and preparation process thereof |
| CN114571804A (en) * | 2022-02-18 | 2022-06-03 | 绍兴舒涛针纺有限公司 | Novel fabric and preparation process thereof |
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