CN106433091A - Bulletproof stab-proof composite material for composite stab-proof anti-explosion blanket - Google Patents
Bulletproof stab-proof composite material for composite stab-proof anti-explosion blanket Download PDFInfo
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- CN106433091A CN106433091A CN201610798978.6A CN201610798978A CN106433091A CN 106433091 A CN106433091 A CN 106433091A CN 201610798978 A CN201610798978 A CN 201610798978A CN 106433091 A CN106433091 A CN 106433091A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/02—Layer formed of wires, e.g. mesh
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/06—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/02—Layered products comprising a layer of natural or synthetic rubber with fibres or particles being present as additives in the layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H1/00—Personal protection gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2571/00—Protective equipment
- B32B2571/02—Protective equipment defensive, e.g. armour plates, anti-ballistic clothing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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Abstract
The invention discloses a bulletproof stab-proof composite material for a composite stab-proof anti-explosion blanket. The bulletproof stab-proof composite material is prepared from, by weight, 10-30 parts of polyurethane rubber, 5-10 parts of polyacrylonitrile-based carbon fibers, 5-15 parts of glass fibers, 2-5 parts of reinforcing materials, 1-3 parts of zinc oxide, 0.3-0.6 part of salicylic acid, 0.8-2.2 part of a fire retardant, 0.008-0.015 part of copper, 0.006-0.01 part of manganese, 0.01-0.05 part of chrome, 0.03-0.09 part of iron and 0.8-1.2 parts of aluminum. The bulletproof stab-proof composite material for the composite stab-proof anti-explosion blanket has the good water resistance, wear resistance and high temperature resistance, the strength and the hardness are good, the quality is good, and the weight is light; the bulletproof stab-proof composite material is used for manufacturing the composite stab-proof anti-explosion blanket, and the stab-proof anti-explosion effect is good. The invention also provides a preparing method for the bulletproof stab-proof composite material for the composite stab-proof anti-explosion blanket, the raw materials are simple and easy to obtain, production and operating are easy, pollution is avoided in the production process, the cost is low, and the bulletproof stab-proof composite material is worthy of popularization.
Description
Technical field
The present invention relates to technical field of composite materials, more particularly, to a kind of bulletproof anti-puncturing for composite anti-stabbing explosion-proof blanket is again
Condensation material.
Background technology
With the development of social economy, the raising of people's security protection consciousness, security protection equipment Requirement is increasing, plus
The attack of terrorism in recent years happen occasionally with incident of violence, there is a growing awareness that inherently safe protection importance, country
Also increase the supporting dynamics to safety protection field, country also clearly indicates in the middle of " 12 " planning and public safety is led
Domain increases support dynamics, particularly exists《Fabrics for industrial use 12 are planned》In the 4th point give priority to field and should be particularly mentioned that out
Send out flexible puncture-proof Anti-cutting fabric, so the development of security protection material meets the direction of National Textile industry development, and flexible
Stab-resistant material is relatively difficult to solution as one in safety protection field and is the scientific research field that emphasis need to solve, presently relevant
Flexible puncture-proof product considerably less, actual production life in application also especially few, bulletproof anti-puncturing composite wood in the market
Expect how hard heaviness, the composite anti-stabbing explosion-proof blanket prepared carries difficulty, and relatively costly.Based on the problems referred to above, the present invention carries
Go out a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket.
Content of the invention
The invention aims to shortcoming present in solution prior art, and the one kind proposing is used for composite anti-stabbing and prevents
The bulletproof anti-puncturing composite of quick-fried blanket.
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket, including the raw material of following weight portion：Poly- amino
10～30 parts of formic acid esters rubber, 5～10 parts of polyacrylonitrile-based carbon fibre, 5～15 parts of glass fibre, 2～5 parts of reinforcing material, oxygen
Change 1～3 part of zinc, 0.3～0.6 part of salicylic acid, 0.8～2.2 part of fire retardant, 0.008～0.015 part of copper, manganese 0.006～0.01
Part, 0.01～0.05 part of chromium, 0.03～0.09 part of ferrum, 0.8～1.2 part of aluminum.
Preferably, described a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket, including following weight portion
Raw material：12～24 parts of polyurethane rubber, 6～8 parts of polyacrylonitrile-based carbon fibre, 6～12 parts of glass fibre, strengthening material
3～4 parts of material, 1.5～2.5 parts of zinc oxide, 0.4～0.5 part of salicylic acid, 1～2 part of fire retardant, 0.01～0.012 part of copper, manganese
0.007～0.009 part, 0.02～0.04 part of chromium, 0.04～0.06 part of ferrum, 0.9～1.1 part of aluminum.
