CN106433938B - A kind of environmental-friendly high-performance enginer cylinder body grinding fluid - Google Patents

A kind of environmental-friendly high-performance enginer cylinder body grinding fluid Download PDF

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Publication number
CN106433938B
CN106433938B CN201610842111.6A CN201610842111A CN106433938B CN 106433938 B CN106433938 B CN 106433938B CN 201610842111 A CN201610842111 A CN 201610842111A CN 106433938 B CN106433938 B CN 106433938B
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environmental
cylinder body
grinding fluid
friendly high
body grinding
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CN106433938A (en
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敖小平
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Guangdong Hengchang Technology Lubricant Co Ltd
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Dongguan Yinxing Technology Development Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C10M2209/1045—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C10M2209/1055—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C10M2209/1075—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106 used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/108—Phenothiazine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/72—Extended drain
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention relates to a kind of environmental-friendly high-performance enginer cylinder body grinding fluids, its component and mass percentage are as follows: block polyether 20~35%, organic three acid of 6~carbon of carbon 12: 1~5%, nonionic surfactant: 1~10%, compounding antirust agent: 1~3%, cation quaternary ammonium salt precipitating depressant prescription: 1~5%, stabilizer: 1~3% water: surplus.This grinding fluid has excellent anti-rust and lubrication, and settling property outstanding is able to maintain consumer product easy cleaning.Working solution is as clear as crystal for a long time, does not generate peculiar smell, protects the health of employee；Long service life reduces the cost for changing liquid.

Description

A kind of environmental-friendly high-performance enginer cylinder body grinding fluid
Technical field
The invention belongs to lubricating oil fields, are related to grinding fluid, especially a kind of environmental-friendly high-performance enginer cylinder body top gem of a girdle-pendant Grinding fluid.
Background technique
Due to needing certain roughness (can neither be excessively coarse, and cannot mistake between engine cylinder body cylinder holes and piston ring It is excessively smooth then without oil film presence in smooth), so, engine inner wall needs very strict mechanical processing technique ----the top gem of a girdle-pendant Mill.
Using this special processing process of honing, oilstone, the cleaning that the abrasive materials such as diamond generate grinding is grinding fluid one A important requirement.In high precision, the technique of high surface roughness requirements has extraordinary requirement to this product lubricity.
Tradition uses the processing method of the pure oil such as kerosene, during honing, due to the continuous crust deformation of metal, to produce Raw a large amount of heat, for temperature up to 110 DEG C, the temperature of partial points may be up to 270 DEG C, as the processing oil of the low viscosity of kerosene class, Flash-point is often only greater than 60 DEG C, can there is great security risk in process；There are environmental odors with products such as kerosene Greatly, at high cost, the disadvantages of workpiece bad cleaning, since the thermal coefficient of the products such as kerosene only has the 20-25% of aqueous machining fluid, Heat is not easy timely to export, and high temperature is easy the problems such as keeping converted products surface dimmed, and suface processing quality is caused to decline.
The processing method of the pure oil such as traditional kerosene, the clast generated during honing is not easily settled, if bringing into again To processing district, it will cause secondary abrasion, influence machining accuracy, need filter plant to handle in the processing of the products such as kerosene, compared to use Aqueous machining fluid needs more coolant liquids, bigger memory space, it is meant that needs the honing device of bigger scale.
Summary of the invention
It is a kind of with excellent anti-rust and lubrication it is an object of the invention to provide in place of overcome the deficiencies in the prior art, Settling property outstanding, easy cleaning, environmental-friendly high-performance enginer cylinder body grinding fluid.
The technical proposal for solving the technical problem of the invention is:
A kind of environmental-friendly high-performance enginer cylinder body grinding fluid, component and mass percentage are as follows:
Block polyether 20~35%,
Organic three acid of 6~carbon of carbon 12: 1~5%,
Nonionic surfactant: 1~10%,
Compounding antirust agent: 1~3%,
Cation quaternary ammonium salt precipitating depressant prescription: 1~5%,
Stabilizer: 1~3%
Water: surplus.
Moreover, the block polyether is the mixture of EO-PO-EO and PO-EO-PO.
Moreover, the EO-PO-EO is RPE 1720.
Moreover, the PO-EO-PO is L61.
Moreover, organic three acid of the 6~carbon of carbon 12 is L190plus.
Moreover, the nonionic surfactant is N, N '-dialkyl group-N, N ' glucosulfone malonamide.
Moreover, the compounding antirust agent is sour using thiadiazoles as Material synthesis substitution thiadiazoles, then by substitution thiadiazoles The thiadiazole type antirust agent that acylation reaction synthesizes occurs with diethanol amine for acid.
Moreover, the cation quaternary ammonium salt precipitating depressant prescription is to use epoxychloropropane for bridging agent, oleic acid, divinyl three Amine is respectively hydrophobic and a kind of imidazolinyl quaternary structure of hydrophilic radical synthesis.
Moreover, the stabilizer is to be closed using 4,4 '-two (1,1,3,3- tetramethyl-butyl)-diphenylamines and reaction of Salmon-Saxl At 3,7- bis- (1,1,3,3- tetramethyl-butyl)-phenthazine.
The advantages and positive effects of the present invention are:
1, this grinding fluid has excellent anti-rust and lubrication, and settling property outstanding is able to maintain consumer product easy cleaning.Work It is as clear as crystal for a long time to make liquid, does not generate peculiar smell, protects the health of employee；Long service life reduces the cost for changing liquid.
2, this grinding fluid can be watered, and ratio is 1:20-25 times, be greatly improved thermal coefficient, and hidden without safety Suffer from, reduces cost.
3, the clear color of the long-term water of this grinding fluid, can be convenient for observation processing cylinder body, and settleability is good, to improve cylinder surface matter Amount.
4, this grinding fluid is in hone processing course, the clast that can effectively generate during surface cleaning, guarantee board with Product surface cleaning is not in that cylinder body cylinder holes inner wall generates a large amount of attachment greasy dirt phenomenons without is sticked.
5, this grinding fluid has antimicrobial properties strong, is not likely to produce peculiar smell and goes bad, long service life.This product is free of first Aldehyde, the harmful substances such as nitrite, protection staff health.
Specific embodiment
Below by specific embodiment, the invention will be further described, and it is not limit that following embodiment, which is descriptive, Qualitatively, this does not limit the scope of protection of the present invention.
Embodiment 1
Embodiment 2
Embodiment 3
Embodiment 4
This product appearance is yellow transparent liquid, faint odor, specific gravity 0.985.
High/low temperature storage stability: (- 25 DEG C/55 DEG C, 3 hours) stabilizations.
5% dilution:
Corrosion test: 45# steel pendant rust prevention test (failure) is more than or equal to 200 hours, iron filings rust prevention test, level-one.Boat Empty aluminium, electrolytic aluminium, standard aluminum are level-one.Rust-preventing characteristic (55 DEG C of cast iron) monolithic > 48H, lamination > 24H.
Processing stability experiment: defoaming is qualified.Graining, the equal < 0.1ml of condensate oil.
PH value is 8.5.
Case column, in certain processing factory's service condition: using the kerosene of low viscosity to process before client, due to break flour settleability Difference needs two Honing process, first rough honing, then microhoning, and the oil product of microhoning is monthly one to change, and in process, has on fire Phenomenon.After product of the invention, two Honing process techniques are not necessarily to, the replacement cycle is 1 year, greatly reduces dosage, saves About production cost.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art For, under the premise of not departing from inventive concept, various modifications and improvements can be made, these belong to protection of the invention Range.

