CN106435433A - Thermal barrier coating spraying method applied to empennage - Google Patents

Thermal barrier coating spraying method applied to empennage Download PDF

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Publication number
CN106435433A
CN106435433A CN201610859312.7A CN201610859312A CN106435433A CN 106435433 A CN106435433 A CN 106435433A CN 201610859312 A CN201610859312 A CN 201610859312A CN 106435433 A CN106435433 A CN 106435433A
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CN
China
Prior art keywords
spraying
empennage
spray
coating
nicr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610859312.7A
Other languages
Chinese (zh)
Inventor
李龙飞
霍文娟
刘巍浩
张忠亮
薛新勇
孙丙辰
石世发
周伟强
董平
杨东星
许国娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jinxi Industries Group Co Ltd
Original Assignee
Jinxi Industries Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinxi Industries Group Co Ltd filed Critical Jinxi Industries Group Co Ltd
Priority to CN201610859312.7A priority Critical patent/CN106435433A/en
Publication of CN106435433A publication Critical patent/CN106435433A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention relates to a thermal barrier coating spraying method applied to an empennage and belongs to the field of thermal spraying. The spraying method provided by the invention comprises the following steps: firstly, performing abrasive blasting treatment on a spraying region of the overall empennage, wherein the requirement that the roughness Ra of the spraying region is larger than or equal to 8.0 microns should be satisfied; subsequently spraying a NiCr bottom layer and a ZrO2 face layer, wherein the spraying sequence of each of the bottom layer and the face layer is wind receiving surface to top edge to front surface to rear surface. By adopting the spraying method provided by the invention, the uniformity and compactness of the microcosmic structure of an empennage coating are greatly improved, so the adhesive force between the coating and the empennage is remarkably increased, and the effective coating formed after spraying is as large as 0.9 mm in thickness, so the problem of ablation of the empennage during a flying process is effectively solved, and especially the quality of the coating on the wind receiving surface can satisfy the flying requirements of the present stage.

Description

A kind of thermal barrier coating spraying method for empennage
Technical field
The present invention relates to a kind of thermal barrier coating spraying method for empennage, belongs to field of thermal spray.
Background technology
Empennage is one of vitals of rocket projectile, the flight stability of principal security rocket projectile.When rocket projectile flight speed When degree exceedes certain Mach number, during flight, pneumatic heating phenomena is more serious, can reduce the holding of intensity, rigidity and empennage of material Loading capability, increases deformation.With the increase of rocket projectile range, the resistance to pneumatic heating efficiency of empennage is required to improve, particularly right In the rocket projectile that the flight time is longer, lasting Aerodynamic Heating can bring serious ablation phenomen with pneumatic washing away, and make empennage in the past Edge separately begins to melt, and causes aerofoil to destroy, affects control of the empennage to the flight stability of rocket projectile.Solve empennage ablation existing As adopting the method for spraying thermal barrier coating in stabilizing surfaces, and the key of thermal barrier coating effect is to see spraying thermal boundary painting on empennage The effective thickness of layer.The thickness of spraying thermal barrier coating is too low, and resistance to ablation effect is limited, but the thickness of coating is too high can affect coating With the adhesive force of fin, may result in before thermal barrier coating do not play resistance to ablation effect completely, just lower and fin is washed away pneumatic Sur-face peeling.With NiCr bottom conventional at present, ZrO2As a example by the thermal barrier coating of surface layer, using conventional spray paint technique on empennage Sprayed, the effective thickness of thermal barrier coating is less than 0.4mm.How the effective of spraying thermal barrier coating is improved on empennage Thickness, is the technological difficulties for restricting rocket projectile long-distance flight stability.
Content of the invention
The invention aims to improving the effective thickness for spraying thermal barrier coating on empennage, and provide a kind of for empennage Thermal barrier coating spraying method.
The purpose of the present invention is achieved through the following technical solutions:
A kind of thermal barrier coating spraying method for empennage of the present invention, comprises the following steps that:
1) surface preparation
Blasting treatment is carried out to the spraying area of whole empennage, it is desirable to spraying area roughness Ra >=8.0 μm;
2) NiCr bottom is sprayed
Spraying order according to spraying windward side → top rib → front → reverse side successively completes to spray NiCr bottom to whole empennage Layer, wherein, windward side is with top rib spraying direction using spraying in the width direction, and the spraying direction of front and reverse side is along windward side The direction of angle;Each spray parameters are:Spraying current 500-550A, spray voltage 55-60V, spray distance 110-130mm, spray Tu Ya road amount is 1 with spraying " hot spot " diameter ratio:3~1:5, powder sending quantity is that 40-50g/min, coating thickness is less than 0.3mm;
3) ZrO is sprayed2Surface layer
Using with spraying NiCr bottom identical spraying order, spraying direction, spray ZrO on NiCr bottom2Surface layer, respectively Spray parameters are:Spraying current 600-650A, spray voltage 65-70V, spray distance 100-120mm, spraying pressure road amount and spraying " hot spot " diameter ratio about 1:7~1:9, powder sending quantity 30-40g/min, coating thickness is less than 0.6mm.
Beneficial effect:
Using the spraying method of the present invention, the uniformity of empennage coating microstructure, compactness are greatly improved, And then so that the adhesive force between coating and empennage is significantly improved, the effective coating after spraying is effectively solved up to 0.9mm The coating quality of problem, particularly windward side of empennage ablation in flight course of having determined disclosure satisfy that flight at this stage will Ask.
Description of the drawings
Fig. 1 needs the schematic diagram of spray-coating surface for empennage;
Fig. 2 is windward side, the schematic diagram in top rib spraying direction;
In figure, 1- front, 2- windward side, 3- pushes up rib, 4- reverse side.
Specific embodiment
With reference to the accompanying drawings and examples present disclosure is further described:
Embodiment
As shown in figure 1, using the spraying method of the present invention, certain rocket projectile empennage is sprayed, specifically
Step is as follows:
1) surface preparation
Blasting treatment is carried out to the spraying area of whole empennage, it is desirable to spraying area roughness Ra >=8.0 μm.
2) NiCr bottom is sprayed
Spraying order for first spray windward side → top rib → front → reverse side, windward side with top rib spraying direction using along Width is sprayed, as illustrated, direction of the spraying direction of front and reverse side along windward side angle.Each spray parameters are: Spraying current 500A, spray voltage 55-60V, spray distance 110-120mm, spraying pressure road amount with spraying " hot spot " diameter ratio is 1:4, powder sending quantity 42-45g/min, coating thickness is 0.3mm.
3) ZrO is sprayed2Surface layer
ZrO2The spraying order of surface layer, spraying direction are consistent with NiCr bottom powder, regulation spray parameters, spraying current 600A, Spray voltage 65-70V, spray distance 100-110mm, spraying pressure road amount is 1 with spraying " hot spot " diameter ratio:8, powder sending quantity 32- 35g/min, sprays ZrO2Thickness 0.6mm.
The coating integral thickness is up to 0.9mm, and coating resistance to elevated temperatures and flushing resistance meet pneumatic in flight course The hot and pneumatic requirement that washes away.