Preferably, described a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket, including following weight portion
Raw material：20 parts of polyurethane rubber, 8 parts of polyacrylonitrile-based carbon fibre, 10 parts of glass fibre, 4 parts of reinforcing material, oxidation
2 parts of zinc, 0.5 part of salicylic acid, 1.6 parts of fire retardant, 0.012 part of copper, 0.008 part of manganese, 0.03 part of chromium, 0.05 part of ferrum, 1 part of aluminum.
Preferably, the weight of described polyurethane rubber, polyacrylonitrile-based carbon fibre, glass fibre is than for 2～3:
1:1～1.5.
Preferably, described glass fibre is high intensity S glass fibre.
Preferably, described reinforcing material is Fanglun l414 pulp.
Preferably, described fire retardant is the built agent of red phosphorus and aluminium hydroxide, and red phosphorus with the amount ratio of aluminium hydroxide is
1:0.3～0.8.
The invention allows for a kind of preparation method of the bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket, including
Following steps：
S1, the copper of described proportion, manganese, chromium, ferrum and aluminum are melted under 1550～1800 DEG C of high temperature, wait to be completely melt
Afterwards, keeping temperature is constant, high-speed stirred 20～30min, makes each metal mixed uniformly, forms alloy；
S2, by gained alloy in step S1 pressure be 0.4～0.6MPa, temperature be 800～1000 DEG C in the case of extrude,
It is cooled to 200～500 DEG C of insulations, repeats to roll with calender, until alloy material becomes thickness and is 0.1～1 μm, mesh number is
The Metal screen cloth of 300～800 mesh；
S3, the polyurethane rubber of described proportion, zinc oxide, salicylic acid are added in rubber vulcanizing tank, 120
Under～150 DEG C of high temperature, vulcanize 3～7h, the polyacrylonitrile-based carbon fibre of the insulation described proportion of addition, glass fibre, strengthening material
Material, fire retardant, high-speed stirred 30～50min, obtain blend glue stuff；
S4, the blend glue stuff of step S3 gained is extruded with the speed of 5～10kg/min, rolled in step S2 with calender
The Metal screen cloth two sides of middle gained, treats natural cooling, obtains final product the bulletproof anti-puncturing composite that thickness is 2～5mm.
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket proposed by the present invention, have good waterproof,
Wear-resisting, resistance to elevated temperatures, and intensity is high, hardness is high, quality is good, lightweight, is made explosion-proof interior with the good alloy material of ductility
Basic unit, is mixed and made into waterproof outer, high-abrasive material with the rubber of high intensity and fibrous material, and bulletproof anti-puncturing proposed by the present invention is multiple
Condensation material is used for manufacturing anti-stab explosion-proof blanket, and anti-stab explosion-proof effect is good, and light weight is easy to carry, the invention allows for a kind of use
In the preparation method of the bulletproof anti-puncturing composite of composite anti-stabbing explosion-proof blanket, make Metal screen cloth by after metal congruent melting, by rubber
It is mixed and made into outer layer sizing material with fibrous material, by calender, Metal screen cloth and outer layer sizing material roller-compaction are obtained final product, used former
Material is simple and easy to get, and production operation is simple, and production process is pollution-free, low cost, is worthy to be popularized.
Specific embodiment
With reference to specific embodiment, the present invention is explained further.
Embodiment one
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket proposed by the present invention, including following weight portion
Raw material：22 parts of polyurethane rubber, 8 parts of polyacrylonitrile-based carbon fibre, 10 parts of high intensity S glass fibre, Fanglun l414 slurry
3.5 parts of the dregs of rice, 1 part of zinc oxide, 0.4 part of salicylic acid, red phosphorus and 1.5 parts of aluminium hydroxide built agent, 0.012 part of copper, 0.008 part of manganese,
0.02 part of chromium, 0.06 part of ferrum, 1 part of aluminum.