Claims (6)

1. a kind of environmental-friendly high-performance enginer cylinder body grinding fluid, component and mass percentage are as follows:
Block polyether 20~35%,
Organic three acid of 6~carbon of carbon 12: 1~5%,
Nonionic surfactant: 1~10%,
Compounding antirust agent: 1~3%,
Cation quaternary ammonium salt precipitating depressant prescription: 1~5%,
Stabilizer: 1~3%
Water: surplus；
The compounding antirust agent is sour using thiadiazoles as Material synthesis substitution thiadiazoles, then by substitution thiadiazoles acid and diethanol The thiadiazole type antirust agent of acylation reaction synthesis occurs for amine；
The cation quaternary ammonium salt precipitating depressant prescription is to use epoxychloropropane for bridging agent, and oleic acid, diethylenetriamine are respectively A kind of imidazolinyl quaternary structure of hydrophobic and hydrophilic radical synthesis；
The stabilizer is the 3,7- bis- synthesized using 4,4 '-two (1,1,3,3- tetramethyl-butyl)-diphenylamines and reaction of Salmon-Saxl (1,1,3,3- tetramethyl-butyl)-phenthazine.
2. environmental-friendly high-performance enginer cylinder body grinding fluid according to claim 1, it is characterised in that: the block Polyethers is the mixture of EO-PO-EO and PO-EO-PO.
3. environmental-friendly high-performance enginer cylinder body grinding fluid according to claim 2, it is characterised in that: the EO- PO-EO is RPE1720.
4. environmental-friendly high-performance enginer cylinder body grinding fluid according to claim 2, it is characterised in that: the PO- EO-PO is L61.
5. environmental-friendly high-performance enginer cylinder body grinding fluid according to claim 1, it is characterised in that: the carbon 6 Organic three acid of~carbon 12 is L190plus.
6. environmental-friendly high-performance enginer cylinder body grinding fluid according to claim 1, it is characterised in that: it is described it is non-from Sub- surfactant is N, N '-dialkyl group-N, N ' glucosulfone malonamide.
CN201610842111.6A 2016-09-22 2016-09-22 A kind of environmental-friendly high-performance enginer cylinder body grinding fluid Active CN106433938B (en)

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CN109135705A (en) * 2018-09-05 2019-01-04 石家庄长宏能源科技有限公司 A kind of pressure reducing and injection increasing agent used for flooding well and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1123962A1 (en) * 2000-02-08 2001-08-16 Mobil Oil Francaise Neat cutting oil composition
CN102703194A (en) * 2012-05-28 2012-10-03 上海福岛化工科技发展有限公司 Aluminum-magnesium alloy cutting fluid
CN104046500A (en) * 2014-06-29 2014-09-17 青岛极致节能环保有限公司 Special cutting fluid for aluminum alloys
CN104911015A (en) * 2015-06-30 2015-09-16 陕西航宇化工有限公司 Honing solution and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1123962A1 (en) * 2000-02-08 2001-08-16 Mobil Oil Francaise Neat cutting oil composition
CN102703194A (en) * 2012-05-28 2012-10-03 上海福岛化工科技发展有限公司 Aluminum-magnesium alloy cutting fluid
CN104046500A (en) * 2014-06-29 2014-09-17 青岛极致节能环保有限公司 Special cutting fluid for aluminum alloys
CN104911015A (en) * 2015-06-30 2015-09-16 陕西航宇化工有限公司 Honing solution and preparation method thereof

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Address after: 516700 floor 1, plant 3, Anxing smart Park, Xinhe Industrial Zone, Hekou Town, Luhe County, Shanwei City, Guangdong Province

Patentee after: Guangdong Hengchang technology Lubricant Co., Ltd

Address before: 523662, Guangzhou City, Guangdong province Dongguan Qingxi Town Rome Natural Lake Village

Patentee before: Dongguan City Yinxing Technology Development Co., Ltd.