Claims (1)

1. a kind of thermal barrier coating spraying method for empennage, is characterized in that:Comprise the following steps that:
1) surface preparation
Blasting treatment is carried out to the spraying area of whole empennage, it is desirable to spraying area roughness Ra >=8.0 μm;
2) NiCr bottom is sprayed
Spraying order according to spraying windward side → top rib → front → reverse side successively completes to spray NiCr bottom to whole empennage;Respectively Spray parameters are:Spraying current 500-550A, spray voltage 55-60V, spray distance 110-130mm, spraying pressure road amount and spraying " hot spot " diameter ratio is 1:3~1:5, powder sending quantity is 40-50g/min;
3) ZrO is sprayed2Surface layer
Using with the spraying of spraying NiCr bottom identical sequentially, ZrO is sprayed on NiCr bottom2Surface layer, each spray parameters are:Spray Apply electric current 600-650A, spray voltage 65-70V, spray distance 100-120mm, spraying pressure road amount and spraying " hot spot " diameter ratio About 1:7~1:9, powder sending quantity 30-40g/min.
CN201610859312.7A 2016-09-28 2016-09-28 Thermal barrier coating spraying method applied to empennage Pending CN106435433A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610859312.7A CN106435433A (en) 2016-09-28 2016-09-28 Thermal barrier coating spraying method applied to empennage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610859312.7A CN106435433A (en) 2016-09-28 2016-09-28 Thermal barrier coating spraying method applied to empennage

Publications (1)

Publication Number Publication Date
CN106435433A true CN106435433A (en) 2017-02-22

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610859312.7A Pending CN106435433A (en) 2016-09-28 2016-09-28 Thermal barrier coating spraying method applied to empennage

Country Status (1)

Country Link
CN (1) CN106435433A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108950457A (en) * 2018-06-11 2018-12-07 中国航发哈尔滨东安发动机有限公司 A kind of impeller chimney class part heat spraying method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102094164A (en) * 2009-12-15 2011-06-15 沈阳天贺新材料开发有限公司 Nanometer zirconium oxide thermal barrier coating and preparation method thereof
CN103026003A (en) * 2010-08-05 2013-04-03 西门子公司 Turbine airfoil and method for thermal barrier coating
JP2013163480A (en) * 2012-02-13 2013-08-22 Mitsubishi Heavy Ind Ltd Anti-icing device and aircraft main wing
CN104897009A (en) * 2015-05-04 2015-09-09 晋西工业集团有限责任公司 Ablation-resisting interlayer compound structure tail wing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102094164A (en) * 2009-12-15 2011-06-15 沈阳天贺新材料开发有限公司 Nanometer zirconium oxide thermal barrier coating and preparation method thereof
CN103026003A (en) * 2010-08-05 2013-04-03 西门子公司 Turbine airfoil and method for thermal barrier coating
JP2013163480A (en) * 2012-02-13 2013-08-22 Mitsubishi Heavy Ind Ltd Anti-icing device and aircraft main wing
CN104897009A (en) * 2015-05-04 2015-09-09 晋西工业集团有限责任公司 Ablation-resisting interlayer compound structure tail wing

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
田永生等: ""ZrO2热障涂层研究进展"", 《中国机械工程》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108950457A (en) * 2018-06-11 2018-12-07 中国航发哈尔滨东安发动机有限公司 A kind of impeller chimney class part heat spraying method

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Application publication date: 20170222