Its preparation method, comprises the following steps：
S1, the copper of described proportion, manganese, chromium, ferrum and aluminum are melted under 1600 DEG C of high temperature, until completely melted, keep
Temperature-resistant, high-speed stirred 25min, make each metal mixed uniformly, form alloy；
S2, gained alloy in step S1 is 0.4MPa in pressure, temperature is extruded in the case of being 900 DEG C, is cooled to 300 DEG C
Insulation, repeats to roll with calender, until alloy material becomes thickness and is 0.4 μm, mesh number is the Metal screen cloth of 600 mesh；
S3, the polyurethane rubber of described proportion, zinc oxide, salicylic acid are added in rubber vulcanizing tank, 135
DEG C high temperature under, vulcanize 5h, insulation adds the polyacrylonitrile-based carbon fibre of described proportion, high intensity S glass fibre, Fanglun l414
Pulp and amount ratio are 1:0.5 red phosphorus and aluminium hydroxide built agent, high-speed stirred 40min, obtain blend glue stuff；
S4, the blend glue stuff of step S3 gained is extruded with the speed of 6kg/min, roll institute in step s 2 with calender
The Metal screen cloth two sides obtaining, treats natural cooling, obtains final product the bulletproof anti-puncturing composite that thickness is 4mm.
Embodiment two
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket proposed by the present invention, including following weight portion
Raw material：12 parts of polyurethane rubber, 5 parts of polyacrylonitrile-based carbon fibre, 7 parts of high intensity S glass fibre, Fanglun l414 pulp
4 parts, 2.5 parts of zinc oxide, 0.3 part of salicylic acid, red phosphorus and 2 parts of aluminium hydroxide built agent, 0.008 part of copper, 0.007 part of manganese, chromium
0.01 part, 0.09 part of ferrum, 0.8 part of aluminum.
Its preparation method, comprises the following steps：
S1, the copper of described proportion, manganese, chromium, ferrum and aluminum are melted under 1700 DEG C of high temperature, until completely melted, keep
Temperature-resistant, high-speed stirred 22min, make each metal mixed uniformly, form alloy；
S2, gained alloy in step S1 is 0.5MPa in pressure, temperature is extruded in the case of being 800 DEG C, is cooled to 200 DEG C
Insulation, repeats to roll with calender, until alloy material becomes thickness and is 1 μm, mesh number is the Metal screen cloth of 300 mesh；
S3, the polyurethane rubber of described proportion, zinc oxide, salicylic acid are added in rubber vulcanizing tank, 140
DEG C high temperature under, vulcanize 4h, insulation adds the polyacrylonitrile-based carbon fibre of described proportion, high intensity S glass fibre, Fanglun l414
Pulp and amount ratio are 1:0.8 red phosphorus and aluminium hydroxide built agent, high-speed stirred 35min, obtain blend glue stuff；
S4, the blend glue stuff of step S3 gained is extruded with the speed of 8kg/min, roll institute in step s 2 with calender
The Metal screen cloth two sides obtaining, treats natural cooling, obtains final product the bulletproof anti-puncturing composite that thickness is 4.5mm.
Embodiment three
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket proposed by the present invention, including following weight portion
Raw material：30 parts of polyurethane rubber, 10 parts of polyacrylonitrile-based carbon fibre, 15 parts of high intensity S glass fibre, Fanglun l414 slurry
2 parts of the dregs of rice, 3 parts of zinc oxide, 0.6 part of salicylic acid, red phosphorus and 0.8 part of aluminium hydroxide built agent, 0.01 part of copper, 0.01 part of manganese, chromium
0.05 part, 0.08 part of ferrum, 1.2 parts of aluminum.
Its preparation method, comprises the following steps：
S1, the copper of described proportion, manganese, chromium, ferrum and aluminum are melted under 1650 DEG C of high temperature, until completely melted, keep
Temperature-resistant, high-speed stirred 28min, make each metal mixed uniformly, form alloy；
S2, gained alloy in step S1 is 0.6MPa in pressure, temperature is extruded in the case of being 850 DEG C, is cooled to 400 DEG C
Insulation, repeats to roll with calender, until alloy material becomes thickness and is 0.8 μm, mesh number is the Metal screen cloth of 500 mesh；
S3, the polyurethane rubber of described proportion, zinc oxide, salicylic acid are added in rubber vulcanizing tank, 130
DEG C high temperature under, vulcanize 6h, insulation adds the polyacrylonitrile-based carbon fibre of described proportion, high intensity S glass fibre, Fanglun l414
Pulp and amount ratio are 1:0.3 red phosphorus and aluminium hydroxide built agent, high-speed stirred 50min, obtain blend glue stuff；
S4, the blend glue stuff of step S3 gained is extruded with the speed of 5kg/min, roll institute in step s 2 with calender
The Metal screen cloth two sides obtaining, treats natural cooling, obtains final product the bulletproof anti-puncturing composite that thickness is 3.5mm.
Example IV
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket proposed by the present invention, including following weight portion
Raw material：15 parts of polyurethane rubber, 6 parts of polyacrylonitrile-based carbon fibre, 9 parts of high intensity S glass fibre, Fanglun l414 pulp
3 parts, 1.5 parts of zinc oxide, 0.4 part of salicylic acid, red phosphorus and 1.8 parts of aluminium hydroxide built agent, 0.015 part of copper, 0.006 part of manganese, chromium
0.03 part, 0.04 part of ferrum, 0.9 part of aluminum.
Its preparation method, comprises the following steps：
S1, the copper of described proportion, manganese, chromium, ferrum and aluminum are melted under 1550 DEG C of high temperature, until completely melted, keep
Temperature-resistant, high-speed stirred 30min, make each metal mixed uniformly, form alloy；
S2, gained alloy in step S1 is 0.4MPa in pressure, temperature is extruded in the case of being 1000 DEG C, is cooled to 500
DEG C insulation, repeat to roll with calender, until alloy material become thickness be 0.2 μm, mesh number is the Metal screen cloth of 800 mesh；
S3, the polyurethane rubber of described proportion, zinc oxide, salicylic acid are added in rubber vulcanizing tank, 120
DEG C high temperature under, vulcanize 7h, insulation adds the polyacrylonitrile-based carbon fibre of described proportion, high intensity S glass fibre, Fanglun l414
Pulp and amount ratio are 1:0.6 red phosphorus and aluminium hydroxide built agent, high-speed stirred 45min, obtain blend glue stuff；
S4, the blend glue stuff of step S3 gained is extruded with the speed of 10kg/min, rolled in step s 2 with calender
The Metal screen cloth two sides of gained, treats natural cooling, obtains final product the bulletproof anti-puncturing composite that thickness is 2mm.
Embodiment five
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket proposed by the present invention, including following weight portion
Raw material：24 parts of polyurethane rubber, 9 parts of polyacrylonitrile-based carbon fibre, 9 parts of high intensity S glass fibre, Fanglun l414 pulp
5 parts, 2 parts of zinc oxide, 0.5 part of salicylic acid, red phosphorus and 2.2 parts of aluminium hydroxide built agent, 0.009 part of copper, 0.009 part of manganese, chromium
0.04 part, 0.05 part of ferrum, 1.1 parts of aluminum.
Its preparation method, comprises the following steps：
S1, the copper of described proportion, manganese, chromium, ferrum and aluminum are melted under 1800 DEG C of high temperature, until completely melted, keep
Temperature-resistant, high-speed stirred 20min, make each metal mixed uniformly, form alloy；
S2, gained alloy in step S1 is 0.6MPa in pressure, temperature is extruded in the case of being 950 DEG C, is cooled to 350 DEG C
Insulation, repeats to roll with calender, until alloy material becomes thickness and is 0.5 μm, mesh number is the Metal screen cloth of 400 mesh；
S3, the polyurethane rubber of described proportion, zinc oxide, salicylic acid are added in rubber vulcanizing tank, 150
DEG C high temperature under, vulcanize 3h, insulation adds the polyacrylonitrile-based carbon fibre of described proportion, high intensity S glass fibre, Fanglun l414
Pulp and amount ratio are 1:0.4 red phosphorus and aluminium hydroxide built agent, high-speed stirred 30min, obtain blend glue stuff；
S4, the blend glue stuff of step S3 gained is extruded with the speed of 9kg/min, roll institute in step s 2 with calender
The Metal screen cloth two sides obtaining, treats natural cooling, obtains final product the bulletproof anti-puncturing composite that thickness is 3mm.
The bulletproof anti-puncturing composite that will prepare in five groups of embodiments proposed by the present invention, using Brinell hardness test side
Method is tested to its hardness respectively, hardens steel ball in the case that outer power is 500N with a diameter of 3cm, Specimen table
Face, after stopping 10s, removes external force, measures the area of indentation immediately, draws following result：(impression is less, and hardness is bigger)
| Embodiment | One | Two | Three | Four | Five |
| The area of indentation | 1.95cm2 | 1.89cm2 | 2.14cm2 | 3.02cm2 | 2.48cm2 |
A kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket proposed by the present invention, have good waterproof,
Wear-resisting, resistance to elevated temperatures, and intensity is high, hardness is high, quality is good, lightweight, is made explosion-proof interior with the good alloy material of ductility
Basic unit, is mixed and made into waterproof outer, high-abrasive material with the rubber of high intensity and fibrous material, and bulletproof anti-puncturing proposed by the present invention is multiple
Condensation material is used for manufacturing anti-stab explosion-proof blanket, and anti-stab explosion-proof effect is good, and light weight is easy to carry, the invention allows for a kind of use
In the preparation method of the bulletproof anti-puncturing composite of composite anti-stabbing explosion-proof blanket, make Metal screen cloth by after metal congruent melting, by rubber
It is mixed and made into outer layer sizing material with fibrous material, by calender, Metal screen cloth and outer layer sizing material roller-compaction are obtained final product, used former
Material is simple and easy to get, and production operation is simple, and production process is pollution-free, low cost, is worthy to be popularized.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (8)
1. a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket is it is characterised in that include the former of following weight portion
Material：10～30 parts of polyurethane rubber, 5～10 parts of polyacrylonitrile-based carbon fibre, 5～15 parts of glass fibre, reinforcing material 2
～5 parts, 1～3 part of zinc oxide, 0.3～0.6 part of salicylic acid, 0.8～2.2 part of fire retardant, 0.008～0.015 part of copper, manganese 0.006
～0.01 part, 0.01～0.05 part of chromium, 0.03～0.09 part of ferrum, 0.8～1.2 part of aluminum.
2. a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket according to claim 1 it is characterised in that
Raw material including following weight portion：12～24 parts of polyurethane rubber, 6～8 parts of polyacrylonitrile-based carbon fibre, glass fibre
6～12 parts, 3～4 parts of reinforcing material, 1.5～2.5 parts of zinc oxide, 0.4～0.5 part of salicylic acid, 1～2 part of fire retardant, copper 0.01
～0.012 part, 0.007～0.009 part of manganese, 0.02～0.04 part of chromium, 0.04～0.06 part of ferrum, 0.9～1.1 part of aluminum.
3. a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket according to claim 1 it is characterised in that
Raw material including following weight portion：20 parts of polyurethane rubber, 8 parts of polyacrylonitrile-based carbon fibre, 10 parts of glass fibre, increasing
Strong 4 parts of material, 2 parts of zinc oxide, 0.5 part of salicylic acid, 1.6 parts of fire retardant, 0.012 part of copper, 0.008 part of manganese, 0.03 part of chromium, ferrum
0.05 part, 1 part of aluminum.
4. a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket according to claim 1 it is characterised in that
Described polyurethane rubber, polyacrylonitrile-based carbon fibre, the weight of glass fibre are than for 2～3:1:1～1.5.
5. a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket according to claim 1 it is characterised in that
Described glass fibre is high intensity S glass fibre.
6. a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket according to claim 1 it is characterised in that
Described reinforcing material is Fanglun l414 pulp.
7. a kind of bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket according to claim 1 it is characterised in that
Described fire retardant is the built agent of red phosphorus and aluminium hydroxide, and red phosphorus is 1 with the amount ratio of aluminium hydroxide:0.3～0.8.
8. a kind of preparation method of the bulletproof anti-puncturing composite for composite anti-stabbing explosion-proof blanket is it is characterised in that include following
Step：
S1, the copper of described proportion, manganese, chromium, ferrum and aluminum are melted under 1550～1800 DEG C of high temperature, until completely melted, protect
Hold temperature-resistant, high-speed stirred 20～30min, make each metal mixed uniformly, form alloy；
S2, by gained alloy in step S1 pressure be 0.4～0.6MPa, temperature be 800～1000 DEG C in the case of extrude, cooling
To 200～500 DEG C be incubated, repeat to roll with calender, until alloy material become thickness be 0.1～1 μm, mesh number be 300～
The Metal screen cloth of 800 mesh；
S3, the polyurethane rubber of described proportion, zinc oxide, salicylic acid are added in rubber vulcanizing tank, 120～
Under 150 DEG C of high temperature, vulcanize 3～7h, insulation add the polyacrylonitrile-based carbon fibre of described proportion, glass fibre, reinforcing material,
Fire retardant, high-speed stirred 30～50min, obtain blend glue stuff；
S4, the blend glue stuff of step S3 gained is extruded with the speed of 5～10kg/min, roll institute in step s 2 with calender
The Metal screen cloth two sides obtaining, treats natural cooling, obtains final product the bulletproof anti-puncturing composite that thickness is 2～5mm.
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| CN201610798978.6A CN106433091A (en) | 2016-08-31 | 2016-08-31 | Bulletproof stab-proof composite material for composite stab-proof anti-explosion blanket |
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| CN113278244A (en) * | 2021-06-22 | 2021-08-20 | 昆山恒光塑胶股份有限公司 | High-heat-resistance reinforced modified ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
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